ES2612312B1 - Tinta de naturaleza acuosa y procedimiento de utilización para la obtención de efectos ópticos metálicos sobre sustratos cerámicos - Google Patents

Tinta de naturaleza acuosa y procedimiento de utilización para la obtención de efectos ópticos metálicos sobre sustratos cerámicos Download PDF

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Publication number
ES2612312B1
ES2612312B1 ES201430597A ES201430597A ES2612312B1 ES 2612312 B1 ES2612312 B1 ES 2612312B1 ES 201430597 A ES201430597 A ES 201430597A ES 201430597 A ES201430597 A ES 201430597A ES 2612312 B1 ES2612312 B1 ES 2612312B1
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Prior art keywords
ink
inkjet
optical effects
ceramic substrates
ceramic
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Application number
ES201430597A
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English (en)
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ES2612312A1 (es
Inventor
Jorge GONZÁLEZ MORENO
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Coloronda SL
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Coloronda SL
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Publication date
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Priority to ES201430597A priority Critical patent/ES2612312B1/es
Priority to PCT/ES2015/070329 priority patent/WO2015162326A1/es
Priority to EP15783503.4A priority patent/EP3159382A4/en
Publication of ES2612312A1 publication Critical patent/ES2612312A1/es
Application granted granted Critical
Publication of ES2612312B1 publication Critical patent/ES2612312B1/es
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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/02Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23Oxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C04B41/5023Glass-ceramics
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/26Printing on other surfaces than ordinary paper
    • B41M1/34Printing on other surfaces than ordinary paper on glass or ceramic surfaces
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Composite Materials (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

Tinta de naturaleza acuosa y procedimiento de utilización para la obtención de efectos ópticos metálicos sobre sustratos cerámicos, dicha tinta presenta en su composición de una mezcla de componentes sólidos de naturaleza cristalina y/o vítrea, también denominados como multi-componentes, caracterizados por presentar un tamaño de partícula inferior a 5 {mi}m que confieren al sustrato cerámico de efectos metálicos, lustres, nácar y/o iridiscentes; agua como medio dispersante de dichos componentes sólidos; y una mezcla de aditivos capaces de proporcionar a las tintas de unas propiedades físicas y químicas adecuadas para asegurar la perfecta idoneidad de las suspensiones para facilitar su aplicación a través de los sistemas de impresión digital por chorro de tinta, también denominado inkjet.#Dicho procedimiento comprende la aplicación de dichas formulaciones sobre baldosas cerámicas mediante la técnica de decoración por chorro de tinta inkjet, y la cocción posterior de los sustratos así obtenidos mediante tratamientos térmicos de mono-cocción.

Description

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Tabla 1
Componente
Función (%) en peso
Agua
Medio dispersión 45
1,4-Butanodiol
Reductor velocidad evaporación 8
Polisiloxano modificado
Antiespumante/Humectante 0.4
Formaldehido
Conservante 0.01
Poliacrilato modificado
Dispersante/Desfloculante 7
Bentonita
Suspensionante/Reológico 0.09
Frita (CeO2, CaO)
Favorecer y potenciar cristalizaciones 35
Tungsteno metal (polvo)
Aporte de Tungsteno 4
Petalita
Aporte de Litio 0.5
Tras el filtrado de la tinta obtenida a 20 µm, se llevó a cabo su caracterización completa, 5 obteniéndose:
-Tamaño de partícula: <5 µm. -Densidad: 1.425 g/cm3 (a 25ºC). -Viscosidad: aproximadamente 50 mPa·s (a 25ºC y 15 s-1).
10 -Comportamiento reológico pseudoplástico. -Tensión superficial estática: 42 mN/m (a 25ºC).
Mediante la impresión por chorro de tinta (inkjet) se decoraron piezas de pavimento de gres de dimensiones 30x30 cm2. A continuación, se dejaron secar empleando una 15 P20143059estufa a 100ºC, para someterlas, posteriormente a un ciclo industrial de cocción de a 1120ºC.
Las superficies cerámicas obtenidas de esta forma presentaban un aspecto brillante con matices iridiscentes y nacarados.
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Claims (1)

