ES2549864T3 - Producción de dihidronepetalactona por hidrogenación de nepetalactona - Google Patents
Producción de dihidronepetalactona por hidrogenación de nepetalactona Download PDFInfo
- Publication number
- ES2549864T3 ES2549864T3 ES07863146.2T ES07863146T ES2549864T3 ES 2549864 T3 ES2549864 T3 ES 2549864T3 ES 07863146 T ES07863146 T ES 07863146T ES 2549864 T3 ES2549864 T3 ES 2549864T3
- Authority
- ES
- Spain
- Prior art keywords
- temperatures
- temperature
- nepetalactone
- dihydronepetalactone
- trans
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/94—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un procedimiento para preparar dihidronepetalactona que comprende: (a) poner en contacto en una mezcla de reacción una cantidad inicial de trans-cis nepetalactona, descrita por la estructura de la fórmula I, y una cantidad inicial de cis-trans nepetalactona descrita por la estructura de fórmula II, **Fórmula** con hidrógeno y un primer catalizador de hidrogenación sólido a una primera temperatura o temperaturas, hasta que la cantidad en peso de trans-cis nepetalactona en la mezcla de reacción no es mayor que aproximadamente 50% de su cantidad inicial, para formar una primera mezcla de productos; y (b) poner en contacto la primera mezcla de productos con hidrógeno y un segundo catalizador de hidrogenación sólido a una segunda temperatura o temperaturas, para formar una dihidronepetalactona; en donde la etapa (a) se lleva a cabo a una temperatura o temperaturas en el intervalo de 0ºC a 100ºC, y la etapa (b) se lleva a cabo a una temperatura o temperaturas en el intervalo de 50ºC a 150ºC; y en donde la temperatura o temperaturas en la etapa (b) son mayores que la temperatura o temperaturas en la etapa (a), caracterizado porque el primer y segundo catalizadores de hidrogenación sólidos contienen platino.
Description
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12
14
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US87656806P | 2006-12-21 | 2006-12-21 | |
US876568P | 2006-12-21 | ||
PCT/US2007/025987 WO2008079252A1 (en) | 2006-12-21 | 2007-12-20 | Production of dihydronepetalactone by hydrogenation of nepetalactone |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2549864T3 true ES2549864T3 (es) | 2015-11-02 |
Family
ID=39273109
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES07863146.2T Active ES2549864T3 (es) | 2006-12-21 | 2007-12-20 | Producción de dihidronepetalactona por hidrogenación de nepetalactona |
Country Status (9)
Country | Link |
---|---|
US (1) | US8765975B2 (es) |
EP (1) | EP2114911B1 (es) |
CN (1) | CN101563334B (es) |
CA (1) | CA2673047C (es) |
DK (1) | DK2114911T3 (es) |
ES (1) | ES2549864T3 (es) |
HK (1) | HK1136295A1 (es) |
SI (1) | SI2114911T1 (es) |
WO (1) | WO2008079252A1 (es) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7547793B2 (en) * | 2003-03-19 | 2009-06-16 | E.I. Du Pont De Nemours And Company | Method for making insect repellent composition |
CN101442908B (zh) * | 2006-05-10 | 2016-09-28 | 纳幕尔杜邦公司 | 配制的壁虱和昆虫驱除组合物 |
CA2671989C (en) * | 2006-12-21 | 2016-08-09 | E. I. Du Pont De Nemours And Company | Steam distillation of catmint plants |
SI2125770T1 (sl) | 2006-12-21 | 2014-11-28 | E.I. Du Pont De Nemours And Company | Hidrogenacija olja mačje mete |
ES2549864T3 (es) | 2006-12-21 | 2015-11-02 | E. I. Du Pont De Nemours And Company | Producción de dihidronepetalactona por hidrogenación de nepetalactona |
US8293217B2 (en) * | 2006-12-21 | 2012-10-23 | E I Du Pont De Nemours And Company | Hydrogenation of caryophellene |
