ES2087460T3 - Preparacion enzimatica de n-(fosfonometil)glicina. - Google Patents
Preparacion enzimatica de n-(fosfonometil)glicina.Info
- Publication number
- ES2087460T3 ES2087460T3 ES92310063T ES92310063T ES2087460T3 ES 2087460 T3 ES2087460 T3 ES 2087460T3 ES 92310063 T ES92310063 T ES 92310063T ES 92310063 T ES92310063 T ES 92310063T ES 2087460 T3 ES2087460 T3 ES 2087460T3
- Authority
- ES
- Spain
- Prior art keywords
- acid
- phosphonometil
- glycine
- enzymatic preparation
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000002360 preparation method Methods 0.000 title abstract 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 title 2
- 239000004471 Glycine Substances 0.000 title 1
- 230000002255 enzymatic effect Effects 0.000 title 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 abstract 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 abstract 4
- MGRVRXRGTBOSHW-UHFFFAOYSA-N (aminomethyl)phosphonic acid Chemical compound NCP(O)(O)=O MGRVRXRGTBOSHW-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P13/00—Preparation of nitrogen-containing organic compounds
- C12P13/04—Alpha- or beta- amino acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/373—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in doubly bound form
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
- C12P7/42—Hydroxy-carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un procedimiento para la preparación de una mezcla de ácido glioxílico y ácido aminometilfosfónico que comprende la etapa de oxidar ácido glicólico con oxígeno en una solución acuosa, en presencia de (i) ácido aminometilfosfónico, (ii) un primer catalizador adaptado para catalizar la oxidación con oxígeno de un componente ácido glicólico a un componente ácido glioxílico y peróxido de hidrógeno y (iii) un segundo catalizador adaptado para catalizar la descomposición del peróxido de hidrógeno.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78864091A | 1991-11-06 | 1991-11-06 | |
US07/788,683 US5135860A (en) | 1991-11-06 | 1991-11-06 | Process for preparing glyoxylic acid/aminomethylphosphonic acid mixtures |
US07/788,648 US5180846A (en) | 1991-11-06 | 1991-11-06 | Hydrogenation of enzymatically-produced glycolic acid/aminomethylphosphonic acid mixtures |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2087460T3 true ES2087460T3 (es) | 1996-07-16 |
Family
ID=27419857
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES92310063T Expired - Lifetime ES2087460T3 (es) | 1991-11-06 | 1992-11-03 | Preparacion enzimatica de n-(fosfonometil)glicina. |
Country Status (16)
Country | Link |
---|---|
EP (4) | EP0611399A1 (es) |
JP (2) | JPH07501940A (es) |
CN (2) | CN1073482A (es) |
AU (2) | AU658956B2 (es) |
BR (2) | BR9206882A (es) |
CA (2) | CA2123081C (es) |
CZ (2) | CZ111494A3 (es) |
DE (1) | DE69210771T2 (es) |
ES (1) | ES2087460T3 (es) |
HU (2) | HUT71955A (es) |
ID (1) | ID1002B (es) |
IL (2) | IL103646A (es) |
MX (2) | MX9206363A (es) |
MY (1) | MY130099A (es) |
NZ (2) | NZ245011A (es) |
WO (2) | WO1993009243A1 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2123081C (en) * | 1991-11-06 | 2003-02-25 | David L. Anton | Enzymatic preparation of n-(phosphonomethyl) glycine |
JPH10501984A (ja) * | 1993-03-03 | 1998-02-24 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | 形質転換微生物を用いて製造されるグリオキシル酸/アミノメチルホスホン酸混合物 |
CN1124981A (zh) * | 1993-05-28 | 1996-06-19 | 纳幕尔杜邦公司 | 水合乙醛酸/氨甲基膦酸二烷基酯混合物的制备方法 |
