ES2061387B1 - Sensor optico de oxigeno basado en complejos fosforescentes metal-ferron. - Google Patents

Sensor optico de oxigeno basado en complejos fosforescentes metal-ferron.

Info

Publication number
ES2061387B1
ES2061387B1 ES09202641A ES9202641A ES2061387B1 ES 2061387 B1 ES2061387 B1 ES 2061387B1 ES 09202641 A ES09202641 A ES 09202641A ES 9202641 A ES9202641 A ES 9202641A ES 2061387 B1 ES2061387 B1 ES 2061387B1
Authority
ES
Spain
Prior art keywords
ferron
complexes
immobilized
metal
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES09202641A
Other languages
English (en)
Other versions
ES2061387A1 (es
Inventor
Medel Alfredo Sanz
Garcia M Del Rosario Pereiro
Garcia Marta Elena Diaz
Yi-Ming Liu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universidad de Oviedo
Original Assignee
Universidad de Oviedo
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universidad de Oviedo filed Critical Universidad de Oviedo
Priority to ES09202641A priority Critical patent/ES2061387B1/es
Priority to EP93500176A priority patent/EP0605355A1/en
Publication of ES2061387A1 publication Critical patent/ES2061387A1/es
Application granted granted Critical
Publication of ES2061387B1 publication Critical patent/ES2061387B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01—Arrangements or apparatus for facilitating the optical investigation
    • G01N21/03—Cuvette constructions
    • G01N21/05—Flow-through cuvettes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/62—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing gallium, indium or thallium
    • C09K11/621—Chalcogenides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/64—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing aluminium
    • C09K11/648—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/67—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing refractory metals
    • C09K11/679—Sulfates
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64—Fluorescence; Phosphorescence
    • G01N21/6408—Fluorescence; Phosphorescence with measurement of decay time, time resolved fluorescence
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64—Fluorescence; Phosphorescence
    • G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
    • G01N35/08—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor using a stream of discrete samples flowing along a tube system, e.g. flow injection analysis
    • G01N35/085—Flow Injection Analysis
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01—Arrangements or apparatus for facilitating the optical investigation
    • G01N21/03—Cuvette constructions
    • G01N2021/0325—Cells for testing reactions, e.g. containing reagents
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01—Arrangements or apparatus for facilitating the optical investigation
    • G01N21/03—Cuvette constructions
    • G01N2021/0346—Capillary cells; Microcells
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64—Fluorescence; Phosphorescence
    • G01N2021/6417—Spectrofluorimetric devices

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Physics & Mathematics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Pathology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Optics & Photonics (AREA)
  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Investigating Or Analysing Biological Materials (AREA)

Abstract

SENSOR OPTICO DE OXIGENO BASADO EN COMPLEJOS FOSFORESCENTES METAL-FERRON QUE PUEDEN SER INMOVILIZADOS SOBRE LA SUPERFICIE SOLIDA DE LAS PARTICULAS DE UNA RESINA INTERCAMBIADORA ANIONICA. LOS COMPLEJOS CONTIENEN UN GRUPO SOSI3 SC QUE HACE POSIBLE LA INMOVILIZACION Y CONSISTENCIA EN AL MENOS UN ION ALUMINIO COMPLEJADO CON UNA MOLECULA DE FERRON. LA FASE SENSORA EMITE FOSFORESCENCIA CON UN MAXIMO DE UNOS 600 NM CUANDO ES EXCITADA UTILIZANDO UNA LONGITUD DE ONDA DE APROXIMADAMENTE 390 NM, LOGRANDO UN TIEMPO DE VIDA DE LA EMISION FOSFORESCENTE MUY LARGO. LA EMISION FOSFORESCENTE ES ALTAMENTE SENSIBLE A LA DESACTIVACION POR OXIGENO. LOS COMPLEJOS SON INMOVILIZADOS SOBRE UN SOPORTE SOLIDO POR UN PROCESO DE CAMBIO IONICO. EL INDICADOR INMOVILIZADO NO SE LIXIVIA EN PRESENCIA DE AGUA O DISOLVENTES ORGANICOS COMUNES. SE PROPORCIONA UN SISTEMA FIA ADECUADO PARA LA CONSTRUCCION DE BIOSENSORES EN QUE EL OXIGENO FORMA PARTE DE LA REACCION DE RECONOCIMIENTO.
ES09202641A 1992-12-30 1992-12-30 Sensor optico de oxigeno basado en complejos fosforescentes metal-ferron. Expired - Fee Related ES2061387B1 (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES09202641A ES2061387B1 (es) 1992-12-30 1992-12-30 Sensor optico de oxigeno basado en complejos fosforescentes metal-ferron.
EP93500176A EP0605355A1 (en) 1992-12-30 1993-12-29 Oxygen-quenchable phosphorescent materials and their applications in oxygen sensing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES09202641A ES2061387B1 (es) 1992-12-30 1992-12-30 Sensor optico de oxigeno basado en complejos fosforescentes metal-ferron.

Publications (2)

Publication Number Publication Date
ES2061387A1 ES2061387A1 (es) 1994-12-01
ES2061387B1 true ES2061387B1 (es) 1995-07-01

Family

ID=8279251

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09202641A Expired - Fee Related ES2061387B1 (es) 1992-12-30 1992-12-30 Sensor optico de oxigeno basado en complejos fosforescentes metal-ferron.

Country Status (2)

Country Link
EP (1) EP0605355A1 (es)
ES (1) ES2061387B1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1235185A (zh) * 1998-05-12 1999-11-17 湖南大学 用于荧光熄灭氧传感器的高灵敏度氧敏感发光材料
SG147471A1 (en) * 2003-10-18 2008-11-28 Bayer Healthcare Ag Direct observation of molecular modifications in biological test systems by measuring fluorescence lifetime
ES2279692B1 (es) * 2005-07-02 2008-07-16 Universidad De Granada Instrumento portatil y metodo para la medida de la concentracion de gases.
AR066836A1 (es) * 2008-06-03 2009-09-16 Jenck S A Composicion para la deteccion y/o determinacion colorimetrica de cationes metalicos en solucion columna de reaccion celda de flujo y metodo para la deteccion y/o determinacion colorimetrica de cationes metalicos en solucion
CN106118631A (zh) * 2016-06-17 2016-11-16 华东理工大学 一种纯有机室温磷光聚合物材料的制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3612866A (en) * 1969-07-08 1971-10-12 Brian Stevens Instrument for determining oxygen quantities by measuring oxygen quenching of fluorescent radiation
US4900933A (en) * 1986-09-08 1990-02-13 C. R. Bard, Inc. Excitation and detection apparatus for remote sensor connected by optical fiber
US4861727A (en) * 1986-09-08 1989-08-29 C. R. Bard, Inc. Luminescent oxygen sensor based on a lanthanide complex
US5047627A (en) * 1990-05-18 1991-09-10 Abbott Laboratories Configuration fiber-optic blood gas sensor bundle and method of making

Also Published As

Publication number Publication date
ES2061387A1 (es) 1994-12-01
EP0605355A1 (en) 1994-07-06

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Effective date: 20141120