ES2379140B1 - GLASS CERAMICS. - Google Patents
GLASS CERAMICS. Download PDFInfo
- Publication number
- ES2379140B1 ES2379140B1 ES201001272A ES201001272A ES2379140B1 ES 2379140 B1 ES2379140 B1 ES 2379140B1 ES 201001272 A ES201001272 A ES 201001272A ES 201001272 A ES201001272 A ES 201001272A ES 2379140 B1 ES2379140 B1 ES 2379140B1
- Authority
- ES
- Spain
- Prior art keywords
- glass
- epoxy
- layer
- polyurethane
- application
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002241 glass-ceramic Substances 0.000 title claims 4
- 239000011521 glass Substances 0.000 claims abstract description 37
- 239000004593 Epoxy Substances 0.000 claims abstract description 32
- 239000004814 polyurethane Substances 0.000 claims abstract description 31
- 229920002635 polyurethane Polymers 0.000 claims abstract description 31
- 239000004917 carbon fiber Substances 0.000 claims abstract description 13
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 8
- 239000003365 glass fiber Substances 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 5
- 238000009408 flooring Methods 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- 230000001464 adherent effect Effects 0.000 claims description 3
- 239000000047 product Substances 0.000 claims 6
- 238000006243 chemical reaction Methods 0.000 claims 4
- 239000000835 fiber Substances 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 3
- 229920005989 resin Polymers 0.000 claims 3
- 239000011347 resin Substances 0.000 claims 3
- 239000003822 epoxy resin Substances 0.000 claims 2
- 229920000647 polyepoxide Polymers 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- 238000001723 curing Methods 0.000 claims 1
- 230000007547 defect Effects 0.000 claims 1
- 150000004985 diamines Chemical class 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 239000011152 fibreglass Substances 0.000 claims 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000003223 protective agent Substances 0.000 claims 1
- 230000001681 protective effect Effects 0.000 claims 1
- 239000000178 monomer Substances 0.000 abstract description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract description 2
- 239000007921 spray Substances 0.000 abstract description 2
- 239000013078 crystal Substances 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052572 stoneware Inorganic materials 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000007519 figuring Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000010804 inert waste Substances 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
Sobre una superficie de cristal, (1), aplicamos una capa de poliuretano (2) coloreado, por aspersión por aire. La imprimación se deja secar, hasta su total adherencia al cristal. A continuación se aplica por el mismo sistema, una capa de epoxi, (3) que se reacciona con la capa de poliuretano sin mezclarse, uniéndose los monómeros del uretano con los monómeros de epoxi para polimerizar ambos y formar una interfase.#Para otorgarle una mayor consistencia y seguridad, aplicamos sobre la capa de epoxi, una malla de fibra de carbono o de vidrio (4), y aplicamos de nuevo otra capa de epoxi (5), de manera que la malla de fibra de carbono o de vidrio, queda entre las dos capas de epoxi, formando un conjunto solidario, de máxima resistencia, y que a su vez, han quedado adheridas a la capa de poliuretano y el cristal.On a glass surface, (1), we apply a colored polyurethane layer (2), by air spray. The primer is allowed to dry, until its total adhesion to the glass. Next, an epoxy layer is applied by the same system, (3) that reacts with the polyurethane layer without mixing, joining the urethane monomers with the epoxy monomers to polymerize both and form an interface. greater consistency and safety, we apply on the epoxy layer, a carbon fiber or glass mesh (4), and again apply another epoxy layer (5), so that the carbon fiber or glass mesh, It is between the two layers of epoxy, forming a solidarity assembly, of maximum resistance, and which in turn, have been adhered to the polyurethane layer and the glass.
Description
Cerámica de cristal. Ceramic glass.
La presente invención se refiere a un material compuesto de cristal, poliuretano, epoxi y malla de fibra de carbono ó vidrio, de manera que el conjunto se comporta con las mismas prestaciones que la cerámica, pero con la luminosidad y alto brillo del cristal. El presente proceso, se incluye en el sector nuevos materiales y supone un avance cualitativo en los procesos conocidos hasta ahora, en el mundo de los solados y revestimientos, cuyas mejoras suponen un ahorro térmico en los edificios, por la facultad de reflexión térmica del cristal y la facilidad de colocación sobre los elementos de soporte preexistentes, lo que elimina residuos de inertes en de los desescombros. The present invention relates to a composite material of glass, polyurethane, epoxy and carbon fiber or glass mesh, so that the assembly behaves with the same performance as ceramics, but with the luminosity and high brightness of the glass. The present process includes new materials in the sector and represents a qualitative advance in the processes known so far, in the world of flooring and cladding, whose improvements imply a thermal saving in buildings, by the power of thermal reflection of the glass and the ease of placement on the pre-existing support elements, which eliminates inert waste in the debris.
