EP4263770A1 - Laundry detergent composition containing dye fixative and stabilizing agent - Google Patents

Laundry detergent composition containing dye fixative and stabilizing agent

Info

Publication number
EP4263770A1
EP4263770A1 EP20966231.1A EP20966231A EP4263770A1 EP 4263770 A1 EP4263770 A1 EP 4263770A1 EP 20966231 A EP20966231 A EP 20966231A EP 4263770 A1 EP4263770 A1 EP 4263770A1
Authority
EP
European Patent Office
Prior art keywords
composition
weight
laundry detergent
surfactant system
detergent composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20966231.1A
Other languages
German (de)
English (en)
French (fr)
Inventor
Ming Tang
Dongpeng WANG
Jiahe KANG
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of EP4263770A1 publication Critical patent/EP4263770A1/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719—Polyamides or polyimides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38618—Protease or amylase in liquid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the present invention relates to a laundry detergent composition containing a dye fixative and a stabilizing agent.
  • Colored textiles may fade over several wash cycles due to the release of the dyes from the textiles, especially in the case of dark-colored textiles made of cotton and mixed cotton fabrics.
  • color bleeding might occur, i.e., a differently colored or white textile might be stained with the dye released from dyed textiles as a result relatively high dye concentration in the wash liquor if they were washed at the same time.
  • Color fading or color bleeding would result in a rapid deterioration of the appearance of colored textiles.
  • laundry detergent compositions that are capable of preventing color fading and/or color bleeding.
  • dye fixatives are employed in detergent compositions.
  • Such dye fixatives are usually cationic polymers which could bind negative-charged dyes on the textiles or in the washing liquor so as to prevent the detachment of dyes from colored textiles or redeposition of dyes onto white textiles or textiles with a different dye.
  • the introduction of such dye fixatives into a liquid detergent composition might compromise the stability of the liquid detergent composition, i.e., the dye fixatives have a tendency to separate from the aqueous phase and/or flocculation.
  • the present invention in one aspect relates to a laundry detergent composition, comprising:
  • reaction products of polyamines with cyanamides and acids such as organic and/or inorganic acids
  • the composition is a liquid composition comprising:
  • HCO hydrogenated castor oil
  • MCC microcrystalline cellulose
  • a nonionic surfactant system comprising C10-C16 ethoxylated alcohol having a weight average degree of ethoxylation ranging from 5to 15, preferably 6 to 12, and more preferably 7 to 10;
  • an anionic surfactant system comprising C10-C16 LAS and C10-C16 alkyl ethoxy sulfates in which preferably, the C10-C16 LAS is present in an amount ranging from 10%to 90%, by weight of the anionic surfactant system;
  • weight ratio of the nonionic surfactant system to the anionic surfactant system is between 1.5 and 8.
  • composition is an unit dose composition comprising:
  • said dye fixative is selected from the group consisting of reaction products of dimethylamine with epichlorohydrin;
  • anionic surfactant system comprising C 10 -C 16 LAS and C 10 -C 16 alkyl ethoxy sulfates in which said C 10 -C 16 LAS is present in an amount ranging from 40%to 90%, by weight of the anionic surfactant system;
  • weight ratio of the nonionic surfactant system to the anionic surfactant system is between 1.5 and 8.
  • the present invention relates to a method of protecting color in a colored fabric comprising contacting the colored fabric with the laundry detergent composition as mentioned hereinabove.
  • the protection of the color is achieved by fixing dyes in the colored fabric and/or preventing color fading or color bleeding from the colored fabric.
  • the present invention relates to a method of preventing color fading or color bleeding of a colored fabric comprising contacting the colored fabric with the laundry detergent composition as mentioned hereinabove.
  • the present invention relates to a method of fixing dyes in a colored fabric comprising contacting the colored fabric with the laundry detergent composition as mentioned hereinabove.
  • the terms “comprise” , “comprises” , “comprising” , “include” , “includes” , “including” , “contain” , “contains” , and “containing” are meant to be non-limiting, i.e., other steps and other ingredients which do not affect the end of result can be added.
  • the above terms encompass the terms “consisting of” and “consisting essentially of” .
  • composition is “substantially free” of a specific ingredient, it is meant that the composition comprises less than a trace amount, alternatively less than 0.1%, alternatively less than 0.01%, alternatively less than 0.001%, by weight of the composition, of the specific ingredient.
