EP4545205A1 - Tundish for continuous casting, continuous casting method for steel, and weir - Google Patents
Tundish for continuous casting, continuous casting method for steel, and weir Download PDFInfo
- Publication number
- EP4545205A1 EP4545205A1 EP23862833.3A EP23862833A EP4545205A1 EP 4545205 A1 EP4545205 A1 EP 4545205A1 EP 23862833 A EP23862833 A EP 23862833A EP 4545205 A1 EP4545205 A1 EP 4545205A1
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- EP
- European Patent Office
- Prior art keywords
- weir
- inert gas
- wall portion
- molten steel
- continuous casting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
- B22D11/11—Treating the molten metal
- B22D11/116—Refining the metal
- B22D11/118—Refining the metal by circulating the metal under, over or around weirs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/003—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like with impact pads
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
- B22D11/11—Treating the molten metal
- B22D11/116—Refining the metal
- B22D11/117—Refining the metal by treating with gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
- B22D1/002—Treatment with gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
- B22D1/002—Treatment with gases
- B22D1/005—Injection assemblies therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/001—Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/16—Controlling or regulating processes or operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/12—Travelling ladles or similar containers; Cars for ladles
Definitions
- the present invention relates to a continuous casting tundish, a method for continuously casting steel, and a weir.
- a process for manufacturing steel materials is as follows. Molten steel is supplied from a ladle to a tundish. The molten steel is then supplied to a casting mold and cast to form a cast steel. The cast steel is subjected to processes including rolling and thus formed into a predetermined shape to serve as a steel material.
- Inclusions in molten steel can cause a defect in the steel material, and, therefore, it is preferable to separate and remove inclusions from molten steel prior to casting.
- an approach being used in tundishes is to separate inclusions present in molten steel by causing the inclusions to float.
- an approach being used is to provide a tundish with a weir that separates a steel receiving region, to which molten steel is supplied, from a steel quasi-static region, from which the molten steel is discharged through an outlet provided in a bottom portion.
- a weir described in Patent Literature 1 has holes formed in a region adjacent to a bottom portion of a tundish, the holes extending from an area of a steel receiving region-side to an area of a steel quasi-static region-side.
- the weir limits the movement of inclusions that have a lower specific gravity than molten steel.
- the molten steel flows from the steel receiving region-side to the steel quasi-static region-side by passing through the holes of the weir.
- Patent Literature 2 discloses that a weir described in Patent Literature 1 is provided in a tundish and also discloses that a rib extending upward from a bottom portion of the tundish is provided on the steel quasi-static region-side. Accordingly, even when inclusions move to the steel quasi-static region-side through the holes of the weir, the direction of their movement can be changed to an upper direction by the rib. Accordingly, the inclusions can be floated even on the steel receiving region-side.
- Patent Literature 3 discloses that a weir described in Patent Literature 1 is provided in a tundish and also discloses that an inert gas is supplied to the steel quasi-static region-side from a bottom portion of the tundish toward an upper end. Accordingly, even when inclusions move to the steel quasi-static region-side through the holes of the weir, the inclusions are floated by the inert gas.
- Patent Literature 2 Regarding the floating of inclusions by using a rib as disclosed in Patent Literature 2, a need exists to more effectively float inclusions, and, therefore, there is still room for improvement. Furthermore, a problem arises in that the molten steel between the rib and the weir remains when the casting is completed, which results in an increase in cost associated with the disposal of the remaining steel.
- the present invention has been made in view of the problems described above, and objects of the present invention are to provide a continuous casting tundish capable of increasing the cleanliness of molten steel, to provide a method for continuously casting steel, and to provide a weir.
- the present invention is directed toward solving the problems described above and has the following features.
- the present invention is designed to allow an inert gas to be supplied through a porous portion and, consequently, enables fine bubbles of the inert gas to be supplied to a molten steel pouring region.
- a volume fraction of the inert gas in the molten steel can be increased, and, accordingly, inclusions present in the molten steel poured into a tundish from a ladle can be efficiently floated.
- the cleanliness of the molten steel can be increased.
- Fig. 1 is a diagram illustrating a structure of a continuous casting tundish.
- Fig. 2 is a diagram illustrating a side view of the continuous casting tundish.
- a continuous casting tundish 100 is disposed between a ladle (not illustrated), in which molten steel MS is stored, and a casting mold 30, in which the molten steel MS is cooled.
- the continuous casting tundish 100 includes a reservoir 10, which has a box shape with an open upper portion and a closed bottom.
- the reservoir 10 of the continuous casting tundish 100 has an inverted frustum shape, with the upper base being longer than the lower base.
- the reservoir 10 includes one or more molten steel outlets 11, which allows the molten steel MS to exit therethrough to the casting mold.
- molten steel outlets 11 are formed at one end and another end of a bottom portion 12 of the tundish 100 in a left-and-right direction, as illustrated in Fig. 1 .
- the reservoir 10 includes a weir 20, which is disposed between the molten steel pouring region AR1 and the molten steel outlets 11.
- the weir 20 is located at upstream of the molten steel MS from the molten steel outlets 11.
- the weir 20 is hollow and has a cylindrical shape with a closed bottom.
- the weir 20 includes a wall portion 21 and a bottom portion 22.
- the wall portion 21 is formed to enclose the molten steel pouring region AR1.
- the bottom portion 22 is provided at one end of the wall portion 21, which is a lower end. In other words, the wall portion 21 rises from the bottom portion 22.
- the bottom portion 22 faces the bottom portion 12 of the tundish 100 and is in contact with the bottom portion 12.
- the weir 20 has a generally U-shaped side-cross-section.
- the weir 20 has an interior space 20a, which is enclosed by the wall portion 21 and the bottom portion 22. A portion of the molten steel pouring region AR1 is held within the interior space 20a of the weir 20.
- a nozzle N2 is provided at each of the molten steel outlets 11.
- the nozzle N2 connects the tundish 100 to the casting mold 30.
- the molten steel MS is supplied to the casting mold 30 from the molten steel outlets 11 via the nozzles N2.
- the molten steel MS is cooled in the casting mold 30 to form a cast steel 40.
- Fig. 3 is a diagram illustrating a structure of the weir 20.
