ES2137618T3 - Procedimiento perfeccionado para la fabricacion en continuo de poli-epsilon-caprolactonas. - Google Patents

Procedimiento perfeccionado para la fabricacion en continuo de poli-epsilon-caprolactonas.

Info

Publication number
ES2137618T3
ES2137618T3 ES96200803T ES96200803T ES2137618T3 ES 2137618 T3 ES2137618 T3 ES 2137618T3 ES 96200803 T ES96200803 T ES 96200803T ES 96200803 T ES96200803 T ES 96200803T ES 2137618 T3 ES2137618 T3 ES 2137618T3
Authority
ES
Spain
Prior art keywords
epsilon
caprolactones
poly
continuous manufacture
perfected procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES96200803T
Other languages
English (en)
Inventor
Henri Wautier
Lucienne Detournay
Martine Kaszacs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Application granted granted Critical
Publication of ES2137618T3 publication Critical patent/ES2137618T3/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

LOS POLI- EP -CAPROLACTONAS SE PRODUCEN POR POLIMERIZACION CONTINUA DE {EP}-CAPROLACTONA EN MASA FUNDIDA EN UNA PRENSA DE EXTRUSION (EXTRUSION REACTIVA) CON INTERVENCION COMO CEBADOR DE POLIMERIZACION DE TRIALCOXIDOS DE ALUMINIO DE LOS QUE AL MENOS UN RADICAL ALCOXI COMPRENDE ADEMAS EL ATOMO DE OXIGENO CONSTITUTIVO DEL ENLACE ALUMINOXANO (AL-O) AL MENOS OTRO ATOMO DE OXIGENO. VENTAJOSAMENTE, ESTE ATOMO DE OXIGENO ESTA PRESENTE EN FORMA DE UNA FUNCION ESTER O ETER. ESTOS CEBADORES SE PRESENTAN GENERALMENTE EN ESTADO DE LIQUIDO A TEMPERATURA AMBIENTE Y SE PUEDEN POR OTRA PARTE MEZCLAR CON {EP}CAPROLACTONA, DE MANERA QUE PUEDEN SER UTILIZADOS EN AUSENCIA DE SOLVENTE. EL AJUSTE APROPIADO DE LOS CAUDALES DE ALIMENTACION DE LA PRENSA DE EXTRUSION DE {EP}-CAPROLACTONA Y DE CEBADOR PERMITE LA FABRICACION A MODO DE POLI-{EP}-CAPROLACTONAS QUE TIENEN MASAS MOLECULARES MEDIAS EN PESO PREESTABLECIDAS.
ES96200803T 1995-04-07 1996-03-25 Procedimiento perfeccionado para la fabricacion en continuo de poli-epsilon-caprolactonas. Expired - Fee Related ES2137618T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE9500324A BE1009255A3 (fr) 1995-04-07 1995-04-07 Procede perfectionne pour la fabrication en continu de poly- -caprolactones.

Publications (1)

Publication Number Publication Date
ES2137618T3 true ES2137618T3 (es) 1999-12-16

Family

ID=3888917

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96200803T Expired - Fee Related ES2137618T3 (es) 1995-04-07 1996-03-25 Procedimiento perfeccionado para la fabricacion en continuo de poli-epsilon-caprolactonas.

Country Status (8)

Country Link
US (1) US5656718A (es)
EP (1) EP0736559B1 (es)
JP (1) JPH08283397A (es)
AT (1) ATE182908T1 (es)
BE (1) BE1009255A3 (es)
BR (1) BR9601280A (es)
DE (1) DE69603529T2 (es)
ES (1) ES2137618T3 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2741351B1 (fr) * 1995-11-22 1998-01-16 Solvay Film semi-rigide en poly-epsilon-caprolactone et procede pour le produire
US5801224A (en) * 1996-04-26 1998-09-01 Board Of Trustees Operating Michigan State University Bulk reactive extrusion polymerization process producing aliphatic ester polymer compositions
BE1010619A3 (fr) * 1996-09-13 1998-11-03 Solvay Procede pour la stabilisation au stockage des poly- -caprolactones.
US6900267B2 (en) * 2001-12-12 2005-05-31 North Carolina State University Methods of CO2-assisted reactive extrusion
CN102534840B (zh) * 2010-12-29 2014-11-12 圣欧芳纶（江苏）股份有限公司 制备间位芳纶纤维的方法
CN103304786B (zh) * 2013-05-06 2015-12-09 常州大学 一种连续化制备高分子量聚羟基酸的方法
EP4059979A1 (en) 2021-03-18 2022-09-21 Sulzer Management AG A process of continuously manufacturing a poly(hydroxy acid) homo- or copolymer with tunable molecular weight, structure and composition

