ES2063789T3 - Un metodo para obtener un articulo de espuma de poliuretano en un molde empleando un nuevo compuesto de desprendimiento con base acuosa que contiene agentes superficialmente activos de poli(siloxano-glicol). - Google Patents

Un metodo para obtener un articulo de espuma de poliuretano en un molde empleando un nuevo compuesto de desprendimiento con base acuosa que contiene agentes superficialmente activos de poli(siloxano-glicol).

Info

Publication number
ES2063789T3
ES2063789T3 ES89112755T ES89112755T ES2063789T3 ES 2063789 T3 ES2063789 T3 ES 2063789T3 ES 89112755 T ES89112755 T ES 89112755T ES 89112755 T ES89112755 T ES 89112755T ES 2063789 T3 ES2063789 T3 ES 2063789T3
Authority
ES
Spain
Prior art keywords
mold
article
composition
polyurethane foam
glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89112755T
Other languages
English (en)
Inventor
Mark E Harakal
George J Wasilczyk
Gary D Andrew
Michael Scarpati
Zdzislaw Makus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Application granted granted Critical
Publication of ES2063789T3 publication Critical patent/ES2063789T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • C08L83/06Polysiloxanes containing silicon bound to oxygen-containing groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60Releasing, lubricating or separating agents
    • B29C33/62Releasing, lubricating or separating agents based on polymers or oligomers
    • B29C33/64Silicone
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01Wetting, emulsifying, dispersing, or stabilizing agents

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

LA INCORPORACION DE UN SURFACTANTE DE POLI(SILOXANO-GLICOL) CON UN PUNTO DE CRISTALIZACION QUE VA DE 25 A 50 GRADOS EN UNA COMPOSICION DE LIBERACION DE MOLDE BASADA EN AGUA, QUE CONSTA DE UNA EMULSION O DISPERSION ACUOSA DE AL MENOS UNA SUSTANCIA EFICAZ DE LIBERACION Y PREFERIBLEMENTE AL MENOS UN AGENTE EMULSIONANTE QUE DA UNA CALIDAD MEJORADA DE LA SUPERFICIE DEL PRODUCTO DE ESPUMA. TAMBIEN SE REVELA UN METODO PARA LA PREPARACION DE UN ARTICULO DE ESPUMA DE POLIURETANO EN UN MOLDE MEDIANTE LA APLICACION A UNA SUPERFICIE DE MOLDE DE UNA COMPOSICION DE LIBERACION BASADA EN AGUA QUE CONSTA DE UN SISTEMA EFICAZ DE LIBERACION QUE SE ENCUENTRA EN ESTADO SOLIDO (ENDURECIDO) EN LA TEMPERATURA DE FUNDICION DEL MOLDE Y EN ESTADO LIQUIDO EN LA TEMPERATURA DE DESMOLDEAMIENTO, FUNDIENDO UNA COMPOSICION DE LA ESPUMA DE POLIURETANO EN EL MOLDE, CURANDO LA COMPOSICION Y DESMOLDEANDO EL ARTICULO DE ESPUMA. EL USO DE DICHO SISTEMA EN LA COMPOSICION ACUOSA DE LIBERACION DE MOLDE PROPORCIONA UNA REDUCCION DELOS DEFECTOS DE LA SUPERFICIE DEL ARTICULO DE ESPUMA DE POLIURETANO.
ES89112755T 1988-01-12 1989-07-11 Un metodo para obtener un articulo de espuma de poliuretano en un molde empleando un nuevo compuesto de desprendimiento con base acuosa que contiene agentes superficialmente activos de poli(siloxano-glicol). Expired - Lifetime ES2063789T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/142,971 US4936917A (en) 1988-01-12 1988-01-12 Water based mold release compositions containing poly(siloxane-glycol) surfactants for making polyurethane foam article in a mold

Publications (1)

Publication Number Publication Date
ES2063789T3 true ES2063789T3 (es) 1995-01-16

Family

ID=22502014

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89112755T Expired - Lifetime ES2063789T3 (es) 1988-01-12 1989-07-11 Un metodo para obtener un articulo de espuma de poliuretano en un molde empleando un nuevo compuesto de desprendimiento con base acuosa que contiene agentes superficialmente activos de poli(siloxano-glicol).

