ES2055377T3 - Procedimiento para la preparacion de halogenoacetales a partir de enaminas. - Google Patents
Procedimiento para la preparacion de halogenoacetales a partir de enaminas.Info
- Publication number
- ES2055377T3 ES2055377T3 ES90403392T ES90403392T ES2055377T3 ES 2055377 T3 ES2055377 T3 ES 2055377T3 ES 90403392 T ES90403392 T ES 90403392T ES 90403392 T ES90403392 T ES 90403392T ES 2055377 T3 ES2055377 T3 ES 2055377T3
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- preparation
- halogenoacetals
- enamines
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000002081 enamines Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 229940088594 vitamin Drugs 0.000 abstract 1
- 229930003231 vitamin Natural products 0.000 abstract 1
- 235000013343 vitamin Nutrition 0.000 abstract 1
- 239000011782 vitamin Substances 0.000 abstract 1
- 150000003722 vitamin derivatives Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/06—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals
- C07D295/067—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals with the ring nitrogen atoms and the substituents attached to the same carbon chain, which is not interrupted by carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
- C07C403/14—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/30—Compounds having groups
- C07C43/313—Compounds having groups containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D317/16—Radicals substituted by halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A UN PROCEDIMIENTO DE PREPARACION DE HALOGENO-ACETALES ETILINICOS POR REACCION DE UN CATION HALOGENO EN UNA ENAMINA SEGUIDA POR UN HIDROLISO Y LA REACCION CON UN ALCOHOL, UN GLICOL O UN ORTOFORMIATO. ESTOS HALOGENO-ACETALES SON UTILIZADOS COMO INTERMEDIARIOS DE SINTESIS DE VITAMINAS A Y E.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR898915868A FR2655333B1 (fr) | 1989-12-01 | 1989-12-01 | Procede de preparation d'halogenoacetals a partir d'enamines. |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2055377T3 true ES2055377T3 (es) | 1994-08-16 |
Family
ID=9388026
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90403392T Expired - Lifetime ES2055377T3 (es) | 1989-12-01 | 1990-11-29 | Procedimiento para la preparacion de halogenoacetales a partir de enaminas. |
Country Status (8)
Country | Link |
---|---|
US (2) | US5145972A (es) |
EP (1) | EP0430806B1 (es) |
JP (1) | JPH03220150A (es) |
AT (1) | ATE106858T1 (es) |
CA (1) | CA2031249A1 (es) |
DE (1) | DE69009698T2 (es) |
ES (1) | ES2055377T3 (es) |
FR (1) | FR2655333B1 (es) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5344995A (en) * | 1992-07-14 | 1994-09-06 | Basf Aktiengesellschaft | Preparation of cyclic acetals of 3-formyl-2-butenyltriphenylphosphonium chloride |
DE4426561A1 (de) * | 1994-07-27 | 1996-02-01 | Basf Ag | Verfahren zur Herstellung von Phosphonsäureestern |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3428633A (en) * | 1966-12-19 | 1969-02-18 | Monsanto Co | Salts of enaminoketones and processes for their preparation |
BE794872A (fr) * | 1972-02-02 | 1973-08-01 | Rhone Poulenc Sa | Nouvelles sulfones derivees de dimethyl-1,5 hexadiene-1,5 ylene |
NL176165C (nl) * | 1976-02-25 | 1985-03-01 | Rhone Poulenc Ind | Werkwijze voor het bereiden van halogeenacetalen van alkenisch onverzadigde aldehyden. |
NL175906C (nl) * | 1976-02-25 | 1985-01-16 | Rhone Poulenc Ind | Werkwijze voor het bereiden van halogeenacetalen van alkenisch onverzadigde aldehyden. |
US4087405A (en) * | 1977-08-26 | 1978-05-02 | Eastman Kodak Company | Polyhydrazides as stabilizers for polyolefins |
FR2655342A1 (fr) * | 1989-12-01 | 1991-06-07 | Rhone Poulenc Sante | Nouveaux intermediaires, leur procede de preparation et leur utilisation pour la synthese des vitamines a et e. |
-
1989
- 1989-12-01 FR FR898915868A patent/FR2655333B1/fr not_active Expired - Lifetime
-
1990
- 1990-11-29 AT AT90403392T patent/ATE106858T1/de not_active IP Right Cessation
- 1990-11-29 ES ES90403392T patent/ES2055377T3/es not_active Expired - Lifetime
- 1990-11-29 EP EP90403392A patent/EP0430806B1/fr not_active Expired - Lifetime
- 1990-11-29 DE DE69009698T patent/DE69009698T2/de not_active Expired - Fee Related
- 1990-11-30 JP JP2336846A patent/JPH03220150A/ja active Pending
- 1990-11-30 CA CA002031249A patent/CA2031249A1/fr not_active Abandoned
- 1990-12-03 US US07/620,610 patent/US5145972A/en not_active Expired - Fee Related
-
1992
- 1992-03-27 US US07/858,406 patent/US5292897A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2031249A1 (fr) | 1991-06-02 |
FR2655333A1 (fr) | 1991-06-07 |
ATE106858T1 (de) | 1994-06-15 |
DE69009698D1 (de) | 1994-07-14 |
JPH03220150A (ja) | 1991-09-27 |
DE69009698T2 (de) | 1994-11-03 |
US5292897A (en) | 1994-03-08 |
EP0430806A1 (fr) | 1991-06-05 |
US5145972A (en) | 1992-09-08 |
EP0430806B1 (fr) | 1994-06-08 |
FR2655333B1 (fr) | 1992-02-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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