US8558015B2 (en) * | 2006-12-21 | 2013-10-15 | E I Du Pont De Nemours And Company | Solvent addition and removal in the hydrogenation of catmint oil |
US9521844B2 (en) | 2006-12-21 | 2016-12-20 | E I Du Pont De Nemours And Company | Solvent addition and removal in the hydrogenation of catmint oil |
ES2442010T3 (es) * | 2007-11-26 | 2014-02-07 | E. I. Du Pont De Nemours And Company | Método para convertir trans-cis nepetalactona en cis-trans nepetalactona utilizando tamices moleculares |
CA2779416C (en) | 2009-11-11 | 2017-12-12 | E.I. Du Pont De Nemours And Company | Method for the enhanced recovery of catmint oil |
CN104181239B (zh) * | 2013-05-23 | 2015-09-30 | 湖北航天化学技术研究所 | 硝酸酯增塑聚醚推进剂中功能助剂含量的测定方法 |
CN105738545A (zh) * | 2014-12-12 | 2016-07-06 | 湖北航天化学技术研究所 | 叠氮聚醚推进剂中有机功能助剂含量色谱测定方法 |
EP3720944A1 (en) | 2017-12-07 | 2020-10-14 | Zymergen Inc. | Engineered biosynthetic pathways for production of (6e)-8-hydroxygeraniol by fermentation |
CN111868047A (zh) | 2017-12-21 | 2020-10-30 | 齐默尔根公司 | 荆芥内半缩醛氧化还原酶、荆芥内半缩醛合酶和能够产生荆芥内酯的微生物 |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4416881A (en) * | 1979-05-18 | 1983-11-22 | The United States Of America As Represented By The Secretary Of Agriculture | Insect repellents employing cyclohexane-carbonyl morpholine compounds |
US4476147A (en) * | 1982-05-20 | 1984-10-09 | International Flavors & Fragrances Inc. | Flavoring of alliaceous-flavored foodstuffs |
US4496467A (en) * | 1983-02-23 | 1985-01-29 | International Flavors & Fragrances Inc. | Insect repellent, pheremonal, animal repellent diagnostic and/or aroma augmenting or enhancing compositions and articles containing at least a major proportion of poly(epsilon caprolactone)homopolymers, and having imbedded therein one or more functional |
US4869896A (en) * | 1984-05-30 | 1989-09-26 | Angus Chemical Company | Potentiated insect repellent composition and method |
US6013255A (en) * | 1994-04-18 | 2000-01-11 | Gist-Brocades B.V. | Stable water-in-oil emulsions |
US6524605B1 (en) * | 1999-08-06 | 2003-02-25 | Iowa State University Research Foundation, Inc. | Biorational repellents obtained from terpenoids for use against arthropods |
US7250174B2 (en) * | 1999-12-07 | 2007-07-31 | Schott Ag | Cosmetic, personal care, cleaning agent, and nutritional supplement compositions and methods of making and using same |
US20030223878A1 (en) * | 2000-05-04 | 2003-12-04 | Keudell Leopold Von | Pump and overflow valve assembly |
US6623694B1 (en) * | 2000-08-29 | 2003-09-23 | Bath & Body Works, Inc. | Non-foaming water fountain and composition |
US6673756B2 (en) * | 2000-09-20 | 2004-01-06 | Symrise Gmbh & Co. Kg | Multiphase soaps |
US6462015B1 (en) * | 2000-11-10 | 2002-10-08 | International Flavors & Fragrances Inc. | Bicyclic lactones, perfumery uses thereof, processes for preparing same and intermediates therefor |
US6707000B2 (en) * | 2001-08-24 | 2004-03-16 | Illinois Tool Works Inc. | Consumables storage box |
US20030079786A1 (en) * | 2001-10-30 | 2003-05-01 | Diana Michael J. | Modular fluid pressure regulator with bypass |
CN100396674C (zh) * | 2002-01-23 | 2008-06-25 | 纳幕尔杜邦公司 | 芳香化合物 |
US20040127553A1 (en) * | 2002-03-20 | 2004-07-01 | Hallahan David L. | Insect repellent compositions comprising dihydronepetalactone |
US20030235601A1 (en) * | 2002-03-20 | 2003-12-25 | Hallahan David L. | Insect repellent compounds |
EP1490351B1 (en) | 2002-04-03 | 2007-06-06 | E.I. Du Pont De Nemours And Company | Production of dihydronepetalactone by hydrogenation of nepetalactone |
