ES2135258T3 - Procedimiento para la obtencion de copolimeros, formados por compuestos vinilaromaticos y olefinicos, mediante polimerizacion en dispersion en presencia de sistemas catalizadores de metaloceno. - Google Patents

Procedimiento para la obtencion de copolimeros, formados por compuestos vinilaromaticos y olefinicos, mediante polimerizacion en dispersion en presencia de sistemas catalizadores de metaloceno.

Info

Publication number
ES2135258T3
ES2135258T3 ES96937290T ES96937290T ES2135258T3 ES 2135258 T3 ES2135258 T3 ES 2135258T3 ES 96937290 T ES96937290 T ES 96937290T ES 96937290 T ES96937290 T ES 96937290T ES 2135258 T3 ES2135258 T3 ES 2135258T3
Authority
ES
Spain
Prior art keywords
compounds
olephinic
copolymers
procedure
catalyst systems
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96937290T
Other languages
English (en)
Inventor
Michael Geprags
Josef Wunsch
Joachim Rosch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2135258T3 publication Critical patent/ES2135258T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PROCEDIMIENTO PARA LA PRODUCCION DE COPOLIMEROS DE COMPUESTOS AROMATICOS DE VINILO Y COMPUESTOS OLEFINICOS, DONDE LA POLIMERIZACION EN DISPERSION SE REALIZA EN PRESENCIA DE SISTEMAS DE CATALIZADOR DE METALOCENO.
ES96937290T 1995-11-14 1996-10-30 Procedimiento para la obtencion de copolimeros, formados por compuestos vinilaromaticos y olefinicos, mediante polimerizacion en dispersion en presencia de sistemas catalizadores de metaloceno. Expired - Lifetime ES2135258T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19542356A DE19542356A1 (de) 1995-11-14 1995-11-14 Verfahren zur Herstellung von Copolymerisaten aus vinylaromatischen und olefinischen Verbindungen durch Dispersionspolymerisation in Gegenwart von Metallocenkatalysatorsystemen

Publications (1)

Publication Number Publication Date
ES2135258T3 true ES2135258T3 (es) 1999-10-16

Family

ID=7777391

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96937290T Expired - Lifetime ES2135258T3 (es) 1995-11-14 1996-10-30 Procedimiento para la obtencion de copolimeros, formados por compuestos vinilaromaticos y olefinicos, mediante polimerizacion en dispersion en presencia de sistemas catalizadores de metaloceno.

Country Status (7)

Country Link
US (1) US6221983B1 (es)
EP (1) EP0861273B1 (es)
JP (1) JP2000500179A (es)
CN (1) CN1202178A (es)
DE (2) DE19542356A1 (es)
ES (1) ES2135258T3 (es)
WO (1) WO1997018248A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19621969A1 (de) * 1996-05-31 1997-12-04 Basf Ag Verfahren zur Herstellung von kristallinen Polymerisaten durch Dispersionspolymerisation in Gegenwart von Metallocenkatalysatorsystemen
CA2322569A1 (en) 1998-03-11 1999-09-16 The Dow Chemical Company Fibers made from alpha-olefin/vinyl or vinylidene aromatic and/or hindered cycloaliphatic or aliphatic vinyl or vinylidene interpolymers
AU3077999A (en) * 1998-03-11 1999-09-27 Dow Chemical Company, The Structures and fabricated articles having shape memory made from alpha-olefin/vinyl or vinylidene aromatic and/or hindered aliphatic vinyl or vinylidene interpolymers
DE19825713A1 (de) * 1998-06-09 1999-12-16 Basf Ag Verfahren zur Herstellung von Polymerisaten aus vinylaromatischen Verbindungen durch Dispersionspolymerisation unter Zusatz von Schmiermitteln
WO2012054541A2 (en) * 2010-10-18 2012-04-26 California Institute Of Technology Methods and systems for synthesis of an ultra high molecular weight polymer

