ES2008314A6 - Procedimiento de obtencion de sales de amonio cuaternario, utiles como catalizadores de transferencia de fase. - Google Patents

Procedimiento de obtencion de sales de amonio cuaternario, utiles como catalizadores de transferencia de fase.

Info

Publication number
ES2008314A6
ES2008314A6 ES8703170A ES8703170A ES2008314A6 ES 2008314 A6 ES2008314 A6 ES 2008314A6 ES 8703170 A ES8703170 A ES 8703170A ES 8703170 A ES8703170 A ES 8703170A ES 2008314 A6 ES2008314 A6 ES 2008314A6
Authority
ES
Spain
Prior art keywords
quaternary ammonium
ammonium salts
phase transfer
transfer catalysts
salts used
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES8703170A
Other languages
English (en)
Inventor
Carlos Sunkel
De Casa Juana Miguel Fau
Fernando Dorrego
Basilio Pando
Julio Alvarez-Builla
Juan J Vaquero
Carlos Galera
Maria L Vazquez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alter SA
Original Assignee
Alter SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alter SA filed Critical Alter SA
Publication of ES2008314A6 publication Critical patent/ES2008314A6/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C331/00—Derivatives of thiocyanic acid or of isothiocyanic acid
    • C07C331/02—Thiocyanates
    • C07C331/04—Thiocyanates having sulfur atoms of thiocyanate groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases
    • B01J2531/985—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases in a water / organic solvent system

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Indole Compounds (AREA)

Abstract

PROCEDIMIENTO DE OBTENCION DE SALES DE AMONIO CUATERNARIO, UTILES COMO CATALIZADORES DE TRANSFERENCIA DE FASE. COMPRENDE: HACER REACCIONAR BIS-N,N-DIALQUILAMINO)ALQUIL ETERES DE FORMULA GENERAL (II) CON HALOGENUROS DE FORMULA GENERAL (III) PARA OBTENER SALES DE AMONIO CUATERNARIO DE FORMULA GENERAL (I), DONDE R ES UN RADICAL ALQUILO, SATURADO O INSATURADO, LINEAL O RAMIFICADO DE 1 A 8 ATOMOS DE CARBONO; R'' ES UN RADICAL ALQUILO, SATURADO O INSATURADO, LINEAL O RAMIFICADO DE 1 A 12 ATOMOS DE CARBONO; O UN RADICAL BENCILO; N ES UN NUMERO IGUAL A 2 O 3; X- ES UN ANION HALOGENURO COMO CL-, BR-, I-. SE UTILIZAN COMO CATALIZADORES DE TRANSFERENCIA DE FASE EN REACCIONES IONICAS HETEROGENEAS EN LAS QUE LOS REACTIVOS ESTAN EN DIFERENTE FASE Y TIENEN DIFERENTE POLARIDAD.
ES8703170A 1986-11-05 1987-11-05 Procedimiento de obtencion de sales de amonio cuaternario, utiles como catalizadores de transferencia de fase. Expired ES2008314A6 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB8626438A GB2198725B (en) 1986-11-05 1986-11-05 Use of a series of quaternary ammonium salts as phase-transfer catalysts

Publications (1)

Publication Number Publication Date
ES2008314A6 true ES2008314A6 (es) 1989-07-16

Family

ID=10606838

Family Applications (1)

Application Number Title Priority Date Filing Date
ES8703170A Expired ES2008314A6 (es) 1986-11-05 1987-11-05 Procedimiento de obtencion de sales de amonio cuaternario, utiles como catalizadores de transferencia de fase.

Country Status (11)

Country Link
US (1) US4880894A (es)
EP (1) EP0267136B1 (es)
JP (1) JPS63147550A (es)
AT (1) ATE56635T1 (es)
CA (1) CA1305486C (es)
DE (1) DE3765087D1 (es)
DK (1) DK167212B1 (es)
ES (1) ES2008314A6 (es)
FI (1) FI87195C (es)
GB (1) GB2198725B (es)
GR (1) GR3000855T3 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02500363A (ja) * 1986-10-01 1990-02-08 ネルソン　リサーチ　アンド　デベロプメント　カンパニー 酸を触媒とする方法
DE3834748A1 (de) * 1988-10-12 1990-04-19 Bayer Ag Verfahren zur herstellung eines gegebenenfalls substituierten chinacridons
US5082956A (en) * 1990-03-08 1992-01-21 Eastman Kodak Company Isomerization of epoxyalkenes to 2,5-dihydrofurans
US5227509A (en) * 1990-05-07 1993-07-13 Isp Investments Inc. Process for manufacture of organic esters of strong acids
US5242684A (en) * 1991-10-25 1993-09-07 Isp Investments Inc. Antimicrobial, low toxicity, non-irritating composition comprising a blend of bis-quaternary ammonium compounds coprecipitated with a copolymer of vinylpyrrolidone and an acrylamido or vinyl quaternary ammonium monomer
GB9313080D0 (en) * 1993-06-25 1993-08-11 Solvay Interox Ltd Oxidative cleavage of alkenes
HU220961B1 (hu) * 1996-11-18 2002-07-29 AGRO-CHEMIE Növényvédőszer Gyártó, Értékesítő és Forgalmazó Kft. Eljárás benzil-éterek előállítására fázistranszferrel
US5726337A (en) * 1996-12-13 1998-03-10 E. I. Du Pont De Nemours And Company Fluorinated alkylthiocyanate process
JP5480131B2 (ja) * 2007-05-30 2014-04-23 シトクロマ インコーポレイテッド ホスフィンオキシドビタミンｄ前駆物質の製造方法
US8710260B2 (en) * 2009-03-06 2014-04-29 Perkinelmer Health Sciences, Inc. Process for preparing substituted aromatic carboxylic acids
US8053606B2 (en) * 2009-04-30 2011-11-08 E.I. Du Pont De Nemours And Company Alkoxylation of fluorinated alcohols
US8039677B2 (en) 2009-04-30 2011-10-18 E.I. Du Pont De Nemours And Company Fluoroalkylalkoxylates
JP5604761B2 (ja) 2009-11-11 2014-10-15 健治 吉田 印刷媒体、情報処理方法、情報処理装置
CN102746077B (zh) * 2012-07-16 2014-08-20 苏州大学 一种制备酰胺化合物的方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA567527A (en) * 1958-12-16 Morren Henri Production of quaternary ammonium compounds
GB744061A (en) * 1952-03-25 1956-02-01 Pharmacia Ab Improvements in new bis-alkylammonium ethers
DE3362615D1 (en) * 1982-09-27 1986-04-24 Toyo Soda Mfg Co Ltd Method for producing bis(beta-(n,n-dimethylamino)alkyl)ether
JPS59186943A (ja) * 1983-04-07 1984-10-23 Toyo Soda Mfg Co Ltd ビス〔β−（Ｎ，Ｎ−ジメチルアミノ）エチル〕エ−テルの製造法