- Fig. 4 is a top view of the weir 20.
- the weir 20 includes an eave portion 23 at another end of the wall portion 21, which is an upper end.
- the eave portion 23 covers a periphery of the wall portion 21 and faces the bottom portion 22.
- the eave portion 23 may have any shape and is preferably formed to project toward the molten steel pouring region AR1. In the present embodiment, the eave portion 23 is formed to extend toward the molten steel pouring portion AR1 in a direction parallel to the bottom portion 22 (e.g., a horizontal direction).
- the weir 20 includes a gas supply unit 24, which supplies an inert gas from above the bottom portion 22 toward the molten steel pouring region AR1.
- the gas supply unit 24 is provided below the eave portion 23. In other words, the gas supply unit 24 supplies an inert gas to the interior space from above the bottom portion 22. A portion of the inert gas supplied from the gas supply unit 24 comes into contact with the eave portion 23 and travels upward.
- the gas supply unit 24 includes a porous portion 25 and a support portion 26, which supports the porous portion 25.
- the porous portion 25 has pores 25a in an entirety thereof.
- the gas supply unit 24 also includes a pipe 27, which allows an inert gas GS to be delivered therethrough.
- the pipe 27 is provided in the wall portion 21 between the porous portion 25 and the bottom portion 22.
- the porous portion 25 is formed of a refractory material that is a ceramic.
- the refractory material may be, for example, a material obtained by sintering refractory inorganic particles, which may include one, or a mixture of two or more, selected from alumina, silica, and the like. Particularly preferably, the refractory material is a material formed primarily of alumina.
- the porous portion 25 can be prepared by firing spherical particles formed primarily of alumina, which are used as aggregates, at 1600°C or greater.
- the porous portion 25 can be produced, for example, by slip-casting a dense castable refractory material.
- the pores 25a of the porous portion 25 can be formed to have an average pore size of, for example, 10 to 40 ⁇ m as measured by mercury intrusion porosimetry.
- the bubbles of the inert gas supplied from the porous portion 25 can be fine bubbles.
- the size of the bubbles is approximately 100 ⁇ m, whereas when the inert gas is supplied in the manner just described, the size of the bubbles can be approximately 1/10 to 1/20 that of the related art.
- a flow rate of the inert gas can be appropriately controlled.
- the porous portion 25 may have any shape and, in the present embodiment, has a plate shape. Specifically, the shape is a rectangular shape in a top view, as illustrated in Fig. 4 .
- the support portion 26 is formed of a refractory material that is a ceramic.
- the refractory material may be, for example, a material obtained by sintering refractory inorganic particles, which may include one, or a mixture of two or more, selected from alumina, silica, and the like. Particularly preferably, the refractory material is a material formed primarily of alumina.
- the support portion 26 is formed to have a frame shape that can support an edge of a bottom portion of the porous portion 25.
- the support portion 26 may have any shape and, in the present embodiment, has a rectangular frame shape in a top view.
- the support portion 26 is provided on the wall portion 21.
- the support portion 26 is secured, for example, by being fit into a mating recess (not illustrated) formed in the wall portion 21.
- the weir 20 includes a reception chamber 28, which is enclosed by the porous portion 25, the support portion 26, the wall portion 21, and the bottom portion 22.
- the wall portion 21 enclosing the reception chamber 28 has the pipe 27 provided therein.
- the pipe 27 may be refractory.
- Fig. 5 illustrates a state in which the pipe 27 is installed.
- the pipe 27 is disposed along a wall portion 13 of the reservoir 10.
- the pipe 27 is covered with a covering material 50, which is refractory.
- the covering material 50 include precast refractory materials.
- the covering material 50 may be a combination of a precast refractory material and a patching material.
- the covering material 50 located adjacent to the periphery of the reservoir 10 is made of a precast refractory material 51.
- Another covering material 50 located adjacent to the bottom portion 12 of the tundish 100 is made of a patching material 52.
- the covering material 50 may be a pipe cover.
- Fig. 6 illustrates another state in which the pipe 27 is installed.
- a pipe cover 53 is used instead of a precast refractory material, which has been described in the example illustrated in Fig. 5 .
- the pipe cover 53 may be a plurality of pipe covers. In the example illustrated in Fig. 6 , four pipe covers 53 are connected together in an axial direction of the pipe 27.
- the installation of a refractory material can be facilitated.
- the maintainability of the pipe 27 can be improved compared to an instance in which the pipe 27 is inserted through the bottom portion 12 of the tundish 100.
- processing of the bottom portion 12 of the tundish 100 for inserting the pipe 27 through the bottom portion 12 is unnecessary, and, therefore, leakage of the molten steel from the bottom portion 12 can be inhibited.
- the pipe 27 is provided with an adjustment means 29, which adjusts the flow rate of the inert gas.
- the adjustment means 29 may be a valve.
- the adjustment means 29 may be manually operated, or a controller (not illustrated) may be used to adjust the opening degree.
- the inert gas supplied from the pipe 27 is introduced to the reception chamber 28. Once the inert gas is introduced to the reception chamber 28, a pressure of the inert gas is uniformly applied to a surface of the porous portion 25 that faces the bottom portion 22. As a result, the inert gas passes from the reception chamber 28 through the pores 25a of the porous portion 25 to be supplied to the molten steel pouring region AR1. By supplying the inert gas in this manner, variations in the state of supply of the inert gas can be inhibited. Examples of the inert gas include, but are not limited to, Ar, N 2 , and CO 2 .
- the inert gas is supplied to the porous portion 25 from the reception chamber 28.
- the inert gas may be supplied to the porous portion 25 without being passed through the reception chamber 28.
- an attachment (not illustrated) that can cover the bottom-portion-22-side surface of the porous portion 25 may be attached to the pipe 27 and used for supplying the inert gas.
- a method for continuously casting steel includes a step of supplying the molten steel MS to the tundish 100 through the nozzle N1 connected to the ladle (not illustrated); a step of removing inclusions present in the molten steel MS in the tundish 100; a step of allowing the molten steel MS to exit through the molten steel outlet 11 of the tundish 100 to the casting mold 30; and a step of cooling the molten steel MS in the casting mold 30 to manufacture a cast steel.
