ES2157838A1 - Procedimiento y catalizadores (acidos y basicos) para la obtencion de -alquilcinamaldehidos. - Google Patents

Procedimiento y catalizadores (acidos y basicos) para la obtencion de -alquilcinamaldehidos.

Info

Publication number
ES2157838A1
ES2157838A1 ES009902349A ES9902349A ES2157838A1 ES 2157838 A1 ES2157838 A1 ES 2157838A1 ES 009902349 A ES009902349 A ES 009902349A ES 9902349 A ES9902349 A ES 9902349A ES 2157838 A1 ES2157838 A1 ES 2157838A1
Authority
ES
Spain
Prior art keywords
catalysts
basic
oxynitrided
cinamaldehydes
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009902349A
Other languages
English (en)
Other versions
ES2157838B1 (es
Inventor
Canos Avelino Corma
Olmedo Maria Jose Climent
Ruth Guil-Lopez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES009902349A priority Critical patent/ES2157838B1/es
Priority to EP00972911A priority patent/EP1243574A1/en
Priority to PCT/ES2000/000404 priority patent/WO2001028968A1/es
Priority to JP2001531773A priority patent/JP2003512345A/ja
Publication of ES2157838A1 publication Critical patent/ES2157838A1/es
Application granted granted Critical
Publication of ES2157838B1 publication Critical patent/ES2157838B1/es
Priority to US10/125,330 priority patent/US20030009058A1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

En la presente invención se describe un catalizador y un proceso para la obtención selectiva de {al}-alquilcinamaldehidos, y más específicamente Jasminaldehido, por reacción directa entre n- alquilaldehidos y derivados del benzaldehido utilizando como catalizadores ácidos heterogéneos: fosfatos de aluminio (ALPO), silicoaluminofosfatos (SAPO), y silicoaluminatos (SAM) y cómo catalizadores básicos sus correspondientes nitrurados: fosfatos de aluminio oxinitrurados (ALPON) silicoaluminofosfatos oxinitrurados (SAPON) y silicoaluminatos oxinitrurados (SAMON).
ES009902349A 1999-10-19 1999-10-19 Procedimiento y catalizadores (acidos y basicos) para la obtencion de -alquilcinamaldehidos. Expired - Fee Related ES2157838B1 (es)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ES009902349A ES2157838B1 (es) 1999-10-19 1999-10-19 Procedimiento y catalizadores (acidos y basicos) para la obtencion de -alquilcinamaldehidos.
EP00972911A EP1243574A1 (en) 1999-10-19 2000-10-19 Method and (acid and basic) catalysts for obtaining alpha-alkyl cinamaldehydes
PCT/ES2000/000404 WO2001028968A1 (es) 1999-10-19 2000-10-19 PROCEDIMIENTO Y CATALIZADORES (ACIDOS Y BASICOS) PARA LA OBTENCION DE sg(a)-ALQUILCINAMALDEHIDOS
JP2001531773A JP2003512345A (ja) 1999-10-19 2000-10-19 α−アルキルシンナムアルデヒドを得るための方法および（酸および塩基）触媒
US10/125,330 US20030009058A1 (en) 1999-10-19 2002-04-18 Process and (acid and Basic) catalysts for the obtainment of alpha-alkylcinnamaldehydes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES009902349A ES2157838B1 (es) 1999-10-19 1999-10-19 Procedimiento y catalizadores (acidos y basicos) para la obtencion de -alquilcinamaldehidos.

Publications (2)

Publication Number Publication Date
ES2157838A1 true ES2157838A1 (es) 2001-08-16
ES2157838B1 ES2157838B1 (es) 2002-03-16

Family

ID=8310370

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009902349A Expired - Fee Related ES2157838B1 (es) 1999-10-19 1999-10-19 Procedimiento y catalizadores (acidos y basicos) para la obtencion de -alquilcinamaldehidos.

Country Status (5)

Country Link
US (1) US20030009058A1 (es)
EP (1) EP1243574A1 (es)
JP (1) JP2003512345A (es)
ES (1) ES2157838B1 (es)
WO (1) WO2001028968A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5001549B2 (ja) 2005-12-06 2012-08-15 花王株式会社 α−アルキルシンナムアルデヒド類の製造方法
DE102007041856A1 (de) 2007-09-03 2009-03-05 Wacker Chemie Ag Vernetzbare Massen auf der Basis von Organosiliciumverbindungen
GB201011091D0 (en) 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters
GB201011092D0 (en) 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst system and a process for the production of ethylenically unsaturated carboxylic acids or esters

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995021123A1 (fr) * 1994-02-01 1995-08-10 Universite De Rennes I Catalyseurs a base d'un aluminophosphate, leur procede de preparaion et leur application a des reactions de condensation et de deshydrogenation
WO1998035928A1 (es) * 1997-02-12 1998-08-20 Consejo Superior De Investigaciones Cientificas PROCEDIMIENTO Y CATALIZADORES PARA LA OBTENCION SELECTIVA DE α-ALQUILCINAMADEHIDOS

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995021123A1 (fr) * 1994-02-01 1995-08-10 Universite De Rennes I Catalyseurs a base d'un aluminophosphate, leur procede de preparaion et leur application a des reactions de condensation et de deshydrogenation
WO1998035928A1 (es) * 1997-02-12 1998-08-20 Consejo Superior De Investigaciones Cientificas PROCEDIMIENTO Y CATALIZADORES PARA LA OBTENCION SELECTIVA DE α-ALQUILCINAMADEHIDOS

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Journal of Catalysis, Volumen 175, 1998, paginas 70-79. M.J. CLIMENT et al. "Use of mesoporous MCM-41 alumino-silicates as catalysts in the preparation of fine chemicals". Paginas 70,71. *

Also Published As

Publication number Publication date
EP1243574A1 (en) 2002-09-25
WO2001028968A1 (es) 2001-04-26
US20030009058A1 (en) 2003-01-09
JP2003512345A (ja) 2003-04-02
ES2157838B1 (es) 2002-03-16

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