Antecedentes de la invención Background of the invention
Los revestimientos y solados de las viviendas, tanto en viviendas de nueva construcción, como en reformas de viviendas ya construidas, es una de las áreas de innovación más importantes en la economía de los países. The coatings and floorings of homes, both in newly built homes, and in renovations of already built homes, is one of the most important areas of innovation in the economy of the countries.
En muy pocas décadas, hemos pasado de los azulejos tradicionales de pasta roja, al gres y del gres al porcelanico. Esta evolución innovadora de los revestimientos, han ido mejorando las prestaciones de absorción, dureza y decoración. En los últimos avances técnicos, se ha conseguido en el mundo de la cerámica acabados de pizarra, de madera y últimamente de reflejos tipo cristal, en el avance continuo de presentar nuevos productos y diseños al mercado. Dentro de la búsqueda de nuevos materiales para revestimientos y solados, con prestaciones de absorción cero, resistencia al impacto, dureza y estética, que mejoren los materiales ya existentes, es donde debemos encuadrar la presente invención. In a few decades, we have gone from traditional red-paste tiles, stoneware and porcelain stoneware. This innovative evolution of coatings has improved absorption, hardness and decoration performance. In the latest technical advances, slate finishes, wood finishes and lately glass-like reflections have been achieved in the world of ceramics, in the continuous advance of presenting new products and designs to the market. Within the search for new materials for coatings and flooring, with zero absorption benefits, impact resistance, hardness and aesthetics, which improve existing materials, is where we should frame the present invention.
Descripción de la invención Description of the invention
Sobre una superficie de un cristal, aplicamos una capa de poliuretano con color, que queda adherido al cristal, dada las propiedades adherentes del poliuretano. Por la cara transparente, donde no se ha producido la imprimación, el cristal trasmite el color del poliuretano aplicado, otorgándole una imagen de profundidad y color. Para fijar el poliuretano al cristal y hacerlo totalmente impermeable, se aplica una primera capa de epoxi, que fija el poliuretano y forma un cuerpo con el mismo, reaccionando de manera superficial sin mezclarse, formando una interfase. Para conseguir que el cristal sea de seguridad y en caso de impacto, no se fraccione en pequeños cristales que pueda ocasionar su rotura, se coloca una malla de carbono ó fibra de vidrio en toda la superficie del cristal. En la última fase, se aplica otra capa de epoxi, que une y compacta la malla, entre las dos capas de epoxi, que a su vez han quedado adheridas al poliuretano y al cristal. On a surface of a glass, we apply a color polyurethane layer, which is adhered to the glass, given the adherent properties of the polyurethane. On the transparent face, where the primer has not been produced, the crystal transmits the color of the applied polyurethane, giving it an image of depth and color. To fix the polyurethane to the glass and make it completely waterproof, a first epoxy layer is applied, which fixes the polyurethane and forms a body with it, reacting on a surface without mixing, forming an interface. To ensure that the glass is safe and in case of impact, do not break up into small crystals that may cause it to break, a carbon or glass fiber mesh is placed on the entire surface of the glass. In the last phase, another epoxy layer is applied, which joins and compacts the mesh, between the two epoxy layers, which in turn have been adhered to the polyurethane and the glass.
Estado de la técnica State of the art
Existen numerosos procesos que buscan la coloración del cristal, figurando entre ello, la utilización de fundentes, como plomo, cobalto, níquel etc., en la formación del vidrio ó cristal. There are numerous processes that seek the coloration of the crystal, figuring among them, the use of fluxes, such as lead, cobalt, nickel etc., in the formation of glass or crystal.
Asimismo, también se han formulado soluciones para aplicar a la cerámica una película reflectante que busca el efecto cristal. De la misma forma se han buscado pinturas ó pigmentos que permitan dar color a los cristales trasparentes. Likewise, solutions have also been formulated to apply a reflective film to ceramics that seeks the crystal effect. In the same way, paints or pigments have been sought to give color to the transparent crystals.
La característica esencial de la presente invención, consiste en crear un solo cuerpo que teniendo las características de dureza, brillo, profundidad y reflejo de los cristales, se pueda aplicar el color, formando un cuerpo compacto, con el poliuretano, la malla y el epoxi, que den la resistencia al impacto y la adherencia para alicatados y solados. The essential feature of the present invention is to create a single body that having the characteristics of hardness, brightness, depth and reflection of the crystals, the color can be applied, forming a compact body, with polyurethane, mesh and epoxy , which give impact resistance and adhesion for tiling and flooring.
