EP4263907A2 - Agencement de cellules électrochimiques - Google Patents

Agencement de cellules électrochimiques

Info

Publication number
EP4263907A2
EP4263907A2 EP21836475.0A EP21836475A EP4263907A2 EP 4263907 A2 EP4263907 A2 EP 4263907A2 EP 21836475 A EP21836475 A EP 21836475A EP 4263907 A2 EP4263907 A2 EP 4263907A2
Authority
EP
European Patent Office
Prior art keywords
cathode
anode
arrangement
electrically conductive
electrochemical cells
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP21836475.0A
Other languages
German (de)
English (en)
Inventor
Maximilian SCHALENBACH
Hermann TEMPEL
Hans Kungl
Rüdiger-A. Eichel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Forschungszentrum Juelich GmbH
Original Assignee
Forschungszentrum Juelich GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Forschungszentrum Juelich GmbH filed Critical Forschungszentrum Juelich GmbH
Publication of EP4263907A2 publication Critical patent/EP4263907A2/fr
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60—Constructional parts of cells
    • C25B9/63—Holders for electrodes; Positioning of the electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60—Constructional parts of cells
    • C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • C25B9/75—Assemblies comprising two or more cells of the filter-press type having bipolar electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • C25B9/77—Assemblies comprising two or more cells of the filter-press type having diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/049—Processes for forming or storing electrodes in the battery container
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/471—Spacing elements inside cells other than separators, membranes or diaphragms; Manufacturing processes thereof
    • H01M50/474—Spacing elements inside cells other than separators, membranes or diaphragms; Manufacturing processes thereof characterised by their position inside the cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/471—Spacing elements inside cells other than separators, membranes or diaphragms; Manufacturing processes thereof
    • H01M50/477—Spacing elements inside cells other than separators, membranes or diaphragms; Manufacturing processes thereof characterised by their shape
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/531—Electrode connections inside a battery casing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the invention relates to an arrangement of electrochemical cells, in particular for alkaline electrolysis of water.
  • All cells are supplied with electrical energy by connecting the anode of one of the two cells arranged at the edge of the stack to a voltage source and the cathode of the other cell arranged at the edge of the stack being connected to this voltage source.
  • the generally metallic electrodes are pressed onto the metallic bipolar plates in order to ensure electrical contact between the electrodes and the bipolar plate, which, however, is accompanied by not inconsiderable contact resistances.
  • Oxide layers can grow at the interfaces between the electrodes and the bipolar plate, which additionally increase the contact resistance between the respective electrode and the bipolar plate.
  • the electrolyte in a cell is in direct contact with both electrodes, so that a liquid electrolyte, as in alkaline electrolysis, is also in contact with the bipolar plate.
  • bipolar plate So that the bipolar plate is not corroded by the electrolyte and the applied potentials, the bipolar plate is usually coated with corrosion-resistant metals.
  • the use of bipolar plates requires a considerable amount of material.
  • contact resistances between the electrodes and the bipolar plates are considerable. Scratches on the bipolar plates can cause protective layers that are typically applied by electroplating to peel off and the substrate underneath to dissolve.
  • a protective layer requires expensive production and an expensive material, since thick metal layers made of expensive metals such as nickel, platinum or gold are often used for bipolar plates.
  • Known bipolar plates also have a complex three-dimensional design with channels and inflows and outflows. In this respect, known stacks are expensive to produce and energetically inefficient to operate.
  • an arrangement which has a plurality of electrochemical cells arranged adjacent to one another in a stacking direction, with adjacent electrochemical cells being separated from one another by a respective electrically insulating separating element, with the electrochemical cells each having an anode compartment with an anode, a cathode compartment with a cathode and have a membrane arranged between the anode compartment and the cathode compartment, wherein the anodes are each connected to the cathode of the following electrochemical cell in the stacking direction via at least one electrically conductive connection, which is preferably separate from the respective anode compartment and the respective cathode compartment, and wherein the electrically conductive connections pass through the separating element arranged between the respective anode and the respective cathode and/or a boundary of the electrochemical cells.
  • the arrangement described does not require bipolar plates. In that regard, the cost of materials is reduced.
  • the operation of the arrangement described is particularly efficient in terms of energy because there are no energy losses due to contact resistances
  • the arrangement can be designed in particular for electrolysis. In that case the arrangement can also be referred to as an electrolysis arrangement.
  • the electrolysis arrangement is preferably set up for alkaline water electrolysis. However, the electrolysis arrangement can also be set up for other electrochemical systems, such as chloralkali electrolysis. Alternatively, the arrangement can be designed as a battery or fuel cell, for example.
  • the assembly includes multiple electrochemical cells.
  • An electrochemical cell is to be understood as meaning an element which is set up to carry out an electrochemical process.
  • the electrochemical cells can be electrolysis cells, galvanic cells, electrodialysis cells, fuel cells or battery cells. All electrochemical cells of the arrangement are preferably designed in the same way, in particular all as electrolytic cells. In the case of electrolysis cells, the arrangement can also be referred to as an electrolysis stack or as a stack for short.
