ES2181270T3 - Preparado catalizador para la (co)polimerizacion de alqu-1-enos. - Google Patents

Preparado catalizador para la (co)polimerizacion de alqu-1-enos.

Info

Publication number
ES2181270T3
ES2181270T3 ES98946384T ES98946384T ES2181270T3 ES 2181270 T3 ES2181270 T3 ES 2181270T3 ES 98946384 T ES98946384 T ES 98946384T ES 98946384 T ES98946384 T ES 98946384T ES 2181270 T3 ES2181270 T3 ES 2181270T3
Authority
ES
Spain
Prior art keywords
polymerization
alqu
enso
prepared catalyst
alk
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98946384T
Other languages
English (en)
Inventor
Andrei Gonioukh
Andreas Deckers
Eckard Schauss
Roger Klimesch
Wilhelm Weber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7840315&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2181270(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Application granted granted Critical
Publication of ES2181270T3 publication Critical patent/ES2181270T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Preparado catalizador apropiado para la (co)polimerización de alqu-1-enos, obtenible mediante: a) mezclado de un complejo de metaloceno de la fórmula general I , en la que los substituyentes tienen el siguiente significado: M titanio, circonio, hafnio, vanadio, niobio o tántalo, X hidrógeno, alquilo con 1 a 10 átomos de carbono, arilo con 6 a 15 átomos de carbono, alquilarilo con 1 a 10 átomos de carbono en el resto alquilo, y 6 a 20 átomos de carbono en el resto arilo, -OR6 o -NR6R7, significando R6 y R7 alquilo con 1 a 10 átomos de carbono, arilo con 6 a 15 átomos de carbono, alquilarilo, arilalquilo, alquilo fluorado o arilo fluorado respectivamente con 1 a 10 átomos de carbono en el resto alquilo, y 6 a 20 átomos de carbono en el resto arilo, R1 a R5 hidrógeno, alquilo con 1 a 10 átomos de carbono, cicloalquilo de 5 a 7 eslabones, que puede portar por su parte un alquilo con 1 a 10 átomos de carbono como substituyente,arilo con 6 a 15 átomos de carbono o arilalquilo, pudiendo representar, en caso dado, también dos restos adyacentes conjuntamente grupos cíclicos que presentan 4 a 15 átomos de carbono, saturados o insaturados, o Si(R8)3 con R8 alquilo con 1 a 10 átomos de carbono, cicloalquilo con 3 a 10 átomos de carbono, o arilo con 6 a 15 átomos de carbono, Z representa X o , significando los restos R9 a R13 hidrógeno, alquilo con 1 a 10 átomos de carbono, cicloalquilo con 5 a 7 eslabones, que puede portar por su parte un alquilo con 1 a 10 átomos de carbono como substituyente, arilo con 6 a 15 átomos de carbono o arilalquilo, y pudiendo representar, en caso dado, también dos restos adyacentes conjuntamente grupos cíclicos que presentan 4 a 15 átomos de carbono, o Si(R14)3 con R14 alquilo con 1 a 10 átomos de carbono, arilo con 6 a 15 átomos de carbono, o cicloalquilo con 3 a 10 átomos de carbono, o formando los restos R4 y Zconjuntamente una agrupación ¿R15-A-, en la que R15 es = BR16, = AlR16, -Ge-, -Sn-, -O-, -S-, = SO, =SO2, = NR16, = CO, = PR16 o = P(O)R16, donde R16, R17 y R18 son iguales o diferentes, y significan un átomo de hidrógeno, un átomo de halógeno, un grupo alquilo con 1 a 10 átomos de carbono, un grupo alquilo fluorado con 1 a 10 átomos de carbono, un grupo arilo fluorado con 6 a 10 átomos de carbono, un grupo arilo con 6 a 10 átomos de carbono, un grupo alcoxi con 1 a 10 átomos de carbono, un grupo alquenilo con 2 a 10 átomos de carbono, un grupo arilalquilo con 7 a 40 átomos de carbono, un grupo arilalquenilo con 8 a 40 átomos de carbono, o un grupo alquilarilo con 7 a 40 átomos de carbono, o formando dos restos adyacentes un anillo respectivamente con los átomos que los unen, y M2 es silicio, germanio o estaño, A significa , con R19 alquilo con 1 a 10 átomos de carbono, arilo con 6 a 15 átomos de carbono, cicloalquilo con 3 a 10 átomos de carbono, alquilarilo, o Si(R20)3, R20 hidrógeno, alquilo con 1 a 10 átomos de carbono, arilo con 6 a 15 átomos de carbono, que puede estar substituido por su parte con grupos alquilo con 1 a 4 átomosde carbono, o cicloalquilo con 3 a 10 átomos de carbono, o formando los restos R4 y R12 conjuntamente una agrupación R15-, con un alqu-1-eno con 3 a 20 átomos de carbono en un disolvente inerte, situándose la proporción molar de complejo de metaloceno respecto a alqu-1-eno en el intervalo de 1 : 0,1 a 1 : 100, b) reacción controlada de la mezcla según a) con un compuesto que forma iones metalocenio (II), y c) dilución de la mezcla según b) con un disolvente inerte apolar, esencialmente alifático, así como, en caso dado d) aplicación del preparado catalizador según c) sobre un material soporte particular.
ES98946384T 1997-08-27 1998-08-19 Preparado catalizador para la (co)polimerizacion de alqu-1-enos. Expired - Lifetime ES2181270T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19737306A DE19737306A1 (de) 1997-08-27 1997-08-27 Katalysatorzubereitung für die (Co)polymerisation von Alk-l-enen

