ES2181605A1 - Cation tiopirilio y derivados de dicho cation atrapados en un materialzeolitico. - Google Patents

Cation tiopirilio y derivados de dicho cation atrapados en un materialzeolitico.

Info

Publication number
ES2181605A1
ES2181605A1 ES200101839A ES200101839A ES2181605A1 ES 2181605 A1 ES2181605 A1 ES 2181605A1 ES 200101839 A ES200101839 A ES 200101839A ES 200101839 A ES200101839 A ES 200101839A ES 2181605 A1 ES2181605 A1 ES 2181605A1
Authority
ES
Spain
Prior art keywords
cation
thiopyryl
trapped
zeolitic material
derivatives
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200101839A
Other languages
English (en)
Other versions
ES2181605B1 (es
Inventor
Rodriguez Mercedes Alvaro
Gomez Hermenegildo Garcia
Pillai Manoj Narayana
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universidad Politecnica de Valencia
Original Assignee
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universidad Politecnica de Valencia filed Critical Universidad Politecnica de Valencia
Priority to ES200101839A priority Critical patent/ES2181605B1/es
Priority to AT02764894T priority patent/ATE375822T1/de
Priority to PCT/ES2002/000377 priority patent/WO2003011456A1/es
Priority to DE60223055T priority patent/DE60223055D1/de
Priority to EP02764894A priority patent/EP1424127B1/en
Publication of ES2181605A1 publication Critical patent/ES2181605A1/es
Application granted granted Critical
Publication of ES2181605B1 publication Critical patent/ES2181605B1/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0218—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39—Photocatalytic properties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D335/00—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom
    • C07D335/02—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0254—Nitrogen containing compounds on mineral substrates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Cosmetics (AREA)

Abstract

Catión tiopirilio y derivados de dicho catión atrapados en un material zeolítico. La presente invención se refiere a un material que comprende un catión orgánico atrapado en un soporte caracterizado porque dicho catión está seleccionado entre un catión tiopirilio, un derivado de un catión tiopirilio y mezclas de ellos, y dicho catión está atrapado en un material zeolítico, tal como una zeolita o aluminosilicato poroso estructurado. Preferentemente el catión es 2,4,6-trifeniltiopirilio. La invención se refiere también a un procedimiento para preparar un material que comprende al menos un catión tiopirilio o un derivado de un catión tiopirilio atrapado en un material zeolítico tal como una zeolita o aluminosilicato poroso estructurado, caracterizado porque comprende una adsorción directa del catión desde disolución o una síntesis de "barco-en- botella".
ES200101839A 2001-07-27 2001-07-27 Cation tiopirilio y derivados de dicho cation atrapados en un materialzeolitico. Expired - Lifetime ES2181605B1 (es)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ES200101839A ES2181605B1 (es) 2001-07-27 2001-07-27 Cation tiopirilio y derivados de dicho cation atrapados en un materialzeolitico.
AT02764894T ATE375822T1 (de) 2001-07-27 2002-07-26 Thiopyrylkation und derivate davon, eingeschlossen in einem zeolithischen material
PCT/ES2002/000377 WO2003011456A1 (es) 2001-07-27 2002-07-26 Catión tiopirilio y derivados de dicho catión atrapados en un material zeolítico
DE60223055T DE60223055D1 (de) 2001-07-27 2002-07-26 Thiopyrylkation und derivate davon, eingeschlossen in einem zeolithischen material
EP02764894A EP1424127B1 (en) 2001-07-27 2002-07-26 Thiopyryl cation and derivatives of same trapped in a zeolitic material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200101839A ES2181605B1 (es) 2001-07-27 2001-07-27 Cation tiopirilio y derivados de dicho cation atrapados en un materialzeolitico.

Publications (2)

Publication Number Publication Date
ES2181605A1 true ES2181605A1 (es) 2003-02-16
ES2181605B1 ES2181605B1 (es) 2004-01-16

Family

ID=8498648

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200101839A Expired - Lifetime ES2181605B1 (es) 2001-07-27 2001-07-27 Cation tiopirilio y derivados de dicho cation atrapados en un materialzeolitico.

Country Status (5)

Country Link
EP (1) EP1424127B1 (es)
AT (1) ATE375822T1 (es)
DE (1) DE60223055D1 (es)
ES (1) ES2181605B1 (es)
WO (1) WO2003011456A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102847557B (zh) * 2012-09-18 2014-02-26 山东大学 一种y型沸石固载磷钨酸的瓶中船型催化剂及其制备方法
CN108927206A (zh) * 2018-07-10 2018-12-04 大连理工大学 金属掺杂介孔分子筛的制备方法及其用途

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
A. CORMA et al. "Carbocations and organic radical cations inside zeolite matrices: Generation, characterization, stability and properties", Topics in Catalysis, 1998, Vol. 6 (1-4), pßginas 127-140, apartados 3 y 4. *
A. CORMA et al. "Highly Efficient Photoinduced Electron Transfer with 2,4,6-Triphenylpyrylium Cation Incorporated inside Extra Large Pore Zeotype MCM-41", J. Am. Chem. Soc., 1994, Vol. 116, Nö 21, páginas 9767-9768. *
A. CORMA et al. "Photoinduced Electron transfer within Zeolite Cavities: cis-Stilbene Isomerization Photosensitized by 2,4,6-Triphenylpyrylium Cation Imprisoned inside Zeolite Y", J. Am. Chem. Soc., 1994, Vol. 116, Nö 6, páginas 2276-2280. *
A. SANJUAN et al. "An organic sensitizer within Ti-zeolites as photocatalyst for the selective oxidation of olefins using oxygen and water as reagents", Chem. Comm., 1999, Vol. 17, pßginas 1641-1642. *
M.L. CANO et al. "Intrazeolite Photochemistry. 13. Photophysical properties of bulky 2,4,6-Triphenylpyrylium and Tritylium cations with large- and extra-large pore Zeolites", J. Phys. Chem., 1996, Vol. 100, Nö 46, páginas 18152-18157. *
R. WIZINGER et al. "Thiapyrylium salts", Helv. Chim. Acta., 1956, Vol. 39, Nö 22-23, páginas 207-216. *
S. PARRET et al. "Fluorescence properties of Pyrylium and Thiopyrylium salts", Bull. Chem. Soc. Japan, 1995, Vol. 68, Nö 10, páginas 2791-2795. *
S.S. JAYANTHI et al. "Excited Singlet State reactions of Thiopyrylium with electron donors: Electron transfer, induction of triplet by internal and external heavy atom effect, and comparison of Pyrylium and Thiopyrylium reactions", J. Phys., Chem. A., 1998, Vol. 102, Nö 3, páginas 511-518. *

Also Published As

Publication number Publication date
ES2181605B1 (es) 2004-01-16
DE60223055D1 (de) 2007-11-29
EP1424127A1 (en) 2004-06-02
EP1424127B1 (en) 2007-10-17
ATE375822T1 (de) 2007-11-15
WO2003011456A1 (es) 2003-02-13

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