De todo lo descrito se desprenden las ventajas que presenta con respecto a otras realizaciones precedentes, debido a la dureza resistencia y adherencia que supone una mejora. From all of the above, the advantages that it presents with respect to other preceding embodiments are apparent, due to the hardness, resistance and adhesion that an improvement implies.
Breve descripción de los dibujos Brief description of the drawings
En la figura 1, se describe la invención. Así el 1) es el cristal. El 2) es el poliuretano coloreado que se proyecta. El 3), es la imprimación del epoxi, sobre el poliuretano. El 4) es la malla de fibra de carbono ó de vidrio. El 5) es la segunda imprimación de epoxi sobre la malla de fibra de carbono ó de vidrio. In Figure 1, the invention is described. Thus 1) is the crystal. 2) is the colored polyurethane that is projected. 3), is the primer of the epoxy, on the polyurethane. 4) is the carbon fiber or glass mesh. 5) is the second epoxy primer on the carbon fiber or glass mesh.
Descripción de la forma de realización preferida Description of the preferred embodiment
Sobre una superficie de cristal, (1) previamente desengrasada y sin partículas de volátiles, aplicamos una capa de poliuretano (2) coloreado, mediante un sistema de aspersión por aire, que proyecta el poliuretano de una forma continua sobre la superficie del cristal. La imprimación se deja secar para que se evaporen los compuestos orgánicos volátiles, hasta su total adherencia al cristal. Una vez evaporados los compuestos orgánicos volátiles, se aplica por el mismo sistema de aspersión por aire, una capa de epoxi, (3) que se reacciona con la capa de poliuretano sin mezclarse, uniéndose los monómeros del uretano: On a glass surface, (1) previously degreased and without volatile particles, we apply a colored polyurethane layer (2), by means of an air sprinkler system, which projects the polyurethane continuously on the surface of the glass. The primer is allowed to dry so that the volatile organic compounds evaporate, until their total adhesion to the glass. Once the volatile organic compounds have evaporated, an epoxy layer is applied by the same air spray system, (3) that reacts with the polyurethane layer without mixing, joining the urethane monomers:
con los monómeros de epoxi para polimerizar ambos y formar una interfase. with the epoxy monomers to polymerize both and form an interface.
Para otorgarle una mayor consistencia y seguridad al conjunto del material, aplicamos sobre la capa de epoxi, una malla de fibra de carbono ó de vidrio (4). Sobre la malla de fibra de carbono ó de vidrio, aplicamos de nuevo otra capa de epoxi (5), de manera que la malla de fibra de carbono ó de vidrio, queda entre las dos capas de epoxi, formando un conjunto solidario, de máxima resistencia, y que a su vez, han quedado adheridas a la capa de poliuretano y el cristal. To give greater consistency and safety to the material as a whole, we apply a carbon fiber or glass mesh (4) onto the epoxy layer. On the carbon fiber or glass mesh, we apply another layer of epoxy (5), so that the carbon fiber or glass mesh is between the two epoxy layers, forming a joint, maximum resistance, and that in turn, have been adhered to the polyurethane layer and the glass.
Serán independientes del objeto de la invención, la forma de aplicación de materiales empleados así como las dimensiones y detalles accesorios, siempre y cuando no afecten a la esencialidad. They will be independent of the object of the invention, the form of application of materials used as well as the dimensions and accessory details, as long as they do not affect the essentiality.
Claims (2)
- --
- A la capa de epoxi, se une una malla de fibra vidrio ó de fibra de carbono y se proyecta sobre la malla y la capa de epoxi, otra capa de epoxi, para formar un conjunto que le elasticidad, resistencia al impacto y dureza. To the epoxy layer, a glass fiber or carbon fiber mesh is attached and projected onto the mesh and the epoxy layer, another epoxy layer, to form an assembly that gives it elasticity, impact resistance and hardness.
- Categoría Category
- 56 Documentos citados Reivindicaciones afectadas 56 Documents cited Claims Affected
- A TO
- GB 2248208 A (MITCHELL PATRICK et al.) 01.04.1992, 1-2 GB 2248208 A (MITCHELL PATRICK et al.) 01.04.1992, 1-2
- reivindicaciones 2,6. claims 2.6.
- A TO
- US 2006252328 A1 (BINGENHEIMER MEL) 09.11.2006, 1-2 US 2006252328 A1 (BINGENHEIMER MEL) 09.11.2006, 1-2
- reivindicaciones 1,7. claims 1.7.
- A TO
- US 2009197026 A1 (VILATO PABLO et al.) 06.08.2009, 1-2 US 2009197026 A1 (VILATO PABLO et al.) 06.08.2009, 1-2
- reivindicaciones 1,4,10. claims 1,4,10.
- A TO
- US 3616185 A (GOLDBERG SAMUEL) 26.10.1971, 1-2 US 3616185 A (GOLDBERG SAMUEL) 26.10.1971, 1-2
- reivindicaciones 1-2. claims 1-2.