  • Each of the electrochemical cells has an anode compartment with an anode, a cathode compartment with a cathode, and a membrane disposed between the anode compartment and the cathode compartment.
  • the membrane can also be referred to as a diaphragm.
  • the anode and the cathode are also referred to below as electrodes.
  • the electrodes are preferably made of nickel. Nickel electrodes can be hot dip galvanized and then specifically etched to obtain large catalytic surface areas. It is therefore generally preferred that the anode and/or the cathode of at least one of the electrochemical cells is formed from hot dip galvanized nickel.
  • the electrochemical cells can be operated with an electrolyte.
  • the electrochemical cells can be designed as electrolytic cells be set up for electrolysis of the electrolyte.
  • the electrolyte is preferably an alkaline solution.
  • the electrochemical cells are designed in such a way that the electrolyte can come into contact with the anode and the cathode.
  • the electrochemical cells have a respective anode compartment for the anode and a respective cathode compartment for the cathode.
  • the anode compartments and the cathode compartments are at least partially filled with the electrolyte.
  • the anode spaces and the cathode spaces of the electrochemical cells are connected to one another via the respective membrane to the extent that the membrane is ionically conductive but electrically insulating.
  • the electrochemical cells are arranged adjacent to each other in a stacking direction. That is, the electrochemical cells are typically arranged in a row, with adjacent ones of the electrochemical cells abutting one another.
  • the direction in which the electrochemical cells are arranged adjacent to each other is referred to as the stacking direction.
  • the arrangement is described using a coordinate system in which the stacking direction is a first direction and which also has a second and a third direction, the stacking direction, the second direction and the third direction being pairs perpendicular to one another.
  • the electrochemical cells are arranged along a straight line.
  • the described functionality with the described advantages can be achieved equally if neighboring electrochemical cells are at an angle to one another.
  • the electrochemical cells can be arranged along an arc of a circle.
  • the stacking direction can therefore be curved.
  • an angle between adjacent ones of the electrochemical cells is at most 20°.
  • the separating elements are electrically insulating and can be made of corrosion-resistant materials such as plastics or ceramics. In this way in particular, the separating elements differ from the bipolar plates known from the prior art. That the separating elements are electrically insulating means that there is no electrical connection between the two opposing surfaces of the separator.
  • the separating elements are preferably designed in the form of plates. It is not necessary for the separating elements to be formed entirely from electrically insulating material. It is possible that the separators consist of corrosion-resistant surfaces that clad an electrically conductive material such as a metal. Such an interconnected metal plate is protected against electrochemical corrosion and gives the separating element mechanical stability.
  • the surfaces are electrically insulated from one another. It is possible that the surfaces themselves are formed of an electrically conductive material, but are separated from each other by an electrically insulating material so that there is no electrical connection between the surfaces. This is the case, for example, with a plastic plate that is coated on both sides with a metal.
  • the separators extend across an entire cross-section of the electrochemical cells when viewed in a plane perpendicular to the stacking direction. It is preferred that the electrolyte spaces are each delimited by one of the membranes, a delimitation of the electrochemical cells and one of the separating elements.
  • the boundary may be integral for all of the electrochemical cells or may comprise a respective portion for each of the electrochemical cells. In this respect, the electrolyte spaces can be continuously delimited on all sides by an electrically insulating material.
  • the anodes are each electrically conductively connected to the cathode of the electrochemical cell that follows in the stacking direction, preferably via a metallic connection that is interconnected or sealed by the electrolyte.
  • a metallic connection that is interconnected or sealed by the electrolyte.
  • the cathode of the first electrochemical cell is connected to a voltage source
  • the anode of the first electrochemical cell is connected to the cathode of the second electrochemical cell
  • the anode of the second electrochemical cell is connected to the cathode of the third electrochemical cell
  • the anode of the third electrochemical cell is connected to the voltage source.
  • Any number of electrochemical cells can be provided between the electrochemical cells at the edge of the arrangement, here the first and third electrochemical cells.
  • the arrangement preferably has at least 5 and/or at most 200 of the electrochemical cells.
  • all electrochemical cells can be electrically contacted in that only one of the electrodes of the electrochemical cells arranged at the edge of the arrangement is directly connected to a voltage source.
  • the remaining electrodes are indirectly connected to the voltage source via other electrodes, via the electrical connections between them and via the electrolyte.
  • the electrical connection between the electrodes of the adjacent electrochemical cells means that the bipolar plates can be dispensed with. This is expressed in that the separating elements between the electrochemical cells are designed to be electrically insulating. This is not possible in an embodiment with bipolar plates known according to the prior art.
  • the electrically conductive connection comprises the electrically conductive material which is arranged between the respective anode and the respective cathode and via which a continuous electrical conduction path is formed between the anode and the cathode.
  • the electrically conductive connection can be integrally formed with the anode and/or with the cathode, for example by laser welding. With laser welding, there is only a comparatively low temperature input, so that plastic parts are protected.
  • the electrically conductive connection can be formed with a separate element.
