EP4569052B1 - Verbesserungen an brennstoffen - Google Patents
Verbesserungen an brennstoffenInfo
- Publication number
- EP4569052B1 EP4569052B1 EP23757684.8A EP23757684A EP4569052B1 EP 4569052 B1 EP4569052 B1 EP 4569052B1 EP 23757684 A EP23757684 A EP 23757684A EP 4569052 B1 EP4569052 B1 EP 4569052B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- formula
- fuel
- units
- diesel
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1625—Hydrocarbons macromolecular compounds
- C10L1/1633—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
- C10L1/1641—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
- C10L1/1966—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof poly-carboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
- C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
- C10L1/1976—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid poly-carboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/224—Amides; Imides carboxylic acid amides, imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2381—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds polyamides; polyamide-esters; polyurethane, polyureas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/14—Use of additives to fuels or fires for particular purposes for improving low temperature properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
- C10L2200/0259—Nitrogen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/04—Organic compounds
- C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
- C10L2200/0438—Middle or heavy distillates, heating oil, gasoil, marine fuels, residua
- C10L2200/0446—Diesel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/04—Organic compounds
- C10L2200/0461—Fractions defined by their origin
- C10L2200/0469—Renewables or materials of biological origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/04—Organic compounds
- C10L2200/0461—Fractions defined by their origin
- C10L2200/0469—Renewables or materials of biological origin
- C10L2200/0476—Biodiesel, i.e. defined lower alkyl esters of fatty acids first generation biodiesel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2250/00—Structural features of fuel components or fuel compositions, either in solid, liquid or gaseous state
- C10L2250/04—Additive or component is a polymer
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2270/00—Specifically adapted fuels
- C10L2270/02—Specifically adapted fuels for internal combustion engines
- C10L2270/026—Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
Claims (7)
- Kraftstoffzusammensetzung, umfassend durch Hydrodesoxygenierung von Fetten und Ölen erhaltenen erneuerbaren Diesel und 70 bis 1000 ppm eines oder mehrerer das Tieftemperaturverhalten verbessernder Additive, ausgewählt aus:(a) einem Copolymer, umfassend Einheiten der Formel (I):
und Einheiten der Formel (II): wobei R für eine Alkylgruppe steht und R1 und R2 jeweils für eine Alkyl- oder Alkenylgruppe mit 10 bis 14 Kohlenstoffatomen, vorzugsweise 12 bis 14 Kohlenstoffatomen, stehen und das Copolymer ein zahlenmittleres Molekulargewicht von 4000 bis 25.000, vorzugsweise 5000 bis 20.000, weiter bevorzugt 6000 bis 15.000, aufweist. - Verfahren zur Verbesserung der Tieftemperatureigenschaften einer Kraftstoffzusammensetzung, die durch Hydrodesoxygenierung von Fetten und Ölen erhaltenen erneuerbaren Diesel umfasst, wobei das Verfahren das Einmischen eines oder mehrerer das Tieftemperaturverhalten verbessernder Additive, ausgewählt aus:(a) einem Copolymer, umfassend Einheiten der Formel (I):
und Einheiten der Formel (II): wobei R für eine Alkylgruppe steht und R1 und R2 jeweils für eine Alkyl- oder Alkenylgruppe mit 6 bis 22 Kohlenstoffatomen stehen, in die Zusammensetzung umfasst; wobei durch das Verfahren eine Erniedrigung des Trübungspunkts der Kraftstoffzusammensetzung um mindestens 1 °C erreicht wird. - Verwendung eines oder mehrerer das Tieftemperaturverhalten verbessernder Additive, ausgewählt aus:(a) einem Copolymer, umfassend Einheiten der Formel (I):
und Einheiten der Formel (II):wobei R für eine Alkylgruppe steht und R1 und R2 jeweils für eine Alkyl- oder Alkenylgruppe mit 6 bis 22 Kohlenstoffatomen stehen; zur Verbesserung der Tieftemperatureigenschaften einer Kraftstoffzusammensetzung, die durch Hydrodesoxygenierung von Fetten und Ölen erhaltenen erneuerbaren Diesel umfasst;wobei durch die Verwendung eine Erniedrigung des Trübungspunkts der Kraftstoffzusammensetzung um mindestens 1 °C erreicht wird. - Verfahren bzw. Verwendung nach Anspruch 2 oder Anspruch 3, wobei das eine oder die mehreren das Tieftemperaturverhalten verbessernde Additive ein Copolymer umfasst bzw. umfassen, das Einheiten der Formel (I) :
und Einheiten der Formel (II): umfasst, wobei R für eine Alkylgruppe steht und R1 und R2 jeweils für eine Alkylgruppe mit 10 bis 14 Kohlenstoffatomen, vorzugsweise 12 bis 14 Kohlenstoffatomen, stehen und das Copolymer ein zahlenmittleres Molekulargewicht von 4000 bis 25.000, vorzugsweise 5000 bis 20.000, weiter bevorzugt 6000 bis 15.000, aufweist. - Zusammensetzung, Verfahren bzw. Verwendung nach einem der vorhergehenden Ansprüche, wobei das Copolymer 40 bis 60 Mol-% Einheiten der Formel (I) und 60 bis 40 Mol-% Einheiten der Formel (II) umfasst.