Country Status (10)

Country Link
US (1) US4936917A (es)
EP (1) EP0407636B1 (es)
JP (1) JPH0618698B2 (es)
KR (1) KR920000449B1 (es)
AU (1) AU596330B2 (es)
BR (1) BR8900072A (es)
CA (1) CA1339906C (es)
DE (1) DE68918089T2 (es)
ES (1) ES2063789T3 (es)
MX (1) MX163762B (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5618870A (en) * 1994-03-16 1997-04-08 Shell Oil Company Polyketone polymer blend
US5746961A (en) * 1995-12-04 1998-05-05 Michael J. Stevenson Method for enhancement of the surfaces of molded plastic products
US6495084B1 (en) * 1997-11-10 2002-12-17 Henkel Corporation Molding facilitator and use thereof
US6372160B1 (en) 1998-08-06 2002-04-16 Genesee Polymers Corporation Process for using aqueous release compound
RU2158746C2 (ru) * 1999-02-18 2000-11-10 Зао "Басайри" Антиадгезивный состав
US6080800A (en) * 1999-03-29 2000-06-27 Air Products And Chemicals, Inc. Aqueous wax dispersions as cell openers in making polyurethane flexible foams
WO2003028971A1 (en) * 2001-09-20 2003-04-10 Great Lakes Supply, Inc. Release composition and related method of use
US7030066B1 (en) 2001-11-12 2006-04-18 Charles Piskoti Wetting composition for high temperature metal surfaces, and method of making the same
EP1364761B1 (en) 2002-05-17 2009-07-29 Chukyo Yushi Co., Ltd. Aqueous release agent composition for molding polyurethane foam
US7018966B2 (en) * 2002-06-13 2006-03-28 General Electric Company Compositions and methods for preventing gel formation comprising a siloxane and an alkylamine
DE102005054034A1 (de) * 2005-11-12 2007-05-16 Goldschmidt Gmbh Wässriges Trennmittel und seine Verwendung bei der Herstellung von Polyurethan-Formkörpern
DE102009005084A1 (de) 2009-01-16 2010-07-22 Acmos Chemie Kg Trennmittel und dessen Verwendung für die Herstellung von Polyurethan-Formkörpern
DE102009012074A1 (de) 2009-01-16 2010-09-23 Acmos Chemie Kg Trennmittel und dessen Verwendung für die Herstellung von Polyurethan-Formförpern
JP5802525B2 (ja) * 2011-11-22 2015-10-28 松本油脂製薬株式会社 タイヤ内面用離型剤およびそれを用いたタイヤの製造方法
DE102013009458A1 (de) 2013-06-06 2014-12-11 Acmos Chemie Kg Trennmittel und dessen Verwendung für die Herstellung von Polyurethan-Formkörpern
DE102013009636A1 (de) 2013-06-06 2014-12-11 Acmos Chemie Kg Trennmittel und dessen Verwendung für die Herstellung von Polyurethan-Formkörpern
HUE045347T2 (hu) * 2014-08-19 2019-12-30 Evonik Degussa Gmbh Hibrid diszperzió és alkalmazása
WO2018074257A1 (ja) * 2016-10-18 2018-04-26 東レ・ダウコーニング株式会社 ポリエーテル変性シリコーン組成物、それを含む界面活性剤、整泡剤、ポリウレタン発泡体形成組成物、化粧料およびその製造方法
KR101917355B1 (ko) * 2018-03-06 2019-01-24 황윤익 폴리우레탄 성형폼용 이형제의 제조방법
CN113290751A (zh) * 2021-04-14 2021-08-24 泉州凯平肯拓化工有限公司 一种用于聚氨酯类弹性体的水性离型剂
EP4215333B1 (en) 2022-01-24 2026-02-18 Productos Concentrol, S.A. Process for preparing an aqueous mould release agent
EP4574886A1 (en) 2023-12-22 2025-06-25 Productos Concentrol, S.A. Additive for a release agent for moulded polyurethane foams

