ES2524540T3 - Un procedimiento para generar una salida seleccionada de H2 gas de síntesis, vapor y CO2 - Google Patents

Un procedimiento para generar una salida seleccionada de H2 gas de síntesis, vapor y CO2 Download PDF

Info

Publication number
ES2524540T3
ES2524540T3 ES10712240.0T ES10712240T ES2524540T3 ES 2524540 T3 ES2524540 T3 ES 2524540T3 ES 10712240 T ES10712240 T ES 10712240T ES 2524540 T3 ES2524540 T3 ES 2524540T3
Authority
ES
Spain
Prior art keywords
reactor
production
reducer
oxidizer
cas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES10712240.0T
Other languages
English (en)
Inventor
John H. Chiu
Gregory N. Liljedahl
Paul R. Thibeault
Carl R. Bozzuto
Corinne Beal
Michal T. Bialkowski
Andreas Brautsch
Michel Vandycke
Laurent Maghdissian
Jr. Herbert E. Andrus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Technology GmbH
Original Assignee
Alstom Technology AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alstom Technology AG filed Critical Alstom Technology AG
Application granted granted Critical
Publication of ES2524540T3 publication Critical patent/ES2524540T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/725—Redox processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
    • F23C2900/99008—Unmixed combustion, i.e. without direct mixing of oxygen gas and fuel, but using the oxygen from a metal oxide, e.g. FeO
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

Un procedimiento (10, 32, 52, 72, 92, 112, 130) selectivamente operable para fines de generación de al menos una salida (12, 13, 34, 54, 74, 94, 114, 132) predeterminada, basado en lo que es la naturaleza específica del fin principal del procedimiento (10, 32, 52, 72, 92, 112, 130) de sólidos calientes para el que se está produciendo al menos una salida (12, 13, 34, 54, 74, 94, 114, 132) predeterminada, que comprende: pre-seleccionar un fin principal del procedimiento (10, 32, 52, 72, 92, 112, 130) de sólidos calientes de un grupo de fines principales del procedimiento (10, 32, 52, 72, 92, 112, 130) de sólidos calientes, que incluye al menos dos de la generación de una materia prima tal como H2 para uso para fines de producción de energía eléctrica, la generación de Gas de Síntesis para uso para fines de producción de energía eléctrica así como para otros usos industriales, producción de vapor para generación de energía eléctrica así como para otros usos, producción de calor del procedimiento, la producción de CO2 para fines agrícolas y la generación de H2 para uso para la producción de hidrocarburos líquidos; proporcionar un primer reactor que pueda operar como un reactor (14, 36, 56, 76, 96, 116, 134) reductor; proporcionar un segundo reactor que pueda operar como un reactor (16, 38, 58, 78, 98, 118, 136) oxidante; suministrar como entradas al reactor (14, 36, 56, 76, 96, 116, 134) reductor tanto un combustible carbonoso sólido que contenga azufre como una fuente de calcio; suministrar aire como una entrada al reactor (16, 38, 58, 78, 98, 118, 136) oxidante; efectuar en el reactor (14, 36, 56, 76, 96, 116, 134) reductor con la fuente de calcio la captura del azufre en el combustible carbonoso sólido que contiene azufre para producir de ese modo CaS en el reactor (14, 36, 56, 76, 96, 116, 134) reductor; efectuar la descarga del CaS como una salida del reactor (14, 36, 56, 76, 96, 116, 134) reductor y suministrar después dicho CaS como una entrada al reactor (16, 38, 58, 78, 98, 118,136) oxidante; efectuar en el reactor (16, 38, 58, 78, 98, 118, 136) oxidante la producción de CaSO4 del CaS que se suministra como una entrada al reactor (16, 38, 58, 78, 98, 118, 136) oxidante; efectuar la descarga del CaSO4 que se produce en el reactor (16, 38, 58, 78, 98, 118, 136) oxidante como una salida del reactor (16, 38, 58, 78, 98, 118,136) oxidante y después suministrar dicho CaSO4 como una entrada al reactor (14, 36, 56, 76, 96,116,134) reductor; generar selectivamente al menos una salida (12, 13, 34, 54, 74, 94, 114,132) predeterminada basada en lo que es la naturaleza específica del fin principal del procedimiento (10, 32, 52, 72, 92,112,130) de sólidos calientes, para el que se está produciendo al menos una salida (12, 13, 34, 54, 74, 94, 114, 132) predeterminada de la realización de uno de lo siguiente, en el que se utiliza CaSO4 en el reactor (14, 36, 56, 76, 96, 116, 134) reductor tanto como una fuente de oxígeno como como una fuente de calor para efectuar de ese modo la generación en el reactor (14, 36, 56, 76, 96, 116, 134) reductor de al menos una salida predeterminada del combustible carbonoso sólido que contiene azufre y en el que se quema CaS en una reacción de liberación de calor en el reactor (16, 38, 58, 78, 98, 118, 136) oxidante para efectuar la generación de al menos una salida predeterminada en el reactor (16, 38, 58, 78, 98, 118,136) oxidante del calor liberado durante la calcinación del CaS en el reactor (16, 38, 58, 78, 98,118, 136) oxidante; efectuar la descarga de al menos una salida (12, 13, 34, 54, 74, 94, 114, 132) predeterminada que se genera selectivamente en uno de, el reactor (14, 36, 56, 76, 96, 116, 134) reductor y el reactor (16, 38, 58, 78, 98, 118, 136) oxidante y, suministrar agua de alimentación como una entrada adicional al reactor (16, 38, 58, 78, 98, 118, 136) oxidante, en el que la naturaleza específica del fin principal preseleccionado del procedimiento para el que se está produciendo al menos una salida predeterminada es la producción de vapor (28, 44, 64, 144) para generación de energía eléctrica así como para otros usos.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
imagen7
imagen8

