ES2078930T3 - Alquilacion en posicion orto de aminas aromaticas. - Google Patents

Alquilacion en posicion orto de aminas aromaticas.

Info

Publication number
ES2078930T3
ES2078930T3 ES90119354T ES90119354T ES2078930T3 ES 2078930 T3 ES2078930 T3 ES 2078930T3 ES 90119354 T ES90119354 T ES 90119354T ES 90119354 T ES90119354 T ES 90119354T ES 2078930 T3 ES2078930 T3 ES 2078930T3
Authority
ES
Spain
Prior art keywords
toluenediamine
rent
aromatic amines
diethyltoluenediamine
zinc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90119354T
Other languages
English (en)
Inventor
Guo-Shuh John Lee
Rao V Durvasula
Georg E Hartwell
Kirk D Anderson
Louis N Moreno
Nirad N Shah
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2078930T3 publication Critical patent/ES2078930T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

DIAMINAS AROMATICAS, TALES COMO TOLUENODIAMINA, SON ALQUILATADAS EN LA POSICION ORTO POR CALENTAR UNA DIAMINA AROMATICA EN LA PRESENCIA DE UNA ALEACION DE ALUMINIO, CLORURO DE ALUMINIO Y, OPCIONALMENTE, CINC; Y ENTONCES REACCIONAR CON UN ALQUENO A TEMPERATURAS Y PRESIONES ELEVADAS. EN UN CASO, EL TOLUENODIAMINA, EL DIETILTOLUENODIAMINA O SUS MEZCLAS SON CALENTADAS CON UNA ALEACION DE ALUMINIO, CLORURO DE ALUMINIO Y CINC, TENIENDO UN DIAMETRO DE PARTICULAR MEDIO DE 75 A 850 MICRONES, 20 A 200 MESH, U.S. STANDARD PARA FORMAR UN SISTEMA CATALIZADOR. ESTE ES REACCIONADO CON ETENO Y TOLUENODIAMINA PARA FORMAR DIETILTOLUENODIAMINA.
ES90119354T 1989-10-10 1990-10-09 Alquilacion en posicion orto de aminas aromaticas. Expired - Lifetime ES2078930T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US41905989A 1989-10-10 1989-10-10

Publications (1)

Publication Number Publication Date
ES2078930T3 true ES2078930T3 (es) 1996-01-01

Family

ID=23660636

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90119354T Expired - Lifetime ES2078930T3 (es) 1989-10-10 1990-10-09 Alquilacion en posicion orto de aminas aromaticas.

Country Status (11)

Country Link
EP (2) EP0422591B1 (es)
JP (1) JPH03135439A (es)
KR (1) KR910007577A (es)
AT (2) ATE152441T1 (es)
AU (1) AU634585B2 (es)
BR (1) BR9005108A (es)
CA (1) CA2027191A1 (es)
DE (2) DE69030629T2 (es)
DK (1) DK0422591T3 (es)
ES (1) ES2078930T3 (es)
GR (1) GR3018221T3 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4329172A1 (de) * 1993-08-30 1995-03-02 Sel Alcatel Ag Verfahren zur Anruflenkung für ein privates, virtuelles Netz, sowie Dienstrechner und Vermittlungsstelle dafür
US8563489B2 (en) * 2007-12-12 2013-10-22 Chemtura Corporation Alkylated 1,3-benzenediamine compounds and methods for producing same
CN102807493A (zh) * 2012-05-30 2012-12-05 中国石油大学(北京) 一种离子液体催化甲苯二胺烷基化合成二乙基甲苯二胺的方法
CN102731319A (zh) * 2012-07-09 2012-10-17 赤峰万泽制药有限责任公司 一种合成2-甲基-6-异丙基苯胺的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE951501C (de) * 1953-12-24 1956-10-31 Bayer Ag Verfahren zur Herstellung von kernalkylierten aromatischen Aminen
GB823223A (en) * 1955-01-22 1959-11-11 Bayer Ag Process for the production of aromatic amines which are alkylated on the nucleus
DE3402983A1 (de) * 1984-01-28 1985-08-01 Bayer Ag, 5090 Leverkusen Verfahren zur orthoalkylierung von gegebenenfalls alkylsubstituierten m-phenylendiaminen

Also Published As

Publication number Publication date
ATE152441T1 (de) 1997-05-15
CA2027191A1 (en) 1991-04-11
EP0422591A2 (en) 1991-04-17
AU6393390A (en) 1991-04-18
DE69030629T2 (de) 1997-08-14
DK0422591T3 (da) 1996-01-29
DE69023451T2 (de) 1996-04-04
EP0614880B1 (en) 1997-05-02
BR9005108A (pt) 1991-09-17
EP0422591A3 (en) 1991-08-28
GR3018221T3 (en) 1996-02-29
ATE129994T1 (de) 1995-11-15
DE69023451D1 (de) 1995-12-14
EP0614880A1 (en) 1994-09-14
JPH03135439A (ja) 1991-06-10
KR910007577A (ko) 1991-05-30
DE69030629D1 (de) 1997-06-05
EP0422591B1 (en) 1995-11-08
AU634585B2 (en) 1993-02-25

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