ES2482915A2 - Pyrolysis of biomass in the production of biofuels - Google Patents

Pyrolysis of biomass in the production of biofuels Download PDF

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Publication number
ES2482915A2
ES2482915A2 ES201390104A ES201390104A ES2482915A2 ES 2482915 A2 ES2482915 A2 ES 2482915A2 ES 201390104 A ES201390104 A ES 201390104A ES 201390104 A ES201390104 A ES 201390104A ES 2482915 A2 ES2482915 A2 ES 2482915A2
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ES
Spain
Prior art keywords
production
biomass
lemna
biofuels
pyrolysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES201390104A
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Spanish (es)
Other versions
ES2482915B1 (en
ES2482915R1 (en
Inventor
John Daniel Elliott
David Allan Wedlake
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Foster Wheeler Inc
Amec Foster Wheeler USA Corp
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Foster Wheeler USA Corp
Foster Wheeler Inc
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Filing date
Publication date
Application filed by Foster Wheeler USA Corp, Foster Wheeler Inc filed Critical Foster Wheeler USA Corp
Publication of ES2482915A2 publication Critical patent/ES2482915A2/en
Publication of ES2482915R1 publication Critical patent/ES2482915R1/en
Application granted granted Critical
Publication of ES2482915B1 publication Critical patent/ES2482915B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
    • C10B55/02—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
    • C10B55/02—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials
    • C10B55/04—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials with moving solid materials
    • C10B55/08—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials with moving solid materials in dispersed form
    • C10B55/10—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material with solid materials with moving solid materials in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C10B57/045—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing mineral oils, bitumen, tar or the like or mixtures thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Abstract

Production of a biofuel from a feedstock that includes a solid biomass material such as lemna. Aquatic plants such as pre-processed or whole lemna serve as a rich source of lipids, carbohydrates, residual proteins, cellulose and other organic materials that have the potential to be converted to hydrocarbons. A hydrocarbon feedstock is fed into the coking process and reaction products generated from the thermal process are collected. A coke product has an isotropic structure.

Description

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P201390104 20-12-2013 P201390104 12-20-2013

rendimientos del líquido cada experimento se realizó a una presión baja de 15 psig y con cero reciclajes, es decir, ninguno. Las alimentaciones y los productos se analizaron. Los resultados se sometieron a revisión y análisis y la estructura del rendimiento neto de la biomasa se determinó por diferencia. Liquid yields each experiment was performed at a low pressure of 15 psig and with zero recycling, that is, none. Feeds and products were analyzed. The results were subject to review and analysis and the structure of the net biomass yield was determined by difference.

5 Se sometieron a ensayo concentraciones de suspensión con el 10 y el 20% en peso de biomasa en el residuo de petróleo. Este era el límite de la capacidad de la planta piloto. No obstante, en una unidad comercial, dependiendo de la capacidad de la unidad comercial, son posibles concentraciones superiores de hasta el 40 o 50% en peso o superior. 5 Suspension concentrations were tested with 10 and 20% by weight of biomass in the petroleum residue. This was the limit of the capacity of the pilot plant. However, in a commercial unit, depending on the capacity of the commercial unit, higher concentrations of up to 40 or 50% by weight or greater are possible.

10 La Tabla 2 a continuación muestra los resultados de la coquización de biomasa de la lenteja de agua en forma de mezcla al 10% con un residuo de ligero vacío. 10 Table 2 below shows the results of the biomass coking of the duckweed in the form of a 10% mixture with a slight vacuum residue.

Tabla 2 Table 2

Rendimiento y composición elemental de los productos de coquización de biomasa de la lenteja de agua Performance and elemental composition of biomass coke products from duckweed

% en peso % in weigh
Metales y Minerales C H N S O Total Metals and Minerals C H N S OR Total

Gas Gas
24,66 0,00 28,22 0,00 0,00 0,00 71,78 100,00 24.66 0.00 28.22 0.00 0.00 0.00 71.78 100.00

CO2 disuelto Dissolved CO2
0,51 0,00 27,27 0,00 0,00 0,00 72,73 100,00 0.51 0.00 27.27 0.00 0.00 0.00 72.73 100.00

NH3 NH3
3,41 0,00 0,00 17,65 82,35 0,00 0,00 100,00 3.41 0.00 0.00 17.65 82.35 0.00 0.00 100.00

H2O de reacción H2O reaction
17,34 0,00 0,00 11,11 0,00 0,00 88,89 100,00 17.34 0.00 0.00 11.11 0.00 0.00 88.89 100.00

