ES2063789T3 - Un metodo para obtener un articulo de espuma de poliuretano en un molde empleando un nuevo compuesto de desprendimiento con base acuosa que contiene agentes superficialmente activos de poli(siloxano-glicol). - Google Patents
Un metodo para obtener un articulo de espuma de poliuretano en un molde empleando un nuevo compuesto de desprendimiento con base acuosa que contiene agentes superficialmente activos de poli(siloxano-glicol).Info
- Publication number
- ES2063789T3 ES2063789T3 ES89112755T ES89112755T ES2063789T3 ES 2063789 T3 ES2063789 T3 ES 2063789T3 ES 89112755 T ES89112755 T ES 89112755T ES 89112755 T ES89112755 T ES 89112755T ES 2063789 T3 ES2063789 T3 ES 2063789T3
- Authority
- ES
- Spain
- Prior art keywords
- mold
- article
- composition
- polyurethane foam
- glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005830 Polyurethane Foam Polymers 0.000 title abstract 3
- 239000011496 polyurethane foam Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 2
- 239000013543 active substance Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 5
- 239000006260 foam Substances 0.000 abstract 3
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/60—Releasing, lubricating or separating agents
- B29C33/62—Releasing, lubricating or separating agents based on polymers or oligomers
- B29C33/64—Silicone
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
LA INCORPORACION DE UN SURFACTANTE DE POLI(SILOXANO-GLICOL) CON UN PUNTO DE CRISTALIZACION QUE VA DE 25 A 50 GRADOS EN UNA COMPOSICION DE LIBERACION DE MOLDE BASADA EN AGUA, QUE CONSTA DE UNA EMULSION O DISPERSION ACUOSA DE AL MENOS UNA SUSTANCIA EFICAZ DE LIBERACION Y PREFERIBLEMENTE AL MENOS UN AGENTE EMULSIONANTE QUE DA UNA CALIDAD MEJORADA DE LA SUPERFICIE DEL PRODUCTO DE ESPUMA. TAMBIEN SE REVELA UN METODO PARA LA PREPARACION DE UN ARTICULO DE ESPUMA DE POLIURETANO EN UN MOLDE MEDIANTE LA APLICACION A UNA SUPERFICIE DE MOLDE DE UNA COMPOSICION DE LIBERACION BASADA EN AGUA QUE CONSTA DE UN SISTEMA EFICAZ DE LIBERACION QUE SE ENCUENTRA EN ESTADO SOLIDO (ENDURECIDO) EN LA TEMPERATURA DE FUNDICION DEL MOLDE Y EN ESTADO LIQUIDO EN LA TEMPERATURA DE DESMOLDEAMIENTO, FUNDIENDO UNA COMPOSICION DE LA ESPUMA DE POLIURETANO EN EL MOLDE, CURANDO LA COMPOSICION Y DESMOLDEANDO EL ARTICULO DE ESPUMA. EL USO DE DICHO SISTEMA EN LA COMPOSICION ACUOSA DE LIBERACION DE MOLDE PROPORCIONA UNA REDUCCION DELOS DEFECTOS DE LA SUPERFICIE DEL ARTICULO DE ESPUMA DE POLIURETANO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/142,971 US4936917A (en) | 1988-01-12 | 1988-01-12 | Water based mold release compositions containing poly(siloxane-glycol) surfactants for making polyurethane foam article in a mold |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2063789T3 true ES2063789T3 (es) | 1995-01-16 |
Family
ID=22502014
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES89112755T Expired - Lifetime ES2063789T3 (es) | 1988-01-12 | 1989-07-11 | Un metodo para obtener un articulo de espuma de poliuretano en un molde empleando un nuevo compuesto de desprendimiento con base acuosa que contiene agentes superficialmente activos de poli(siloxano-glicol). |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4936917A (es) |
| EP (1) | EP0407636B1 (es) |
| JP (1) | JPH0618698B2 (es) |
| KR (1) | KR920000449B1 (es) |
| AU (1) | AU596330B2 (es) |
| BR (1) | BR8900072A (es) |
| CA (1) | CA1339906C (es) |
| DE (1) | DE68918089T2 (es) |
| ES (1) | ES2063789T3 (es) |
