ES2070865T3 - Adhesivo estructural reactivo de fusion en caliente. - Google Patents

Adhesivo estructural reactivo de fusion en caliente.

Info

Publication number
ES2070865T3
ES2070865T3 ES89109505T ES89109505T ES2070865T3 ES 2070865 T3 ES2070865 T3 ES 2070865T3 ES 89109505 T ES89109505 T ES 89109505T ES 89109505 T ES89109505 T ES 89109505T ES 2070865 T3 ES2070865 T3 ES 2070865T3
Authority
ES
Spain
Prior art keywords
hot melting
structural adhesive
adhesive reagent
reagent
peel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89109505T
Other languages
English (en)
Inventor
Michael E Kimball
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel Teroson GmbH
Original Assignee
Henkel Teroson GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Teroson GmbH filed Critical Henkel Teroson GmbH
Application granted granted Critical
Publication of ES2070865T3 publication Critical patent/ES2070865T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58Component parts, details or accessories; Auxiliary operations
    • B29B7/72Measuring, controlling or regulating
    • B29B7/726Measuring properties of mixture, e.g. temperature or density
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6688Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/80Masked polyisocyanates
    • C08G18/8003Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C08G18/8012Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with diols
    • C08G18/8019Masked aromatic polyisocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00Compositions for adhesives
    • C08G2170/20Compositions for hot melt adhesives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31511Of epoxy ether
    • Y10T428/31515As intermediate layer
    • Y10T428/31522Next to metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

UNOS NUEVOS ADHESIVOS ESTRUCTURALES DE UN REACTIVO DE FUSION CALIENTE QUE COMPRENDEN UN OLIGOMERO DE URETANO Y UNA MEZCLA EPOXI EN RADIOS ESPECIFICADOS, LAS COMPOSICIONES OFRECEN UNA MUY ALTA CIZALLATURA BATIDURA Y FUERZAS DE IMPACTO, PROPIEDADES DE UN VALOR PARTICULAR EN ADHERENCIA DE ENLACES EN UNA LINEA DE MONTAJE DE ANTICUERPO.
ES89109505T 1988-05-27 1989-05-26 Adhesivo estructural reactivo de fusion en caliente. Expired - Lifetime ES2070865T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/199,491 US4962138A (en) 1988-05-27 1988-05-27 Reactive hot melt structural adhesive

Publications (1)

Publication Number Publication Date
ES2070865T3 true ES2070865T3 (es) 1995-06-16

Family

ID=22737740

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89109505T Expired - Lifetime ES2070865T3 (es) 1988-05-27 1989-05-26 Adhesivo estructural reactivo de fusion en caliente.

Country Status (10)