  • laundry detergent composition means a composition for cleaning soiled materials, including fabrics. Such compositions may be used as a pre-laundering treatment, a post-laundering treatment, or may be added during the rinse or wash cycle of the laundering operation.
  • the laundry detergent composition compositions may have a form selected from liquid, powder, unit dose such as single-compartment or multi-compartment unit dose, pouch, tablet, gel, paste, bar, or flake.
  • the laundry detergent composition is a liquid or a unit dose composition.
  • liquid laundry detergent composition herein refers to compositions that are in a form selected from the group consisting of pourable liquid, gel, cream, and combinations thereof.
  • the liquid laundry detergent composition may be either aqueous or non-aqueous, and may be anisotropic, isotropic, or combinations thereof.
  • unit dose laundry detergent composition herein refers to a water-soluble pouch containing a certain volume of liquid wrapped with a water-soluble film.
  • main surfactant refers to a surfactant that is present in a composition at an amount that is greater than any other surfactant contained by such composition.
  • main anionic surfactant refers to an anionic surfactant that is present in a composition at an amount that is greater than any other anionic surfactant contained by such composition
  • major surfactant refers to a surfactant that is present in a composition at an amount that is at least 50%by weight of the total surfactant content in such composition.
  • major anionic surfactant refers to an anionic surfactant that is present in a composition at an amount that is at least 50%by weight of the total anionic surfactant content in such composition.
  • alkyl means a hydrocarbyl moiety which is branched or unbranched, substituted or unsubstituted. Included in the term “alkyl” is the alkyl portion of acyl groups.
  • washing solution refers to the typical amount of aqueous solution used for one cycle of laundry washing, preferably from 1 L to 50 L, alternatively from 1 L to 20 L for hand washing and from 20 L to 50 L for machine washing.
  • oiled fabric is used non-specifically and may refer to any type of natural or artificial fibers, including natural, artificial, and synthetic fibers, such as, but not limited to, cotton, linen, wool, polyester, nylon, silk, acrylic, and the like, as well as various blends and combinations.
  • the dye fixatives of the present invention are cationic polymers. Without being bound by any theory, it is believed that such dye fixatives with positive charges can bind dyes with negative charges through charge interactions and then prevent the dyes out of the textiles or prevent the redeposition of the dyes onto a different colored textiles.
  • the dye fixatives may be selected from the group consisting of reaction products of: i) polyamines with cyanamides and organic and/or inorganic acids, ii) cyanamides with aldehydes and ammonium salts, iii) cyanamides with aldehydes and amines, or iv) amines with epichlorohydrin.
  • the dye fixative may be selected from the group consisting of reaction products of amines with epichlorohydrin in which the amines are primary, secondary or tertiary amines. More preferably, the dye fixative may be selected from the group consisting of reaction products of dimethylamine with epichlorohydrin. Most preferably, the dye fixative may be poly (2-hydroxypropyldimethylammonium chloride) , also called poly (dimethylamine-co-epichlorohydrin) , for example the polymer commercially available under the trade name of TEXCARE DFC 6 from Clariant (CAS#: 25988-97-0) .
  • amines comprises monoamines and polyamines.
  • the monoamines used herein may be primary, secondary and tertiary amines. They may be aliphatic amines, for example dialkylamines, especially dimethylamine, alicyclic amines, for example cyclohexylamine, and aromatic amines, for example aniline.
  • the amines used herein may also simultaneously have aliphatic, alicyclic and aromatic substituents.
  • heterocyclic compounds for example pyridine.
  • polyamines herein includes, for example diamines, triamines, tetraamines, etc, and also the analogous N-alkylpolyamines and N, N-dialkylpolyamines. Examples thereof are ethylenediamine, propylenediamine, butylenediamine, pentylenediamine, hexylenediamine, diethylenetriamine, triethylenetetraamine and higher polyamines. Particularly preferred polyamines may be ethylenediamine, diethylenetriamine and dimethylaminopropylamine.
  • the ammonium salts are salts of ammonia, especially ammonium chloride or the abovementioned amines or polyamines with different inorganic or organic acids, or else quaternary ammonium salts.
  • the cyanamides may be cyanamide or dicyandiamide.