  • the electrically conductive connection can be formed in that the respective anode and the respective cathode are connected to one another with at least one connecting pin such as a screw or a rivet.
  • the electrodes each have at least one through hole, at least one thread and/or have at least one socket, by means of which the at least one connecting pin can be connected to the respective electrode.
  • the at least one through hole, the at least one thread and/or the at least one bushing of the respective anode is preferably opposite the at least one through hole, the at least one thread and/or the at least one bushing of the respective cathode.
  • the at least one connecting pin can pass through the corresponding separating element and thus connect the respective anode and the respective cathode to one another.
  • the electrically conductive connection can also pass through the separating element arranged between the connected electrodes because the electrically conductive connection comprises a part of the separating element.
  • the electrically conductive connection is preferably at the same time a mechanical connection via which the electrodes are held.
  • the electrically conductive connection can pass through the boundary of the electrochemical cells.
  • the electrochemical connection thus passes through an element which encloses the electrolyte in the respective electrochemical cell. This element can be the separating element between the respective electrochemical cells or the boundary of the electrochemical cell.
  • the electrically conductive connections pass through the respective separating element and/or the delimitation of the electrochemical cells in a fluid-tight manner.
  • the electrolyte cannot escape from the electrolyte spaces at the point where an electrically conductive connection passes through the electrolyte space.
  • the electrically conductive connection passes through the respective separating element and/or the delimitation of the electrochemical cells in a gas-tight manner. In that case, a gas formed in the electrolyte space cannot escape from the electrolyte space either.
  • the fluid-tight or gas-tight design of the passage points can be achieved, for example, by seals.
  • At least one seal is arranged between each of the electrically conductive connections and the separating element or the boundary. This can prevent electrolyte from coming into contact with a connecting pin, for example.
  • the electrically conductive connection is preferably separate from the anode space and the cathode space. This means that the electrically conductive connection does not come into contact with an electrolyte in the anode compartment and/or in the cathode compartment during operation.
  • the bipolar plates known from the prior art come into contact with the electrolyte, which places corresponding demands on the material of the bipolar plates, especially with regard to corrosion resistance and electrical conductivity.
  • the electrically conductive connection can be formed from any desired and particularly favorable material, for example steel.
  • the electrochemical properties of the material of the electrical connection are irrelevant.
  • the electrical connection can be separated from the anode space and/or from the cathode space, for example, by casing and/or a seal.
  • the electrically conductive connection can be a connecting pin with a plastic coating and/or with a plastic cover.
  • the embodiment of the arrangement is preferred in which the electrically conductive connection is separated from the respective anode space and the respective cathode space by casing and/or a seal.
  • the anodes and/or the cathodes each have a plurality of mesh supports and a metal mesh attached to them.
  • the "and" case is preferred.
  • the anodes and/or the cathodes preferably also each have at least one fastening element. Electrical contact can be established between the electrodes of the adjacent electrochemical cells via the fastening elements, in particular via connections which pass through the respective separating elements.
  • the electrodes are preferably realized in the manner of a skeleton structure.
  • the electrodes are self-supporting.
  • the metal mesh allows the electrode to do its job.
  • the metal mesh has a catalyst material. This is located at a short distance from the membrane.
  • the net carriers serve in particular to hold the metal net.
  • the mesh supports are preferably made of metal, preferably of the same material as the metal mesh and the fastening element.
  • the metal mesh and the mesh supports are preferably made of nickel.
  • the mesh supports can be welded to the metal mesh.
  • the fastening elements and the holding element can also be welded, in particular by means of laser welding, or can be produced straight from one piece. The welding, in particular laser welding, can take place after the elements to be connected to one another have been plugged together.
  • the entire electrode can then be hot-dip galvanized and specifically etched to obtain large catalytic surfaces. It is therefore generally preferred that the mesh supports and the metal mesh attached to the anode and/or the cathode of at least one of the electrochemical cells are made of hot-dip galvanized nickel.
  • the electrical conductivity between the metal mesh and the mesh supports remains intact.
  • the metal mesh is preferably formed in a plane perpendicular to the stacking direction.
  • the mesh supports preferably have an axis aligned in the direction of stacking.
  • the mesh carriers are preferably designed as a flat metal strip. The mesh carriers are preferably aligned perpendicular to the metal mesh.
  • the anodes can each be materially connected via at least one connecting pin to the cathode of the electrochemical cell that follows in the stacking direction, for example by welding, in particular laser welding.
  • the corresponding separating element can then be produced between the anode and cathode, for example by casting, clamping or gluing in the separating element. In this case, no holes, bushings or threads have to be provided on the anodes and/or on the cathodes.
  • the electrically conductive connections thereby are designed such that the anodes are each materially connected to the cathode of the electrochemical cell that follows in the stacking direction, for example by means of laser welding, the separating element being cast, clamped and/or glued between the respective anode and the respective cathode.
  • the anode and cathode can also be connected through the partition wall, with the connecting pin being welded after the anode, cathode and separator are arranged.
