ES2578704B1 - Procedimiento para la reducción de dióxido de carbono a metano mediante catalizador activado por plasma DBD - Google Patents

Procedimiento para la reducción de dióxido de carbono a metano mediante catalizador activado por plasma DBD Download PDF

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Publication number
ES2578704B1
ES2578704B1 ES201530109A ES201530109A ES2578704B1 ES 2578704 B1 ES2578704 B1 ES 2578704B1 ES 201530109 A ES201530109 A ES 201530109A ES 201530109 A ES201530109 A ES 201530109A ES 2578704 B1 ES2578704 B1 ES 2578704B1
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Prior art keywords
methane
procedure
carbon dioxide
dbd plasma
catalyst
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Expired - Fee Related
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ES201530109A
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ES2578704A1 (es
Inventor
Teresa ANDREU ARBELLA
Juan Ramón Morante Lleonart
Jacques Amouroux
Simeon Cavadias
Magdalena NIZIO
Stéphanie OGNIER
Carlos Manuel FARIA DE BARROS HENRIQUES
José Manuel Felix MADEIRA LOPES
Inès Sofia BISCAYA SEMEDO PEREIRA DA GRAÇA
Maria Filipa Gomes Ribeiro
María Del Carmen BACARIZA REY
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Fundacio Institut de Recerca en Energia de Catalunya
Original Assignee
Instituto Superior Tecnico-Universidade De Lisboa
Universitat Autonoma de Barcelona UAB
Universitat de Barcelona UB
Fundacio Institut de Recerca en Energia de Catalunya
Universite Pierre et Marie Curie Paris 6
Inst Superior Tecnico-Universidade De Lisboa
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Application filed by Instituto Superior Tecnico-Universidade De Lisboa, Universitat Autonoma de Barcelona UAB, Universitat de Barcelona UB, Fundacio Institut de Recerca en Energia de Catalunya, Universite Pierre et Marie Curie Paris 6, Inst Superior Tecnico-Universidade De Lisboa filed Critical Instituto Superior Tecnico-Universidade De Lisboa
Priority to ES201530109A priority Critical patent/ES2578704B1/es
Priority to EP15202925.2A priority patent/EP3050865B1/en
Publication of ES2578704A1 publication Critical patent/ES2578704A1/es
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    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00—Generating plasma; Handling plasma
    • H05H1/24—Generating plasma
    • H05H1/2406—Generating plasma using dielectric barrier discharges, i.e. with a dielectric interposed between the electrodes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/349—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of flames, plasmas or lasers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00—Aliphatic saturated hydrocarbons
    • C07C9/02—Aliphatic saturated hydrocarbons with one to four carbon atoms
    • C07C9/04—Methane
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08—Production of synthetic natural gas
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00—Generating plasma; Handling plasma
    • H05H1/24—Generating plasma
    • H05H1/2406—Generating plasma using dielectric barrier discharges, i.e. with a dielectric interposed between the electrodes
    • H05H1/2443—Generating plasma using dielectric barrier discharges, i.e. with a dielectric interposed between the electrodes the plasma fluid flowing through a dielectric tube
    • H05H1/245—Generating plasma using dielectric barrier discharges, i.e. with a dielectric interposed between the electrodes the plasma fluid flowing through a dielectric tube the plasma being activated using internal electrodes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • C07C2529/072—Iron group metals or copper
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H2245/00—Applications of plasma devices
    • H05H2245/10—Treatment of gases
    • H05H2245/15—Ambient air; Ozonisers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Optics & Photonics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Procedimiento para la reducción de dióxido de carbono a metano mediante catalizador activado por plasma DBD.#La presente invención se refiere a procedimiento para llevar a cabo la siguiente reacción con un catalizador:#CO{sub,2} + 4H{sub,2} -> CH{sub,4} + 2H{sub,2}O#caracterizado porque:#- dicho catalizador se basa en la combinación de dióxido de cerio y níquel; y#- dicho catalizador está activado por un plasma DBD (descarga de barrera dieléctrica).

Description

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Claims (1)

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ES201530109A 2015-01-28 2015-01-28 Procedimiento para la reducción de dióxido de carbono a metano mediante catalizador activado por plasma DBD Expired - Fee Related ES2578704B1 (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES201530109A ES2578704B1 (es) 2015-01-28 2015-01-28 Procedimiento para la reducción de dióxido de carbono a metano mediante catalizador activado por plasma DBD
EP15202925.2A EP3050865B1 (en) 2015-01-28 2015-12-29 Process for the reduction of carbon dioxide to methane by dbd plasma-activated catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201530109A ES2578704B1 (es) 2015-01-28 2015-01-28 Procedimiento para la reducción de dióxido de carbono a metano mediante catalizador activado por plasma DBD

Publications (2)

Publication Number Publication Date
ES2578704A1 ES2578704A1 (es) 2016-07-29
ES2578704B1 true ES2578704B1 (es) 2017-05-10

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ES201530109A Expired - Fee Related ES2578704B1 (es) 2015-01-28 2015-01-28 Procedimiento para la reducción de dióxido de carbono a metano mediante catalizador activado por plasma DBD

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ES (1) ES2578704B1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101788808B1 (ko) * 2015-11-26 2017-11-15 조선대학교산학협력단 상온 및 상압 조건하에서 이산화탄소와 수소를 이용한 메탄가스 합성방법 및 합성장치
AU2019393943B2 (en) 2018-12-03 2022-03-17 Shell Internationale Research Maatschappij B.V. A process and reactor for converting carbon dioxide into carbon monoxide
FR3090409B1 (fr) * 2018-12-21 2023-04-14 Paris Sciences Lettres Quartier Latin Reacteur pour la conversion du dioxyde de carbone
GB202009093D0 (en) * 2020-06-15 2020-07-29 Univ Liverpool Catalyst, apparatus and method
US11591226B1 (en) 2020-08-25 2023-02-28 Advanced Energy Materials, Llc Plasma assisted distributed chemical production
FR3115711A1 (fr) 2020-10-29 2022-05-06 Paris Sciences Et Lettres - Quartier Latin Système catalytique mixte pour la conversion du CO2 et/ou du CO dans un procédé hybride plasma froid-catalyse
DE102021123883A1 (de) 2021-09-15 2023-03-16 Synreform GmbH Spaltung und Synthese von wasserstoffenthaltendem Gas mittels dielektrischer Barriereentladung

Family Cites Families (5)

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Publication number Priority date Publication date Assignee Title
GB8607268D0 (en) * 1986-03-24 1986-04-30 Atomic Energy Authority Uk Methanation & steam reforming catalyst
DE4220865A1 (de) * 1991-08-15 1993-02-18 Asea Brown Boveri Verfahren und vorrichtung zur hydrierung von kohlendioxid
US7622088B2 (en) * 2005-09-15 2009-11-24 Gm Global Technology Operations, Inc. Rapid activation catalyst system in a non-thermal plasma catalytic reactor
CN101880214B (zh) * 2010-06-08 2013-02-27 大连理工大学 一种非热等离子体与过渡金属协同催化co2加氢的方法
CN102600854A (zh) * 2012-02-16 2012-07-25 四川大学 二氧化碳甲烷化用催化剂及其制备方法

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ES2578704A1 (es) 2016-07-29
EP3050865B1 (en) 2021-02-24
EP3050865A1 (en) 2016-08-03

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