ES2138167T3 - Proceso de separacion de nitrogeno de una mezcla gaseosa por adsorcion. - Google Patents

Proceso de separacion de nitrogeno de una mezcla gaseosa por adsorcion.

Info

Publication number
ES2138167T3
ES2138167T3 ES95401678T ES95401678T ES2138167T3 ES 2138167 T3 ES2138167 T3 ES 2138167T3 ES 95401678 T ES95401678 T ES 95401678T ES 95401678 T ES95401678 T ES 95401678T ES 2138167 T3 ES2138167 T3 ES 2138167T3
Authority
ES
Spain
Prior art keywords
nitrogen
adsorption
separation
gas mixture
mass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95401678T
Other languages
English (en)
Inventor
Xavier Vigor
Pierre Petit
Serge Moreau
Bernard Sardan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9465450&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2138167(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Application granted granted Critical
Publication of ES2138167T3 publication Critical patent/ES2138167T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/10—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/12—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
    • B01D2259/4006—Less than four
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00—Gas separation: processes
    • Y10S95/90—Solid sorbent
    • Y10S95/902—Molecular sieve

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

PROCESO DE SEPARACION DE UNA MEZCLA GASEOSA QUE CONTIENE NITROGENO POR ADSORCION SELECTIVA DEL NITROGENO DE DICHA MEZCLA GASEOSA EN UNA MASA DE ADSORCION, CON VARIACIONES CICLICAS DE PRESION QUE COMPRENDE AL MENOS UNA FASE DE ADSORCION DE NITROGENO REALIZADA A ALTA PRESION Y AL MENOS UNA FASE DE DESERCION DEL NITROGENO REALIZADA A BAJA PRESION, SEGUN EL CUAL LA MASA DE ABSORBENTE ESTA DISPUESTA EN UN ADSORBEDOR GIRATORIO Y ESTA CONSTITUIDO POR UNA ZEOLITA INTERCAMBIADA CON LITIO EN MAS DE 50%.
ES95401678T 1994-07-18 1995-07-12 Proceso de separacion de nitrogeno de una mezcla gaseosa por adsorcion. Expired - Lifetime ES2138167T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9408822A FR2722426B1 (fr) 1994-07-18 1994-07-18 Procede de separation d'azote d'un melange gazeux par adsorption

Publications (1)

Publication Number Publication Date
ES2138167T3 true ES2138167T3 (es) 2000-01-01

Family

ID=9465450

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95401678T Expired - Lifetime ES2138167T3 (es) 1994-07-18 1995-07-12 Proceso de separacion de nitrogeno de una mezcla gaseosa por adsorcion.

Country Status (10)

Country Link
US (1) US5658370A (es)
EP (1) EP0693309B1 (es)
JP (1) JPH08196850A (es)
KR (1) KR960004207A (es)
CN (1) CN1127153A (es)
BR (1) BR9503350A (es)
DE (1) DE69511800T2 (es)
ES (1) ES2138167T3 (es)
FI (1) FI953455A (es)
FR (1) FR2722426B1 (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111498817A (zh) * 2020-04-23 2020-08-07 华北制药股份有限公司 氮气回收循环利用工艺及氮气回收循环利用系统