  • At least one respective spring element is provided for each of the metal nets, which is set up to tension the metal net away from the respective nearest separating element and to bring it closer to the membrane.
  • the arrangement thus has spring elements which are each arranged between a metal net and a separating element and are set up to tension the respective metal net away from the corresponding separating element.
  • the spring elements serve to bring the metal nets close to the respective membrane.
  • the spring elements therefore generate a force which acts on the respective metal mesh parallel to the stacking direction.
  • the spring elements can be made of plastic or metal.
  • the spring elements can each be implemented as a piece of fleece, a spring or a bent piece of wire.
  • the electrically conductive connections each comprise a connecting element arranged outside a boundary of the electrochemical cells.
  • the electrodes are not connected to one another via the corresponding separator, but via a connecting element arranged outside the boundary of the electrochemical cells.
  • the connecting element is preferably made of metal. Because the connector is located outside the confines of the electrochemical cells, it does not come into contact with the electrolyte in contact.
  • the connections between the electrodes and the connecting element are preferably separated from the anode compartments and the cathode compartments. The electrolyte therefore does not come into contact with the connection.
  • it is preferred that the electrically conductive connections each pass through the boundary of the electrochemical cells. It is not necessary for the electrically conductive connections to also pass through a separating element.
  • the electrically conductive connections each comprise at least one connecting pin between the respective anode and the respective cathode.
  • the connecting pin can be a screw, rivet or bolt.
  • the connecting pin is preferably made of metal.
  • the anodes are preferably each connected directly via at least one connecting pin to the cathode of the electrochemical cells that follow in the stacking direction. This means that the anode and the cathode connected to it are each in direct contact with the connecting pin.
  • the anodes can each be connected indirectly via at least one connecting pin to the cathode of the electrochemical cell that follows in the stacking direction.
  • the anode may be connected directly with a connector pin to a connector located outside the perimeter of the electrochemical cells, and the corresponding cathode may be directly connected with another connector pin to the connector.
  • the anode and the cathode can be screwed to the connecting element and to this extent indirectly connected to one another via two screws as connecting pins.
  • the separating elements each have an electrically conductive core and an electrically insulating cover, the electrically conductive connections each comprising the electrically conductive core of the separating element arranged between the respective anode and the respective cathode. Due to the electrically insulating cover, the electrolyte does not come into contact with the electrically conductive core of the separating elements. Any material, and in particular an inexpensive one, can be used for the core, in particular a metal such as steel. In comparison to the bipolar plates known from the prior art, the separating elements are therefore more favorable because the electrochemical properties of the metallic core are not important due to the separation from the electrolyte. Due to the metallic core, the separating elements are particularly stable.
  • the electrochemical cells are delimited by a plastic delimitation, metal stabilizing elements being provided within the delimitation.
  • the boundary can be formed by walls between which the electrolyte spaces are formed.
  • the boundary extends across all electrochemical cells and can be formed in one piece or be composed of respective boundary parts for the individual electrochemical cells.
  • the delimitation can be formed, for example, as a wall surrounding the stacking direction.
  • a boundary made of plastic is particularly favorable and also has no influence on the electrochemical processes taking place within the electrochemical cells. However, plastic can deform under the influence of temperature and pressure. This is counteracted by the metallic stabilizing elements.
  • the stabilizing elements are preferably designed and arranged in such a way that they in particular stabilize with respect to parallel to the stacking direction enable acting forces. By locating the metallic stabilizing elements within the plastic boundary, the metallic stabilizing elements do not come into contact with the electrolyte within the electrochemical cells.
  • the electrical connections each comprise two connection pins which point in opposite directions.
  • the connecting pins have a preferred direction. This makes it possible to see whether two connecting pins are aligned in opposite directions or parallel to one another.
  • the connecting pins are preferably designed as screws. In particular, two screws point in opposite directions when a first screw is screwed through a separating element from a first side and a second screw is screwed through the separating element from a second side.
  • the electrically conductive connection can be formed by first connecting a first electrode to the corresponding separating element from a first side and then connecting a second electrode to the separating element from a second side.
  • the separating elements have a core and that a cover is arranged between the electrodes and the core of the respective separating element.
  • the core can be formed from a metal.
  • the anode and corresponding cathode may be bonded together by first applying a cover to a first side of the core of the separator.
  • the cathode can then be attached to the core of the separator with a connecting pin.
  • Another cover may then be applied to a second side of the separator core and the anode secured to the core with a second connector pin.
  • the second connecting pin in particular a head of the second connecting pin, can be be sealed with a seal.
  • the electrically conductive connections are formed with a respective threaded socket on one of the electrodes and with a through hole on the other electrode, the through hole preferably having a cross-section which tapers towards the respective separator.
  • the through hole has a cross section which tapers in the direction of the respective separating element means that the cross section becomes smaller in the direction of the separating element.
  • the anode and the cathode are formed by a respective metal mesh, the assembly further comprising an electrically conductive plate, the metal mesh forming the cathode being connected to the plate, the electrically conductive connection being formed with a connecting pin which is connected to the anode and which is connected to the plate.