- A TO
- BASE DE DATOS WPI EN EPOQUE, AN 1993-216241, 1-2 WPI DATA BASE IN EPOQUE, AN 1993-216241, 1-2
- JP 5138815 A (MITSUBOSHI BELTING LTD) 08.06.1993, resumen. JP 5138815 A (MITSUBOSHI BELTING LTD) 08.06.1993, summary.
- Categoría de los documentos citados X: de particular relevancia Y: de particular relevancia combinado con otro/s de la misma categoría A: refleja el estado de la técnica O: referido a divulgación no escrita P: publicado entre la fecha de prioridad y la de presentación de la solicitud E: documento anterior, pero publicado después de la fecha de presentación de la solicitud Category of the documents cited X: of particular relevance Y: of particular relevance combined with other / s of the same category A: reflects the state of the art O: refers to unwritten disclosure P: published between the priority date and the date of priority submission of the application E: previous document, but published after the date of submission of the application
- El presente informe ha sido realizado • para todas las reivindicaciones • para las reivindicaciones nº: This report has been prepared • for all claims • for claims no:
- Fecha de realización del informe 20.03.2012 Date of realization of the report 20.03.2012
- Examinador J. García Cernuda Gallardo Página 1/4 Examiner J. García Cernuda Gallardo Page 1/4
- Novedad (Art. 6.1 LP 11/1986) Novelty (Art. 6.1 LP 11/1986)
- Reivindicaciones Reivindicaciones 1-2 SI NO Claims Claims 1-2 IF NOT
- Actividad inventiva (Art. 8.1 LP11/1986) Inventive activity (Art. 8.1 LP11 / 1986)
- Reivindicaciones Reivindicaciones 1-2 SI NO Claims Claims 1-2 IF NOT
- Documento Document
- Número Publicación o Identificación Fecha Publicación Publication or Identification Number publication date
- D01 D01
- GB 2248208 A (MITCHELL PATRICK et al.) 01.04.1992 GB 2248208 A (MITCHELL PATRICK et al.) 01.04.1992
- D02 D02
- US 2006252328 A1 (BINGENHEIMER MEL) 09.11.2006 US 2006252328 A1 (BINGENHEIMER MEL) 09.11.2006
- D03 D03
- US 2009197026 A1 (VILATO PABLO et al.) 06.08.2009 US 2009197026 A1 (VILATO PABLO et al.) 06.08.2009
- D04 D04
- US 3616185 A (GOLDBERG SAMUEL) 26.10.1971 US 3616185 A (GOLDBERG SAMUEL) 10/26/1971
- D05 D05
- JP 5138815 A (MITSUBOSHI BELTING LTD) 08.06.1993 JP 5138815 A (MITSUBOSHI BELTING LTD) 08.06.1993
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES201001272A ES2379140B1 (en) | 2010-09-27 | 2010-09-27 | GLASS CERAMICS. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES201001272A ES2379140B1 (en) | 2010-09-27 | 2010-09-27 | GLASS CERAMICS. |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2379140A1 ES2379140A1 (en) | 2012-04-23 |
ES2379140B1 true ES2379140B1 (en) | 2013-03-04 |
Family
ID=45922925
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES201001272A Expired - Fee Related ES2379140B1 (en) | 2010-09-27 | 2010-09-27 | GLASS CERAMICS. |
Country Status (1)
Country | Link |
---|---|
ES (1) | ES2379140B1 (en) |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3616185A (en) * | 1970-06-17 | 1971-10-26 | Samuel Goldberg | Glass fiber articles with a protective layer of polyurethane and method of preparation |
GB2248208B (en) * | 1990-09-27 | 1995-05-24 | Patrick Mitchell | Reinforced translucent panel |
JP2661653B2 (en) * | 1991-11-20 | 1997-10-08 | 三ツ星ベルト株式会社 | Mat molded products |
US20060252328A1 (en) * | 2004-01-13 | 2006-11-09 | Mel Bingenheimer | Fiber reinforced resin/construction and method for providing blast absorption and deflection characteristics and associated fastening system utilized with such a contruction |
FR2872507B1 (en) * | 2004-07-02 | 2007-05-18 | Eurokera | PROCESSING COMPOSITION OF A VITROCERAMIC FOR IMPROVING THE MECHANICAL RESISTANCE BY HEALING SURFACE DEFECTS, CORRESPONDING PROCESSING METHODS AND TREATED VITROCERAMIC PRODUCTS OBTAINED |
-
2010
- 2010-09-27 ES ES201001272A patent/ES2379140B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ES2379140A1 (en) | 2012-04-23 |
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