ES2548718T3 - Distribution device for the distribution of active substance fluids - Google Patents

Distribution device for the distribution of active substance fluids Download PDF

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Publication number
ES2548718T3
ES2548718T3 ES01996653.0T ES01996653T ES2548718T3 ES 2548718 T3 ES2548718 T3 ES 2548718T3 ES 01996653 T ES01996653 T ES 01996653T ES 2548718 T3 ES2548718 T3 ES 2548718T3
Authority
ES
Spain
Prior art keywords
distribution
fluids
active substance
thickener
add
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES01996653.0T
Other languages
Spanish (es)
Inventor
Ralph Butter-Jentsch
Lutz Grässer
Ronald Menke
Frank Pessel
Hans-Georg MÜHLHAUSEN
Detlef Lehmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27512401&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2548718(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from DE10113036A external-priority patent/DE10113036B4/en
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Application granted granted Critical
Publication of ES2548718T3 publication Critical patent/ES2548718T3/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E03WATER SUPPLY; SEWERAGE
    • E03DWATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
    • E03D9/00Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
    • E03D9/02Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
    • E03D9/03Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
    • E03D9/032Devices connected to or dispensing into the bowl

Landscapes

  • Public Health (AREA)
  • Health & Medical Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Epidemiology (AREA)
  • Detergent Compositions (AREA)
  • Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Sanitary Device For Flush Toilet (AREA)
  • External Artificial Organs (AREA)

Abstract

The device for delivering fluids with active substances into flushing water in a toilet bowl comprises storage containers (2, 3) which hold such fluids, and are protected against entry of flushing water into their interior. The outlet openings of these containers are arranged in such a way that given amounts of fluids with active substances are delivered only during each flushing operation.

Description

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E01996653 E01996653

30-09-2015 09-30-2015

FA-C12-C18+7 OE* FA-C12-C18 + 7 OE *
12,50 % tensioactivo básico / emulsionante 12.50% basic surfactant / emulsifier

alquil(C8-10)-1,5-glucósido alcohol oleil-cetílico + 5 OE ** (C8-10) alkyl -1,5-glycoside oleyl-cetyl alcohol + 5 OE **
5,44 % 3,00 % co-tensioactivo co-emulsionante 5.44% 3.00% co-emulsifying co-surfactant

ácido cítrico polisacárido / goma xantana citric acid polysaccharide / xanthan gum
5,00 % 0,20 % agente descalcificante espesante 5.00% 0.20%  thickener decalcifying agent

etanol al 96 %, desnaturalizado con el 1 % de MEK 96% ethanol, denatured with 1% MEK
3,00 % co-emulsionante 3.00% co-emulsifier

aceite de perfume, nota de naranja combinación de hemiacetal-isotiazolina perfume oil, orange note combination of hemiacetal-isothiazoline
12,00 % 0,05 % aroma conservante 12.00% 0.05% preservative aroma

colorante Colorant
< 1,0 % <1.0%

agua del grifo tap water
añadir hasta 100 add up to 100

* por ejemplo Dehydol LT 7 ** por ejemplo Eumulgin O 5 * for example Dehydol LT 7 ** for example Eumulgin O 5

aproximadamente 3500 mPas, 20 ºC, Rotovisko LVT, husillo 2, 20 r/min pH 2,5, no diluida disolución transparente approximately 3500 mPas, 20 ° C, Rotovisko LVT, spindle 2, 20 r / min pH 2.5, undiluted clear solution

Preparación Preparation

Disponer agua. Con agitador en funcionamiento, añadir colorante y conservante y a continuación disolver durante 5 min. Esparcir el espesante con número de revoluciones de medio a alto. Durante el tiempo de hinchamiento de aproximadamente 60 minutos dejar funcionar posteriormente el agitador. Añadir tensioactivos, después alcoholes. Como último alimentar el perfume y ácido cítrico y Examinar la mezcla de reacción para determinar los parámetros de liberación. Have water With stirrer running, add dye and preservative and then dissolve for 5 min. Spread the thickener with medium to high speed. During the swelling time of approximately 60 minutes, let the stirrer run later. Add surfactants, then alcohols. As a last feed the perfume and citric acid and examine the reaction mixture to determine the release parameters.