Claims (1)

  1. imagen1
    imagen2
ES10712240.0T 2009-03-31 2010-03-30 Un procedimiento para generar una salida seleccionada de H2 gas de síntesis, vapor y CO2 Active ES2524540T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US749221 1991-08-23
US165094P 1999-11-12
US16509409P 2009-03-31 2009-03-31
US12/749,221 US8562933B2 (en) 2009-03-31 2010-03-29 Hot solids process selectively operable based on its primary purpose
PCT/US2010/029191 WO2010117778A2 (en) 2009-03-31 2010-03-30 A hot solids process selectively operable based on its primary purpose

Publications (1)

Publication Number Publication Date
ES2524540T3 true ES2524540T3 (es) 2014-12-10

Family

ID=42936811

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10712240.0T Active ES2524540T3 (es) 2009-03-31 2010-03-30 Un procedimiento para generar una salida seleccionada de H2 gas de síntesis, vapor y CO2

Country Status (9)

Country Link
US (1) US8562933B2 (es)
EP (1) EP2414288B1 (es)
JP (1) JP2012522121A (es)
CN (1) CN102449120A (es)
AU (1) AU2010234841B2 (es)
CA (1) CA2757280C (es)
ES (1) ES2524540T3 (es)
PL (1) PL2414288T3 (es)
WO (1) WO2010117778A2 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100281769A1 (en) * 2009-03-31 2010-11-11 Alstom Technology Ltd. Hot solids process selectively operable based on the type of application that is involved
US9951689B2 (en) * 2014-07-17 2018-04-24 Saudi Arabian Oil Company Integrated calcium looping combined cycle for sour gas applications
CN106118699A (zh) * 2016-06-17 2016-11-16 昆明理工大学 一种利用磷石膏制备合成气的方法
US11434132B2 (en) 2019-09-12 2022-09-06 Saudi Arabian Oil Company Process and means for decomposition of sour gas and hydrogen generation