Publications (1)

Publication Number Publication Date
ES2181270T3 true ES2181270T3 (es) 2003-02-16

Family

ID=7840315

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98946384T Expired - Lifetime ES2181270T3 (es) 1997-08-27 1998-08-19 Preparado catalizador para la (co)polimerizacion de alqu-1-enos.

Country Status (9)

Country Link
US (1) US6458904B1 (es)
EP (1) EP1012193B1 (es)
JP (1) JP4270745B2 (es)
KR (1) KR100548104B1 (es)
CN (1) CN1127521C (es)
AT (1) ATE220692T1 (es)
DE (2) DE19737306A1 (es)
ES (1) ES2181270T3 (es)
WO (1) WO1999010388A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1656394B1 (en) * 2003-08-22 2012-10-03 Ineos Commercial Services UK Limited Supported polymerisation catalysts
CN100374204C (zh) * 2005-04-18 2008-03-12 中国科学院成都有机化学有限公司 一种酯交换反应合成碳酸二苯酯的方法
US20090124771A1 (en) * 2005-04-28 2009-05-14 Idemitsu Kosan Co., Ltd Polymerization catalyst and method for producing poly-alpha-olefin using the catalyst
JP5311805B2 (ja) * 2007-11-21 2013-10-09 日本ポリエチレン株式会社 オレフィン重合用触媒及びそれを用いたオレフィンの重合方法
BR122013014965B1 (pt) 2009-06-16 2019-10-29 Chevron Phillps Chemical Company Lp composições compreendendo polialfaolefina e composições compreendendo produto oligomérico alfa olefina
EP2485839A1 (en) * 2009-10-06 2012-08-15 Chevron Phillips Chemical Company LP Oligomerization of olefin waxes using metallocene-based catalyst systems
US9481749B1 (en) 2015-06-26 2016-11-01 Chevron Phillips Chemical Company Lp Processes for preparing metallocene-based catalyst systems in cyclohexene
US10131725B2 (en) 2015-06-26 2018-11-20 Chevron Phillips Chemical Company Lp Production of high haze films using metallocene-based catalyst systems in cyclohexene
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993025590A1 (en) 1992-06-15 1993-12-23 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
JP3332051B2 (ja) * 1992-12-18 2002-10-07 出光興産株式会社 重合用触媒及び該触媒系を用いる重合体の製造方法
US5416179A (en) * 1994-03-16 1995-05-16 Phillips Petroleum Company Catalyst compositions and olefin polymerization
EP0709393A3 (en) 1994-10-25 2003-04-16 Tosoh Corporation Olefin polymerization catalyst and process for producing olefin polymer
IT1273615B (it) * 1995-05-05 1997-07-08 Enichem Spa Catalizzatore a migliorata attivita' per la (co)polimerizzazione dell'etilene
US6136742A (en) * 1996-09-24 2000-10-24 Exxon Chemical Patents, Inc. Metallocene catalyst systems

Also Published As

Publication number Publication date
EP1012193A1 (de) 2000-06-28
JP2001514271A (ja) 2001-09-11
WO1999010388A1 (de) 1999-03-04
US6458904B1 (en) 2002-10-01
ATE220692T1 (de) 2002-08-15
DE59804819D1 (de) 2002-08-22
CN1127521C (zh) 2003-11-12
EP1012193B1 (de) 2002-07-17
KR100548104B1 (ko) 2006-02-02
KR20010023345A (ko) 2001-03-26
CN1268956A (zh) 2000-10-04
JP4270745B2 (ja) 2009-06-03
DE19737306A1 (de) 1999-03-04

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