ES2576631T3 - Diiniciadores de la polimerización aniónica y a un procedimiento para preparar la misma - Google Patents

Diiniciadores de la polimerización aniónica y a un procedimiento para preparar la misma Download PDF

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Publication number
ES2576631T3
ES2576631T3 ES04784675.3T ES04784675T ES2576631T3 ES 2576631 T3 ES2576631 T3 ES 2576631T3 ES 04784675 T ES04784675 T ES 04784675T ES 2576631 T3 ES2576631 T3 ES 2576631T3
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Prior art keywords
diisopropenylbenzene
methyl
anionic polymerization
preparing
procedure
Prior art date
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ES04784675.3T
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English (en)
Inventor
Carl L. Willis
Daniel E. Goodwin
Grant W. Haddix
Pierre N. Tutunjian
Joy P. Cocchiara
Harvey E. Atwood
Craig A. Stevens
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Kraton Polymers US LLC
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Kraton Polymers US LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/02—Lithium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Diiniciador de la polimerización aniónica preparado mediante la mezcla de un compuesto de diisopropenilbenceno seleccionado de entre el grupo que comprende 1,2-diisopropenilbenceno; 1,3- diisopropenilbenceno; 1,4-diisopropenilbenceno; 3,4,5,6-tetrametil-1,2-diisopropenilbenceno; 2,4,5,6-tetraetil- 1,3-diisopropenilbenceno; 2,3,5,6-tetra-n-hexil-1,4-diisopropenilbenceno; 3,4-diciclohexil-1,2- diisopropenilbenceno; 5-(3-metilciclopentil)-1,3-diisopropenilbenceno; 3-ciclopentilmetil-6-n-propil-1,4- diisopropenilbenceno; 4- (2-ciclobutil-1-etil)-1,2-diisopropenilbenceno; 3-(2-n-propilciclopropil)-1,4- diisopropenilbenceno; 2-metil-5-n-hexil-1,3-diisopropenilbenceno; 4-metil-1,2-diisopropenilbenceno; 5-etil-1,3- diisopropenilbenceno; 3-metil-1,4-diisopropenilbenceno y mezclas de los mismos, con éter dietílico, etileno, un compuesto de organolitio y un disolvente a una temperatura comprendida entre 0 °C y 150 °C en unas condiciones suficientes para preparar un diiniciador que presente sitios reactivos primarios de alquilo de litio.

Description

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Claims (1)

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ES04784675.3T 2003-09-24 2004-09-22 Diiniciadores de la polimerización aniónica y a un procedimiento para preparar la misma Active ES2576631T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US50567003P 2003-09-24 2003-09-24
US505670P 2003-09-24
PCT/US2004/030890 WO2005030816A1 (en) 2003-09-24 2004-09-22 Anionic polymerization diinitiator and process for preparing same

Publications (1)

Publication Number Publication Date
ES2576631T3 true ES2576631T3 (es) 2016-07-08

Family

ID=34393053

Family Applications (1)

Application Number Title Priority Date Filing Date
ES04784675.3T Active ES2576631T3 (es) 2003-09-24 2004-09-22 Diiniciadores de la polimerización aniónica y a un procedimiento para preparar la misma

Country Status (8)

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US (2) US7285596B2 (es)
EP (1) EP1709090B1 (es)
JP (1) JP4685018B2 (es)
KR (1) KR100788111B1 (es)
CN (2) CN101402693B (es)
ES (1) ES2576631T3 (es)
TW (1) TWI314562B (es)
WO (1) WO2005030816A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2576631T3 (es) * 2003-09-24 2016-07-08 Kraton Polymers U.S. Llc Diiniciadores de la polimerización aniónica y a un procedimiento para preparar la misma
KR101044070B1 (ko) 2008-09-23 2011-06-27 주식회사 엘지화학 이관능성 유기 리튬 개시제 및 이를 이용하여 생산되는 공역디엔계 공중합체 및 이들의 제조방법
JP5602000B2 (ja) * 2010-12-15 2014-10-08 旭化成ケミカルズ株式会社 粘接着剤用共重合体、その製造方法及び粘接着剤用組成物
KR101800496B1 (ko) * 2014-06-16 2017-11-22 주식회사 엘지화학 변성 공액 디엔계 중합체, 이를 포함하는 변성 고무 조성물 및 변성 공액 디엔계 중합체의 제조방법
KR101775761B1 (ko) * 2014-07-30 2017-09-19 주식회사 엘지화학 변성 공액 디엔계 중합체, 이를 포함하는 변성 고무 조성물 및 변성 공액 디엔계 중합체의 제조방법

