EP4408955A4 - Raffinierungsverfahren von kunststoffabfallpyrolyseöl unter verwendung einer schwefelquelle und eines hydrierungskatalysators auf molybdänbasis sowie kontinuierliches betriebsverfahren dafür - Google Patents

Raffinierungsverfahren von kunststoffabfallpyrolyseöl unter verwendung einer schwefelquelle und eines hydrierungskatalysators auf molybdänbasis sowie kontinuierliches betriebsverfahren dafür

Info

Publication number
EP4408955A4
EP4408955A4 EP22896059.7A EP22896059A EP4408955A4 EP 4408955 A4 EP4408955 A4 EP 4408955A4 EP 22896059 A EP22896059 A EP 22896059A EP 4408955 A4 EP4408955 A4 EP 4408955A4
Authority
EP
European Patent Office
Prior art keywords
molybdenum
operation method
continuous operation
hydrogenation catalyst
pyrolysis oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP22896059.7A
Other languages
English (en)
French (fr)
Other versions
EP4408955A1 (de
Inventor
Kayoung Kim
Okyoun Kim
Youngmoo PARK
Heejung JEON
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SK Innovation Co Ltd
SK Geo Centric Co Ltd
Original Assignee
SK Innovation Co Ltd
SK Geo Centric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SK Innovation Co Ltd, SK Geo Centric Co Ltd filed Critical SK Innovation Co Ltd
Publication of EP4408955A1 publication Critical patent/EP4408955A1/de
Publication of EP4408955A4 publication Critical patent/EP4408955A4/de
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1003Waste materials
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006Temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012Pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018Spatial velocity, e.g. LHSV, WHSV

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
EP22896059.7A 2021-11-16 2022-11-16 Raffinierungsverfahren von kunststoffabfallpyrolyseöl unter verwendung einer schwefelquelle und eines hydrierungskatalysators auf molybdänbasis sowie kontinuierliches betriebsverfahren dafür Withdrawn EP4408955A4 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020210157620A KR20230071424A (ko) 2021-11-16 2021-11-16 황 공급원(sulfur source)과 몰리브덴계 수소화 촉매를 이용한 폐플라스틱 열분해유의 정제 방법및 이의 연속 운전 방법
PCT/KR2022/018108 WO2023090854A1 (en) 2021-11-16 2022-11-16 Refining method of waste plastic pyrolysis oil using sulfur source and molybdenum-based hydrogenation catalyst, and continuous operation method thereof

Publications (2)

Publication Number Publication Date
EP4408955A1 EP4408955A1 (de) 2024-08-07
EP4408955A4 true EP4408955A4 (de) 2025-02-26

Family

ID=86397348

Family Applications (1)

Application Number Title Priority Date Filing Date
EP22896059.7A Withdrawn EP4408955A4 (de) 2021-11-16 2022-11-16 Raffinierungsverfahren von kunststoffabfallpyrolyseöl unter verwendung einer schwefelquelle und eines hydrierungskatalysators auf molybdänbasis sowie kontinuierliches betriebsverfahren dafür

Country Status (6)

Country Link
US (1) US20250019599A1 (de)
EP (1) EP4408955A4 (de)
JP (1) JP2024543468A (de)
KR (1) KR20230071424A (de)
CN (1) CN118215723A (de)
WO (1) WO2023090854A1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4424796A1 (de) * 2023-03-02 2024-09-04 OMV Downstream GmbH Verfahren zur reinigung eines synthetischen rohölstroms
EP4424797A1 (de) * 2023-03-02 2024-09-04 OMV Downstream GmbH Verfahren zur reinigung eines synthetischen rohölstroms
KR20240172852A (ko) * 2023-06-02 2024-12-10 에스케이이노베이션 주식회사 열분해유 내 불순물 저감 방법

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10865348B2 (en) * 2016-07-13 2020-12-15 Sabic Global Technologies B.V. Process which does simultaneous dehydrochlorination and hydrocracking of pyrolysis oils from mixed plastic pyrolysis while achieving selective hydrodealkylation of C9+ aromatics

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3776335B2 (ja) 2001-07-25 2006-05-17 独立行政法人科学技術振興機構 油中の塩素及び窒素の同時除去方法
US7214309B2 (en) * 2004-09-10 2007-05-08 Chevron U.S.A. Inc Process for upgrading heavy oil using a highly active slurry catalyst composition
CA2780575C (en) * 2009-11-24 2015-09-22 Shell Internationale Research Maatschappij B.V. Process for catalytic hydrotreatment of a pyrolysis oil
CN104927914A (zh) * 2014-03-23 2015-09-23 何巨堂 包含使用供氢烃的低氢油比预加氢过程的高芳烃加氢方法
FI20195446A1 (en) * 2019-05-28 2020-11-29 Neste Oyj Alkali-enhanced hydrothermal purification of plastic pyrolysis oils
EP4133037B1 (de) * 2020-04-07 2024-07-17 TotalEnergies OneTech Belgium Durch direktes katalytisches cracken zu hochwertigen chemikalien veredeltes altöl auf kunststoffbasis

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10865348B2 (en) * 2016-07-13 2020-12-15 Sabic Global Technologies B.V. Process which does simultaneous dehydrochlorination and hydrocracking of pyrolysis oils from mixed plastic pyrolysis while achieving selective hydrodealkylation of C9+ aromatics

Also Published As

Publication number Publication date
CN118215723A (zh) 2024-06-18
US20250019599A1 (en) 2025-01-16
JP2024543468A (ja) 2024-11-21
KR20230071424A (ko) 2023-05-23
WO2023090854A1 (en) 2023-05-25
EP4408955A1 (de) 2024-08-07

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