ES2160342T3 - Procedimiento para la obtencion de n-butilalquileteres. - Google Patents

Procedimiento para la obtencion de n-butilalquileteres.

Info

Publication number
ES2160342T3
ES2160342T3 ES97919009T ES97919009T ES2160342T3 ES 2160342 T3 ES2160342 T3 ES 2160342T3 ES 97919009 T ES97919009 T ES 97919009T ES 97919009 T ES97919009 T ES 97919009T ES 2160342 T3 ES2160342 T3 ES 2160342T3
Authority
ES
Spain
Prior art keywords
addition product
yielding
butadiene
transition metal
heterogeneous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97919009T
Other languages
English (en)
Inventor
Jurgen Kanand
Michael Roper
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2160342T3 publication Critical patent/ES2160342T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/20—Preparation of ethers by reactions not forming ether-oxygen bonds by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/32—Preparation of ethers by isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/48—Preparation of compounds having groups
    • C07C41/50—Preparation of compounds having groups by reactions producing groups
    • C07C41/54—Preparation of compounds having groups by reactions producing groups by addition of compounds to unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

EN UN PROCEDIMIENTO PARA OBTENER N-BUTILALQUILETERES, (A) UNA MEZCLA DE HIDROCARBUROS DE 1,3 - BUTADIENO O QUE CONTIENEN BUTADIENO SE HACE REACCIONAR CON UN ALCOHOL DE FORMULA ROH (I) EN LA QUE EL RADICAL R ES UN GRUPO ALQUILO C 2 C 20 O ALQUENILO SUSTITUIDO O NO CON 1 A 2 GRUPOS ALCOXI C 1 C 10 O HIDROXI, UN GRUPO ARILO C 6 C 10 O ARALQ UILO C 7 - C 11 O UN GRUPO METILO, A UNA TEMPERATURA Y PRESION ELEVADAS, EN PRESENCIA DE UN ACIDO DE BRONSTED O EN PRESENCIA DE UN COMPLEJO DE UN ELEMENTO DE LOS GRUPOS IB, VIIB O VIIIB DE LA TABLA PERIODICA DE ELEMENTOS CON UN LIGANDO QUE CONTIENE FOSFORO O NITROGENO, PRODUCIENDO UNA MEZCLA DE PRODUCTOS DE ADICION DE LAS FORMULAS (II) Y (III); (B) SE SEPARAN LOS ISOMEROS; (C) SE ISOMERIZA EL PRODUCTO DE ADICION III EN PRODUCTO DE ADICION II; (D) EL PRODUCTO DE ADICION II SE HIDROGENA EN PRESENCIA DE UN CATALIZADOR DE ELEMENTO METALICO DE TRANSICION, HOMOGENEO O HETEROGENEO EN LA FASE LIQUIDA, O EN PRESENCIA DE UN CATALIZADOR QUE CONTIENE UN ELEMENTO METALICO HETEROGENEO DE TRANSICION EN LA FASE GASEOSA, PRODUCIENDOSE N-BUTILALQUILETER DE FORMULA (IV).
ES97919009T 1996-09-17 1997-08-29 Procedimiento para la obtencion de n-butilalquileteres. Expired - Lifetime ES2160342T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19637895A DE19637895A1 (de) 1996-09-17 1996-09-17 Verfahren zur Herstellung von n-Butylalkylethern

Publications (1)

Publication Number Publication Date
ES2160342T3 true ES2160342T3 (es) 2001-11-01

Family

ID=7805910

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97919009T Expired - Lifetime ES2160342T3 (es) 1996-09-17 1997-08-29 Procedimiento para la obtencion de n-butilalquileteres.

Country Status (16)

Country Link
EP (1) EP0931046B1 (es)
JP (1) JP2001500868A (es)
KR (1) KR20000036150A (es)
CN (1) CN1232444A (es)
AT (1) ATE202550T1 (es)
AU (1) AU4300297A (es)
BR (1) BR9711485A (es)
CA (1) CA2265494A1 (es)
CZ (1) CZ85399A3 (es)
DE (2) DE19637895A1 (es)
ES (1) ES2160342T3 (es)
ID (1) ID18558A (es)
MY (1) MY130941A (es)
NO (1) NO991267L (es)
TW (1) TW372957B (es)
WO (1) WO1998012164A2 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19838449A1 (de) * 1998-08-25 2000-03-02 Basf Ag Verfahren zur Abtrennung von 1,3-Butadien und Wasser aus Stoffgemischen enthaltend 1,3-Butadien, 1-n-Butoxybuten-2, 3-n-Butoxybuten-1, n-Butanol, Di-n-butylether und Wasser
GB9823980D0 (en) 1998-11-02 1998-12-30 Bp Chem Int Ltd A process for making n-butyl ethers of glycols
KR101363208B1 (ko) * 2011-11-29 2014-02-13 롯데케미칼 주식회사 탄소수 4 내지 5의 디엔계 화합물의 선택적 알콕시화 제조방법
GB201818905D0 (en) * 2018-11-20 2019-01-02 Bp Plc Process for making ethers via enol ethers
CN109529906B (zh) * 2018-12-25 2021-06-15 西安近代化学研究所 一种合成1,1,2,3,3,3-六氟丙基甲醚的催化剂及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3670032A (en) * 1969-03-19 1972-06-13 Exxon Research Engineering Co Preparation of unsaturated alcohols and ethers
US4843180A (en) * 1986-11-13 1989-06-27 The Dow Chemical Company Preparation of ethers
DE4400837A1 (de) * 1994-01-14 1995-07-20 Basf Ag Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol

Also Published As

Publication number Publication date
KR20000036150A (ko) 2000-06-26
CZ85399A3 (cs) 1999-12-15
CA2265494A1 (en) 1998-03-26
MY130941A (en) 2007-07-31
BR9711485A (pt) 1999-08-24
AU4300297A (en) 1998-04-14
WO1998012164A3 (de) 1999-04-01
DE59703924D1 (de) 2001-08-02
ATE202550T1 (de) 2001-07-15
EP0931046A2 (de) 1999-07-28
TW372957B (en) 1999-11-01
JP2001500868A (ja) 2001-01-23
WO1998012164A2 (de) 1998-03-26
DE19637895A1 (de) 1998-03-19
NO991267D0 (no) 1999-03-16
CN1232444A (zh) 1999-10-20
NO991267L (no) 1999-03-16
EP0931046B1 (de) 2001-06-27
ID18558A (id) 1998-04-16

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