Family Cites Families (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2514296A (en) * 1947-12-19 1950-07-04 Standard Oil Dev Co Solvent resistant low temperature lubricant
US3413390A (en) * 1963-08-19 1968-11-26 Mobay Chemical Corp Process of molding polyurethane plastics
US3423503A (en) * 1964-09-11 1969-01-21 Goodyear Tire & Rubber Mold release agent containing a polyolefin and the reaction product of dicyclopentadiene and a phenol
US3694530A (en) * 1969-11-17 1972-09-26 Goodyear Tire & Rubber Method of producing an integral skin polyurethane foam
US3848037A (en) * 1969-12-03 1974-11-12 Cincinnati Milacron Inc Methods of producing oil-free and wax-free surfaces on polyurethane moldings
US3931381A (en) * 1970-09-04 1976-01-06 The General Tire & Rubber Company Mold release method for polyurethane integral-skin foam
US3706681A (en) * 1971-03-04 1972-12-19 Dow Corning Process for stabilizing a mechanically frothed urethane foam by using a silicon surfactant composition
US3992502A (en) * 1972-04-28 1976-11-16 The Goodyear Tire & Rubber Company Method for using mold release
US3929499A (en) * 1972-09-08 1975-12-30 Frederick L Thomas High water-content water in oil emulsion
DE2255310A1 (de) * 1972-11-11 1974-05-22 Henkel & Cie Gmbh Trennmittelloesungen fuer die formtrennung von polyurethanschaeumen
US3967968A (en) * 1973-05-31 1976-07-06 The Firestone Tire & Rubber Company Band ply dope compositions
US4172870A (en) * 1973-10-09 1979-10-30 Millmaster Onyx Corporation Method for permitting release of molded articles in the absence of a release agent other than a coating of zero grain soft water on the mold
US3968302A (en) * 1974-02-21 1976-07-06 Ball Brothers Research Corporation Mold release composition containing tungsten disulfide
US4098731A (en) * 1974-07-03 1978-07-04 Bayer Aktiengesellschaft Process for the production of foams
US3959242A (en) * 1974-08-12 1976-05-25 The Goodyear Tire & Rubber Company Silane grafted poly(vinyl alcohol) film
JPS5121589A (ja) * 1974-08-19 1976-02-20 Fuji Polymer Ind Shirikoonrikeizaisoseibutsu
US4028120A (en) * 1974-12-20 1977-06-07 Exxon Research And Engineering Company Mold release agent for urethane foamed rubber
US4038088A (en) * 1975-03-10 1977-07-26 The Goodyear Tire & Rubber Company Mold release agent
US4118235A (en) * 1975-09-18 1978-10-03 Daikin Kogyo Co., Ltd. Mold release agent
DE2552283C3 (de) * 1975-11-21 1979-09-06 Bayer Ag, 5090 Leverkusen Trennmittel für Artikel aus Kautschukmischungen und Kunststoffen und deren Verwendung
JPS5295586A (en) * 1976-02-07 1977-08-11 Fuji Koubunshi Kougiyou Kk Metal mold releasing agent composition
GB1575205A (en) * 1976-03-29 1980-09-17 Ici Ltd Process for the production of polyurethane foam mouldings
GB1575608A (en) * 1976-04-06 1980-09-24 Ici Ltd Mould release agent for isocyanate bound composite bodies or sheets
DE2641699C3 (de) * 1976-09-16 1981-02-12 Wacker-Chemie Gmbh, 8000 Muenchen Wäßrige Trennmitteldiorganopolysiloxanemulsionen