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2602809A (en) 1948-07-10 1952-07-08 Kellogg M W Co Treatment of solid carbon containing materials to produce carbon monoxide for the synthesis of organic materials
US3969089A (en) 1971-11-12 1976-07-13 Exxon Research And Engineering Company Manufacture of combustible gases
DE2624302A1 (de) 1976-05-31 1977-12-22 Metallgesellschaft Ag Verfahren zur durchfuehrung exothermer prozesse
GB2039293B (en) * 1979-01-09 1982-11-17 Exxon Research Engineering Co Conversion of fuel to reducing and/or synthesis gas
US4272399A (en) 1979-09-21 1981-06-09 Monsanto Company Conversion of carbon-containing materials to synthesis gas
EP0061326B1 (en) 1981-03-24 1985-06-19 Exxon Research And Engineering Company Apparatus for converting a fuel into combustible gas
US4704136A (en) 1984-06-04 1987-11-03 Freeport-Mcmoran Resource Partners, Limited Partnership Sulfate reduction process useful in coal gasification
US4602573A (en) 1985-02-22 1986-07-29 Combustion Engineering, Inc. Integrated process for gasifying and combusting a carbonaceous fuel
GB8600615D0 (en) 1986-01-11 1986-02-19 Moss G Non-polluting method of burning fuel
CA2127394A1 (en) 1993-07-12 1995-01-13 William Martin Campbell Transport gasifier
US6083862A (en) 1994-03-14 2000-07-04 Iowa State University Research Foundation, Inc. Cyclic process for oxidation of calcium sulfide
US5533471A (en) 1994-08-17 1996-07-09 A. Ahlstrom Corporation fluidized bed reactor and method of operation thereof
MXPA04011590A (es) 2002-05-22 2005-07-05 Mfg & Tech Conversion Int Inc Proceso y aparato de gasificacion pulsada y de limpieza mediante gas caliente.
US7083658B2 (en) * 2003-05-29 2006-08-01 Alstom Technology Ltd Hot solids gasifier with CO2 removal and hydrogen production
US20070000177A1 (en) 2005-07-01 2007-01-04 Hippo Edwin J Mild catalytic steam gasification process
JP2007091787A (ja) * 2005-09-27 2007-04-12 Chubu Electric Power Co Inc 流動床ガス化装置の運転方法及び流動床ガス化装置、石炭ガス化複合発電システム
JP5422098B2 (ja) * 2006-12-28 2014-02-19 一般財団法人石炭エネルギーセンター 流動床ガス化装置の運転方法及び流動床ガス化装置並びに石炭ガス化複合発電システム
US8110012B2 (en) 2008-07-31 2012-02-07 Alstom Technology Ltd System for hot solids combustion and gasification

Also Published As

Publication number Publication date
AU2010234841A1 (en) 2011-10-27
CA2757280C (en) 2014-01-21
AU2010234841B2 (en) 2015-11-26
EP2414288B1 (en) 2014-10-08
PL2414288T3 (pl) 2015-03-31
US8562933B2 (en) 2013-10-22
WO2010117778A2 (en) 2010-10-14
CN102449120A (zh) 2012-05-09
US20100284894A1 (en) 2010-11-11
JP2012522121A (ja) 2012-09-20
CA2757280A1 (en) 2010-10-14
WO2010117778A3 (en) 2011-03-31
EP2414288A2 (en) 2012-02-08

Similar Documents

Publication Publication Date Title
US8187568B2 (en) Method and plant for the production of synthesis gas from biogas
Prabowo et al. CO2-recycling biomass gasification system for highly efficient and carbon-negative power generation
US20080182298A1 (en) Method And System For The Transformation Of Molecules,To Transform Waste Into Useful Substances And Energy
PL411560A1 (pl) Sposób i układ wytwarzania biometanu i ekometanu oraz energii elektrycznej i cieplnej
ES2524540T3 (es) Un procedimiento para generar una salida seleccionada de H2 gas de síntesis, vapor y CO2
EP2511487A3 (en) Combined cycle power plant
EP2535542A3 (en) Systems and methods for improving the efficiency of a combined cycle power plant
EP2320049A3 (en) Gasification power generation system provided with carbon dioxide separation and recovery device
DE602007005603D1 (de) Kombinierter gas- und dampfturbinen-prozess mit integrierter kohlevergasung und vorheizung von stickstoff bzw. sauerstoff aus einer luftzerlegungsanlage
WO2008143078A1 (ja) 超臨界水バイオマス燃焼ボイラー
US20080166273A1 (en) Method And System For The Transformation Of Molecules, This Process Being Used To Transform Harmful And Useless Waste Into Useful Substances And Energy
CN102052102A (zh) 煤化学链燃烧发电工艺及其装置
CN108203077A (zh) 一种粗煤气变换工艺
RU2012117799A (ru) Способ эксплуатации электростанции igcc с интегрированным устройством для отделения co2
Calabrò et al. Possible optimal configurations for the ZECOMIX high efficiency zero emission hydrogen and power plant
Ajiwibowo et al. Co-production of hydrogen and power from black liquor via supercritical water gasification, chemical looping and power generation
JP2012522121A5 (es)
JP2009215608A (ja) 水素製造プラント
JP2011122490A (ja) 石炭ガス化複合発電設備
RU2587736C1 (ru) Установка для утилизации низконапорного природного и попутного нефтяного газов и способ её применения
CN201865710U (zh) 煤化学链燃烧发电装置
Hua et al. Packed Bed Chemical Looping Platform: Design and Operation of 30 kWth Pilot Unit
CN203782109U (zh) 一种污泥气化资源化利用系统
KR20130047570A (ko) 복합 발전 시스템
Darmawan et al. Co-production of hydrogen and power from palm mill wastes