ES2570385T3 - N-(1H-pirazolil-metil)-formamidas, procedimiento para su producción y su uso como inhibidores de la nitrificación - Google Patents
N-(1H-pirazolil-metil)-formamidas, procedimiento para su producción y su uso como inhibidores de la nitrificaciónInfo
- Publication number
- ES2570385T3 ES2570385T3 ES12795740T ES12795740T ES2570385T3 ES 2570385 T3 ES2570385 T3 ES 2570385T3 ES 12795740 T ES12795740 T ES 12795740T ES 12795740 T ES12795740 T ES 12795740T ES 2570385 T3 ES2570385 T3 ES 2570385T3
- Authority
- ES
- Spain
- Prior art keywords
- formamides
- pyrazolyl
- methyl
- production
- nitrification inhibitors
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
N-(1H-Pirazolil-metil)-formamidas de fórmula general I:**Fórmula** caracterizadas porque R4 es >= H, halógeno, alquilo C1-C4 o cicloalquilo C3-C8, R1 y R2 independientemente entre sí representan H, alquilo C1-C4 o cicloalquilo C3-C8, R3 representa alquilo C1-C4, cicloalquilo C3-C8 o arilo C6-C10 o H.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011120098.7A DE102011120098B4 (de) | 2011-12-02 | 2011-12-02 | N-(1H-Pyrazolyl-methyl)formamide, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
PCT/EP2012/004918 WO2013079197A1 (de) | 2011-12-02 | 2012-11-28 | N-(1h-pyrazolyl-methyl)formamide, verfahren zu ihrer herstellung und ihre verwendung als nitrifikationsinhibitoren |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2570385T3 true ES2570385T3 (es) | 2016-05-18 |
Family
ID=47294835
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES12795740T Active ES2570385T3 (es) | 2011-12-02 | 2012-11-28 | N-(1H-pirazolil-metil)-formamidas, procedimiento para su producción y su uso como inhibidores de la nitrificación |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP2785697B1 (es) |
DE (1) | DE102011120098B4 (es) |
ES (1) | ES2570385T3 (es) |
WO (1) | WO2013079197A1 (es) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102013021933A1 (de) | 2013-12-20 | 2015-06-25 | Skw Stickstoffwerke Piesteritz Gmbh | Verwendung von Pyrazol-Derivaten als Mittel zur Verbesserung der Trockenstresstoleranz |
MX2017006305A (es) | 2014-11-14 | 2017-08-21 | Basf Se | Bencilpropargileter como inhibidores de la nitrificacion. |
EP3233761B1 (en) | 2014-12-18 | 2019-02-06 | Basf Se | Alkynylpyrazoles as nitrification inhibitors |
US10556844B2 (en) | 2015-02-06 | 2020-02-11 | Basf Se | Pyrazole compounds as nitrification inhibitors |
CA2983964A1 (en) | 2015-05-12 | 2016-11-17 | Basf Se | Thioether compounds as nitrification inhibitors |
TW201705955A (zh) | 2015-05-14 | 2017-02-16 | 輝瑞大藥廠 | 包含吡咯啶-2,5-二酮ido1抑制劑及抗-pd1/抗-pd-l1抗體之組合療法 |
DE102016106592A1 (de) | 2016-04-11 | 2017-10-12 | Skw Stickstoffwerke Piesteritz Gmbh | Verfahren zur Herstellung von N-((3(5)-Methyl-1H-pyrazol-1-yl)methyl)acetamid (MPA) |
CA3024100A1 (en) | 2016-05-18 | 2017-11-23 | Basf Se | Capsules comprising benzylpropargylethers for use as nitrification inhibitors |
CN110891923A (zh) | 2017-07-10 | 2020-03-17 | 巴斯夫欧洲公司 | 包含脲酶抑制剂(ui)和硝化抑制剂如2-(3,4-二甲基-1h-吡唑-1-基)琥珀酸(dmpsa)或3,4-二甲基吡唑鎓乙醇酸盐(dmpg)的混合物 |
KR20200128405A (ko) | 2018-02-28 | 2020-11-12 | 바스프 에스이 | 질화작용 저해제로서의 n-관능화 알콕시 피라졸 화합물의 용도 |
WO2019166558A1 (en) | 2018-02-28 | 2019-09-06 | Basf Se | Use of pyrazole propargyl ethers as nitrification inhibitors |
CN114980741A (zh) | 2020-01-16 | 2022-08-30 | 巴斯夫欧洲公司 | 包含硝化抑制剂和载体的混合物 |
BR112022013894A2 (pt) | 2020-01-16 | 2023-01-10 | Basf Se | Mistura, composição agroquímica, método para aumentar a eficiência de uso de fertilizante e uso da mistura |
AR125955A1 (es) | 2021-05-21 | 2023-08-30 | Basf Se | Uso de un compuesto de alcoxi pirazol n-funcionalizado como inhibidor de nitrificación |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3635690A (en) | 1968-05-16 | 1972-01-18 | Dow Chemical Co | Soil treating method and composition for conserving nitrogen in soil by addition of a pyrazole thereto |