- the step of removing inclusions present in the molten steel MS in the tundish 100 includes a step of injecting an inert gas at a flow rate that satisfies inequality (1), shown below. 0.02 ⁇ R ⁇ 1.0
- R is the flow rate [NL/(s ⁇ m 2 )] of the inert gas per unit area of the porous portion.
- the gas is preferably supplied from the gas supply unit 24 at 0.02 to 1.00 NL/(s ⁇ m 2 ) and more preferably at 0.20 to 1.00 NL/(s ⁇ m 2 ).
- the gas flow rate (R) per unit area of the porous portion 25 can be adjusted by the adjustment means 29.
- the gas flow rate (R) per unit area of the porous portion 25 is 1.00 NL/(s ⁇ m 2 ) or less, the entrainment of tundish slag can be prevented.
- the size of the bubbles of the inert gas can be finer. Consequently, the floating of inclusions can be promoted, and the entrainment of the inclusions into the molten steel can be inhibited.
- the tundish 100 of the present invention is designed to allow an inert gas to be supplied through the porous portion 25 and, consequently, enables fine bubbles of the inert gas to be supplied to the molten steel pouring region AR1.
- a volume fraction of the inert gas in the molten steel MS can be increased, and, accordingly, inclusions present in the molten steel poured into the tundish 100 from a ladle can be efficiently floated.
- the flow speed of the molten steel MS in the molten steel pouring region AR1 of the weir 20 is higher than in other regions. Accordingly, by supplying the inert gas to the molten steel pouring region AR1, it is possible to increase the frequency at which the bubbles of the inert gas come into contact with one another. As a result, the size of the bubbles of the inert gas can be further reduced. Consequently, the volume fraction of the inert gas in the molten steel MS can be further increased.
- the tundish 100 of the present invention can increase the inclusions-floating effect. Furthermore, since the floating of inclusions can be accomplished with a lower flow rate of the inert gas, the entrainment of slag in the tundish 100 can be inhibited.
- the molten steel MS supplied from the nozzle N1 reaches the bottom portion 22 of the weir 20
- the molten steel MS flows and spreads in a direction towards the periphery of the axis AX of the nozzle N1.
- the molten steel MS reaches the wall portion 21 of the weir 20
- the molten steel MS is forced upward by a subsequent supply of molten steel MS.
- the molten steel MS reaches the eave portion 23
- the molten steel MS flows toward a center of the axis AX of the nozzle N1, that is, toward the molten steel pouring region AR1.
- the occurrence of direct flowing of the molten steel MS from the molten steel pouring region AR1 to the molten steel outlet 11, which is a phenomenon called a "short-circuit flow", can be inhibited. Accordingly, a large amount of the molten steel MS can be caused to flow upward of the weir 20. As a result, the floating of inclusions and separation of the inclusions from the molten steel MS can be facilitated. Consequently, the number of inclusions flowing from the molten steel outlet 11 to the casting mold 30 can be reduced.
- the tundish 100 of the present invention in particular, enables the bubbles of the inert gas to be finer than the bubbles of the related art. Fine bubbles make it possible to enhance an inclusions-floating effect. As described, with the tundish 100 of the present invention, inclusions can be floated efficiently, and the entrainment of inclusions into the molten steel can be inhibited; consequently, high-cleanliness steels can be manufactured.
- the slab prepared by continuous casting was subjected to a measurement of the number of inclusions, which was performed by ultrasonic inspection. Regarding the inclusions, those that had a size of 10 ⁇ m or greater were counted. The number of counted inclusions per m 2 of the slab was calculated and designated as a density.
- Fig. 7 illustrates a relationship between the flow rate (R) of the inert gas per unit area of the porous portion and the density of inclusions in the slab. As illustrated in Fig. 7 , when the flow rate (R) of the inert gas was lower than 0.02, the density of inclusions was higher than those obtained under other conditions.
- the density of inclusions was lower than those obtained under other conditions.
- the density of inclusions was lower than those obtained under the conditions in which no inert gas was supplied. Furthermore, under those conditions, the density of inclusions was higher than those obtained under the conditions in which the flow rate (R) of the inert gas was less than or equal to 1.00.
- the inert gas caused tundish slag (inclusions) to be entrained into the molten steel. This is believed to be a reason that under this condition, the density of inclusions was higher than in the instances in which the flow rate (R) of the inert gas was 0.02 to 1.00.
- the weir was provided, and the inert gas was supplied to the molten steel pouring region from the weir.
- the Invention Examples (Present Inventions 1 to 8) were carried out with the flow rate of the inert gas supplied from the gas supply unit of the weir being varied. The flow rates of the inert gas are shown in Table 1. [Table 1] R Conventional Example - Present Invention 1 0.40 Present Invention 2 0.60 Present Invention 3 0.80 Present Invention 4 0.20 Present Invention 5 1.00 Present Invention 6 0.01 Present Invention 7 1.20 Present Invention 8 1.40 R: the flow rate [NL/(s ⁇ m 2 )] of the inert gas per unit area of the porous portion
- Fig. 8 illustrates the density of inclusions of the Conventional Example and Invention Examples 1 to 8. As illustrated in Fig. 8 , it was found that in Present Inventions 1 to 8, the density of inclusions in the slab was much lower than in the Conventional Example. In particular, in Present Inventions 1 to 5, since the flow rate (R) of the inert gas was 0.02 to 1.00, the obtained results were better than those of Present Inventions 6 to 8.
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Abstract
Description
- The present invention relates to a continuous casting tundish, a method for continuously casting steel, and a weir.
- A process for manufacturing steel materials is as follows. Molten steel is supplied from a ladle to a tundish. The molten steel is then supplied to a casting mold and cast to form a cast steel. The cast steel is subjected to processes including rolling and thus formed into a predetermined shape to serve as a steel material.
- Inclusions in molten steel, such as Al2O3, can cause a defect in the steel material, and, therefore, it is preferable to separate and remove inclusions from molten steel prior to casting. Specifically, an approach being used in tundishes is to separate inclusions present in molten steel by causing the inclusions to float.
- Such a cleaning technique for removing inclusions from molten steel is indispensable for the manufacture of high-quality steel materials, and, accordingly, a need exists to improve the technique. In the related art, an approach being used is to provide a tundish with a weir that separates a steel receiving region, to which molten steel is supplied, from a steel quasi-static region, from which the molten steel is discharged through an outlet provided in a bottom portion.
