ES2076719T3 - Catalizador de tipo aluminosilicato y su utilizacion en aromatizacion de hidrocarburos que comprende de 2 a 12 atomos de carbono. - Google Patents

Catalizador de tipo aluminosilicato y su utilizacion en aromatizacion de hidrocarburos que comprende de 2 a 12 atomos de carbono.

Info

Publication number
ES2076719T3
ES2076719T3 ES92403049T ES92403049T ES2076719T3 ES 2076719 T3 ES2076719 T3 ES 2076719T3 ES 92403049 T ES92403049 T ES 92403049T ES 92403049 T ES92403049 T ES 92403049T ES 2076719 T3 ES2076719 T3 ES 2076719T3
Authority
ES
Spain
Prior art keywords
hydrocarbons
galium
aromatization
carbon atoms
type catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92403049T
Other languages
English (en)
Inventor
Fabio Alario
Jean-Marie Deves
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9114205A external-priority patent/FR2683815B1/fr
Priority claimed from FR9114207A external-priority patent/FR2683741B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of ES2076719T3 publication Critical patent/ES2076719T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/87Gallosilicates; Aluminogallosilicates; Galloborosilicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44Noble metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/26After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04Alkali metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48Silver or gold
    • C07C2523/52Gold
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72Copper
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44Noble metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN CATALIZADOR COMPUESTO QUE CONTIENE: QUE CONTIENE EN SU ESTRUCTURA AL MENOS LOS ELEMENTOS SILICIO, ALUMINIO Y/O GALIO, LA FAMILIA DEL PLATINO, AL MENOS UN METAL ADICIONAL ELEGIDO EN EL GRUPO CONSTITUIDO POR EL ESTAÑO, EL GERMANIO, EL INDIO, EL COBRE, EL HIERRO, EL MOLIBDENO, EL GALIO, EL TALIO, EL ORO, LA PLATA, EL RUTENIO, EL CROMO, EL TUNGSTENO U EL PLOMO, OS UN HALOGENO ELEGIDO IMPURIFICADOR ELEGIDO EN EL GRUPO CONSTITUIDO POR EL GALIO Y EL ZINC, LEMENTO ELEGIDO EN EL GRUPO CONSTITUIDO POR LOS METALES ALCALINOS Y LOS ALCALINOTERROSOS. LA INVENCION SE REFIERE TAMBIEN A LA UTILIZACION DE ESTE CATALIZADOR EN LAS REACCIONES DE AROMATIZACION DE LOS HIDROCARBUROS QUE TIENEN DE 4 A 12 ATOMOS DE CARBONO POR MOLECULA.
ES92403049T 1991-11-15 1992-11-12 Catalizador de tipo aluminosilicato y su utilizacion en aromatizacion de hidrocarburos que comprende de 2 a 12 atomos de carbono. Expired - Lifetime ES2076719T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9114205A FR2683815B1 (fr) 1991-11-15 1991-11-15 Procede d'aromatisation d'hydrocarbures comportant 2 a 4 atomes de carbone en presence d'un catalyseur du type aluminosilicate.
FR9114207A FR2683741B1 (fr) 1991-11-15 1991-11-15 Catalyseur du type aluminosilicate, et son utilisation en aromatisation d'hydrocarbures comportant 5 a 12 atomes de carbone.

Publications (1)

Publication Number Publication Date
ES2076719T3 true ES2076719T3 (es) 1995-11-01

Family

ID=26229061

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92403049T Expired - Lifetime ES2076719T3 (es) 1991-11-15 1992-11-12 Catalizador de tipo aluminosilicato y su utilizacion en aromatizacion de hidrocarburos que comprende de 2 a 12 atomos de carbono.

Country Status (3)

Country Link
EP (1) EP0542625B1 (es)
DE (1) DE69203212T2 (es)
ES (1) ES2076719T3 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1079287C (zh) * 1998-04-23 2002-02-20 中国科学院新疆化学研究所 含镓硅酸盐分子筛催化剂的合成方法
CN1102440C (zh) * 1998-08-18 2003-03-05 中国石油化工集团公司 含结晶硅铝酸盐沸石和贵金属的催化剂及其制备方法
US7799729B2 (en) 2009-02-23 2010-09-21 Uop Llc Reforming catalyst
CN101862669B (zh) * 2010-06-23 2012-06-20 东南大学 异丁烷脱氢制异丁烯催化剂及其制备方法
CN103641102B (zh) * 2013-12-24 2015-04-08 上海同助化工科技有限公司 焦炉煤气脱苯剂的制造方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55129232A (en) * 1979-03-29 1980-10-06 Teijin Yuka Kk Isomerization of xylenes
GB8610527D0 (en) * 1986-04-30 1986-06-04 British Petroleum Co Plc Aromatics
US4808763A (en) * 1987-08-05 1989-02-28 Amoco Corporation Process for upgrading light paraffins
US4806701A (en) * 1987-08-05 1989-02-21 Amoco Corporation Process for upgrading light paraffins
FR2634139B1 (fr) * 1988-07-12 1990-09-14 Inst Francais Du Petrole Catalyseur du type gallosilicate et son utilisation en aromatisation des gaz legers c2-c4
FR2662437B1 (fr) * 1990-05-23 1992-08-28 Inst Francais Du Petrole Catalyseur contenant une zeolithe, un metal noble de la famille du platine, un metal alcalin ou alcalino terreux et un metal additionnel et son utilisation dans l'aromatisation des hydrocarbures contenant de 2 a 4 atomes de carbone par molecule.
FR2665375B1 (fr) * 1990-07-31 1992-10-16 Inst Francais Du Petrole Catalyseur de type galloaluminosilicate et son utilisation en aromatisation des hydrocarbures contenant entre 2 et 7 atomes de carbone par molecule.

Also Published As

Publication number Publication date
EP0542625B1 (fr) 1995-06-28
DE69203212T2 (de) 1995-11-02
DE69203212D1 (de) 1995-08-03
EP0542625A1 (fr) 1993-05-19

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