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE38493E1 (en) * 1996-04-24 2004-04-13 Questair Technologies Inc. Flow regulated pressure swing adsorption system
FR2749004B1 (fr) * 1996-05-24 1998-07-10 Air Liquide Procede pour la purification de melanges gazeux a base d'hydrogene utilisant une zeolithe x echangee au lithium
US5868818A (en) * 1996-08-08 1999-02-09 Tosoh Corporation Adsorbent for air separation, production method thereof, and air-separation method using it
FR2753108B1 (fr) * 1996-09-06 1998-10-16 Air Liquide Procede pour la separation de melanges gazeux contenant de l'oxygene et de l'azote
DE19647290A1 (de) * 1996-11-15 1998-05-28 Bayer Ag Verfahren zur Herstellung eines mit Lithium-Ionen ausgetauschten, bindemittelfreien Zeolithgranulats und dessen Verwendung zur adsorptiven Lufttrennung
FR2765491B1 (fr) * 1997-07-07 1999-08-06 Air Liquide Procede de separation d'un flux gazeux par un procede psa
FR2766476B1 (fr) * 1997-07-22 1999-09-03 Ceca Sa Adsorbant zeolitique ameliore pour la separation des gaz de l'air et son procede d'obtention
FR2766384B1 (fr) * 1997-07-25 1999-09-03 Air Liquide Regulation d'un procede psa
FR2771656B1 (fr) * 1997-12-01 2000-01-07 Air Liquide Procede psa mettant en oeuvre un adsorbant a proprietes de capacite et/ou de selectivite heterogenes
FR2775618B1 (fr) * 1998-03-03 2000-05-05 Air Liquide Adsorbant a taux d'echange heterogene et procede psa mettant en oeuvre un tel adsorbant
FR2782460B1 (fr) * 1998-08-21 2000-09-22 Air Liquide Procede psa utilisant un adsorbant agglomere constitue d'une phase zeolitique et d'un liant
FR2782461B1 (fr) * 1998-08-21 2000-09-22 Air Liquide Procede psa utilisant une zeolithe faujasite contenant des cations metalliques en tant qu'adsorbant
FR2782507B1 (fr) * 1998-08-21 2000-09-29 Air Liquide Procede de fabrication de particules de zeolite x echangee par des cations metalliques
US6921597B2 (en) * 1998-09-14 2005-07-26 Questair Technologies Inc. Electrical current generation system
EP1005904A3 (en) * 1998-10-30 2000-06-14 The Boc Group, Inc. Adsorbents and adsorptive separation process
FR2792220B1 (fr) * 1999-04-19 2001-06-15 Air Liquide Procede psa mettant en oeuvre un adsorbant a resistance intrinseque favorable a la cinetique d'adsorption
EP1189677B1 (en) 1999-06-09 2005-03-30 Questair Technologies, Inc. Adsorption element
WO2000076629A1 (en) * 1999-06-10 2000-12-21 Questair Technologies Inc. Chemical reactor with pressure swing adsorption
FR2796570B1 (fr) * 1999-07-22 2002-06-07 Air Liquide Adsorbant a selectivite amelioree pour la separation des gaz
US6340382B1 (en) * 1999-08-13 2002-01-22 Mohamed Safdar Allie Baksh Pressure swing adsorption process for the production of hydrogen
US6514319B2 (en) 1999-12-09 2003-02-04 Questair Technologies Inc. Life support oxygen concentrator
US7250073B2 (en) * 1999-12-09 2007-07-31 Questair Technologies, Inc. Life support oxygen concentrator
CA2306311C (en) 2000-04-20 2007-04-10 Quest Air Gases Inc. Absorbent laminate structures
ES2640910T3 (es) 2000-10-27 2017-11-07 Air Products And Chemicals, Inc. Sistemas y procesos para proporcionar hidrógeno a células de combustible
US7097925B2 (en) * 2000-10-30 2006-08-29 Questair Technologies Inc. High temperature fuel cell power plant
CA2325072A1 (en) * 2000-10-30 2002-04-30 Questair Technologies Inc. Gas separation for molten carbonate fuel cell
US6824590B2 (en) * 2000-11-07 2004-11-30 Air Products And Chemicals, Inc. Use of lithium-containing fau in air separation processes including water and/or carbon dioxide removal
US6866950B2 (en) * 2000-12-08 2005-03-15 Questair Technologies Inc. Methods and apparatuses for gas separation by pressure swing adsorption with partial gas product feed to fuel cell power source
CA2329475A1 (en) * 2000-12-11 2002-06-11 Andrea Gibbs Fast cycle psa with adsorbents sensitive to atmospheric humidity
JP2005519731A (ja) * 2002-03-14 2005-07-07 クエストエアー テクノロジーズ インコーポレイテッド 圧力スイング及び置換パージの組合せによるガス分離
ATE373323T1 (de) * 2002-03-14 2007-09-15 Questair Technologies Inc Wasserstoffrückführung für festoxid- brennstoffzellen
FR2839263B1 (fr) * 2002-05-03 2005-01-14 Air Liquide Systeme embarque de production d'oxygene pour aeronefs, en particulier aeronefs a long rayon d'action
US7285350B2 (en) 2002-09-27 2007-10-23 Questair Technologies Inc. Enhanced solid oxide fuel cell systems
WO2004076017A2 (en) * 2003-02-26 2004-09-10 Questair Technologies Inc. Hydrogen recycle for high temperature fuel cells
US7443803B2 (en) * 2004-03-23 2008-10-28 Fujitsu Limited Estimating and managing network traffic
US7189280B2 (en) * 2004-06-29 2007-03-13 Questair Technologies Inc. Adsorptive separation of gas streams
CA2585963A1 (en) 2004-11-05 2006-05-18 Questair Technologies Inc. Separation of carbon dioxide from other gases
US8388735B2 (en) * 2008-12-17 2013-03-05 Uop Llc Adsorbent media with Li exchanged zeolite
CN104874203B (zh) * 2015-05-28 2017-06-16 长春黄金研究院 沸石动态吸附柱
FR3087670B1 (fr) * 2018-10-26 2020-10-23 Air Liquide Procede de conditionnement d'un recipient comprenant un materiau granulaire