- A weir described in
Patent Literature 1, for example, has holes formed in a region adjacent to a bottom portion of a tundish, the holes extending from an area of a steel receiving region-side to an area of a steel quasi-static region-side. The weir limits the movement of inclusions that have a lower specific gravity than molten steel. The molten steel flows from the steel receiving region-side to the steel quasi-static region-side by passing through the holes of the weir. - Patent Literature 2 discloses that a weir described in
Patent Literature 1 is provided in a tundish and also discloses that a rib extending upward from a bottom portion of the tundish is provided on the steel quasi-static region-side. Accordingly, even when inclusions move to the steel quasi-static region-side through the holes of the weir, the direction of their movement can be changed to an upper direction by the rib. Accordingly, the inclusions can be floated even on the steel receiving region-side. -
Patent Literature 3 discloses that a weir described inPatent Literature 1 is provided in a tundish and also discloses that an inert gas is supplied to the steel quasi-static region-side from a bottom portion of the tundish toward an upper end. Accordingly, even when inclusions move to the steel quasi-static region-side through the holes of the weir, the inclusions are floated by the inert gas. -
- PTL 1:
Japanese Unexamined Patent Application Publication No. 53-6231 - PTL 2:
Japanese Unexamined Patent Application Publication No. 10-216909 - PTL 3:
Japanese Unexamined Patent Application Publication No. 2011-143449 - Even in the instance where a weir is provided in a tundish as disclosed in
Patent Literature 1, inclusions may pass through the holes of the weir. When inclusions are discharged from the molten steel outlet, there is a concern that defects may occur in a steel material. - Regarding the floating of inclusions by using a rib as disclosed in Patent Literature 2, a need exists to more effectively float inclusions, and, therefore, there is still room for improvement. Furthermore, a problem arises in that the molten steel between the rib and the weir remains when the casting is completed, which results in an increase in cost associated with the disposal of the remaining steel.
- In the instance where inclusions are floated by using an inert gas as disclosed in
Patent Literature 3, one problem is that a volume fraction of the inert gas in the molten steel needs to be increased so that a sufficient floating effect can be produced. When the flow rate of the inert gas is increased to increase the volume fraction of the inert gas in the molten steel, there is a concern that tundish slag, which is an inclusion present on a surface of molten steel, may be entrained into the molten steel by the inert gas. When tundish slag is entrained into molten steel, the molten steel is contaminated, and, consequently, there is a concern that defects may occur in a steel material. - The present invention has been made in view of the problems described above, and objects of the present invention are to provide a continuous casting tundish capable of increasing the cleanliness of molten steel, to provide a method for continuously casting steel, and to provide a weir.
- The present invention is directed toward solving the problems described above and has the following features.
- [1] A continuous casting tundish including a reservoir that stores supplied molten steel, wherein
the reservoir includes one or more molten steel outlets that allows the molten steel to exit therethrough, and the reservoir also includes a weir having a hollow cylindrical shape and located at upstream side of the molten steel from the one or more molten steel outlets with respect to a direction of the molten steel, the weir including:- a bottom portion;
- a wall portion rising from the bottom portion;
- an eave portion provided at an end of the wall portion, the eave portion covering a periphery of the wall portion and facing the bottom portion of the weir; and
- a gas supply unit that supplies an inert gas to an interior space enclosed by the wall portion and the bottom portion, the gas supply unit including:
- a porous portion including pores in an entirety of the porous portion;
- a support portion that supports the porous portion, the support portion being provided on the wall portion of the weir; and
- a pipe that allows the inert gas to be delivered therethrough, the pipe being provided in the wall portion of the weir between the support portion and the bottom portion of the weir.
- [2] The continuous casting tundish according to [1], wherein
- the weir further includes a reception chamber enclosed by the porous portion, the support portion, the wall portion of the weir, and the bottom portion of the weir, and
- the pipe is provided in the wall portion of the weir, the wall portion enclosing the reception chamber.
- [3] The continuous casting tundish according to [1] or [2], wherein the gas supply unit further includes an adjustment means that adjusts a flow rate of the inert gas that is supplied from the pipe.
- [4] The continuous casting tundish according to any one of [1] to [3], wherein the pipe is disposed along a wall portion of the reservoir and covered with a covering material that is refractory.
- [5] A method for continuously casting steel including using the continuous casting tundish according to any one of [1] to [4], wherein the method includes a step of injecting an inert gas at a flow rate that satisfies inequality (1), shown below:
where R is the flow rate [NL/(s×m2)] of the inert gas per unit area of the porous portion. - [6] A weir provided in a continuous casting tundish and having a hollow cylindrical shape, the weir including:
- a bottom portion;
- a wall portion rising from the bottom portion;
- an eave portion provided at an end of the wall portion, the eave portion covering a periphery of the wall portion and facing the bottom portion of the weir; and
- a gas supply unit that supplies an inert gas to an interior space enclosed by the wall portion and the bottom portion, the gas supply unit including:
- a porous portion including pores in an entirety of the porous portion;
- a support portion that supports the porous portion, the support portion being provided on the wall portion; and
- a pipe that allows the inert gas to be delivered therethrough, the pipe being provided in the wall portion between the support portion and the bottom portion.
- [7] The weir according to [6], further including a reception chamber enclosed by the porous portion, the support portion, the wall portion of the weir, and the bottom portion of the weir, wherein
the pipe is provided in the wall portion of the weir, the wall portion enclosing the reception chamber. - [8] The weir according to [6] or [7], wherein the gas supply unit further includes an adjustment means that adjusts a flow rate of the inert gas that is supplied from the pipe.
- The present invention is designed to allow an inert gas to be supplied through a porous portion and, consequently, enables fine bubbles of the inert gas to be supplied to a molten steel pouring region. As a result, a volume fraction of the inert gas in the molten steel can be increased, and, accordingly, inclusions present in the molten steel poured into a tundish from a ladle can be efficiently floated. Hence, the cleanliness of the molten steel can be increased.