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3734973A (en) * 1971-11-04 1973-05-22 Phillips Petroleum Co Multifunctional polymerization initiators from diisopropenylbenzene
US5166277A (en) * 1991-10-31 1992-11-24 Shell Oil Company Hydrogenation of unsaturation in low molecular weight diene polymers
US5393843A (en) * 1992-08-31 1995-02-28 Shell Oil Company Butadiene polymers having terminal functional groups
TW381102B (en) * 1994-05-09 2000-02-01 Shell Int Research Process for the preparation of industrially applicable difunctional anionic polymerization initiators and their use
TW322493B (es) * 1994-06-27 1997-12-11 Shell Int Research
US6043316A (en) * 1996-11-13 2000-03-28 Shell Oil Company Crosslinkable hydroxy terminated polydiene polymer coating compositions for use on substrates and a process for preparing them
US6462143B1 (en) * 1998-02-03 2002-10-08 Kraton Polymers Us Llc Gel-free process for making functionalized anionically polymerized polymers
US6242537B1 (en) * 1998-03-30 2001-06-05 Shell Oil Company Gel-free process for making hydrogenated functionalized anionically polymerized polymers
US6242538B1 (en) * 1998-06-04 2001-06-05 Shell Oil Company Process for making hydrogenated gel-free functionalized anionically polymerized polymers
US6613858B1 (en) * 1998-08-31 2003-09-02 Asahi Kasei Kabushiki Kaisha Solution of dilithium polymerization initiator
US6217798B1 (en) * 1998-10-09 2001-04-17 Shell Oil Company Method for synthesis of a dilithium diisopropenylbenzene-based diinitiator
US6455651B1 (en) * 1999-04-23 2002-09-24 Kraton Polymers U.S. Llc Uniform initiation of anionic polymerization using organo-substituted alkali metal initiators
US6391981B1 (en) * 1999-04-23 2002-05-21 Kraton Polymers Us Llc Increased throughput in the manufacture of anionic polymers by reduction in polymer cement viscosity through the addition of metal alkyls
JP2001064328A (ja) * 1999-09-01 2001-03-13 Kuraray Co Ltd α，ω−ジリチオポリマーまたはそれから誘導されるポリマーの製造方法
US20020198343A1 (en) * 2000-03-14 2002-12-26 Willis Carl Lesley Uniform initiation of anionic polymerization using organo-substituted alkali metal initiators
ES2576631T3 (es) * 2003-09-24 2016-07-08 Kraton Polymers U.S. Llc Diiniciadores de la polimerización aniónica y a un procedimiento para preparar la misma

Also Published As

Publication number Publication date
TW200524965A (en) 2005-08-01
EP1709090B1 (en) 2016-03-23
US20050101741A1 (en) 2005-05-12
JP2007506841A (ja) 2007-03-22
KR100788111B1 (ko) 2007-12-21
US20080111256A1 (en) 2008-05-15
WO2005030816A1 (en) 2005-04-07
CN101402693B (zh) 2011-11-30
US7550537B2 (en) 2009-06-23
US7285596B2 (en) 2007-10-23
JP4685018B2 (ja) 2011-05-18
CN1871265A (zh) 2006-11-29
TWI314562B (en) 2009-09-11
KR20060080232A (ko) 2006-07-07
EP1709090A1 (en) 2006-10-11
CN100422225C (zh) 2008-10-01
CN101402693A (zh) 2009-04-08

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