  • the connecting pin is preferably connected to the plate by laser welding.
  • the anode and the cathode are formed by a respective metal mesh, which is preferably formed from nickel.
  • the anode is connected to the cathode via the connecting pin.
  • the connecting pin thus represents the electrically conductive connection.
  • the connecting pin is preferably made of nickel.
  • the separating element is preferably formed from plastic, in particular from polypropylene.
  • the plate can be made of steel, for example. Since the plate and the metal mesh are electrically conductive, the plate can also contribute to the function of the cathode and in this respect can be regarded as part of the cathode.
  • the plate can come into contact with the electrolyte in the cathode compartment.
  • the electrically conductive connection can be formed from any desired and particularly favorable material, for example steel.
  • a cheaper material such as steel can be used at the cathode rather than at the anode.
  • the anode space is preferably delimited by nickel. Particularly in the case of alkaline electrolysis, the requirements for the cathode compartment and the cathode are comparatively low. It is therefore sufficient to use the expensive nickel only for the anode compartment.
  • a particularly small cross-section of the material can be achieved which is exposed to a highly corrosive medium.
  • the metal mesh forming the cathode can be attached directly to the plate. This can be made easier by structuring the plate on the cathode side, for example by corrugations or ridges.
  • the connecting pin is connected to the metal mesh forming the anode.
  • the connecting pins can be connected to one another, for example via a metal band to which the metal mesh forming the anode can be attached.
  • the connecting pin preferably has a collar on the anode side, via which a seal can be pressed onto the separating element.
  • anode compartment and the cathode compartment can be separated from one another in a fluid-tight manner.
  • An embodiment is also conceivable which differs from the embodiment described here only in that the anode and cathode are interchanged. As described above, however, such an embodiment is less preferred in view of the different requirements in the anode compartment and cathode compartment in terms of corrosion resistance.
  • Another aspect of the invention is an arrangement comprising a plurality of electrochemical cells arranged adjacent to one another in a stacking direction, with adjacent electrochemical cells being separated from one another by a respective electrically insulating separating element, with the electrochemical cells each having an anode compartment with an anode, a cathode compartment with a cathode and a membrane arranged between the anode compartment and the cathode compartment, wherein the anodes are each connected to the cathode of the following electrochemical cell in the stacking direction via an electrically conductive connection which is separate from the respective anode compartment and the respective cathode compartment, and wherein the electrically conductive connections pass through the separating element arranged between the respective anode and the respective cathode and/or a boundary of the electrochemical cells.
  • Fig. 2 a first side view of a cathode for an arrangement according to
  • Fig. 3 a second side view of the cathode from Fig. 2,
  • FIG. 4 a detailed view of an arrangement according to FIG. 1
  • Fig. 5a to 5h different connections between electrodes for an arrangement according to Fig. 1,
  • Fig. 6 a section of a boundary for an arrangement according to
  • Fig. 1 shows an arrangement 1 with three electrochemical cells 2, which are designed as electrolysis cells.
  • the electrochemical cells 2 are arranged in a row next to one another in a stacking direction x and adjoin one another. In addition to the stacking direction x, a second direction y and a third direction z are shown.
  • the electrochemical cells 2 each have an anode 4 and a cathode 5 as well as a membrane 6 arranged between them.
  • the anodes 4 are arranged in a respective anode compartment 24 and the cathodes 5 are arranged in a respective cathode compartment 25 .
  • the anode compartment 24 and the cathode compartment 25 of the electrochemical cell 2 on the left are provided with reference symbols.
  • the anode spaces 24 and the cathode spaces 25 are delimited by a delimitation 23 of the electrochemical cells 2 .
  • Adjacent ones of the electrochemical cells 2 are separated from one another by a respective electrically insulating separator 3 .
  • two separating elements 3 are present.
  • the separating elements 3 each have an electrically conductive core 13 and an electrically insulating cover 14 in the form of a coating or casing.
  • the casing can have a thickness of up to 20 mm.
  • the cathode 5 of the electrochemical cell 2 on the left is connected to an end plate 26 via two connecting pins 12 as an electrically conductive connection 11 .
  • the anodes 4 are each connected via two connecting pins 12 as an electrically conductive connection 11 to the cathode 5 of the electrochemical cell 2 following in the stacking direction x. This means that the anode 4 of the left electrochemical cell 2 is connected to the cathode 5 of the middle electrochemical cell 2 and that the Anode 4 of the middle electrochemical cell 2 is connected to the cathode 5 of the right electrochemical cell 2 .
  • No further electrochemical cell 2 follows the right electrochemical cell 2 in the stacking direction x, so that the anode 4 of the right electrochemical cell 2 cannot be electrically conductively connected to the cathode 5 of a following electrochemical cell 2 in the stacking direction x.
  • the anode 4 of the right-hand electrochemical cell 2 is connected to an end plate 26 via two connecting pins 12 as an electrically conductive connection 11 .
  • the two end plates 26 are connected to a voltage source.
  • the end plates 26 are separated from the adjoining anode space 24 or cathode space 25 by a respective cover 14 .