6.) Fase aromática combinada con fase de principio activo que contiene enzima 6.) Aromatic phase combined with active ingredient phase containing enzyme

a.) Fase aromática a.) Aromatic phase

Composición Composition

FAEOS-Na. C12-14 + 2 OE 24,50 % tensioactivo básico alcanosulfonato de Na* 8,50 % co-tensioactivo 1,2-propanodiol 5,00 % emulsionante etanol al 96 %, desnaturalizado con el 1 % de MEK 5,00 % co-emulsionante hidroxietilcelulosa 0,45 % espesante aceite de perfume, floral frutal 9,00 % aroma combinación de hemiacetal-isotiazolina 0,05 % conservantes colorantes <1,0 % agua del grifo añadir hasta 100 FAEOS-Na. C12-14 + 2 OE 24.50% basic surfactant Na alkanesulfonate * 8.50% co-surfactant 1,2-propanediol 5.00% emulsifier 96% ethanol, denatured with 1% MEK 5.00% co -0.45% hydroxyethyl cellulose emulsifier perfume oil thickener, floral fruit 9.00% aroma combination of hemiacetal-isothiazoline 0.05% color preservatives <1.0% tap water add up to 100

* por ejemplo Hostapur SAS 60 / empresa Hoechst * for example Hostapur SAS 60 / Hoechst company

aproximadamente 2500 mPas, 20 ºC, Rotovisko LVT, husillo 2, 6 r/min pH 6,8, no diluida disolución transparente approximately 2500 mPas, 20 ° C, Rotovisko LVT, spindle 2, 6 r / min pH 6.8, undiluted clear solution

Preparación Preparation

Disponer agua caliente de 20-25 ºC. Con agitador en funcionamiento, añadir colorantes y conservantes y a continuación disolver durante 5 min. Provide hot water of 20-25 ºC. With stirrer running, add dyes and preservatives and then dissolve for 5 min.

Esparcir el espesante con número de revoluciones de medio a alto. Durante el tiempo de hinchamiento de aproximadamente 60 minutos dejar funcionar posteriormente el agitador. (someter a ensayo con el ensayo de placa de vidrio para determinar la ausencia de partículas); en caso de que existan aún partículas, debe agitarse posteriormente. Añadir tensioactivos, después alcoholes. Como último alimentar el perfume y examinar la mezcla de reacción para determinar los parámetros de liberación. Spread the thickener with medium to high speed. During the swelling time of approximately 60 minutes, let the stirrer run later. (test with the glass plate test to determine the absence of particles); if there are still particles, it should be stirred later. Add surfactants, then alcohols. As a last feed the perfume and examine the reaction mixture to determine the release parameters.

b). Fase de enzima b). Enzyme phase

Composición Composition

FAEOS-Na, C 12-14 + 2 OE 24,50 % tensioactivo básico alquil(C8-10)-1,5-glucósido 2,88 % co-tensioactivo / emulsionante 1,2-propanodiol 5,00 % emulsionante etanol al 96 %, desnaturalizado con el 1 % de MEK 5,00 % co-emulsionante hidroxietilcelulosa 0,45 % espesante FAEOS-Na, C 12-14 + 2 OE 24.50% basic alkyl surfactant (C8-10) -1,5-glycoside 2.88% co-surfactant / emulsifier 1,2-propanediol 5.00% emulsifier ethanol at 96%, denatured with 1% MEK 5.00% co-emulsifier hydroxyethylcellulose 0.45% thickener

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E01996653 E01996653

30-09-2015 09-30-2015

polisacárido / goma xantana polysaccharide / xanthan gum
0,22 % espesante 0.22% thickener

etanol al 96 %, desnaturalizado con 1 % de MEK 96% ethanol, denatured with 1% MEK
3,00 % aroma 3.00% scent

combinación de hemiacetal-isotiazolina hemiacetal-isothiazoline combination
0,05 % conservante 0.05% preservative

colorantes dyes
>1,0 % > 1.0%

agua del grifo tap water
añadir hasta 100 add up to 100

aproximadamente 3500 mPas, 20 ºC, Rotovisko LVT, husillo 2, 20 r/min pH 3,0, no diluida disolución transparente approximately 3500 mPas, 20 ° C, Rotovisko LVT, spindle 2, 20 r / min pH 3.0, undiluted clear solution

Preparación Preparation

Disponer agua. Con agitador en funcionamiento, añadir colorantes y conservantes y a continuación disolver durante 5 min. Esparcir el espesante con número de revoluciones de medio a alto. Durante el tiempo de hinchamiento de aproximadamente 60 minutos dejar funcionar posteriormente el agitador. Añadir tensioactivos, después alcoholes. Alimentar el perfume y los ácidos, como último añadir el estabilizador y peróxido de hidrógeno y examinar la mezcla de reacción para determinar los parámetros de liberación. Have water With stirrer running, add dyes and preservatives and then dissolve for 5 min. Spread the thickener with medium to high speed. During the swelling time of approximately 60 minutes, let the stirrer run later. Add surfactants, then alcohols. Feed the perfume and acids, finally add the stabilizer and hydrogen peroxide and examine the reaction mixture to determine the release parameters.