H2S H2S
0,05 0,00 0,00 5,88 0,00 94,12 0,00 100,00 0.05 0.00 0.00 5.88 0.00 94.12 0.00 100.00

Producto Líquido Liquid Product
31,83 Mínimo 84,67 8,12 0,77 0,44 6,08 100,08 31.83 Minimum 84.67 8.12 0.77 0.44 6.08 100.08

Coque Coke
22,20 16,79 63,60 2,45 3,56 0,43 13,19 100,02 22.20 16.79 63.60 2.45 3.56 0.43 13.19 100.02

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Claims (1)

imagen1image 1 imagen2image2
ES201390104A 2011-06-23 2012-06-23 Process for the production of biofuels by coprocessing biomass in a thermal processing unit in a refinery. Active ES2482915B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161500250P 2011-06-23 2011-06-23
US61/500,250 2011-06-23
PCT/US2012/043906 WO2012178131A1 (en) 2011-06-23 2012-06-23 Pyrolysis of biomass in the production of biofuels

Publications (3)

Publication Number Publication Date
ES2482915A2 true ES2482915A2 (en) 2014-08-05
ES2482915R1 ES2482915R1 (en) 2014-10-28
ES2482915B1 ES2482915B1 (en) 2015-07-03

Family

ID=47360803

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201390104A Active ES2482915B1 (en) 2011-06-23 2012-06-23 Process for the production of biofuels by coprocessing biomass in a thermal processing unit in a refinery.

Country Status (11)

Country Link
US (1) US20120325641A1 (en)
EP (1) EP2723833A1 (en)
CN (1) CN103890145A (en)
BR (1) BR112013032849A2 (en)
CA (1) CA2840051A1 (en)
CL (1) CL2013003678A1 (en)
DE (1) DE112012002578T5 (en)
ES (1) ES2482915B1 (en)
MY (1) MY177107A (en)
WO (1) WO2012178131A1 (en)
ZA (1) ZA201309579B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10202557B2 (en) * 2014-12-19 2019-02-12 The United States Of America, As Represented By The Secretary Of Agriculture Methods of producing calcined coke from bio-oil and calcined coke produced thereby
EP3636729B1 (en) 2018-10-10 2021-11-24 BDI Holding GmbH Method for the preparation of coker coal
CN110548879A (en) * 2019-06-04 2019-12-10 北京化工大学 Preparation method and application of green synthetic novel iron-carbon material

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GB768209A (en) * 1954-05-11 1957-02-13 Exxon Research Engineering Co Control of bogging in fluidized coking of heavy hydrocarbon oils
GB1481799A (en) * 1973-11-30 1977-08-03 Coal Ind Manufacture of coke
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US5174891A (en) * 1991-10-29 1992-12-29 Conoco Inc. Method for producing isotropic coke
US6187147B1 (en) * 1998-05-15 2001-02-13 Conoco Inc. Delayed coker unit furnace
US6168709B1 (en) * 1998-08-20 2001-01-02 Roger G. Etter Production and use of a premium fuel grade petroleum coke
US20020179493A1 (en) * 1999-08-20 2002-12-05 Environmental & Energy Enterprises, Llc Production and use of a premium fuel grade petroleum coke
US7160437B2 (en) * 2002-12-04 2007-01-09 Exxonmobil Research And Engineering Company Method for determining the source of fouling in thermal conversion process units
US20070129450A1 (en) * 2005-11-18 2007-06-07 Barnicki Scott D Process for producing variable syngas compositions
FR2910485B1 (en) * 2006-12-22 2009-03-06 Inst Francais Du Petrole HYDROTREATMENT PROCESSES OF A MIXTURE CONSISTING OF OILS OF ANIMAL OR VEGETABLE ORIGIN AND OF PETROLEUM CUTTINGS WITH INTERMEDIATE STRIPING
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BRPI0803545A2 (en) * 2008-07-31 2010-06-15 Petroleo Brasileiro Sa bio-oil production process by biomass co-processing in delayed coking unit
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Also Published As

Publication number Publication date
DE112012002578T5 (en) 2014-08-07
EP2723833A1 (en) 2014-04-30
BR112013032849A2 (en) 2017-02-21
CN103890145A (en) 2014-06-25
ES2482915B1 (en) 2015-07-03
CL2013003678A1 (en) 2014-06-20
MY177107A (en) 2020-09-07
ES2482915R1 (en) 2014-10-28
US20120325641A1 (en) 2012-12-27
WO2012178131A1 (en) 2012-12-27
CA2840051A1 (en) 2012-12-27
ZA201309579B (en) 2015-09-30

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