| MX (1) | MX163762B (es) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5618870A (en) * | 1994-03-16 | 1997-04-08 | Shell Oil Company | Polyketone polymer blend |
| US5746961A (en) * | 1995-12-04 | 1998-05-05 | Michael J. Stevenson | Method for enhancement of the surfaces of molded plastic products |
| US6495084B1 (en) * | 1997-11-10 | 2002-12-17 | Henkel Corporation | Molding facilitator and use thereof |
| US6372160B1 (en) | 1998-08-06 | 2002-04-16 | Genesee Polymers Corporation | Process for using aqueous release compound |
| RU2158746C2 (ru) * | 1999-02-18 | 2000-11-10 | Зао "Басайри" | Антиадгезивный состав |
| US6080800A (en) * | 1999-03-29 | 2000-06-27 | Air Products And Chemicals, Inc. | Aqueous wax dispersions as cell openers in making polyurethane flexible foams |
| WO2003028971A1 (en) * | 2001-09-20 | 2003-04-10 | Great Lakes Supply, Inc. | Release composition and related method of use |
| US7030066B1 (en) | 2001-11-12 | 2006-04-18 | Charles Piskoti | Wetting composition for high temperature metal surfaces, and method of making the same |
| EP1364761B1 (en) | 2002-05-17 | 2009-07-29 | Chukyo Yushi Co., Ltd. | Aqueous release agent composition for molding polyurethane foam |
| US7018966B2 (en) * | 2002-06-13 | 2006-03-28 | General Electric Company | Compositions and methods for preventing gel formation comprising a siloxane and an alkylamine |
| DE102005054034A1 (de) * | 2005-11-12 | 2007-05-16 | Goldschmidt Gmbh | Wässriges Trennmittel und seine Verwendung bei der Herstellung von Polyurethan-Formkörpern |
| DE102009005084A1 (de) | 2009-01-16 | 2010-07-22 | Acmos Chemie Kg | Trennmittel und dessen Verwendung für die Herstellung von Polyurethan-Formkörpern |
| DE102009012074A1 (de) | 2009-01-16 | 2010-09-23 | Acmos Chemie Kg | Trennmittel und dessen Verwendung für die Herstellung von Polyurethan-Formförpern |
| JP5802525B2 (ja) * | 2011-11-22 | 2015-10-28 | 松本油脂製薬株式会社 | タイヤ内面用離型剤およびそれを用いたタイヤの製造方法 |
| DE102013009458A1 (de) | 2013-06-06 | 2014-12-11 | Acmos Chemie Kg | Trennmittel und dessen Verwendung für die Herstellung von Polyurethan-Formkörpern |
| DE102013009636A1 (de) | 2013-06-06 | 2014-12-11 | Acmos Chemie Kg | Trennmittel und dessen Verwendung für die Herstellung von Polyurethan-Formkörpern |
| HUE045347T2 (hu) * | 2014-08-19 | 2019-12-30 | Evonik Degussa Gmbh | Hibrid diszperzió és alkalmazása |
| WO2018074257A1 (ja) * | 2016-10-18 | 2018-04-26 | 東レ・ダウコーニング株式会社 | ポリエーテル変性シリコーン組成物、それを含む界面活性剤、整泡剤、ポリウレタン発泡体形成組成物、化粧料およびその製造方法 |
| KR101917355B1 (ko) * | 2018-03-06 | 2019-01-24 | 황윤익 | 폴리우레탄 성형폼용 이형제의 제조방법 |
| CN113290751A (zh) * | 2021-04-14 | 2021-08-24 | 泉州凯平肯拓化工有限公司 | 一种用于聚氨酯类弹性体的水性离型剂 |
| EP4215333B1 (en) | 2022-01-24 | 2026-02-18 | Productos Concentrol, S.A. | Process for preparing an aqueous mould release agent |
| EP4574886A1 (en) | 2023-12-22 | 2025-06-25 | Productos Concentrol, S.A. | Additive for a release agent for moulded polyurethane foams |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2514296A (en) * | 1947-12-19 | 1950-07-04 | Standard Oil Dev Co | Solvent resistant low temperature lubricant |
| US3413390A (en) * | 1963-08-19 | 1968-11-26 | Mobay Chemical Corp | Process of molding polyurethane plastics |
| US3423503A (en) * | 1964-09-11 | 1969-01-21 | Goodyear Tire & Rubber | Mold release agent containing a polyolefin and the reaction product of dicyclopentadiene and a phenol |
| US3694530A (en) * | 1969-11-17 | 1972-09-26 | Goodyear Tire & Rubber | Method of producing an integral skin polyurethane foam |
