ES2064969T3 - Procedimiento de preparacion de catalizadores revestidos a base de molibdatos de bismuto y de hierro impurificados por fosforo y potasio. - Google Patents
Procedimiento de preparacion de catalizadores revestidos a base de molibdatos de bismuto y de hierro impurificados por fosforo y potasio.Info
- Publication number
- ES2064969T3 ES2064969T3 ES91420454T ES91420454T ES2064969T3 ES 2064969 T3 ES2064969 T3 ES 2064969T3 ES 91420454 T ES91420454 T ES 91420454T ES 91420454 T ES91420454 T ES 91420454T ES 2064969 T3 ES2064969 T3 ES 2064969T3
- Authority
- ES
- Spain
- Prior art keywords
- phosphorus
- potassium
- preparation
- coated
- bismute
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 title abstract 4
- 239000011574 phosphorus Substances 0.000 title abstract 4
- 229910052698 phosphorus Inorganic materials 0.000 title abstract 4
- 239000011591 potassium Substances 0.000 title abstract 4
- 229910052700 potassium Inorganic materials 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- 229910052742 iron Inorganic materials 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 abstract 5
- 238000001354 calcination Methods 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B01J27/192—Molybdenum with bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A UN PROCESO DE PREPARACION DE CATALIZADORES REVESTIDOS A BASE DE MOLIBDATOS DE BISMUT Y DE HIERRO EXCITADOS POR FOSFORO Y POTASIO. EL PROCESO COMPRENDE LA PREPARACION DE CATALIZADORES REVESTIDOS DEL TIPO MOLIBDATOS DE BISMUT Y DE HIERRO, EXCITADOS POR FOSFORO Y POTASIO, COMPRENDIENDO LA PREPARACION DE UNA COMPOSICION INTERMEDIA CATALITICAMENTE ACTIVA, SU CALCINACION SEGUIDA DE SU TRITURACION, EL REVESTIMIENTO DE PARTICULAS DE UN SOPORTE SOLIDO E INERTE CUYA SUPERFICIE EXTERNA ES RUGOSA POR DICHA COMPOSICION TRITURADA O UNA MEZCLA QUE LA CONTIENE SEGUIDA DE LA CALCINACION DE LAS PARTICULAS ASI REVESTIDAS Y SE CARACTERIZA EN QUE: A) LA COMPOSICION INTERMEDIA CATALITICAMENTE ACTIVA ESTA EXENTA DE POTASIO Y DE FOSFORO, Y EN QUE B) LA INTRODUCCION DEL POTASIO Y DEL FOSFORO SE REALIZA DURANTE LA ETAPA DE REVESTIMIENTO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9016389A FR2670685B1 (fr) | 1990-12-20 | 1990-12-20 | Procede de preparation de catalyseurs enrobes a base de molybdates de bismuth et de fer dopes par du phosphore et du potassium. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2064969T3 true ES2064969T3 (es) | 1995-02-01 |
Family
ID=9403763
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES91420454T Expired - Lifetime ES2064969T3 (es) | 1990-12-20 | 1991-12-16 | Procedimiento de preparacion de catalizadores revestidos a base de molibdatos de bismuto y de hierro impurificados por fosforo y potasio. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5221653A (es) |
| EP (1) | EP0493275B1 (es) |
| JP (1) | JPH0763630B2 (es) |
| CN (1) | CN1032461C (es) |
| BR (1) | BR9105533A (es) |
| CA (1) | CA2058073C (es) |
| DE (1) | DE69105709T2 (es) |
| ES (1) | ES2064969T3 (es) |
| FR (1) | FR2670685B1 (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2718061B1 (fr) * | 1994-04-01 | 1996-04-26 | Rhone Poulenc Chimie | Compositions catalytiques du type enrobées, comprenant du nickel, cobalt, molybdène et leur utilisation pour la préparation d'aldéhydes insaturés. |
| JP3793317B2 (ja) * | 1996-05-14 | 2006-07-05 | 日本化薬株式会社 | 触媒及び不飽和アルデヒドおよび不飽和酸の製造方法 |
| DE19855913A1 (de) * | 1998-12-03 | 2000-06-08 | Basf Ag | Multimetalloxidmasse zur gasphasenkatalytischen Oxidation organischer Verbindungen |
| WO2003100421A1 (en) * | 2002-05-28 | 2003-12-04 | Bio Strand, Inc. | Specimen distributing device, coating part manufacturing method, specimen distributing method, and substrate activating device |
| GB0413605D0 (en) * | 2004-06-17 | 2004-07-21 | Addex Pharmaceuticals Sa | Novel compounds |
| US7851397B2 (en) | 2005-07-25 | 2010-12-14 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
| US7649112B2 (en) | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon |
| US7649111B2 (en) | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same |
| US7732367B2 (en) | 2005-07-25 | 2010-06-08 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
| KR100932373B1 (ko) * | 2007-05-30 | 2009-12-16 | 에스케이에너지 주식회사 | pH 변화에 따른 다성분계 비스무스 몰리브데이트 촉매제조방법 및 상기촉매를 이용하여 1,3-부타디엔을 제조하는방법 |