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ES201430597A 2014-04-22 2014-04-22 Tinta de naturaleza acuosa y procedimiento de utilización para la obtención de efectos ópticos metálicos sobre sustratos cerámicos Active ES2612312B1 (es)

Priority Applications (3)

Application Number Priority Date Filing Date Title
ES201430597A ES2612312B1 (es) 2014-04-22 2014-04-22 Tinta de naturaleza acuosa y procedimiento de utilización para la obtención de efectos ópticos metálicos sobre sustratos cerámicos
PCT/ES2015/070329 WO2015162326A1 (es) 2014-04-22 2015-04-21 Tinta de naturaleza acuosa y procedimiento de utilización para la obtención de efectos ópticos metálicos sobre sustratos cerámicos
EP15783503.4A EP3159382A4 (en) 2014-04-22 2015-04-21 Aqueous ink and method for using same to obtain metallic optical effects on ceramic substrates

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201430597A ES2612312B1 (es) 2014-04-22 2014-04-22 Tinta de naturaleza acuosa y procedimiento de utilización para la obtención de efectos ópticos metálicos sobre sustratos cerámicos

Publications (2)

Publication Number Publication Date
ES2612312A1 ES2612312A1 (es) 2017-05-16
ES2612312B1 true ES2612312B1 (es) 2018-04-18

Family

ID=54331791

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201430597A Active ES2612312B1 (es) 2014-04-22 2014-04-22 Tinta de naturaleza acuosa y procedimiento de utilización para la obtención de efectos ópticos metálicos sobre sustratos cerámicos

Country Status (3)

Country Link
EP (1) EP3159382A4 (es)
ES (1) ES2612312B1 (es)
WO (1) WO2015162326A1 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112017005437A2 (pt) 2014-09-19 2017-12-12 Zschimmer & Schwarz Ceram S P A tinta cerâmica pra impressão por jato de tinta
CN108439948A (zh) * 2018-06-05 2018-08-24 唐林元 一种多孔陶瓷保温板的制备方法
CN109320086A (zh) * 2018-12-19 2019-02-12 湖南华联瓷业股份有限公司 一种高温结晶釉及其制备方法
CN112777934B (zh) * 2021-01-22 2022-08-02 佛山森蒂泰珂科技有限公司 一种适用于高压数字喷釉工艺的油水两性数码釉及其制备方法
IT202100005810A1 (it) * 2021-03-11 2022-09-11 Sicer S P A Preparato antibatterico e virucida per superfici amorfe o cristalline, composizione che lo contiene e relativo uso
CN113372136B (zh) * 2021-07-08 2023-02-28 广东博智林机器人有限公司 无机人造石板材及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9104171D0 (en) * 1991-02-27 1991-04-17 British Ceramic Res Ltd Improved ink
US5443628B1 (en) * 1994-08-08 1998-06-09 Videojet Systems Int High temperature jet printing ink
ITMI20072385A1 (it) * 2007-12-19 2009-06-20 Metco S R L Nuovi coloranti per stampa digitale su materiali ceramici, nuovo procedimento per la stampa digitale su materiali ceramici facente uso di detti coloranti e materiali ceramici ottenuti mediante detto nuovo procedimento di stampa
ES2382514B1 (es) * 2010-11-15 2013-05-07 Consejo Superior De Investigaciones Científicas (Csic) Esmalte cerámico hidrofóbico con brillo metálico y su procedimiento de obtención.
ES2386267B2 (es) * 2012-04-24 2013-02-11 Esmalglass, Sau Tinta esmalte digital

Also Published As

Publication number Publication date
EP3159382A4 (en) 2018-04-18
ES2612312A1 (es) 2017-05-16
WO2015162326A1 (es) 2015-10-29
EP3159382A1 (en) 2017-04-26

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