-
- [
Fig. 1] Fig. 1 is a diagram illustrating a structure of a continuous casting tundish. - [
Fig. 2] Fig. 2 is a diagram illustrating a side view of the continuous casting tundish. - [
Fig. 3] Fig. 3 is a diagram illustrating a structure of a weir, illustrated inFig. 1 . - [
Fig. 4] Fig. 4 is a top view of the weir, illustrated inFig. 3 . - [
Fig. 5] Fig. 5 is a diagram illustrating a state in which a pipe is installed. - [
Fig. 6] Fig. 6 is a diagram illustrating another state in which a pipe is installed. - [
Fig. 7] Fig. 7 is a graph illustrating a relationship between a gas flow rate per unit area and a number density of inclusions. - [
Fig. 8] Fig. 8 is a graph illustrating the number density of inclusions of a Conventional Example and Present Inventions. -
Fig. 1 is a diagram illustrating a structure of a continuous casting tundish.Fig. 2 is a diagram illustrating a side view of the continuous casting tundish. As illustrated inFig. 1 , acontinuous casting tundish 100 is disposed between a ladle (not illustrated), in which molten steel MS is stored, and a castingmold 30, in which the molten steel MS is cooled. - As illustrated in
Figs. 1 and 2 , the continuous casting tundish (hereinafter simply referred to as a "tundish") 100 includes areservoir 10, which has a box shape with an open upper portion and a closed bottom. In the present embodiment, thereservoir 10 of thecontinuous casting tundish 100 has an inverted frustum shape, with the upper base being longer than the lower base. - The
reservoir 10 includes a molten steel pouring region AR1, to which the molten steel MS is poured from a nozzle N1 of the ladle. The molten steel pouring region AR1 is formed along an axis AX of the nozzle N1. In other words, the molten steel pouring region AR1 is formed to extend from an end of the nozzle N1 along the axis AX of the nozzle N1. The molten steel pouring region AR1 is a region expanding in a direction towards a periphery of the axis AX of the nozzle N1. - The
reservoir 10 includes one or moremolten steel outlets 11, which allows the molten steel MS to exit therethrough to the casting mold. In the present embodiment,molten steel outlets 11 are formed at one end and another end of abottom portion 12 of thetundish 100 in a left-and-right direction, as illustrated inFig. 1 . - The
reservoir 10 includes aweir 20, which is disposed between the molten steel pouring region AR1 and themolten steel outlets 11. Theweir 20 is located at upstream of the molten steel MS from themolten steel outlets 11. Theweir 20 is hollow and has a cylindrical shape with a closed bottom. - The
weir 20 includes awall portion 21 and abottom portion 22. Thewall portion 21 is formed to enclose the molten steel pouring region AR1. Thebottom portion 22 is provided at one end of thewall portion 21, which is a lower end. In other words, thewall portion 21 rises from thebottom portion 22. Thebottom portion 22 faces thebottom portion 12 of thetundish 100 and is in contact with thebottom portion 12. - The
weir 20 has a generally U-shaped side-cross-section. Theweir 20 has aninterior space 20a, which is enclosed by thewall portion 21 and thebottom portion 22. A portion of the molten steel pouring region AR1 is held within theinterior space 20a of theweir 20. - A nozzle N2 is provided at each of the
molten steel outlets 11. The nozzle N2 connects thetundish 100 to the castingmold 30. The molten steel MS is supplied to the castingmold 30 from themolten steel outlets 11 via the nozzles N2. The molten steel MS is cooled in the castingmold 30 to form acast steel 40. -
Fig. 3 is a diagram illustrating a structure of theweir 20.Fig. 4 is a top view of theweir 20. As illustrated inFigs. 3 and 4 , theweir 20 includes aneave portion 23 at another end of thewall portion 21, which is an upper end. Theeave portion 23 covers a periphery of thewall portion 21 and faces thebottom portion 22. - The
eave portion 23 may have any shape and is preferably formed to project toward the molten steel pouring region AR1. In the present embodiment, theeave portion 23 is formed to extend toward the molten steel pouring portion AR1 in a direction parallel to the bottom portion 22 (e.g., a horizontal direction). - The
weir 20 includes agas supply unit 24, which supplies an inert gas from above thebottom portion 22 toward the molten steel pouring region AR1. Thegas supply unit 24 is provided below theeave portion 23. In other words, thegas supply unit 24 supplies an inert gas to the interior space from above thebottom portion 22. A portion of the inert gas supplied from thegas supply unit 24 comes into contact with theeave portion 23 and travels upward. - The
gas supply unit 24 includes aporous portion 25 and asupport portion 26, which supports theporous portion 25. Theporous portion 25 haspores 25a in an entirety thereof. Thegas supply unit 24 also includes apipe 27, which allows an inert gas GS to be delivered therethrough. Thepipe 27 is provided in thewall portion 21 between theporous portion 25 and thebottom portion 22. - The
porous portion 25 is formed of a refractory material that is a ceramic. The refractory material may be, for example, a material obtained by sintering refractory inorganic particles, which may include one, or a mixture of two or more, selected from alumina, silica, and the like. Particularly preferably, the refractory material is a material formed primarily of alumina. - The
porous portion 25 can be prepared by firing spherical particles formed primarily of alumina, which are used as aggregates, at 1600°C or greater. Theporous portion 25 can be produced, for example, by slip-casting a dense castable refractory material. - The use of spherical particles as aggregates enables the formation of the
pores 25a of theporous portion 25. Without limitation, thepores 25a of theporous portion 25 can be formed to have an average pore size of, for example, 10 to 40 µm as measured by mercury intrusion porosimetry. In the instance where thepores 25a are formed as such, the bubbles of the inert gas supplied from theporous portion 25 can be fine bubbles. Specifically, when the inert gas is supplied in a manner of the related art, the size of the bubbles is approximately 100 µm, whereas when the inert gas is supplied in the manner just described, the size of the bubbles can be approximately 1/10 to 1/20 that of the related art. Furthermore, when thepores 25a of theporous portion 25 are 10 to 40 µm, a flow rate of the inert gas can be appropriately controlled. - The
porous portion 25 may have any shape and, in the present embodiment, has a plate shape. Specifically, the shape is a rectangular shape in a top view, as illustrated inFig. 4 . - The
support portion 26 is formed of a refractory material that is a ceramic. The refractory material may be, for example, a material obtained by sintering refractory inorganic particles, which may include one, or a mixture of two or more, selected from alumina, silica, and the like. Particularly preferably, the refractory material is a material formed primarily of alumina. - The