  • connection between the anodes 4 and the cathodes 5 takes place via connecting pins 12. These are (which is not emphasized in the schematic representation of FIG. 1) separated from the anode compartments 24 and the cathode compartments 25. This means that the electrolyte in the anode compartments 24 and the cathode compartments 25 does not come into contact with the connecting pins 12. Because the connecting pins 12 pass through the separators 3 including the respective electrically conductive core 13, the anodes 4 and the cathodes 5 can, but must, be connected to the conductive core via the electrically conductive core 13 of the respective separator 3 in the event of contact not if there is no contact.
  • FIG. 2 shows a cathode 5 for an arrangement 1 according to FIG. 1.
  • An anode 4 can be designed in the same way. However, the electrode shown is oriented like the cathodes 5 in FIG. 1. An anode 4 would accordingly be mirrored about the plane from the second direction y and the third direction z.
  • the cathode 5 has a plurality of mesh carriers 7 and a metal mesh 8 attached to them.
  • Fastening elements 16 are arranged on the mesh supports 7, via which the cathode 5 can be connected to the anode 4 of an adjacent electrochemical cell 2.
  • the fastening elements 16 each have a thread for a screw, for example.
  • the mesh supports 7 are connected to the fastening elements 16 and to the metal mesh 8 via spot welds 17 .
  • the holding elements 16 and the fastening elements are made of one piece.
  • the connection between the metal mesh 8 and the mesh supports 7 can be made by sintering.
  • FIG. 3 shows the cathode 5 from FIG. 2 from a further perspective.
  • the cathode 5 shown is particularly suitable for an arrangement 1 having anode compartments 24 and cathode compartments 25 with a round cross-section when viewed perpendicularly to the stacking direction x.
  • FIG. 4 shows a detailed view of an arrangement 1 according to FIG. 1.
  • Two electrochemical cells 2 are each shown in half.
  • the membrane 6, the anode space 24 and the cathode space 25 as well as one of the electrodes 4, 5 with the metal mesh 8 are shown.
  • the separating element 3 with the core 13 and the cover 14 is shown between the two electrolytic cells 2.
  • the cathode 5 of the left electrolytic cell 2 is connected to the anode 4 of the right electrolytic cell 2 via two connecting pins 11 .
  • two respective spring elements 9 are arranged, which are set up to tension the metal net 8 away from the separating element 3 .
  • the metal mesh 8 of the electrochemical cell 2 on the left is thus stretched to the left, and the metal mesh 8 of the electrochemical cell 2 on the right is stretched to the right.
  • Electrodes 4.5 show different electrically conductive connections 11 between electrodes 4.5 for an arrangement 1 according to FIG. 1.
  • the designation of the electrodes 4.5 as anode 4 and cathode 5 is only an example. In all of the embodiments of FIGS. 5a to 5f, the anode 4 and the cathode 5 could also be interchanged. In all cases, the electrodes 4.5 are connected to one another directly via a connecting pin 12 as the electrically conductive connection 11.
  • the separating element 3 could therefore be made entirely of plastic, for example. For reasons of stability, however, it is still preferred that the separating element 3 has a metallic core 13 and an electrically insulating cover 14 . This is shown in Figures 5a to 5f.
  • each of the embodiments of FIGS. 5a to 5f it is possible in each of the embodiments of FIGS. 5a to 5f to use flat or ring seals in order to keep the electrolyte away from the electrically conductive connection 11.
  • seals 27 are used so that the electrolyte cannot penetrate into the connection point.
  • the electrodes 4.5 are connected via a connecting pin 12 which engages in a respective socket 18 of the electrodes 4.5. If the connecting pin 12 is a rivet pin, the electrically conductive connection 11 can be formed by pressing. If the connecting pin 12 is a threaded pin, the electrodes 4.5 can be connected to one another by twisting.
  • a seal 27 is arranged between the electrodes 4 , 5 and the cover 14 of the separating element 3 . The seals 27 prevent electrolyte from coming into contact with the connecting pin 12 via the gaps between the electrodes 4 , 5 and the covers 14 of the separating element 3 .
  • the anode 4 has a bushing 18
  • the cathode 5 has a through hole 19
  • a screw as a connecting pin 12 extends through the through hole 19 and is screwed into the bushing 18 .
  • a head 20 of the screw rests against the edge of the through hole 19 on the outside.
  • a seal 27 is arranged between the electrodes 4 , 5 and the cover 14 of the separating element 3 .
  • a further seal 27 is arranged between the head 20 of the screw and the cathode 5 . This seal 27 is designed in such a way that it does not prevent an electrically conductive contact between the head 20 of the screw and the cathode 5 .
  • the connecting pin 12 is formed in one piece with the cathode 5.
  • FIG. 5c The connecting pin 12 is screwed or pressed into the socket 18 of the anode 4 .
  • a seal 27 is arranged between the electrodes 4 , 5 and the cover 14 of the separating element 3 .
  • both electrodes 4, 5 have a respective through hole 19, through which a screw as connecting pin 12 extends.