| US3848037A (en) * | 1969-12-03 | 1974-11-12 | Cincinnati Milacron Inc | Methods of producing oil-free and wax-free surfaces on polyurethane moldings |
| US3931381A (en) * | 1970-09-04 | 1976-01-06 | The General Tire & Rubber Company | Mold release method for polyurethane integral-skin foam |
| US3706681A (en) * | 1971-03-04 | 1972-12-19 | Dow Corning | Process for stabilizing a mechanically frothed urethane foam by using a silicon surfactant composition |
| US3992502A (en) * | 1972-04-28 | 1976-11-16 | The Goodyear Tire & Rubber Company | Method for using mold release |
| US3929499A (en) * | 1972-09-08 | 1975-12-30 | Frederick L Thomas | High water-content water in oil emulsion |
| DE2255310A1 (de) * | 1972-11-11 | 1974-05-22 | Henkel & Cie Gmbh | Trennmittelloesungen fuer die formtrennung von polyurethanschaeumen |
| US3967968A (en) * | 1973-05-31 | 1976-07-06 | The Firestone Tire & Rubber Company | Band ply dope compositions |
| US4172870A (en) * | 1973-10-09 | 1979-10-30 | Millmaster Onyx Corporation | Method for permitting release of molded articles in the absence of a release agent other than a coating of zero grain soft water on the mold |
| US3968302A (en) * | 1974-02-21 | 1976-07-06 | Ball Brothers Research Corporation | Mold release composition containing tungsten disulfide |
| US4098731A (en) * | 1974-07-03 | 1978-07-04 | Bayer Aktiengesellschaft | Process for the production of foams |
| US3959242A (en) * | 1974-08-12 | 1976-05-25 | The Goodyear Tire & Rubber Company | Silane grafted poly(vinyl alcohol) film |
| JPS5121589A (ja) * | 1974-08-19 | 1976-02-20 | Fuji Polymer Ind | Shirikoonrikeizaisoseibutsu |
| US4028120A (en) * | 1974-12-20 | 1977-06-07 | Exxon Research And Engineering Company | Mold release agent for urethane foamed rubber |
| US4038088A (en) * | 1975-03-10 | 1977-07-26 | The Goodyear Tire & Rubber Company | Mold release agent |
| US4118235A (en) * | 1975-09-18 | 1978-10-03 | Daikin Kogyo Co., Ltd. | Mold release agent |
| DE2552283C3 (de) * | 1975-11-21 | 1979-09-06 | Bayer Ag, 5090 Leverkusen | Trennmittel für Artikel aus Kautschukmischungen und Kunststoffen und deren Verwendung |
| JPS5295586A (en) * | 1976-02-07 | 1977-08-11 | Fuji Koubunshi Kougiyou Kk | Metal mold releasing agent composition |
| GB1575205A (en) * | 1976-03-29 | 1980-09-17 | Ici Ltd | Process for the production of polyurethane foam mouldings |
| GB1575608A (en) * | 1976-04-06 | 1980-09-24 | Ici Ltd | Mould release agent for isocyanate bound composite bodies or sheets |
| DE2641699C3 (de) * | 1976-09-16 | 1981-02-12 | Wacker-Chemie Gmbh, 8000 Muenchen | Wäßrige Trennmitteldiorganopolysiloxanemulsionen |
| FR2383000A1 (fr) * | 1977-03-08 | 1978-10-06 | Saint Gobain | Procede pour la preparation de films, feuilles ou plaques de hautes qualites optiques en matiere plastique transparente |
| US4131662A (en) * | 1978-01-03 | 1978-12-26 | Mobay Chemical Corporation | Talc-based external mold release agent for polyurethane foams |
| DE2916700A1 (de) * | 1979-04-25 | 1980-10-30 | Metzeler Kautschuk | Trennmittel zum ausformen von kunststoffen, insbesondere polyurethan-kunststoffen |
| US4309508A (en) * | 1980-06-30 | 1982-01-05 | Union Carbide Corporation | Siloxane copolymer mixtures useful as foam stabilizers in high resilience polyurethane foam |
| US4396673A (en) * | 1980-08-22 | 1983-08-02 | Imperial Chemical Industries Limited | Methods for the manufacture of particle board utilizing an isocyanate binder and mineral wax release agent in an aqueous emulsion |