  • Aldehydes used herein may include, for example, aliphatic aldehydes such as formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde; dialdehydes, for example glyoxal; unsaturated aldehydes, for example acrolein, crotonaldehyde and aromatic aldehydes, for example benzaldehyde.
  • Particularly preferred aldehydes may be aliphatic aldehydes such as formaldehyde.
  • the dye fixatives used herein may also be homo-and copolymers based on diallyldimethylammonium chloride (DADMAC) .
  • DADMAC diallyldimethylammonium chloride
  • Copolymers based on DADMAC contain, as further components, other vinylic monomers, for example vinylimidazole, vinylpyrrolidone, vinyl alcohol, vinyl acetate, (meth) acrylic acid/ester, acrylamide, styrene, styrenesulfonic acid, acrylamidomethylpropanesulfonic acid (AMPS) , etc.
  • Homopolymers based on DADMAC are obtainable under the trade names 3954, Dodigen 4033 and Genamin PDAC (from Clariant) .
  • the dye fixative suitable for use in the present disclosure can be selected from the group consisting of reaction products of amines with epichlorohydrin in which the amines are primary, secondary or tertiary amines. More preferably, the dye fixative suitable for use in the present invention can be selected from the group consisting of reaction products of dimethylamine with epichlorohydrin. Most preferably, the dye fixative may be poly (2-hydroxypropyldimethylammonium chloride) .
  • the dye fixative is poly (2-hydroxypropyldimethylammonium chloride) of formula (I) :
  • n is an integer from 5 to 1000.
  • the dye fixative in the composition according to the present disclosure may be present in an amount ranging from 0.02%to 5%, preferably from 0.05%to 2%, more preferably from 0.1%to 1.5%, most preferably from 0.15%to 0.9%, for example 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1.0%or any ranges therebetween, by weight of the composition.;
  • the stabilizing agent suitable for use in the present invention may be a crystalline, hydroxyl-containing stabilizing agent.
  • the stabilizing agent may be selected from the group consisting of microcrystalline cellulose (MCC) or derivatives thereof, castor oil or derivatives thereof, hydrogenated castor oil (HCO) or derivatives thereof, and any combinations thereof. More preferably, the stabilizing agent may be microcrystalline cellulose or derivatives thereof and/or hydrogenated castor oil or derivatives thereof.
  • MCC is a naturally occurring polymer. It is composed of glucose units connected by a 1-4 beta glycosidic bond. These linear cellulose chains are bundled together as microfibril spiralled together in plant cell walls. It has been used in food applications and pharmaceutical tablets.
  • Castor oils may include glycerides, especially triglycerides, comprising C 10 to C 22 alkyl or alkenyl moieties which incorporate a hydroxyl group. Hydrogenation of castor oil to make HCO converts double bonds, which may be present in the starting oil as ricinoleyl moieties, to convert ricinoleyl moieties to saturated hydroxyalkyl moieties, e.g., hydroxystearyl.
  • the HCO herein may, in some embodiments, be selected from: trihydroxystearin; dihydroxystearin; and mixtures thereof.
  • the HCO may be processed in any suitable starting form, including, but not limited those selected from solid, molten and mixtures thereof.
  • the stabilizing agent is incorporated into the liquid detergent composition through the use of external structuring system (s) (ESS) comprising the stabilizing agent.
  • ESS external structuring system
  • the ESS suitable for use in the present invention may comprise: (a) the stabilizing agent; (b) alkanolamine e.g. monoethanolamine (MEA) ; (c) anionic surfactant such as: linear alkyl benzene sulphonate (LAS) ; and (d) additional components.
  • HCO is typically present in the ESS of the present invention at a level of from about 2%to about 10%, from about 3%to about 8%, or from about 4%to about 6%by weight of the structuring system.
  • the corresponding percentage of hydrogenated castor oil delivered into a finished laundry detergent product is below about 1.0%, typically from 0.1%to 0.8%.
  • Useful HCO may have the following characteristics: a melting point of from about 40 °C to about 100 °C, or from about 65 °C to about 95 °C; and/or Iodine value ranges of from 0 to about 5, from 0 to about 4, or from 0 to about 2.6.
  • the melting point of HCO can be measured using either ASTM D3418 or ISO 11357; both tests utilize DSC: Differential Scanning Calorimetry.