  • a nut 22 rests against the edge of the through hole 19 on the anode 4 side, and a head 20 of the screw rests on the edge of the through hole 19 on the cathode 5 side.
  • between the electrodes 4.5 and the cover 14 of the Separating element 3 each have a seal 27 arranged.
  • further seals 27 are arranged between the head 20 of the screw and the cathode 5 and between the nut 22 and the anode 4 . The latter are designed in such a way that they do not prevent an electrically conductive contact between the head 20 of the screw and the cathode 5 or between the anode 4 and the nut 22 .
  • the anode 4 has a bushing 18 into which a screw engages as a connecting pin 12.
  • FIG. A head 20 of the screw is covered with a seal 28 .
  • the seal 28 can - be sealed with seals 27 - as shown here.
  • the seal 28 could be screwed in, glued in or melted on.
  • the head 20 of the screw is oblique. This gives a particularly large contact surface between the fastening element and the screw.
  • a seal 27 is arranged between the electrodes 4 , 5 and the cover 14 of the separating element 3 .
  • the electrically conductive connection 11 is formed with the threaded bushing 18 on the anode 4 and with the through-hole 19 on the cathode 5, the through-hole having a cross-section tapering to the right.
  • the anode 4 and the cathode 5 are connected to one another via a connecting pin 12 which is integrally formed with the anode 4 and the cathode 5, for example by laser welding.
  • the connecting pin 12 can be cast onto the anode 4 and onto the cathode 5, for example. It is also possible for the anode 4 and the cathode 5 to be formed in one piece with the connecting pin 12 . In this case, a subdivision into anode 4, connecting pin 12 and cathode 5 is not possible on the basis of a physical dividing line, but only mentally.
  • a seal 27 is arranged between the electrodes 4 , 5 and the cover 14 of the separating element 3 .
  • 5g shows a screw connection as an electrically conductive connection 11 between the anode 4 and the cathode 5.
  • the anode 4 is connected to a socket 18 which has a left-hand thread with a blind hole.
  • the cathode 5 is equipped with a clockwise and continuous thread.
  • the electrodes 4, 5 are connected via a threaded pin 12, which has a left-hand thread on the cathode side and a right-hand thread on the anode side.
  • the threaded pin 12 can be tightened through the through-hole 19 with a screwdriver, for example.
  • the connection can be shielded from the electrolyte on the cathode side with a threaded piece of plastic as a seal 28 .
  • the anode 4 and the cathode 5 are each designed as a metal mesh 8 .
  • the anode 4 is connected to the cathode 5 via a connecting pin 12 .
  • the connecting pin 12 represents an electrically conductive connection 11.
  • a separating element 3 and an electrically conductive plate 29 are arranged between the anode 4 and the cathode 5, . Since the plate 29 and the metal mesh 8 are electrically conductive, the plate 29 can also contribute to the functioning of the cathode 5 and can be regarded as part of the cathode 5 in this respect.
  • the separating element 3 has a through hole 19 for the connecting pin 12 .
  • the plate 29 has a socket 18 for the connecting pin 12.
  • the socket 18 can be formed in that the plate 29 has a through hole into which the connecting pin 12 can be inserted, whereupon the connecting pin 12 can be connected to the plate 29 on the cathode side, for example by laser welding.
  • the connecting pin 12 On the anode side, the connecting pin 12 is connected to the metal mesh 8 forming the anode 4 . Furthermore, the connecting pin 12 has a collar 30 on the anode side, via which a seal 27 can be pressed onto the separating element 3 .
  • FIG. 6 shows a section of the boundary 23 of the electrochemical cells 2.
  • a metallic stabilizing element 15 is provided in this section.
  • the stabilizing element 15 is designed and arranged in such a way that the delimitation 23 is stabilized against forces along the stacking direction x.
  • FIG. 7 shows a detailed view of an arrangement 1 according to the invention, which can basically be designed like the arrangement 1 according to FIG.
  • a cathode 5, a separating element 3 and an anode 4 are shown.
  • the anode 4 and the cathode 5 are each connected to the core 13 of the separating element 3 via a connecting pin 12.
  • the connecting pin 12 can in particular be a screw.
  • the anode 4 and the cathode 5 are electrically conductively connected to one another via the connecting pins 12 and the core 13 of the separating element 3, provided that the connecting pins 11 and the core 13 of the separating element 3 are electrically conductive.
  • a seal 27 is arranged between the electrodes 4 , 5 and the cover 14 of the separating element 3 . The seals 27 prevent electrolyte from coming into contact with the connecting pins 12 via the gaps between the electrodes 4 , 5 and the covers 14 of the separating element 3 .
  • the anode 4 and the cathode 5 can be connected to each other by first applying a cover 14 to the left of the core 13 of the separator 3 .
  • the cathode 5 can then be attached to the core 13 of the separating element 3 with the upper connecting pin 12 .
  • a further cover 14 can then be placed on the right of the core 13 of the separating element 3 and the anode 4 can be attached to the core 13 with the lower connecting pin 12 .