US3697244A (en) | 1968-10-15 | 1972-10-10 | Dow Chemical Co | Crop culture with 4h-1,2,4-triazoles |
DE2745833C2 (de) | 1977-10-12 | 1986-10-16 | VEB Fahlberg-List Chemische und pharmazeutische Fabriken, DDR 3013 Magdeburg | Mittel zur Hemmung bzw. Regelung der Nitrifikation von Ammoniumstickstoff in Kulturböden |
DE3409317A1 (de) | 1984-03-14 | 1985-09-19 | Basf Ag, 6700 Ludwigshafen | Nitrifikationsinhibierende 1-hydroxipyrazol-derivate |
US4523940A (en) | 1984-06-25 | 1985-06-18 | The Dow Chemical Company | Soil treating method and composition for conserving nitrogen in soil |
AU4348285A (en) | 1984-06-25 | 1986-01-02 | Dow Chemical Company, The | Pyrazole growth enhancer |
US4969946A (en) | 1986-01-29 | 1990-11-13 | The Dow Chemical Company | Soil treating method and composition for conserving nitrogen in naturally alkaline soil |
SU1470737A1 (ru) | 1986-09-19 | 1989-04-07 | Предприятие П/Я Г-4302 | Способ ингибировани нитрификации карбамида в почве |
DE3704359A1 (de) | 1987-02-12 | 1988-08-25 | Basf Ag | Azolhalbaminal-derivate und ihre verwendung als nitrifikationsinhibitoren |
DD292232A5 (de) | 1988-10-17 | 1991-07-25 | Stickstoffwerke Ag Wittenberg-Piesteritz,De | Mittel zur hemmung bzw. regelung der nitrifikation von ammoniumstickstoff in kulturboeden |
DE4018395A1 (de) | 1990-06-08 | 1992-02-20 | Wittenberg Stickstoff Ag | Mittel zur hemmung bzw. regelung der nitrifikation von ammoniumstickstoff in kulturboeden |
DE4111922A1 (de) | 1991-04-12 | 1992-10-15 | Basf Ag | Verfahren zur herstellung von 1-carbamoyl-pyrazolen |
DE4128828A1 (de) | 1991-08-30 | 1993-03-04 | Basf Ag | Ammonium- oder harnstoffhaltige duengemittel und verfahren zu ihrer herstellung |
JPH07104135A (ja) | 1993-10-06 | 1995-04-21 | Sanyo Electric Co Ltd | 立体画像表示装置 |
DE4446194A1 (de) | 1994-12-23 | 1996-06-27 | Basf Ag | Verwendung von Pyrazolderivaten mit hydrophoben Resten als Nitrifikationsinhibitoren |
DE19503827A1 (de) | 1995-02-06 | 1996-08-08 | Basf Ag | Verwendung von schwerflüchtigen Pyrazolderivaten mit hydrophilen Gruppen als Nitrifikationsinhibitoren |
DE19631764A1 (de) | 1996-08-06 | 1998-02-12 | Basf Ag | Neue Nitrifikationsinhibitoren sowie die Verwendung von Polysäuren zur Behandlung von Mineraldüngemitteln die einen Nitrifikationsinhibitor enthalten |
DE19822340B4 (de) | 1998-05-19 | 2008-02-28 | Skw Stickstoffwerke Piesteritz Gmbh | Thermostabile schwerflüchtige Alkyl-1H-1-pyrazolylmethanamin-Derivate und deren Verwendung als Nitrifikationsinhibitoren |
DE10117821A1 (de) | 2000-04-14 | 2001-10-31 | Piesteritz Stickstoff | Hydrophobe, thermostabile und schwerflüchtige 1H-Pyrazol-Derivate, Verfahren zu ihrer Herstellung und deren Verwendung als Nitrifikationsinhibitoren |
DE10135423A1 (de) | 2000-08-08 | 2002-02-21 | Piesteritz Stickstoff | 1H-Pyrazol-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
DE10343277A1 (de) | 2003-09-18 | 2005-04-21 | Piesteritz Stickstoff | N-(1H-Azolyl-methyl)amide, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
-
2011
- 2011-12-02 DE DE102011120098.7A patent/DE102011120098B4/de active Active
-
2012
- 2012-11-28 EP EP12795740.5A patent/EP2785697B1/de not_active Not-in-force
- 2012-11-28 WO PCT/EP2012/004918 patent/WO2013079197A1/de active Application Filing
- 2012-11-28 ES ES12795740T patent/ES2570385T3/es active Active
Also Published As
Publication number | Publication date |
---|---|
WO2013079197A1 (de) | 2013-06-06 |
EP2785697B1 (de) | 2016-02-03 |
EP2785697A1 (de) | 2014-10-08 |
DE102011120098A1 (de) | 2013-06-06 |
DE102011120098B4 (de) | 2021-02-11 |
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