support portion 26 is formed to have a frame shape that can support an edge of a bottom portion of theporous portion 25. Thesupport portion 26 may have any shape and, in the present embodiment, has a rectangular frame shape in a top view. Thesupport portion 26 is provided on thewall portion 21. Thesupport portion 26 is secured, for example, by being fit into a mating recess (not illustrated) formed in thewall portion 21. - The
weir 20 includes areception chamber 28, which is enclosed by theporous portion 25, thesupport portion 26, thewall portion 21, and thebottom portion 22. Thewall portion 21 enclosing thereception chamber 28 has thepipe 27 provided therein. - Advantageously, the
pipe 27 may be refractory.Fig. 5 illustrates a state in which thepipe 27 is installed. As illustrated inFig. 5 , thepipe 27 is disposed along awall portion 13 of thereservoir 10. Thepipe 27 is covered with a coveringmaterial 50, which is refractory. Examples of the coveringmaterial 50 include precast refractory materials. The coveringmaterial 50 may be a combination of a precast refractory material and a patching material. In the example illustrated inFig. 5 , the coveringmaterial 50 located adjacent to the periphery of thereservoir 10 is made of a precastrefractory material 51. Another coveringmaterial 50 located adjacent to thebottom portion 12 of thetundish 100 is made of a patchingmaterial 52. - Furthermore, the covering
material 50 may be a pipe cover.Fig. 6 illustrates another state in which thepipe 27 is installed. In the example illustrated inFig. 6 , apipe cover 53 is used instead of a precast refractory material, which has been described in the example illustrated inFig. 5 . In addition, thepipe cover 53 may be a plurality of pipe covers. In the example illustrated inFig. 6 , four pipe covers 53 are connected together in an axial direction of thepipe 27. - With this configuration of the
pipe 27, the installation of a refractory material can be facilitated. In addition, the maintainability of thepipe 27 can be improved compared to an instance in which thepipe 27 is inserted through thebottom portion 12 of thetundish 100. Furthermore, processing of thebottom portion 12 of thetundish 100 for inserting thepipe 27 through thebottom portion 12 is unnecessary, and, therefore, leakage of the molten steel from thebottom portion 12 can be inhibited. - Preferably, the
pipe 27 is provided with an adjustment means 29, which adjusts the flow rate of the inert gas. The adjustment means 29 may be a valve. The adjustment means 29 may be manually operated, or a controller (not illustrated) may be used to adjust the opening degree. - The inert gas supplied from the
pipe 27 is introduced to thereception chamber 28. Once the inert gas is introduced to thereception chamber 28, a pressure of the inert gas is uniformly applied to a surface of theporous portion 25 that faces thebottom portion 22. As a result, the inert gas passes from thereception chamber 28 through thepores 25a of theporous portion 25 to be supplied to the molten steel pouring region AR1. By supplying the inert gas in this manner, variations in the state of supply of the inert gas can be inhibited. Examples of the inert gas include, but are not limited to, Ar, N2, and CO2. - In the present embodiment, the inert gas is supplied to the
porous portion 25 from thereception chamber 28. Alternatively, the inert gas may be supplied to theporous portion 25 without being passed through thereception chamber 28. For example, an attachment (not illustrated) that can cover the bottom-portion-22-side surface of theporous portion 25 may be attached to thepipe 27 and used for supplying the inert gas. - A method for continuously casting steel includes a step of supplying the molten steel MS to the
tundish 100 through the nozzle N1 connected to the ladle (not illustrated); a step of removing inclusions present in the molten steel MS in thetundish 100; a step of allowing the molten steel MS to exit through themolten steel outlet 11 of thetundish 100 to the castingmold 30; and a step of cooling the molten steel MS in the castingmold 30 to manufacture a cast steel. -
- R is the flow rate [NL/(s×m2)] of the inert gas per unit area of the porous portion.
- Regarding the gas flow rate (R) per unit area of the
porous portion 25, the gas is preferably supplied from thegas supply unit 24 at 0.02 to 1.00 NL/(s×m2) and more preferably at 0.20 to 1.00 NL/(s×m2). The gas flow rate (R) per unit area of theporous portion 25 can be adjusted by the adjustment means 29. - When the gas flow rate (R) per unit area of the
porous portion 25 is 0.02 NL/(s×m2) or greater, the floating of inclusions in the molten steel MS can be promoted. - When the gas flow rate (R) per unit area of the
porous portion 25 is 1.00 NL/(s×m2) or less, the entrainment of tundish slag can be prevented. In the instance where the inert gas is injected under such high flow-speed conditions, the size of the bubbles of the inert gas can be finer. Consequently, the floating of inclusions can be promoted, and the entrainment of the inclusions into the molten steel can be inhibited. - As described, the
tundish 100 of the present invention is designed to allow an inert gas to be supplied through theporous portion 25 and, consequently, enables fine bubbles of the inert gas to be supplied to the molten steel pouring region AR1. As a result, a volume fraction of the inert gas in the molten steel MS can be increased, and, accordingly, inclusions present in the molten steel poured into thetundish 100 from a ladle can be efficiently floated. - The flow speed of the molten steel MS in the molten steel pouring region AR1 of the
weir 20 is higher than in other regions. Accordingly, by supplying the inert gas to the molten steel pouring region AR1, it is possible to increase the frequency at which the bubbles of the inert gas come into contact with one another. As a result, the size of the bubbles of the inert gas can be further reduced. Consequently, the volume fraction of the inert gas in the molten steel MS can be further increased. - Accordingly, the
tundish 100 of the present invention can increase the inclusions-floating effect. Furthermore, since the floating of inclusions can be accomplished with a lower flow rate of the inert gas, the entrainment of slag in thetundish 100 can be inhibited. - When the molten steel MS supplied from the nozzle N1 reaches the
bottom portion 22 of theweir 20, the molten steel MS flows and spreads in a direction towards the periphery of the axis AX of the nozzle N1. When the molten steel MS reaches thewall portion 21 of theweir 20, the molten steel MS is forced upward by a subsequent supply of molten steel MS. When the molten steel MS reaches theeave portion 23, the molten steel MS flows toward a center of the axis AX of the nozzle N1, that is, toward the molten steel pouring region AR1. - At the center of the axis AX of the nozzle N1, that is, a central portion of the molten steel pouring region AR1, vectors of the molten steel MS, which have various directions, cancel each other. As a result, the flow speed of the molten steel MS decreases.