  • HCO of use in the present invention includes those that are commercially available.
  • Non-limiting examples of commercially available HCO of use in the present invention include: from Rheox, Inc.
  • the source of the castor oil for hydrogenation to form HCO can be of any suitable origin, such as from Brazil or India.
  • castor oil is hydrogenated using a precious metal, e.g., palladium catalyst, and the hydrogenation temperature and pressure are controlled to optimize hydrogenation of the double bonds of the native castor oil while avoiding unacceptable levels of dehydroxylation.
  • the stabilizing agent in the composition according to the present disclosure may be present in an amount ranging from 0.01%to 9%, preferably from 0.02%to 8%, more preferably from 0.03%to 5%, yet more preferably from 0.05%to 3%, most preferably from 0.06%to 2%, for example, 0.1%, 0.2%, 0.3%, 0.5%, 0.7%, 1%, 2%or any ranges therebetween, by weight of the composition.
  • the amine oxide suitable for use in the present invention may be selected from the group consisting of C 6 -C 20 alkyldimethyl amine oxides (AO) and combinations thereof.
  • the amine oxide is characterized by the following structure:
  • R 1 is a C 6-20 alkyl, a C 6-20 hydroxyalkyl, or a C 6-20 alkyl phenyl group
  • each R 2 is a C 2-5 alkylene, or a C 2-5 hydroxyalkylene group
  • x is from 0 to about 3
  • each R 3 is a C 1-3 alkyl, a C 1-3 hydroxyalkyl, or a polyethylene oxide containing from about 1 to about 3 ethoxylene (EO) units.
  • the amine oxide may be a C 8-18 alkyldimethyl amine oxide, preferably a C 10-16 alkyldimethyl amine oxide.
  • the amine oxide is selected from the group consisting of dodecyldimethyl amine oxide, tetradecyldimethyl amino oxide, and a combination thereof. More preferably, the amine oxide contains dodecyldimethyl amino oxide having the following formula (III) :
  • Such a compound is also referred to as lauryldimethyl amine oxide or dodecydimethyl amine-N-oxide (DDAO) . It is commercially available from Huntsman under the tradename LO.
  • the amine oxide in the composition according to the present disclosure may be present in an amount ranging from 0.01%to 10%, preferably from 0.02%to 8%, more preferably from 0.1%to 3%, most preferably from 0.15%to 2%, for example 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 1.5%, 2%, 2.5%, 3%, 4%, 5%or any ranges therebetween, by weight of the composition.
  • the laundry detergent composition of the present invention may comprise an anionic surfactant system.
  • the laundry detergent composition of the present invention may comprise from 0.1%to 50%by weight of the composition, of an anionic surfactant system.
  • the anionic surfactant system may comprise an anionic surfactant selected from the group consisting of C 6 -C 20 linear alkylbenzene sulfonates (LAS) , C 6 -C 20 alkyl sulfates (AS) , C 6 -C 20 alkyl alkoxy sulfates (AAS) , C 6 -C 20 methyl ester sulfonates (MES) , C 6 -C 20 alkyl ether carboxylates (AEC) , and any combinations thereof.
  • an anionic surfactant selected from the group consisting of C 6 -C 20 linear alkylbenzene sulfonates (LAS) , C 6 -C 20 alkyl sulfates (AS) , C 6 -C 20 alkyl alkoxy sulfates (AAS) , C 6 -C 20 methyl ester sulfonates (MES) , C 6 -C 20 alkyl ether carboxylates (A
  • the anionic surfactant system may comprise a C 6 -C 20 LAS and optionally an additional anionic surfactant such as a C 6 -C 20 AS and/or a C 6 -C 20 AAS.
  • LAS is C 10 -C 16 LAS, preferably C 12 -C 14 LAS.
  • the LAS is normally prepared by sulfonation (using SO 2 or SO 3 ) of alkylbenzenes followed by neutralization.
  • Suitable alkylbenzene feedstocks can be made from olefins, paraffins or mixtures thereof using any suitable alkylation scheme, including sulfuric and HF-based processes.
  • the precise alkylation catalyst it is possible to widely vary the position of covalent attachment of benzene to an aliphatic hydrocarbon chain. Accordingly, the LAS herein can vary widely in 2-phenyl isomer and/or internal isomer content.