AU7211994A (en) * | 1993-07-01 | 1995-01-24 | E.I. Du Pont De Nemours And Company | Glycolate oxidase production |
BR9407342A (pt) * | 1993-07-01 | 1996-10-08 | Du Pont | Cepa transformante de hansenula microorganismos método de produção de glicolato oxidase enzimaticamente ativa e método de produção de glicolato oxidase e catalase enzimaticamente ativas |
AU674619B2 (en) * | 1994-12-15 | 1997-01-02 | Jack Newman | Stereoscopic micromirror display |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL48619A (en) * | 1974-12-11 | 1978-04-30 | Monsanto Co | Process for the production of n-(phosphonomethyl)-glycine compounds |
NL7514315A (nl) * | 1974-12-11 | 1976-06-15 | Monsanto Co | Werkwijze voor de bereiding van carbonylaldimino- methaanfosfonaten. |
HUT41415A (en) * | 1984-12-28 | 1987-04-28 | Monsanto Co | Process for preparing n-phosphono-methyl-glycine derivatives |
DK0496799T3 (da) * | 1989-10-16 | 1993-10-18 | Du Pont | Fremgangsmåde til fremstilling af glycoxylsyre ved enzymatisk oxidation af glycolsyre |
CA2123081C (en) * | 1991-11-06 | 2003-02-25 | David L. Anton | Enzymatic preparation of n-(phosphonomethyl) glycine |
-
1992
- 1992-11-03 CA CA002123081A patent/CA2123081C/en not_active Expired - Fee Related
- 1992-11-03 ES ES92310063T patent/ES2087460T3/es not_active Expired - Lifetime
- 1992-11-03 CZ CZ941114A patent/CZ111494A3/cs unknown
- 1992-11-03 WO PCT/US1992/009420 patent/WO1993009243A1/en not_active Application Discontinuation
- 1992-11-03 JP JP5508669A patent/JPH07501940A/ja active Pending
- 1992-11-03 AU AU30617/92A patent/AU658956B2/en not_active Ceased
- 1992-11-03 CZ CZ941113A patent/CZ111394A3/cs unknown
- 1992-11-03 EP EP92924228A patent/EP0611399A1/en active Pending
- 1992-11-03 DE DE69210771T patent/DE69210771T2/de not_active Expired - Fee Related
- 1992-11-03 HU HU9401416A patent/HUT71955A/hu unknown
- 1992-11-03 BR BR9206882A patent/BR9206882A/pt not_active Application Discontinuation
- 1992-11-03 JP JP50866893A patent/JP3315119B2/ja not_active Expired - Fee Related
- 1992-11-03 EP EP92310063A patent/EP0545553B1/en not_active Expired - Lifetime
- 1992-11-03 EP EP92924227A patent/EP0611398A1/en active Pending
- 1992-11-03 WO PCT/US1992/009419 patent/WO1993009242A1/en not_active Application Discontinuation
- 1992-11-03 CA CA002123079A patent/CA2123079C/en not_active Expired - Fee Related
- 1992-11-03 BR BR9206884A patent/BR9206884A/pt not_active Application Discontinuation
- 1992-11-03 AU AU30616/92A patent/AU673146B2/en not_active Expired - Fee Related
- 1992-11-03 HU HU9401419A patent/HUT71271A/hu unknown
- 1992-11-03 EP EP92310064A patent/EP0541333A1/en not_active Withdrawn
- 1992-11-04 NZ NZ245011A patent/NZ245011A/en not_active IP Right Cessation
- 1992-11-04 NZ NZ245012A patent/NZ245012A/en not_active IP Right Cessation
- 1992-11-04 MY MYPI92002001A patent/MY130099A/en unknown
- 1992-11-05 MX MX9206363A patent/MX9206363A/es not_active Application Discontinuation
- 1992-11-05 MX MX9206362A patent/MX9206362A/es unknown
- 1992-11-05 IL IL10364692A patent/IL103646A/en not_active IP Right Cessation
- 1992-11-05 IL IL10364592A patent/IL103645A/en not_active IP Right Cessation
- 1992-11-06 CN CN92114383A patent/CN1073482A/zh active Pending
- 1992-11-06 CN CN92114382A patent/CN1073481A/zh active Pending
- 1992-11-06 ID IDP497492A patent/ID1002B/id unknown
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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