| US20090056994A1 (en) * | 2007-08-31 | 2009-03-05 | Kuhr Werner G | Methods of Treating a Surface to Promote Metal Plating and Devices Formed |
| US8921257B2 (en) | 2011-12-02 | 2014-12-30 | Saudi Basic Industries Corporation | Dual function partial oxidation catalyst for propane to acrylic acid conversion |
| US8722940B2 (en) | 2012-03-01 | 2014-05-13 | Saudi Basic Industries Corporation | High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
| CN116273098B (zh) * | 2023-03-20 | 2024-07-02 | 东南大学 | 一种界面活性复合光催化剂及其制备方法和应用 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4077912A (en) * | 1972-10-12 | 1978-03-07 | Standard Oil Company | Catalysts useful for exothermic reactions |
| US4040978A (en) * | 1975-11-28 | 1977-08-09 | Monsanto Company | Production of (amm)oxidation catalyst |
| FR2364061A1 (fr) * | 1976-09-14 | 1978-04-07 | Rhone Poulenc Ind | Nouveau catalyseur pour la preparation d'aldehydes a-b insatures par oxydation d'olefines en phase gazeuse et son procede de preparation |
| US4148757A (en) * | 1977-08-10 | 1979-04-10 | The Standard Oil Company | Process for forming multi-component oxide complex catalysts |
| US4267386A (en) * | 1978-11-13 | 1981-05-12 | Celanese Corporation | Olefin oxidation catalyst |
| DE2909597A1 (de) * | 1979-03-12 | 1980-09-25 | Basf Ag | Verfahren zur herstellung von 3 bis 4 c-atome enthaltenden alpha , beta -olefinisch ungesaettigten aldehyden |
| US4332971A (en) * | 1979-08-09 | 1982-06-01 | Celanese Corporation | Process for the oxidation of olefinically unsaturated hydrocarbons to aldehydes using attrition resistant catalysts |
| FR2481146A1 (fr) * | 1980-04-25 | 1981-10-30 | Rhone Poulenc Ind | Procede pour la preparation de catalyseurs a base d'oxydes de molybdene et/ou de tungstene et d'oxydes d'autres metaux |
| US4414134A (en) * | 1981-01-05 | 1983-11-08 | The Standard Oil Co. | Impregnating catalysts |
| DE3125062C2 (de) * | 1981-06-26 | 1984-11-22 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung von abriebfesten Schalenkatalysatoren und Verwendung eines so erhaltenen Katalysators |
| JPS5872550A (ja) * | 1981-10-26 | 1983-04-30 | Asahi Chem Ind Co Ltd | メタクリロニトリルの製造方法 |
| JPS58119346A (ja) * | 1982-01-06 | 1983-07-15 | Nippon Shokubai Kagaku Kogyo Co Ltd | プロピレン酸化用触媒 |
| US4710484A (en) * | 1982-06-25 | 1987-12-01 | The Standard Oil Company | Method for preparing a supported mixed-metal oxide oxidation catalyst |
| US4537874A (en) * | 1982-10-22 | 1985-08-27 | Nippon Shokubai Kagaku Kogyo Co Ltd | Catalyst for production of unsaturated aldehydes |
| JPS6126419A (ja) * | 1984-07-17 | 1986-02-05 | 三菱電機株式会社 | 遮断器制御装置 |
| DE3827639A1 (de) * | 1988-08-16 | 1990-02-22 | Basf Ag | Katalysator fuer die oxidation und ammonoxidation von (alpha),ss-ungesaettigten kohlenwasserstoffen |
| DE3930533C1 (es) * | 1989-09-13 | 1991-05-08 | Degussa Ag, 6000 Frankfurt, De |
-
1990
- 1990-12-20 FR FR9016389A patent/FR2670685B1/fr not_active Expired - Fee Related
-
1991
- 1991-12-16 DE DE69105709T patent/DE69105709T2/de not_active Expired - Fee Related
- 1991-12-16 EP EP91420454A patent/EP0493275B1/fr not_active Expired - Lifetime
- 1991-12-16 ES ES91420454T patent/ES2064969T3/es not_active Expired - Lifetime
- 1991-12-19 BR BR919105533A patent/BR9105533A/pt not_active IP Right Cessation
- 1991-12-19 CA CA002058073A patent/CA2058073C/fr not_active Expired - Fee Related
- 1991-12-20 US US07/811,127 patent/US5221653A/en not_active Expired - Fee Related
- 1991-12-20 CN CN91111733.4A patent/CN1032461C/zh not_active Expired - Fee Related
- 1991-12-20 JP JP3361144A patent/JPH0763630B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69105709T2 (de) | 1995-07-20 |
| DE69105709D1 (de) | 1995-01-19 |
| BR9105533A (pt) | 1992-09-01 |
| EP0493275B1 (fr) | 1994-12-07 |
| CA2058073C (fr) | 1996-06-18 |
| CA2058073A1 (fr) | 1992-06-21 |
| CN1062676A (zh) | 1992-07-15 |
| FR2670685A1 (fr) | 1992-06-26 |
| CN1032461C (zh) | 1996-08-07 |
| EP0493275A1 (fr) | 1992-07-01 |
| JPH0763630B2 (ja) | 1995-07-12 |
| FR2670685B1 (fr) | 1995-03-10 |
| JPH04300649A (ja) | 1992-10-23 |
| US5221653A (en) | 1993-06-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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