| GB2092165A (en) * | 1981-02-04 | 1982-08-11 | Ici Plc | Polysocyanate wax dispersions and their use in the manufacture of sheets or moulded bodies |
| US4491607A (en) * | 1981-11-23 | 1985-01-01 | Park Chemical Company | Mold release agents and means of application |
| JPS5932513B2 (ja) * | 1982-05-14 | 1984-08-09 | ダイキン工業株式会社 | 離型剤 |
| US4451425A (en) * | 1983-01-28 | 1984-05-29 | The Dow Chemical Company | Method for injection molding polyurethane using internal release agents |
| US4454050A (en) * | 1983-03-21 | 1984-06-12 | Pennwalt Corporation | Aqueous release agent and lubricant |
| US4532096A (en) * | 1983-05-09 | 1985-07-30 | Bogner Ben R | Method of shaping articles using shaping surfaces having release agent coating |
| US4534928A (en) * | 1983-12-19 | 1985-08-13 | Dow Corning Corporation | Molding process using room temperature curing silicone coatings to provide multiple release of articles |
| US4473403A (en) * | 1984-02-15 | 1984-09-25 | Park Chemical Company | Mold release agents for open-cell molded foamed articles and means of application |
| ATE90906T1 (de) * | 1984-03-16 | 1993-07-15 | Air Products And Chemicals Pur | Formtrennmittel und mit diesem durchfuehrbares verfahren zur herstellung von gegenstaenden aus polyurethanschaum. |
| US4678815A (en) * | 1985-06-27 | 1987-07-07 | Stauffer-Wacker Silicones Corporation | Aqueous silicone emulsions as bladder lubricants |
| DE3541513A1 (de) * | 1985-11-21 | 1987-05-27 | Teroson Gmbh | Verfahren zur herstellung von gegenstaenden aus polyurethanschaum und additiv fuer die durchfuehrung dieses verfahrens |
| JPS62277470A (ja) * | 1986-05-23 | 1987-12-02 | Shin Etsu Chem Co Ltd | 合成樹脂用改質剤 |
| US4769174A (en) * | 1987-09-29 | 1988-09-06 | Union Carbide Corporation | Polyether silicone copolymers with secondary or tertiary hydroxy terminated for stabilizing high resiliency urethane foam |
| US5008103A (en) * | 1988-12-29 | 1991-04-16 | General Electric Company | Silicone surfactants |
-
1988
- 1988-01-12 US US07/142,971 patent/US4936917A/en not_active Expired - Lifetime
-
1989
- 1989-01-09 BR BR898900072A patent/BR8900072A/pt not_active IP Right Cessation
- 1989-01-10 CA CA000587845A patent/CA1339906C/en not_active Expired - Fee Related
- 1989-01-11 JP JP1002977A patent/JPH0618698B2/ja not_active Expired - Lifetime
- 1989-01-12 KR KR1019890000258A patent/KR920000449B1/ko not_active Expired
- 1989-01-12 MX MX14516A patent/MX163762B/es unknown
- 1989-01-12 AU AU28392/89A patent/AU596330B2/en not_active Ceased
- 1989-07-11 EP EP89112755A patent/EP0407636B1/en not_active Expired - Lifetime
- 1989-07-11 DE DE68918089T patent/DE68918089T2/de not_active Expired - Fee Related
- 1989-07-11 ES ES89112755T patent/ES2063789T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE68918089D1 (de) | 1994-10-13 |
| BR8900072A (pt) | 1989-09-05 |
| AU2839289A (en) | 1989-07-13 |
| MX163762B (es) | 1992-06-19 |
| US4936917A (en) | 1990-06-26 |
| EP0407636B1 (en) | 1994-09-07 |
| KR890011952A (ko) | 1989-08-23 |
| JPH0618698B2 (ja) | 1994-03-16 |
| CA1339906C (en) | 1998-06-09 |
| JPH0373317A (ja) | 1991-03-28 |
| AU596330B2 (en) | 1990-04-26 |
| DE68918089T2 (de) | 1995-01-12 |
| KR920000449B1 (ko) | 1992-01-14 |
| EP0407636A1 (en) | 1991-01-16 |
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Legal Events
| Date | Code | Title | Description |
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| FG2A | Definitive protection |
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