b.) Fase de principio activo espesada con poliacrilato b.) Active ingredient phase thickened with polyacrylate

Composición Composition

FAEOS-Na, C12-14 + 2 OE 10,10 % tensioactivo básico alquil(C8-10)-1,5-glucósido 2,50 % co-tensioactivo etanol al 96 %, desnaturalizado con 1 % de MEK 3,00 % co-emulsionante hidróxido de sodio (50 %) 1,50 % agente de neutralización aceite de perfume, nota cítrica 4,00 % aroma polímero de poliacrilato*1 0,80 % espesante agua desnaturalizada añadir hasta 100 *1 fabricante BF Goodrich, por ejemplo Carbopol ETD 2690 FAEOS-Na, C12-14 + 2 OE 10.10% basic alkyl surfactant (C8-10) -1,5-glycoside 2.50% co-surfactant 96% ethanol, denatured with 1% MEK 3.00% co-emulsifier sodium hydroxide (50%) 1.50% neutralizing agent perfume oil, citrus note 4.00% polyacrylate polymer aroma * 1.80% thickener denatured water add up to 100 * 1 manufacturer BF Goodrich, per example Carbopol ETD 2690

aproximadamente 3500 mPas, 20 ºC, Rotovisko LVT, husillo 2, 6 r/min pH 10,0, no diluida disolución transparente approximately 3500 mPas, 20 ° C, Rotovisko LVT, spindle 2, 6 r / min pH 10.0, undiluted clear solution

Preparación Preparation

Disponer agua. Esparcir espesante con número de revoluciones de medio a alto (aproximadamente 800 r/min). (someter a ensayo con el ensayo de placa de vidrio para determinar la ausencia de partículas); en caso de que aún existan partículas de polímero, debe agitarse posteriormente. Neutralizar la disolución con NaOH. Con número de revoluciones reducido introducir con agitación el aceite de perfume. Have water Spread thickener with medium to high speed (approximately 800 r / min). (test with the glass plate test to determine the absence of particles); In case there are still polymer particles, it should be stirred later. Neutralize the solution with NaOH. With reduced speed, introduce perfume oil with stirring.

Según la enseñanza adicional y de por sí independiente de la invención, que se refleja en las reivindicaciones 32 y siguientes, se trata de la configuración del lado superior del elemento de distribución fijo 6’ a modo de placa o de un correspondiente elemento de accionamiento móvil 6 a modo de placa. Esto se describe en relación con el dibujo por medio del elemento de distribución fijo 6’ a modo de placa, que presenta una zona de solicitación por la que fluye el líquido de lavado durante el proceso de lavado, encontrándose en contacto el interior de los recipientes de almacenamiento 2, 3 a través de los orificios de salida 4, eventualmente con disposición intermedia respectivamente de una disposición que impide un flujo libre del fluido de principio activo, de manera permanente con el elemento de distribución 6’. Puede pensarse sin más cómo han de transformarse las variantes en este caso propuestas en el caso del elemento de accionamiento móvil 6 a modo de placa de manera correspondiente. According to the additional and in itself independent teaching of the invention, which is reflected in claims 32 and following, it is the configuration of the upper side of the fixed distribution element 6 'as a plate or of a corresponding mobile actuating element 6 as a plate. This is described in relation to the drawing by means of the fixed distribution element 6 'as a plate, which has a solicitation area through which the washing liquid flows during the washing process, the interior of the containers being in contact of storage 2, 3 through the outlet orifices 4, possibly with intermediate arrangement respectively of an arrangement that prevents a free flow of the active ingredient fluid, permanently with the distribution element 6 '. It can be thought without further ado how the variants proposed in this case have to be transformed in the case of the mobile actuating element 6 as a plate correspondingly.