FR2383000A1 (fr) * 1977-03-08 1978-10-06 Saint Gobain Procede pour la preparation de films, feuilles ou plaques de hautes qualites optiques en matiere plastique transparente
US4131662A (en) * 1978-01-03 1978-12-26 Mobay Chemical Corporation Talc-based external mold release agent for polyurethane foams
DE2916700A1 (de) * 1979-04-25 1980-10-30 Metzeler Kautschuk Trennmittel zum ausformen von kunststoffen, insbesondere polyurethan-kunststoffen
US4309508A (en) * 1980-06-30 1982-01-05 Union Carbide Corporation Siloxane copolymer mixtures useful as foam stabilizers in high resilience polyurethane foam
US4396673A (en) * 1980-08-22 1983-08-02 Imperial Chemical Industries Limited Methods for the manufacture of particle board utilizing an isocyanate binder and mineral wax release agent in an aqueous emulsion
GB2092165A (en) * 1981-02-04 1982-08-11 Ici Plc Polysocyanate wax dispersions and their use in the manufacture of sheets or moulded bodies
US4491607A (en) * 1981-11-23 1985-01-01 Park Chemical Company Mold release agents and means of application
JPS5932513B2 (ja) * 1982-05-14 1984-08-09 ダイキン工業株式会社 離型剤
US4451425A (en) * 1983-01-28 1984-05-29 The Dow Chemical Company Method for injection molding polyurethane using internal release agents
US4454050A (en) * 1983-03-21 1984-06-12 Pennwalt Corporation Aqueous release agent and lubricant
US4532096A (en) * 1983-05-09 1985-07-30 Bogner Ben R Method of shaping articles using shaping surfaces having release agent coating
US4534928A (en) * 1983-12-19 1985-08-13 Dow Corning Corporation Molding process using room temperature curing silicone coatings to provide multiple release of articles
US4473403A (en) * 1984-02-15 1984-09-25 Park Chemical Company Mold release agents for open-cell molded foamed articles and means of application
ATE90906T1 (de) * 1984-03-16 1993-07-15 Air Products And Chemicals Pur Formtrennmittel und mit diesem durchfuehrbares verfahren zur herstellung von gegenstaenden aus polyurethanschaum.
US4678815A (en) * 1985-06-27 1987-07-07 Stauffer-Wacker Silicones Corporation Aqueous silicone emulsions as bladder lubricants
DE3541513A1 (de) * 1985-11-21 1987-05-27 Teroson Gmbh Verfahren zur herstellung von gegenstaenden aus polyurethanschaum und additiv fuer die durchfuehrung dieses verfahrens
JPS62277470A (ja) * 1986-05-23 1987-12-02 Shin Etsu Chem Co Ltd 合成樹脂用改質剤
US4769174A (en) * 1987-09-29 1988-09-06 Union Carbide Corporation Polyether silicone copolymers with secondary or tertiary hydroxy terminated for stabilizing high resiliency urethane foam
US5008103A (en) * 1988-12-29 1991-04-16 General Electric Company Silicone surfactants

Also Published As

Publication number Publication date
DE68918089D1 (de) 1994-10-13
BR8900072A (pt) 1989-09-05
AU2839289A (en) 1989-07-13
MX163762B (es) 1992-06-19
US4936917A (en) 1990-06-26
EP0407636B1 (en) 1994-09-07
KR890011952A (ko) 1989-08-23
JPH0618698B2 (ja) 1994-03-16
CA1339906C (en) 1998-06-09
JPH0373317A (ja) 1991-03-28
AU596330B2 (en) 1990-04-26
DE68918089T2 (de) 1995-01-12
KR920000449B1 (ko) 1992-01-14
EP0407636A1 (en) 1991-01-16

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