Also Published As

Publication number Publication date
EP0267136A2 (en) 1988-05-11
GB2198725A (en) 1988-06-22
FI874846A0 (fi) 1987-11-03
DK167212B1 (da) 1993-09-20
DK579487D0 (da) 1987-11-04
FI87195C (fi) 1992-12-10
EP0267136A3 (en) 1989-02-01
GB2198725B (en) 1991-01-16
JPH0442065B2 (es) 1992-07-10
US4880894A (en) 1989-11-14
FI87195B (fi) 1992-08-31
JPS63147550A (ja) 1988-06-20
DE3765087D1 (de) 1990-10-25
GR3000855T3 (en) 1991-11-15
ATE56635T1 (de) 1990-10-15
EP0267136B1 (en) 1990-09-19
FI874846A (fi) 1988-05-06
DK579487A (da) 1988-05-06
CA1305486C (en) 1992-07-21
GB8626438D0 (en) 1986-12-03

Similar Documents

Publication Publication Date Title
ES2008314A6 (es) Procedimiento de obtencion de sales de amonio cuaternario, utiles como catalizadores de transferencia de fase.
BR8602293A (pt) Processo catalitico de preparacao 1,4-cispolibutadieno
PT87422A (pt) Procede de preparation d'une forme de dosage solide pharmaceutque a base de cimetidine
EP0259485A4 (en) HEAVY METAL SALTS OF HYALURONIC ACID FOR USE AS AN ANTIMICROBIAL AGENT.
MX163698B (es) Combinaciones espesadoras liquidas funcionales a base de agua,de agentes tensio activos y de productos de reaccion de acido y/o anhidrido succinico substituido por hidrocarbilo y polo-(oxialquileno)terminado en aminas
PT82851B (pt) Processo para a preparacao de um catalizador contendo prata
EP0219457A3 (en) Process for the preparation of mixtures of metal salts of ring substituted salicylic acid compounds
FR2592041B1 (fr) Procede de preparation d'une amine secondaire
ES2004470B3 (es) Reactores aceleradores de reaccion quimica
AU6807987A (en) Fungicidal agents containing quaternary ammonium salts
DE3750484D1 (de) Quaternäre Ammoniumsalze von Xanthan.
FR2581798B1 (fr) Procede de pointage azimutal des antennes d'une liaison tropospherique
KR880700446A (ko) 보오손의 간섭 비임 발생
PT82888B (pt) Processo para a preparacao de composicoes herbicidas contendo n-(2,4-difluorofenil)-2-(3-trifluorometilfenoxi)-nicotinamida
BR8602486A (pt) Processo para a preparacao de sais do acido 4,4'-dinitroestilben-2,2'-dissulfonico
FR2577221B1 (fr) Procede de preparation d'une phenyluree substituee
IT8521765A0 (it) Tensioattivi derivati dall'acido succinico.
IL58678A0 (en) Preparation of a salt of 3,3-dimethyl-2-oxo-butyric acid
PT81976B (pt) Processo para a preparacao de um novo produto agroquimico denominado "substancia n/ 51262"
DK172289A (da) Fremgangsmaade til fremstilling af 3-amino-2,2,4,4-tetramethylthietan ved leuckardt-reaktionen
GR862445B (en) Process for the preparation of ranitidine or acid addition salts thereof
AU4552489A (en) Amine salts of 1,4,2-oxazaphospholidine-4-acetic acid, 2-alkoxy-2-oxides
EP0201055A3 (en) Process for the preparation of halogenide-free quaternary ammonium salts
FR2628745B1 (fr) Procede de preparation d'une polylactone
PT80563A (en) Chemical process

Legal Events

Date Code Title Description
SA6 Expiration date (snapshot 920101)

Free format text: 2007-11-05