- Zusammensetzung, Verfahren bzw. Verwendung nach einem der vorhergehenden Ansprüche, wobei der Kraftstoff eine Mischung aus erneuerbarem Diesel und einem weiteren Dieselkraftstoff umfasst.
- Zusammensetzung, Verfahren bzw. Verwendung nach Anspruch 6, wobei der weitere Dieselkraftstoff aus Biodiesel, Mineraldiesel und Mischungen davon ausgewählt ist.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202263396321P | 2022-08-09 | 2022-08-09 | |
| GBGB2214655.9A GB202214655D0 (en) | 2022-10-05 | 2022-10-05 | Improvements in fuels |
| PCT/GB2023/052110 WO2024033645A1 (en) | 2022-08-09 | 2023-08-09 | Improvements in fuels |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP4569052A1 EP4569052A1 (de) | 2025-06-18 |
| EP4569052B1 true EP4569052B1 (de) | 2026-05-06 |
Family
ID=87747866
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23757686.3A Pending EP4569053A1 (de) | 2022-08-09 | 2023-08-09 | Verbesserungen an brennstoffen |
| EP23757684.8A Active EP4569052B1 (de) | 2022-08-09 | 2023-08-09 | Verbesserungen an brennstoffen |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23757686.3A Pending EP4569053A1 (de) | 2022-08-09 | 2023-08-09 | Verbesserungen an brennstoffen |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US20240059995A1 (de) |
| EP (2) | EP4569053A1 (de) |
| KR (2) | KR20250049324A (de) |
| CN (2) | CN119731293A (de) |
| AU (2) | AU2023324480A1 (de) |
| CA (2) | CA3262762A1 (de) |
| WO (2) | WO2024033648A1 (de) |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4121026A (en) * | 1973-03-23 | 1978-10-17 | Petrolite Corporation | Copolymers of alpha-olefins and maleic anhydride reacted with amines in the presence of Lewis acids |
| DE19848621A1 (de) * | 1998-10-21 | 2000-04-27 | Basf Ag | Paraffindispergatoren mit Lubricity-Wirkung für Erdölmitteldestillate |
| GB0902009D0 (en) * | 2009-02-09 | 2009-03-11 | Innospec Ltd | Improvements in fuels |
| US20180223178A1 (en) * | 2015-07-14 | 2018-08-09 | Halliburton Energ Services, Inc. | Renewable diesel base fluids for use in subterranean formation operations |
| AU2019209477B2 (en) * | 2018-01-17 | 2024-04-04 | Reg Synthetic Fuels, Llc | Blended fuel compositions with improved emissions profiles |
| GB201810852D0 (en) * | 2018-07-02 | 2018-08-15 | Innospec Ltd | Compositions, uses and methods |
| EP4166633A1 (de) * | 2021-10-15 | 2023-04-19 | Innospec Fuel Specialties LLC | Verbesserungen bei brennstoffen |
| EP4413101B1 (de) * | 2021-10-04 | 2025-08-13 | Innospec Fuel Specialties LLC | Verbesserungen bei brennstoffen |
-
2023
- 2023-08-09 EP EP23757686.3A patent/EP4569053A1/de active Pending
- 2023-08-09 WO PCT/GB2023/052113 patent/WO2024033648A1/en not_active Ceased
- 2023-08-09 KR KR1020257007246A patent/KR20250049324A/ko active Pending
- 2023-08-09 AU AU2023324480A patent/AU2023324480A1/en active Pending
- 2023-08-09 US US18/232,019 patent/US20240059995A1/en active Pending
- 2023-08-09 AU AU2023324483A patent/AU2023324483A1/en active Pending
- 2023-08-09 EP EP23757684.8A patent/EP4569052B1/de active Active
- 2023-08-09 WO PCT/GB2023/052110 patent/WO2024033645A1/en not_active Ceased
- 2023-08-09 CA CA3262762A patent/CA3262762A1/en active Pending
- 2023-08-09 KR KR1020257007245A patent/KR20250049323A/ko active Pending
- 2023-08-09 US US18/232,028 patent/US20240059992A1/en active Pending
- 2023-08-09 CA CA3262760A patent/CA3262760A1/en active Pending
- 2023-08-09 CN CN202380058278.1A patent/CN119731293A/zh active Pending
- 2023-08-09 CN CN202380058281.3A patent/CN119790124A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US20240059992A1 (en) | 2024-02-22 |
| CA3262762A1 (en) | 2024-02-15 |
| WO2024033645A1 (en) | 2024-02-15 |
| CN119790124A (zh) | 2025-04-08 |
| US20240059995A1 (en) | 2024-02-22 |
| CA3262760A1 (en) | 2024-02-15 |
| AU2023324480A1 (en) | 2025-02-06 |
| KR20250049324A (ko) | 2025-04-11 |
| KR20250049323A (ko) | 2025-04-11 |
| EP4569053A1 (de) | 2025-06-18 |
| EP4569052A1 (de) | 2025-06-18 |
| WO2024033648A1 (en) | 2024-02-15 |
| AU2023324483A1 (en) | 2025-02-06 |
| CN119731293A (zh) | 2025-03-28 |
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