US6841570B2 (en) * | 2002-04-08 | 2005-01-11 | Jodi Haenke | Materials and methods for controlling wood-boring insects |
US7820145B2 (en) * | 2003-08-04 | 2010-10-26 | Foamix Ltd. | Oleaginous pharmaceutical and cosmetic foam |
CN1838881A (zh) | 2003-09-18 | 2006-09-27 | 纳幕尔杜邦公司 | 包括二氢荆芥内酯的驱虫剂组合物 |
WO2005054224A2 (en) * | 2003-11-26 | 2005-06-16 | E. I. Du Pont De Nemours And Company | Derivatives of dihydronepetalactone and method for preparation |
US20050137252A1 (en) * | 2003-12-22 | 2005-06-23 | Scialdone Mark A. | Production of dihydronepetalactone |
GB0409542D0 (en) * | 2004-04-29 | 2004-06-02 | Unilever Plc | Cosmetic compositions |
US8748477B2 (en) | 2004-11-03 | 2014-06-10 | E I Du Pont De Nemours And Company | Formulations containing insect repellent compounds |
US20060148842A1 (en) * | 2004-12-29 | 2006-07-06 | Scialdone Mark A | Nepetalactams and N-substituted derivatives thereof |
BRPI0517572A (pt) * | 2004-12-29 | 2008-10-14 | Du Pont | composto, composição de matéria e método para repelir um inseto ou artrópode |
US20060201391A1 (en) * | 2005-03-09 | 2006-09-14 | Scialdone Mark A | Compositions having sustained-release insect repellency |
BRPI0617592A2 (pt) * | 2005-09-30 | 2011-08-02 | Du Pont | composto, composição, método para repelir um inseto ou artrópode e processo para a preparação de um composto |
BRPI0617552A2 (pt) * | 2005-09-30 | 2011-07-26 | Du Pont | composiÇço e mÉtodo para repelir um inseto ou artràpode |
CN101442908B (zh) * | 2006-05-10 | 2016-09-28 | 纳幕尔杜邦公司 | 配制的壁虱和昆虫驱除组合物 |
CA2671989C (en) * | 2006-12-21 | 2016-08-09 | E. I. Du Pont De Nemours And Company | Steam distillation of catmint plants |
US8558015B2 (en) * | 2006-12-21 | 2013-10-15 | E I Du Pont De Nemours And Company | Solvent addition and removal in the hydrogenation of catmint oil |
ES2549864T3 (es) | 2006-12-21 | 2015-11-02 | E. I. Du Pont De Nemours And Company | Producción de dihidronepetalactona por hidrogenación de nepetalactona |
SI2125770T1 (sl) * | 2006-12-21 | 2014-11-28 | E.I. Du Pont De Nemours And Company | Hidrogenacija olja mačje mete |
US8293217B2 (en) * | 2006-12-21 | 2012-10-23 | E I Du Pont De Nemours And Company | Hydrogenation of caryophellene |
DE102007026049A1 (de) * | 2007-05-31 | 2008-12-04 | Beiersdorf Ag | Repellentien gegen Wespen |
ES2442010T3 (es) * | 2007-11-26 | 2014-02-07 | E. I. Du Pont De Nemours And Company | Método para convertir trans-cis nepetalactona en cis-trans nepetalactona utilizando tamices moleculares |
-
2007
- 2007-12-20 ES ES07863146.2T patent/ES2549864T3/es active Active
- 2007-12-20 US US12/519,770 patent/US8765975B2/en active Active
- 2007-12-20 SI SI200731700T patent/SI2114911T1/sl unknown
- 2007-12-20 WO PCT/US2007/025987 patent/WO2008079252A1/en active Application Filing
- 2007-12-20 DK DK07863146.2T patent/DK2114911T3/en active
- 2007-12-20 CN CN2007800472373A patent/CN101563334B/zh not_active Expired - Fee Related
- 2007-12-20 CA CA2673047A patent/CA2673047C/en not_active Expired - Fee Related
- 2007-12-20 EP EP07863146.2A patent/EP2114911B1/en not_active Not-in-force
-
2010
- 2010-04-07 HK HK10103446.2A patent/HK1136295A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN101563334A (zh) | 2009-10-21 |
WO2008079252A1 (en) | 2008-07-03 |
CA2673047C (en) | 2014-08-19 |
CA2673047A1 (en) | 2008-07-03 |
DK2114911T3 (en) | 2015-12-14 |
SI2114911T1 (sl) | 2015-12-31 |
US20100168447A1 (en) | 2010-07-01 |
EP2114911B1 (en) | 2015-09-02 |
EP2114911A1 (en) | 2009-11-11 |
CN101563334B (zh) | 2012-08-22 |
HK1136295A1 (en) | 2010-06-25 |
US8765975B2 (en) | 2014-07-01 |
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