Country Link
US (1) US4962138A (es)
EP (1) EP0343676B1 (es)
JP (1) JP2691021B2 (es)
KR (1) KR0130893B1 (es)
AT (1) ATE122065T1 (es)
AU (1) AU3515089A (es)
DE (1) DE68922434T2 (es)
ES (1) ES2070865T3 (es)
NZ (1) NZ229299A (es)
ZA (1) ZA894010B (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5079094A (en) * 1988-05-27 1992-01-07 W. R. Grace & Co.-Conn. Article comprising metal substrates bonded with reactive hot melt structural adhesive and process thereof
FR2684387A1 (fr) * 1991-11-29 1993-06-04 Bostik Sa Systemes pour adhesifs thermofusibles reticulables, leur preparation et procede d'assemblage les utilisant.
US5936021A (en) * 1996-11-27 1999-08-10 Cabot Corporation Masterbatch and resin systems incorporating same
DE19858921A1 (de) 1998-12-19 2000-06-21 Henkel Teroson Gmbh Schlagfeste Epoxidharz-Zusammensetzungen
EP1214382A1 (en) * 1999-07-22 2002-06-19 PPG Industries Ohio, Inc. Pigmented coatings for ceramic substrates
USH2047H1 (en) 1999-11-10 2002-09-03 Henkel Corporation Reinforcement laminate
US6884854B2 (en) 2000-04-10 2005-04-26 Henkel Kommanditgesellschaft Auf Aktien Composition of epoxy resin, low glass transition temperature copolymer, latent hardener and carboxy-terminated polyamide and/or polyamide
MXPA02011492A (es) * 2001-12-03 2003-06-30 Rohm & Haas Adhesivos de curado con humedad.
US20030157276A1 (en) * 2002-02-06 2003-08-21 Eastman Kodak Company Ink recording element
EP1359202A1 (de) 2002-05-03 2003-11-05 Sika Schweiz AG Hitze-härtbare Epoxydharzzusammensetzung
US7217459B2 (en) 2002-11-25 2007-05-15 Rohm And Haas Company Moisture-curing adhesives
EP1431325A1 (de) 2002-12-17 2004-06-23 Sika Technology AG Hitze-härtbare Epoxidharzzusammensetzung mit verbesserter Tieftemperatur-Schlagzähigkeit
US20040191523A1 (en) * 2003-03-24 2004-09-30 Jihong Kye Reactive hot melt adhesive formulation for joining stamped metal and plastic parts
EP1498441A1 (de) 2003-07-16 2005-01-19 Sika Technology AG Hitzehärtende Zusammensetzungen mit Tieftemperatur-Schlagzähigkeitsmodifikatoren
WO2005047393A1 (en) * 2003-11-11 2005-05-26 Dow Global Technologies Inc. Reactive hot melt adhesive
EP1568749A1 (de) * 2004-02-25 2005-08-31 Sika Technology AG Zweikomponentiger Klebstoff zur Herstellung von Halbzeugen und Sandwich-Verbundwerkstoffen
DE102005018671B4 (de) * 2005-04-21 2008-10-09 Henkel Ag & Co. Kgaa Schlagzähe Epoxidharz-Zusammensetzungen
EP1741734A1 (de) * 2005-07-05 2007-01-10 Sika Technology AG Tieftemperaturschlagzähe hitze-härtbare Epoxidharzzusammensetzung mit Epoxidfestharzen
CN102648262B (zh) 2009-11-05 2014-12-10 陶氏环球技术有限责任公司 含有用酮肟封端的弹性增韧剂的结构环氧树脂胶粘剂
TWI475103B (zh) * 2009-12-15 2015-03-01 Ind Tech Res Inst 散熱結構
KR101981715B1 (ko) 2010-12-26 2019-05-23 다우 글로벌 테크놀로지스 엘엘씨 페놀, 폴리페놀 또는 아미노페놀 화합물로 캡핑된 쇄-연장된 탄성중합체성 강인화제를 함유하는 구조적 에폭시 수지 접착제
DE102011007897A1 (de) * 2011-04-12 2012-10-18 Henkel Ag & Co. Kgaa Schlagzähmodifizierte Klebstoffe
EP3962977A1 (en) * 2019-04-27 2022-03-09 PPG Industries Ohio Inc. Curable coating compositions
CN110041495A (zh) * 2019-05-15 2019-07-23 东莞市瑞环塑料科技有限公司 一种热熔膜用热塑性聚氨酯树脂的制造方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3424719A (en) * 1967-03-06 1969-01-28 Celanese Coatings Co Urethane modified epoxy resins
US3505283A (en) * 1967-05-15 1970-04-07 Merck & Co Inc Isocyanates as thickening agents for epoxy resins
US3635875A (en) * 1967-12-26 1972-01-18 Owens Illinois Inc Adhesive composition
BE794029A (fr) * 1972-02-28 1973-05-02 Du Pont Copolyesters thermoplastiques a segments modifies par des polyepoxydes
US4116937A (en) * 1976-08-25 1978-09-26 Trw Inc. Compliant maleimide based plastics
US4137364A (en) * 1976-11-05 1979-01-30 Monsanto Research Corporation Transparent laminate and adhesive film
US4122073A (en) * 1977-08-01 1978-10-24 National Starch And Chemical Corporation Thermoplastic copolyesters prepared from aromatic dicarboxylic acid, substituted succinic acid or anhydride, a glycol and a polymeric polyol and the use thereof in adhesives
FR2536753B2 (fr) * 1981-11-02 1987-06-19 Grace W R Ltd Compose thermoplastique a epoxy pendant, contenant de l'urethane, composition thermodurcissable le contenant et procede pour faire adherer deux substrats
CA1229192A (en) * 1982-11-29 1987-11-10 Shiow C. Lin One component, hot melt, thermosettable, epoxy containing composition
FR2609996B1 (fr) * 1987-01-22 1989-05-05 Produits Ind Cie Fse Adhesif pour collage d'acier, notamment au ferrage automobile

Also Published As

Publication number Publication date
EP0343676A2 (en) 1989-11-29
JPH0251579A (ja) 1990-02-21
AU3515089A (en) 1989-11-30
EP0343676A3 (en) 1990-06-20
DE68922434T2 (de) 1995-09-07
NZ229299A (en) 1991-05-28
KR900018307A (ko) 1990-12-21
US4962138A (en) 1990-10-09
ZA894010B (en) 1990-02-28
KR0130893B1 (ko) 1998-04-20
EP0343676B1 (en) 1995-05-03
DE68922434D1 (de) 1995-06-08
ATE122065T1 (de) 1995-05-15
JP2691021B2 (ja) 1997-12-17

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