- Consequently, the occurrence of direct flowing of the molten steel MS from the molten steel pouring region AR1 to the
molten steel outlet 11, which is a phenomenon called a "short-circuit flow", can be inhibited. Accordingly, a large amount of the molten steel MS can be caused to flow upward of theweir 20. As a result, the floating of inclusions and separation of the inclusions from the molten steel MS can be facilitated. Consequently, the number of inclusions flowing from themolten steel outlet 11 to the castingmold 30 can be reduced. Thetundish 100 of the present invention, in particular, enables the bubbles of the inert gas to be finer than the bubbles of the related art. Fine bubbles make it possible to enhance an inclusions-floating effect. As described, with thetundish 100 of the present invention, inclusions can be floated efficiently, and the entrainment of inclusions into the molten steel can be inhibited; consequently, high-cleanliness steels can be manufactured. - 300 tons of molten steel, which had undergone oxygen blowing in a converter and an RH vacuum degassing process, was used. The molten steel was supplied to a tundish from a ladle.
- Continuous casting was performed by using Ar as an inert gas that was injected from a weir. Specifically, several tests were performed with the flow rate (R) of the inert gas per unit area of the porous portion being varied (R is the flow rate [NL/(s×m2)] of the inert gas per unit area of the porous portion).
- The slab prepared by continuous casting was subjected to a measurement of the number of inclusions, which was performed by ultrasonic inspection. Regarding the inclusions, those that had a size of 10 µm or greater were counted. The number of counted inclusions per m2 of the slab was calculated and designated as a density.
-
Fig. 7 illustrates a relationship between the flow rate (R) of the inert gas per unit area of the porous portion and the density of inclusions in the slab. As illustrated inFig. 7 , when the flow rate (R) of the inert gas was lower than 0.02, the density of inclusions was higher than those obtained under other conditions. - When the flow rate (R) of the inert gas was 0.02 to 1.00, the density of inclusions was lower than those obtained under other conditions. When the flow rate (R) of the inert gas was greater than 1.00, the density of inclusions was lower than those obtained under the conditions in which no inert gas was supplied. Furthermore, under those conditions, the density of inclusions was higher than those obtained under the conditions in which the flow rate (R) of the inert gas was less than or equal to 1.00.
- Regarding the instance where the flow rate (R) of the inert gas was lower than 0.02, it is believed that under this condition, the effect of floating inclusions in a tundish could not be sufficiently produced. This is believed to be a reason that the density of inclusions was high under this condition.
- Furthermore, it is believed that under the conditions in which the flow rate (R) of the inert gas was greater than 1.00, the inert gas caused tundish slag (inclusions) to be entrained into the molten steel. This is believed to be a reason that under this condition, the density of inclusions was higher than in the instances in which the flow rate (R) of the inert gas was 0.02 to 1.00.
- The same molten steel as that of Test Example 1 was used.
- Continuous casting was performed using tundishes of a Conventional Example and Invention Examples (
Present Inventions 1 to 8). The inert gas that was injected into each of the tundishes was Ar. Specifically, in the Conventional Example, the inert gas was supplied to the molten steel pouring region, with no weir provided in the tundish. - In the Invention Examples, the weir was provided, and the inert gas was supplied to the molten steel pouring region from the weir. The Invention Examples (
Present Inventions 1 to 8) were carried out with the flow rate of the inert gas supplied from the gas supply unit of the weir being varied. The flow rates of the inert gas are shown in Table 1.[Table 1] R Conventional Example - Present Invention 10.40 Present Invention 2 0.60 Present Invention 30.80 Present Invention 4 0.20 Present Invention 5 1.00 Present Invention 6 0.01 Present Invention 7 1.20 Present Invention 8 1.40 R: the flow rate [NL/(s×m2)] of the inert gas per unit area of the porous portion - The measurement was performed in the same manner as in Test Example 1.
-
Fig. 8 illustrates the density of inclusions of the Conventional Example and Invention Examples 1 to 8. As illustrated inFig. 8 , it was found that inPresent Inventions 1 to 8, the density of inclusions in the slab was much lower than in the Conventional Example. In particular, inPresent Inventions 1 to 5, since the flow rate (R) of the inert gas was 0.02 to 1.00, the obtained results were better than those of Present Inventions 6 to 8. -
- 100
- tundish
- 10
- reservoir
- 11
- molten steel outlet
- 20
- weir
- 20a
- interior space
- 21
- wall portion
- 22
- bottom portion
- 23
- eave portion
- 24
- gas supply unit
- 25
- porous portion
- 26
- support portion
- 27
- pipe
- 28
- reception chamber
- 29
- adjustment means
- AR1
- molten steel pouring region
- MS
- molten steel
Claims (12)
- A continuous casting tundish comprising a reservoir that stores supplied molten steel, wherein
the reservoir comprises one or more molten steel outlets that allows the molten steel to exit therethrough, and the reservoir also comprises a weir having a hollow cylindrical shape located at upstream side of the molten steel from the one or more molten steel outlets, the weir comprising:a bottom portion;a wall portion rising from the bottom portion;an eave portion provided at an end of the wall portion, the eave portion covering a periphery of the wall portion and facing the bottom portion of the weir; anda gas supply unit that supplies an inert gas to an interior space enclosed by the wall portion and the bottom portion, the gas supply unit comprising:a porous portion comprising pores in an entirety of the porous portion;a support portion that supports the porous portion, the support portion being provided on the wall portion of the weir; anda pipe that allows the inert gas to be delivered therethrough, the pipe being provided in the wall portion of the weir between the support portion and the bottom portion of the weir. - The continuous casting tundish according to Claim 1, whereinthe weir further comprises a reception chamber enclosed by the porous portion, the support portion, the wall portion of the weir, and the bottom portion of the weir, andthe pipe is provided in the wall portion of the weir, the wall portion enclosing the reception chamber.