Tal como ha mostrado ya el correspondiente estado de la técnica (por ejemplo el documento WO 99/66140 A), el elemento de distribución a modo de placa 6’ presenta sobre el lado superior, de manera próxima a un borde longitudinal para los recipientes de almacenamiento 2 o 3 un punto de conexión 10 para su orificio de salida 4. En el ejemplo de realización representado está realizado el punto de conexión 10 en forma de estrella/en forma de cono a modo de punta para encajar a presión. Con la correspondiente viscosidad del fluido de principio activo resulta en este caso el juego deseado en el sentido de una distribución dirigida respectivamente de una cantidad parcial del fluido de principio activo en el líquido de lavado. As the corresponding state of the art has already shown (for example WO 99/66140 A), the plate-like distribution element 6 'has on the upper side, close to a longitudinal edge for the containers of storage 2 or 3 a connection point 10 for its outlet orifice 4. In the exemplary embodiment shown, the star-shaped / cone-shaped connection point 10 is made to fit under pressure. With the corresponding viscosity of the active ingredient fluid, in this case the desired play results in the direction of a directed distribution of a partial amount of the active ingredient fluid in the washing liquid respectively.

Está previsto ahora en este caso que los puntos de conexión 10 estén dispuestos de manera próxima al borde longitudinal distanciados uno junto a otro y por que el elemento de distribución 6’ presenta concavidades 11 sobre el lado superior partiendo de los puntos de conexión 10 y que llegan aproximadamente hasta el borde longitudinal opuesto, que sirven para la distribución de los fluidos de principio activo en el líquido de lavado. It is now provided in this case that the connection points 10 are arranged close to the longitudinal edge spaced apart from one another and that the distribution element 6 'has concavities 11 on the upper side starting from the connection points 10 and that they reach approximately the opposite longitudinal edge, which serve for the distribution of the active ingredient fluids in the washing liquid.

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Claims (1)

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ES01996653.0T 2000-11-17 2001-11-09 Distribution device for the distribution of active substance fluids Expired - Lifetime ES2548718T3 (en)

Applications Claiming Priority (11)

Application Number Priority Date Filing Date Title
DE10057325 2000-11-17
DE10057325 2000-11-17
DE10113036A DE10113036B4 (en) 2000-11-17 2001-03-17 Device for delivering fluids with active substances into flushing water in a toilet bowl, has storage containers with outlets arranged so that they deliver fluids only during each flushing operation
DE10113036 2001-03-17
DE20113329 2001-08-17
DE20113329U 2001-08-17
DE20116295 2001-10-04
DE20116295U 2001-10-04
DE20116963U 2001-10-16
DE20116963U DE20116963U1 (en) 2000-11-17 2001-10-16 Dispenser for dispensing active fluids
PCT/EP2001/012973 WO2002040787A1 (en) 2000-11-17 2001-11-09 Distributing device for distributing fluids containing active ingredients

Publications (1)

Publication Number Publication Date
ES2548718T3 true ES2548718T3 (en) 2015-10-20

Family

ID=27512401

Family Applications (2)

Application Number Title Priority Date Filing Date
ES01996653.0T Expired - Lifetime ES2548718T3 (en) 2000-11-17 2001-11-09 Distribution device for the distribution of active substance fluids
ES10168718T Expired - Lifetime ES2384348T3 (en) 2000-11-17 2001-11-09 Module for attaching to a dispensing device

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES10168718T Expired - Lifetime ES2384348T3 (en) 2000-11-17 2001-11-09 Module for attaching to a dispensing device

Country Status (7)

Country Link
EP (5) EP1334243B1 (en)
JP (1) JP2004520498A (en)
AT (1) ATE557139T1 (en)
AU (1) AU2002217013A1 (en)
DE (1) DE20116963U1 (en)
ES (2) ES2548718T3 (en)
WO (1) WO2002040787A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2372046A (en) * 2001-02-09 2002-08-14 Jeyes Group Ltd Liquid dispensing unit for a toilet bowl
DE10204928B4 (en) 2002-02-07 2004-04-01 Henkel Kgaa Dispensing device for dispensing an active fluid into the flushing liquid in a toilet bowl
WO2003078747A1 (en) 2002-03-12 2003-09-25 Robert Mcbride Limited Dispenser
DE10234781A1 (en) * 2002-07-30 2004-02-19 Henkel Kgaa Dispensing device for dispensing an active fluid into the flushing liquid in a toilet bowl
US6662380B1 (en) 2002-08-29 2003-12-16 S.C. Johnson & Son, Inc. Dual action toilet rim mounted toilet bowl cleaner
US6898806B2 (en) 2002-10-01 2005-05-31 Skot S.A. Chemical Products Device for dispensing a liquid active substance
DE20215129U1 (en) * 2002-10-01 2003-03-13 Skot S A Chemical Products Att Device for dispensing a liquid active substance
ITMI20022155A1 (en) * 2002-10-11 2004-04-12 Coengineering Srl AUTOMATIC DISPENSER WITH PREDOSED QUANTITY OF LIQUIDS OR GEL, FOR THE DISSEMINATION OF DISINFECTANT CLEANSING PRODUCTS OR PERFUME ESSENCES, IN THE SANITARY SERVICES.
DE10303155A1 (en) * 2003-01-27 2004-08-12 Henkel Kgaa Dispensing device for dispensing an active fluid into the flushing liquid in a toilet bowl
ITRE20030016A1 (en) 2003-02-17 2004-08-18 Re Le Vi Spa "MULTIPLE DISPENSER FOR LIQUID ACTIVE SUBSTANCES, FOR WC POT"
DE602004003101T2 (en) 2003-04-25 2007-02-15 S.C. Johnson & Son, Inc., Racine DEVICE APPLIED TO THE EDGE OF A TOILET BASIN FOR DELIVERING TWO LIQUIDS
GB0605023D0 (en) 2006-03-13 2006-04-19 Jeyes Group Ltd Liquid dispensing device
DE102008037723A1 (en) 2008-08-14 2010-02-25 Henkel Ag & Co. Kgaa Toilet basket with Spülwasserverteilelement