  • C 6 -C 20 LAS may be present in an amount ranging from 1%to 100%, preferably from 10%to 99%, more preferably from 20%to 95%, most preferably from 30%to 90%, for example 40%, 50%, 60%, 70%, 80%, 90%or any ranges therebetween, by weight of the anionic surfactant.
  • the level of LAS is preferably higher than that of any other anionic surfactant contained by such composition, i.e., the LAS is the main anionic surfactant in such composition.
  • the anionic surfactant suitable for use in the present disclosure may further comprise C 6 -C 20 alkyl sulfates (AS) , C 6 -C 20 alkyl alkoxy sulfates (AAS) , C 6 -C 20 methyl ester sulfonates (MES) , C 6 -C 20 alkyl ether carboxylates (AEC) , or any combinations thereof.
  • the laundry detergent composition may contain a C 6 -C 20 alkyl alkoxy sulfates (AA x S) , wherein x is about 1-30, preferably about 1-15, more preferably about 1-10, most preferably x is about 1-3.
  • the alkyl chain in such AA x S can be either linear or branched, with mid-chain branched AA x S surfactants being particularly preferred.
  • a preferred group of AA x S include C 12 -C 14 alkyl alkoxy sulfates with x of about 1-3.
  • the amount of AA x S surfactant (s) in the laundry detergent composition of the present invention may range from about 0.05%to about 100%, preferably from about 0.1%to about 80%, more preferably from about 0.5%to about 50%, most preferably from about 1%to about 30%, for example 5%, 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90%or any ranges therebetween, by weight of the composition.
  • the weight ratio of LAS to AA x S is at least 0.6, preferably at least 0.8, more preferably at least 0.9, most preferably at least 1, for example 0.6, 0.7, 0.8, 0.9, 1, 1.2, 1.5, 2, 2.5, 3, 4, 5, 8, 10 or any ranges therebetween.
  • the anionic surfactant system in the composition according to the present disclosure may be present in an amount ranging from 0.1%to 45%, preferably from 0.5%to 40%, more preferably from 1%to 35%, most preferably from 2%to 30%, for example 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%or any ranges therebetween, by weight of the composition.
  • the anionic surfactant in the composition according to the present disclosure may comprise less than 30%, preferably less than 20%, more preferably less than 10%, most preferably less than 5%, of soap by weight of the anionic surfactant.
  • the laundry detergent composition of the present invention may comprise a nonionic surfactant system.
  • the nonionic surfactant system may comprise a nonionic surfactant selected from the group consisting of alkyl alkoxylated alcohols, alkyl alkoxylated phenols, alkyl polysaccharides, polyhydroxy fatty acid amides, alkoxylated fatty acid esters, alkyl polyglycosides (APG) , methyl ester ethoxylates (MEE) , sucrose esters, sorbitan esters and alkoxylated derivatives of sorbitan esters, and any combinations thereof.
  • the nonionic surfactant system may comprise a C 6 -C 20 alkoxylated alcohol having a weight average degree of alkoxylation ranging from 1 to 20, preferably from 5 to 15, more preferably from 7 to 10. More preferably, the nonionic surfactant system may comprise a C 8 -C 18 ethoxylated alcohol having a weight average degree of ethoxylation ranging from 1 to 20, preferably from 5 to 15, more preferably from 7 to 10.
  • Non-limiting examples of nonionic surfactants suitable for use herein include: C 12 -C 18 alkyl ethoxylates, such as C 12 -C 14 alkyl ethoxylates with EO 7-9; nonionic surfactants available from Shell; C 6 -C 12 alkyl phenol alkoxylates wherein the alkoxylate units are a mixture of ethyleneoxy and propyleneoxy units; C 12 -C 18 alcohol and C 6 -C 12 alkyl phenol condensates with ethylene oxide/propylene oxide block alkyl polyamine ethoxylates such as available from BASF; C 14 -C 22 mid-chain branched alkyl alkoxylates, BAEx, wherein x is from about 1 to about 30; alkylpolysaccharides, specifically alkylpolyglycosides; polyhydroxy fatty acid amides; and ether capped poly (oxyalkylated) alcohol surfactants.