- The continuous casting tundish according to Claim 1 or 2, wherein the gas supply unit further comprises an adjustment means that adjusts a flow rate of the inert gas that is supplied from the pipe.
- The continuous casting tundish according to Claim 1 or 2, wherein the pipe is disposed along a wall portion of the reservoir and covered with a covering material that is refractory.
- The continuous casting tundish according to Claim 3, wherein the pipe is disposed along a wall portion of the reservoir and covered with a covering material that is refractory.
- A method for continuously casting steel comprising using the continuous casting tundish according to Claim 1 or 2, wherein the method comprises a step of injecting the inert gas at a flow rate that satisfies inequality (1), shown below:
where R is the flow rate [NL/(s×m2)] of the inert gas per unit area of the porous portion. - A method for continuously casting steel comprising using the continuous casting tundish according to Claim 3, wherein the method comprises a step of injecting the inert gas at a flow rate that satisfies inequality (1), shown below:
where R is the flow rate [NL/(s×m2)] of the inert gas per unit area of the porous portion. - A method for continuously casting steel comprising using the continuous casting tundish according to Claim 4, wherein the method comprises a step of injecting the inert gas at a flow rate that satisfies inequality (1), shown below:
where R is the flow rate [NL/(s×m2)] of the inert gas per unit area of the porous portion. - A method for continuously casting steel comprising using the continuous casting tundish according to Claim 5, wherein the method comprises a step of injecting the inert gas at a flow rate that satisfies inequality (1), shown below:
where R is the flow rate [NL/(s×m2)] of the inert gas per unit area of the porous portion. - A weir provided in a continuous casting tundish and having a hollow cylindrical shape, the weir comprising:a bottom portion;a wall portion rising from the bottom portion;an eave portion provided at an end of the wall portion, the eave portion covering a periphery of the wall portion and facing the bottom portion of the weir; anda gas supply unit that supplies an inert gas to an interior space enclosed by the wall portion and the bottom portion, the gas supply unit comprising:a porous portion comprising pores in an entirety of the porous portion;a support portion that supports the porous portion, the support portion being provided on the wall portion; anda pipe that allows the inert gas to be delivered therethrough, the pipe being provided in the wall portion between the support portion and the bottom portion.
- The weir according to Claim 10, further comprising a reception chamber enclosed by the porous portion, the support portion, the wall portion of the weir, and the bottom portion of the weir, wherein
the pipe is provided in the wall portion of the weir, the wall portion enclosing the reception chamber. - The weir according to Claim 10 or 11, wherein the gas supply unit further comprises an adjustment means that adjusts a flow rate of the inert gas that is supplied from the pipe.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2022143846 | 2022-09-09 | ||
| PCT/JP2023/028182 WO2024053290A1 (en) | 2022-09-09 | 2023-08-01 | Tundish for continuous casting, continuous casting method for steel, and weir |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP4545205A1 true EP4545205A1 (en) | 2025-04-30 |
| EP4545205A4 EP4545205A4 (en) | 2025-10-22 |
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ID=90190908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23862833.3A Pending EP4545205A4 (en) | 2022-09-09 | 2023-08-01 | INTERMEDIATE TANK FOR CONTINUOUS CASTING, CONTINUOUS CASTING PROCESS FOR STEEL AND WEIR |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20260070119A1 (en) |
| EP (1) | EP4545205A4 (en) |
| JP (1) | JP7677462B2 (en) |
| KR (1) | KR20250044727A (en) |
| CN (1) | CN119789922A (en) |
| WO (1) | WO2024053290A1 (en) |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS536231A (en) | 1976-07-07 | 1978-01-20 | Nippon Kokan Kk | Method of making clean steel |
| JP3520640B2 (en) * | 1995-12-15 | 2004-04-19 | Jfeスチール株式会社 | Method for removing nonmetallic inclusions in molten metal |
| JP3563222B2 (en) | 1997-01-31 | 2004-09-08 | 日本冶金工業株式会社 | Tundish for continuous casting of steel |
| CN2863315Y (en) * | 2005-12-01 | 2007-01-31 | 洛阳铁门耐火材料有限公司 | Blowing type turbulence proof controller for bakie |
| JP5134574B2 (en) | 2009-03-16 | 2013-01-30 | 曙ブレーキ工業株式会社 | Rotation axis stop position setting method in drag test device |
| JP2011143449A (en) | 2010-01-14 | 2011-07-28 | Jfe Steel Corp | Method for removing inclusion in tundish for continuous casting |
| KR101684382B1 (en) * | 2012-06-18 | 2016-12-08 | 제이에프이 스틸 가부시키가이샤 | Method for manufacturing high-purity steel casting, and tundish |
| CN203109191U (en) * | 2013-03-15 | 2013-08-07 | 濮阳濮耐高温材料(集团)股份有限公司 | Tundish current stabilizer with air blowing function |
| US11338357B2 (en) * | 2019-08-19 | 2022-05-24 | Harbisonwalker International, Inc. | Diffusion article |
| CN113564309B (en) * | 2020-04-28 | 2022-10-21 | 宝山钢铁股份有限公司 | Tundish with function of removing molten steel inclusions by blowing argon |
-
2023
- 2023-08-01 WO PCT/JP2023/028182 patent/WO2024053290A1/en not_active Ceased
- 2023-08-01 KR KR1020257006508A patent/KR20250044727A/en active Pending
- 2023-08-01 EP EP23862833.3A patent/EP4545205A4/en active Pending
- 2023-08-01 JP JP2023572688A patent/JP7677462B2/en active Active
- 2023-08-01 US US19/107,239 patent/US20260070119A1/en active Pending
- 2023-08-01 CN CN202380062523.6A patent/CN119789922A/en active Pending
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| KR20250044727A (en) | 2025-04-01 |
| JP7677462B2 (en) | 2025-05-15 |
| EP4545205A4 (en) | 2025-10-22 |
| JPWO2024053290A1 (en) | 2024-03-14 |
| WO2024053290A1 (en) | 2024-03-14 |
| CN119789922A (en) | 2025-04-08 |
| US20260070119A1 (en) | 2026-03-12 |
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