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140933A (en) * 1960-12-02 1964-07-14 Union Carbide Corp Separation of an oxygen-nitrogen mixture
FR2534827A1 (fr) 1982-10-22 1984-04-27 Air Liquide Procede de traitement de gaz par adsorption comportant plusieurs adsorbeurs en phase de production simultanee
FR2579484B1 (fr) 1985-03-29 1987-06-05 Air Liquide Procede de traitement de gaz par adsorption
US4612022A (en) * 1985-06-21 1986-09-16 Progress Equities Incorporated Process for increasing the concentration of one component in a multi-component _gaseous mixture
US4812147A (en) * 1985-11-08 1989-03-14 Union Carbide Corporation Multicomponent adsorption process
FR2612083B1 (fr) 1987-03-11 1989-06-09 Air Liquide Procede de traitement par adsorption d'un melange gazeux
US4859217A (en) * 1987-06-30 1989-08-22 Uop Process for separating nitrogen from mixtures thereof with less polar substances
FR2624759B1 (fr) 1987-12-22 1990-05-04 Air Liquide Procede de traitement d'un melange gazeux par adsorption
US4810265A (en) * 1987-12-29 1989-03-07 Union Carbide Corporation Pressure swing adsorption process for gas separation
FR2633847B1 (fr) 1988-07-08 1991-04-19 Air Liquide Procede de traitement d'un melange gazeux par adsorption
US4925460A (en) * 1989-07-20 1990-05-15 Air Products And Chemicals, Inc. Chabazite for gas separation
US5174979A (en) * 1989-10-06 1992-12-29 Uop Mixed ion-exchanged zeolites and processes for the use thereof in gas separations
USRE35099E (en) * 1989-11-20 1995-11-28 Sequal Technologies, Inc. Fluid fractionator
ES2089202T3 (es) 1990-03-02 1996-10-01 Air Liquide Procedimiento de produccion de oxigeno mediante separacion de aire por adsorcion.
US5074892A (en) * 1990-05-30 1991-12-24 Union Carbide Industrial Gases Technology Corporation Air separation pressure swing adsorption process
FR2667801B1 (fr) * 1990-10-11 1992-12-04 Air Liquide Procede et equipement de separation par adsorption d'au moins un constituant d'un melange gazeux.
US5203887A (en) * 1991-12-11 1993-04-20 Praxair Technology, Inc. Adsorbent beds for pressure swing adsorption operations
US5152813A (en) * 1991-12-20 1992-10-06 Air Products And Chemicals, Inc. Nitrogen adsorption with a Ca and/or Sr exchanged lithium X-zeolite
FR2689785B1 (fr) * 1992-04-13 1994-05-20 Air Liquide Dispositif rotatif de separation par adsorption d'au moins un constituant d'un melange gazeux.
US5266102A (en) * 1992-09-23 1993-11-30 Air Products And Chemicals, Inc. O2 VSA process with low O2 capacity adsorbents
US5258060A (en) * 1992-09-23 1993-11-02 Air Products And Chemicals, Inc. Adsorptive separation using diluted adsorptive phase
US5258058A (en) * 1992-10-05 1993-11-02 Air Products And Chemicals, Inc. Nitrogen adsorption with a divalent cation exchanged lithium X-zeolite
US5268023A (en) * 1992-10-05 1993-12-07 Air Products And Chemicals, Inc. Nitrogen adsorption with highly Li exchanged X-zeolites with low Si/Al ratio
US5464467A (en) * 1994-02-14 1995-11-07 The Boc Group, Inc. Adsorptive separation of nitrogen from other gases