  • alkoxylated ester surfactants such as those having the formula R 1 C (O) O (R 2 O) nR 3 wherein R 1 is selected from linear and branched C 6 -C 22 alkyl or alkylene moieties; R 2 is selected from C 2 H 4 and C 3 H 6 moieties and R 3 is selected from H, CH 3 , C 2 H 5 and C 3 H 7 moieties; and n has a value between about 1 and about 20.
  • alkoxylated ester surfactants include the fatty methyl ester ethoxylates (MEE) and are well-known in the art.
  • the alkoxylated nonionic surfactant contained by the laundry detergent composition of the present invention is a C 6 -C 20 alkoxylated alcohol, preferably C 8 -C 18 alkoxylated alcohol, more preferably C 10 -C 16 alkoxylated alcohol.
  • the C 6 -C 20 alkoxylated alcohol is preferably an alkyl alkoxylated alcohol with an average degree of alkoxylation of from about 1 to about 50, preferably from about 3 to about 30, more preferably from about 5 to about 20, even more preferably from about 5 to about 9.
  • the alkoxylation herein may be ethoxylation, propoxylation, or a mixture thereof, but preferably is ethoxylation.
  • the alkoxylated nonionic surfactant is C 6 -C 20 ethoxylated alcohol, preferably C 8 -C 18 alcohol ethoxylated with an average of about 5 to about 20 moles of ethylene oxides, more preferably C 10 -C 16 alcohol ethoxylated with an average of about 5 to about 9 moles of ethylene oxides.
  • the most preferred alkoxylated nonionic surfactant is C 12 -C 15 alcohol ethoxylated with an average of about 7 moles of ethylene oxide, e.g., 25-7 commercially available from Shell.
  • the nonionic surfactant system in the composition according to the present disclosure may be present in an amount ranging from 1%to 45%, preferably from 2%to 40%, more preferably from 3%to 35%, most preferably from 4%to 30%, for example 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 20%, 25%, 30%or any ranges therebetween, by weight of the composition.
  • the weight ratio of the nonionic surfactant system to the anionic surfactant system is between 1.5 and 20, preferably between 1.7 and 15, more preferably between 1.9 and 10, and most preferably between 2 and 8, for example 1.5, 1.6, 1.7, 1.8, 1.9, 2, 2.1, 2.2, 2.3, 2.5, 3, 4, 5, 6, 7, 8, 9, 10 and any ranges therebetween.
  • the laundry detergent composition according to the present disclosure may further comprise from 0.01%to 10%, preferably from 0.1%to 5%, more preferably from 0.2%to 3%, most preferably from 0.3%to 2%, by weight of the composition, of a surfactant boosting polymer, preferably polyvinyl acetate grafted polyethylene oxide copolymer.
  • a surfactant boosting polymer preferably polyvinyl acetate grafted polyethylene oxide copolymer.
  • the laundry detergent composition of the present invention may further comprise a cationic surfactant.
  • cationic surfactants include: quaternary ammonium surfactants, which can have up to 26 carbon atoms include: alkoxylate quaternary ammonium (AQA) surfactants; dimethyl hydroxyethyl quaternary ammonium; dimethyl hydroxyethyl lauryl ammonium chloride; polyamine cationic surfactants; and amino surfactants, specifically amido propyldimethyl amine (APA) .
  • AQA alkoxylate quaternary ammonium
  • APA amino surfactants
  • adjunct ingredients include but are not limited to: builders, chelating agents, rheology modifiers, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, photobleaches, perfumes, perfume microcapsules, structure elasticizing agents, fabric softeners, carriers, hydrotropes, processing aids, solvents, hueing agents, structurants and/or pigments.
  • the precise nature of these adjunct ingredients and the levels thereof in the laundry detergent composition will depend on the physical form of the composition and the nature of the cleaning operation for which it is to be used.
  • the laundry detergent composition according to the present disclosure may further comprise from 0.01%to 10%, preferably from 0.1%to 5%, more preferably from 0.2%to 3%, most preferably from 0.3%to 2%, by weight of the composition, of a fatty acid.
  • the laundry detergent composition of the present invention is generally prepared by conventional methods such as those known in the art of making laundry detergent compositions. Such methods typically involve mixing the essential and optional ingredients in any desired order to a relatively uniform state, with or without heating, cooling, application of vacuum, and the like, thereby providing laundry detergent compositions containing ingredients in the requisite concentrations.