  • the head 20 of the lower connecting pin 12 can be sealed with a seal 21 .
  • the core 13 of the separating element 3 is separated from the electrolyte on both sides by the covers 14 or by the seal 21 .
  • FIG. 8 shows a detailed view of a further arrangement 1 according to the invention, which can basically be designed like the arrangement 1 according to FIG.
  • the separating element 3 is formed entirely of electrically insulating material.
  • the anode 4 and the cathode 5 are connected to one another via a connecting element 10 arranged outside the boundary 23 of the electrochemical cells 2 .
  • the connecting element 10 is also part of the electrically conductive connection 11.
  • the electrically conductive connection 11 passes through the boundary 23.
  • a seal 27 is arranged in each case between the boundary 23 of the electrochemical cells 2 and the electrodes 4.5. By the seals 27 is prevented. that electrolyte comes into contact with the connecting pins 12 via the gaps between the electrodes 4, 5 and the boundary 23 of the electrochemical cells 2.
  • bipolar plates Due to the electrically conductive connection 11 between the anodes 4 and the cathodes 5, bipolar plates can be dispensed with in the arrangement 1 described. As a result, the arrangement 1 is cheaper to manufacture and more efficient to operate than known arrangements.

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  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Secondary Cells (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Fuel Cell (AREA)

Abstract

L'invention concerne un agencement (1) constitué de plusieurs cellules électrochimiques (2) disposées de manière adjacente les unes aux autres dans une direction d'empilement (x), des cellules électrochimiques adjacentes (2) étant séparées les unes des autres par un élément de séparation (3) électriquement isolant, lesdites cellules électrochimiques (2) comprenant chacune une chambre anodique (24) pourvue d'une anode (4), une chambre cathodique (25) pourvue d'une cathode (5) ainsi qu'une membrane (6) disposée entre la chambre anodique (24) et la chambre cathodique (25), les anodes (4) étant reliées respectivement à la cathode (5) de la cellule électrochimique (2) suivante dans la direction d'empilement (x) par le biais d'une liaison électriquement conductrice (11), et les liaisons électriquement conductrices (11) passant à travers l'élément de séparation (3) disposé entre l'anode (4) respective et la cathode respective (5) et/ou une délimitation (23) des cellules électrochimiques (2). La liaison électriquement conductrice (11) réalisée entre les anodes (4) et les cathodes (5) permet de se passer de plaques bipolaires dans l'agencement décrit (1). Ainsi, ledit agencement (1) est plus avantageux en termes de fabrication et assure un fonctionnement plus efficace que des agencement connus.
EP21836475.0A 2020-12-16 2021-12-13 Agencement de cellules électrochimiques Pending EP4263907A2 (fr)

Applications Claiming Priority (2)

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DE102020133770.1A DE102020133770A1 (de) 2020-12-16 2020-12-16 Anordnung elektrochemischer Zellen
PCT/EP2021/085383 WO2022128856A2 (fr) 2020-12-16 2021-12-13 Agencement de cellules électrochimiques

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EP (1) EP4263907A2 (fr)
JP (1) JP2023553324A (fr)
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WO (1) WO2022128856A2 (fr)

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US11978590B1 (en) * 2023-03-28 2024-05-07 University Of Sharjah Integrated thermal management system with a symmetrical supercapacitor cell

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US3880670A (en) * 1973-07-02 1975-04-29 United Aircraft Corp Electrochemical cell separator plate means
US3950239A (en) * 1974-07-24 1976-04-13 Hooker Chemicals & Plastics Corporation Electrical connector for bipolar electrodes
IT1163737B (it) * 1979-11-29 1987-04-08 Oronzio De Nora Impianti Elettrolizzatore bipolare comprendente mezzi per generare la ricircolazione interna dell'elettrolita e procedimento di elettrolisi
JP4583005B2 (ja) * 2003-06-26 2010-11-17 京セラ株式会社 燃料電池用容器および燃料電池
DE102004015680A1 (de) 2004-03-26 2005-11-03 Condias Gmbh Elektrodenanordnung für eine elektrochemische Behandlung von Flüssigkeiten mit einer geringen Leitfähigkeit
US7785450B2 (en) 2006-02-03 2010-08-31 Med-E-Cell “On-site” carbon dioxide generator
CA2728173C (fr) 2008-06-16 2013-07-02 William R. Richards Electrolyseur alcalin
DE102009016635A1 (de) * 2009-04-08 2010-10-14 Elcomax Gmbh Bipolarplatte für Brennstoff- oder Elektrolysezellen
US10337111B2 (en) 2015-12-15 2019-07-02 Hamilton Sunstrand Corporation Solid oxide electrochemical gas separator inerting system
FR3069107B1 (fr) * 2017-07-13 2022-01-14 Commissariat Energie Atomique Plaque de maintien de cellule electrochimique a etancheite amelioree

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WO2022128856A3 (fr) 2022-08-18
DE102020133770A1 (de) 2022-06-23
US20230349056A1 (en) 2023-11-02
JP2023553324A (ja) 2023-12-21

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