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1001149A6 (fr) * 1989-05-17 1989-08-01 Chimie Macromoleculaire Et De Procede de preparation de polymeres de lactones fonctionnels, polylactones telles qu'ainsi obtenues et leur utilisation.
BE1007036A3 (fr) * 1993-05-17 1995-02-28 Solvay Procede pour la fabrication de poly-epsilonn-caprolactones et poly-epsilonn-caprolactones ayant des masses moleculaires elevees pouvant etre obtenues par ce procede.

Also Published As

Publication number Publication date
BR9601280A (pt) 1998-01-13
EP0736559A1 (fr) 1996-10-09
JPH08283397A (ja) 1996-10-29
DE69603529T2 (de) 2000-02-17
EP0736559B1 (fr) 1999-08-04
BE1009255A3 (fr) 1997-01-07
DE69603529D1 (de) 1999-09-09
ATE182908T1 (de) 1999-08-15
US5656718A (en) 1997-08-12

Similar Documents

Publication Publication Date Title
DZ1911A1 (fr) Procédé pour la synthèse de sulfoxydes substitues.
AU1971499A (en) Synthesis method for block polymers by controlled radical polymerisation from dithioester compounds
AU1794797A (en) Multi-stage process for producing heat resistant dimensionally stable polymethacrylate moulding compounds
ZA985450B (en) Process for synthesizing block polymers by controlled radical polymerization
FR2719847B1 (fr) Procédé de polymérisation d'oléfine en phase gazeuse.
AU6561094A (en) Propylene polymer, process for producing the same, composition thereof, polymerization catalyst component, and process for producing the same
AU1883199A (en) Method for block polymer synthesis by controlled radical polymerisation from dithiocarbamate compounds
FR2708289B1 (fr) Système pour produire des pièces d'aluminium brillantes.
HU9701440D0 (en) Process for producing cured polymers
ES2137618T3 (es) Procedimiento perfeccionado para la fabricacion en continuo de poli-epsilon-caprolactonas.
SG72966A1 (en) Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer
ATE163944T1 (de) Verfahren zur herstellung stabilisierter polyolefine und daraus hergestellte produkte
BR9907913A (pt) Processo para a preparação de copolìmeros em bloco a partir de monÈmeros de vinilaromáticos e dienos
HUP9901552A3 (en) Process for the production of 2-(substituted benzoyl)1,3 cyclohexanediones
HUP9901416A3 (en) Process for the production of 2-(substituted benzoyl)-1,3 cyclohexanediones
FR2794757B1 (fr) Procede de polymerisation de l'isobutene
DZ1438A1 (fr) Procédé de polymérisation d'une oléfine.
FR2723952B1 (fr) Nouveau systeme d'amorcage pour la polymerisation anionique de methacrylate d'alkyle
ZA971744B (en) Process for forming articles directly from melt polymerization.
AU5560498A (en) Method for producing polymers by emulsion polymerization
FR2643863B1 (fr) Feu de signalisation d'aspect uniforme, notamment pour vehicule automobile
ITTO930625A0 (it) Variatore continuo di velocita', particolarmente per veicoli.
AU681466B2 (en) Method for forming (meth)acrolein-containing polymers
ES540166A0 (es) Procedimiento de producir pelicula soplada a partir de una composicion polimera a base de polietileno
FR2731755B1 (fr) Commande hydraulique d'embrayage, notamment pour vehicules automobiles

Legal Events

Date Code Title Description
EC2A Search report published

Date of ref document: 19981001

Kind code of ref document: A1

Effective date: 19981001

FG2A Definitive protection

Ref document number: 736559

Country of ref document: ES

FD1A Patent lapsed

Effective date: 20020401