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3734978A (en) 1971-05-12 1973-05-22 Mobil Oil Corp Blocking polystyrene produced by anionic slurry polymerization
US3770712A (en) 1971-05-12 1973-11-06 Mobil Oil Corp Slurry process for producing styrene homopolymers and block polymers thereof using anionic catalysts
CA974341A (en) * 1971-05-12 1975-09-09 Frederick C. Schwab Slurry process for producing styrene homopolymers and block polymers thereof using anionic catalysts
US4098980A (en) * 1976-06-24 1978-07-04 The Goodyear Tire & Rubber Company Non-aqueous dispersion polymerization of conjugated diolefins
US4357449A (en) * 1981-11-16 1982-11-02 The B. F. Goodrich Company Dispersion polymerization of cycloolefins
US4474924A (en) * 1983-01-27 1984-10-02 Exxon Research & Engineering Co. Stabilized slurries of isoolefin polymers
EP0284708B1 (en) 1987-04-03 1996-01-31 Fina Technology, Inc. Metallocene catalyst systems for olefin polymerization having a silicon hydrocarbyl bridge.
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4950724A (en) * 1988-09-27 1990-08-21 The Dow Chemical Company Suspension polymerization of vinyl aromatic monomers to polymer having high syndiotacticity
AU621474B2 (en) * 1989-03-20 1992-03-12 Dow Chemical Company, The Styrenic copolymer and production thereof
CA2027587A1 (en) * 1989-03-31 1990-10-01 Toshinori Tazaki Styrene copolymer and process for production thereof
TW408155B (en) * 1989-08-31 2000-10-11 Dow Chemical Co Blends of <alpha>-olefin/vinylidene aromatic monomer or hindered aliphatic vinylidene monomer interpolymers with polymers of vinylidene aromatic monomers
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5886117A (en) 1991-08-05 1999-03-23 The Dow Chemical Company Process using borane derived catalysts for preparation of syndiotactic vinyl aromatic polymers
DE69313354T3 (de) * 1992-06-04 2001-01-18 Mitsui Chemicals Inc Verfahren zur Herstellung von einem Ethylencopolymeren
JP3189175B2 (ja) * 1993-07-02 2001-07-16 出光興産株式会社 芳香族ビニル化合物共重合体の製造方法
JP3216748B2 (ja) * 1993-07-23 2001-10-09 出光興産株式会社 芳香族ビニル化合物重合体組成物の製造触媒及びそれを用いた芳香族ビニル化合物重合体組成物の製造方法
US5543484A (en) * 1994-11-18 1996-08-06 The Penn State Research Foundation α-olefin/para-alkylstyrene copolymers

Also Published As

Publication number Publication date
DE59602661D1 (de) 1999-09-09
JP2000500179A (ja) 2000-01-11
CN1202178A (zh) 1998-12-16
DE19542356A1 (de) 1997-05-15
EP0861273A1 (de) 1998-09-02
WO1997018248A1 (de) 1997-05-22
EP0861273B1 (de) 1999-08-04
US6221983B1 (en) 2001-04-24

Similar Documents

Publication Publication Date Title
ES2144146T3 (es) Procedimiento para producir polimeros y copolimeros de etileno de distribucion de peso molecular bimodal.
CA2193882A1 (en) Polymerization catalyst systems, their production and use
BR9810289B1 (pt) processo de preparaÇço de polÍmeros em blocos, e, polÍmero.
HUP9600390A2 (en) Components and catalysts for the polymerization of olefins, process for polymerizing olefins
WO1998035012A3 (en) Methods and products for analyzing polymers
BR0105177A (pt) Processo para produzir homopolìmeros ou copolìmeros substancialmente amorfos de propileno
ES2161066T3 (es) Procedimiento para la obtencion de polimeros de estireno expandibles.
HUP9602907A2 (en) Metallocene compounds, process for their preparation, their use in catalysts for the polymerization of olefins, process for polymerization of olefins and propylene (co)polymer
BR0012763B1 (pt) polìmero de enxerto, processo para evitar ou reduzir a formação de hidratos gasosos em sistemas lìquidos ou gasosos, e, uso de polìmeros de enxerto.
HUP9700674A3 (en) Substituted indenyl unbridged metallocenes, catalyst system containing therefor and useing them for the polymerization of olefins
ES2117065T3 (es) Catalizador para la polimerizacion de olefinas, procedimiento para su obtencion y su empleo.
ES2171668T3 (es) Catalizador en soporte de polimero para la polimerizacion de olefinas.
MX210213B (es) Procedimiento de obtencion de polimeros hidrosolubles, polimeros obtenidos y sus usos.
ES2140779T3 (es) Procedimiento para la fabricacion de una composicion que comprende un polimero vinilaromatico y un caucho por polimerizacion en presencia de un radical libre estable.
SG64939A1 (en) Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer
HUT76863A (en) Catalyst systems, process for polymerizing olefins, process for producing polymer mixtures and (co)polymer products
SG81898A1 (en) Olefin polymerization catalyst component, olefin polymerization catalyst and process for producing olefin polymer
AU9464198A (en) Supported metallocene catalyst, process for preparing the same, and process for producing olefin polymers
AU8647898A (en) Process for the preparation of olefin (co)polymers, olefin copolymers, and application thereof
ES2157445T3 (es) Procedimiento para la preparacion y empleo de un catalizador de metaloceno-alumoxano soportado.
ID30121A (id) Dispersi kopolimer encer, metode produksinya, dan penggunaannya
BR0015594B1 (pt) processo para produzir polietileno e/ou interpolìmeros de etileno e um, ou mais, outros monÈmeros interpolimerizáveis com etileno, e/ou misturas de ditos interpolìmeros.
FR2784111B1 (fr) Polymerisatin radicalaire en presence de plusieurs radicaux libres stables
AU7540700A (en) Modified supported catalysts for the polymerization of olefins
ES2135258T3 (es) Procedimiento para la obtencion de copolimeros, formados por compuestos vinilaromaticos y olefinicos, mediante polimerizacion en dispersion en presencia de sistemas catalizadores de metaloceno.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 861273

Country of ref document: ES