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111498817A (zh) * 2020-04-23 2020-08-07 华北制药股份有限公司 氮气回收循环利用工艺及氮气回收循环利用系统

Also Published As

Publication number Publication date
BR9503350A (pt) 1996-07-16
DE69511800D1 (de) 1999-10-07
FI953455A (fi) 1996-01-19
DE69511800T2 (de) 2000-04-13
EP0693309A1 (fr) 1996-01-24
FI953455A0 (fi) 1995-07-17
JPH08196850A (ja) 1996-08-06
FR2722426A1 (fr) 1996-01-19
FR2722426B1 (fr) 1996-08-23
US5658370A (en) 1997-08-19
CN1127153A (zh) 1996-07-24
EP0693309B1 (fr) 1999-09-01
KR960004207A (ko) 1996-02-23

Similar Documents

Publication Publication Date Title
ES2138167T3 (es) Proceso de separacion de nitrogeno de una mezcla gaseosa por adsorcion.
ATE49132T1 (de) Druckwechseladsorptionsverfahren.
ES2089202T3 (es) Procedimiento de produccion de oxigeno mediante separacion de aire por adsorcion.
ES552728A0 (es) Un procedimiento adiabatico de adsorcion oscilante a presion para la admision selectiva del componente mas facilmente adsorbible de una mezcla gaseosa.
AU4146489A (en) Natural gas liquefaction process using low level, high level and absorption refrigeration cycles
ES2048193T3 (es) Procedimiento y sistema de adsorcion oscilante a presion.
BR9800283A (pt) Processo de adsorção por alternância de pressão para extrair um gás mais preferido de uma mistura do citado gás mais preferido e um gás menos preferido.
MY114542A (en) Removal of carbon dioxide from gas streams
AR216443A1 (es) Un procedimiento mejorado para separar mezclas de gases por adsorcion selectiva,mediante oscilacion de la presion adiabatica,de por lo menos un componente gaseoso en cada uno de multiples lechos adsorbentes
KR960033518A (ko) 가스 스트림으로부터 이산화탄소의 제거방법
TW354768B (en) Process for the purification of nitric oxide
ES2144726T3 (es) Procedimiento para la recuperacion de un gas enriquecido en oxigeno.
FI883102A0 (fi) Foerfarande foer att separera kvaeve fraon dess mindre polaera aemnen innehaollande blandningar.
ES2083002T3 (es) Separacion de mezclas de gases de multiples componentes por adsorcion selectiva.
CA2140181A1 (en) Adsorptive Separation of Nitrogen from Other Gases
GB1258417A (es)
IT1238349B (it) Procedimento per eliminare composti gassosi contaminanti, in particolare di droganti da gas vettori contenenti composti di alogenosilano.
ES462143A1 (es) Procedimiento de tratamiento por absorcion de una mezcla ga-seosa.
BR7905872A (pt) Processo de absorcao adiabatica para purifacao ou separacao de um gas
ES2128496T3 (es) Composiciones de zeolita para separaciones de gas.
EP0193716A3 (en) Adsorptive separation of methane and carbon dioxide gas mixtures
AU574056B2 (en) Method of separating and purifying hydrogen
DE3061843D1 (en) Pressure swing adsorption process for the decomposition or purification of gas mixtures
ES8404870A1 (es) Procedimiento y dispositivo para asegurar el funcionamiento de una instalacion de adsorcion por cambio de presion que trabaja ciclicamente.
IT7867280A0 (it) Rocedimento per la separazione dell etilene dell acetilene e dell ossido di carbonio da miscele gassose

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 693309

Country of ref document: ES