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1067472A (en) * 1912-10-14 1913-07-15 Fred A Creed Disinfectant-holder.
IT1030072B (en) * 1973-11-02 1979-03-30 Tamin El Sioufy DEVICE FOR THE DISINFECTION AND CHEMICAL CLEANING OF THE TOILET VESSEL
US4709424A (en) * 1985-05-10 1987-12-01 Dolan John E Automatic toilet bowl cleaner device
US4995555A (en) 1988-11-14 1991-02-26 American Cyanamid Company Air treatment device and method
GB9110746D0 (en) 1991-05-17 1991-07-10 Davies Raymond C Release device
NL9101759A (en) * 1991-10-22 1993-05-17 Sara Lee De Nv LIQUID CLEANER AND / OR FRESHENER FOR A TOILET POT.
NL1001722C2 (en) 1995-11-22 1997-05-23 Sara Lee De Nv Cleaning and refreshing unit intended to be hung on a toilet bowl rim.
DE775741T1 (en) 1995-11-22 1999-05-20 Sara Lee De Nv Freshener / cleaner system for toilets
DE19808669A1 (en) * 1998-03-02 1999-09-16 Buck Chemie Gmbh Cleaning device
DE19823338A1 (en) 1998-05-26 1999-12-09 Buck Chemie Gmbh Dispenser
JP4058239B2 (en) * 1998-06-15 2008-03-05 エス.シー. ジョンソン アンド サン、インコーポレイテッド Liquid dispensing
GB2345494A (en) * 1998-06-15 2000-07-12 Johnson & Son Inc S C Unit for dispensing a liquid into a toilet bowl
DE19912217C2 (en) 1999-01-12 2002-09-05 Jeyes Deutschland Gmbh Device for dispensing active substances in the flushing water, especially in toilet bowls
DE29902066U1 (en) * 1999-02-08 1999-04-22 Georg Menshen GmbH & Co KG, 57413 Finnentrop Device for conditioning rinsing liquid in sanitary facilities
DE19915322C1 (en) 1999-04-03 2001-01-18 Henkel Kgaa Under-rim device for cleaning and/or freshening toilets on flushing has openable and closable unit, eg of silicone or other rubber membrane, to allow re-filling without demounting
DE19930362C2 (en) 1999-07-01 2003-11-13 Henkel Kgaa Device for dispensing a liquid preparation of active substance into a toilet bowl
WO2001044591A1 (en) * 1999-12-14 2001-06-21 S.C. Johnson & Son, Inc. Improved liquid dispensing toilet bowl cleaner

Also Published As

Publication number Publication date
EP2230358A3 (en) 2011-01-12
EP1334243B1 (en) 2015-07-15
EP2230358A2 (en) 2010-09-22
DE20116963U1 (en) 2002-03-28
EP1334243A1 (en) 2003-08-13
ES2384348T3 (en) 2012-07-04
EP1936051A3 (en) 2012-04-11
ATE557139T1 (en) 2012-05-15
WO2002040787A1 (en) 2002-05-23
EP1936049A2 (en) 2008-06-25
JP2004520498A (en) 2004-07-08
WO2002040787B1 (en) 2002-09-06
EP1936050A2 (en) 2008-06-25
EP1936049A3 (en) 2012-04-11
EP1936051A2 (en) 2008-06-25
EP2230358B1 (en) 2012-05-09
AU2002217013A1 (en) 2002-05-27
EP1936049B1 (en) 2013-10-16
EP1936050A3 (en) 2012-04-11

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