  • Another aspect of the present invention is directed to a method of using the laundry detergent composition to treat a fabric. Such method can deliver a color protection benefit.
  • the method comprises the step of administering from 5 g to 120 g of the above-mentioned laundry detergent composition into a laundry washing basin comprising water to form a washing solution.
  • the washing solution in a laundry washing basin herein preferably has a volume from 1 L to 50 L, alternatively from 1 L to 20 L for hand washing and from 20 L to 50 L for machine washing.
  • the temperatures of the laundry washing solution preferably range from 5°C to 60°C.
  • the dosing amount in the method herein may be different depending on the washing type.
  • the method comprises administering from about 5 g to about 60 g of the laundry detergent composition into a hand washing basin (e.g., about 2-4 L) .
  • the method comprises administering from about 5 g to about 100 g, preferably from about 10 g to about 65 g of the laundry detergent composition into a washing machine (e.g., about 30-45 L) .
  • Step 2) Store the samples prepared in Step 1) under different temperatures (5 ⁇ or 40 ⁇ ) for a certain period (1, 2 or 4 weeks) or subject the samples prepared in Step 1) to Frozen/Thawed (-18 ⁇ and 15 ⁇ ) cycles (1, 2 or 3 cycles) by freezing the samples in refrigerators (at -18 ⁇ ) for 24 hours and then thawing the samples in containers (at 15 ⁇ ) for 24 hours (repeated if more than 1 cycle) ;
  • Step 2 3) Visually inspect the samples to determine if they are still homogeneous systems after Step 2) . If there is any phase separation such as the formation of separated layers or flocculation, it is determined as “fail” . If there is no phase separation, it is determined as “pass” .
  • Dye bleeding test c is conducted by using Tergotometer (Model: RHLQ1V, from Research Institute of Daily Chemical Industry (RIDCI) ) as below:
  • test fabric (ASIE-130 or ASIE-133) in each piece for each tube of tergotometer;
  • RO reverse osmosis
  • Step 7) Take out ⁇ 30ml solution to measure L*/a*/b under same condition as Step 5) ;
  • Example 1 Stability of Liquid Laundry Detergent Compositions Containing Dye Fixative
  • a liquid laundry detergent composition containing a dye fixative was prepared containing the following ingredients as shown in Table 1.
  • Dye fixative poly (2-hydroxypropyldimethylammonium chloride) commercially available under the trade name of TEXCARE DFC 6 from Clariant.
  • Samples 1 to 6 and Control were prepared by adding different stabilizing agents into the liquid laundry detergent composition containing the dye fixative shown in Table 1, in which hydrogenated castor oil (HCO) , microcrystalline cellulose (MCC) , carboxymethyl cellulose (CMC) , starch, alcohol ethoxylate and polymeric thickener were tested as the stabilizing agent and no stabilizing agent was added for Control.
  • HCO hydrogenated castor oil
  • MCC microcrystalline cellulose
  • CMC carboxymethyl cellulose
  • starch alcohol ethoxylate and polymeric thickener
  • a sample liquid laundry detergent composition containing a dye fixative (Sample 7) and a control (Comparative Sample 2, i.e. China National Standard Liquid Detergent) containing no dye fixative were prepared containing the following ingredients.
  • Dye fixative poly (2-hydroxypropyldimethylammonium chloride) commercially available under the trade name of TEXCARE DFC 6 from Clariant.
  • sample liquid laundry detergent composition containing a dye fixative (Sample 8) and a control (Comparative Sample 3) containing a similar surfactant system but no color fixative were prepared containing the following ingredients.
  • Dye fixative poly (2-hydroxypropyldimethylammonium chloride) commercially available under the trade name of TEXCARE DFC 6 from Clariant.
  • Example 3 Exemplary Formulations of Liquid Laundry Detergent Compositions Containing Dye Fixative
  • liquid laundry detergent compositions shown in Table 5 are made comprising the listed ingredients in the listed proportions (weight %) .
  • Example 4 Exemplary Formulations of Unite Dose Laundry Detergent Compositions Containing a Dye Fixative
  • compositions shown in Table 6 are made for unit dose laundry detergent. These compositions are encapsulated into compartment (s) of the unit dose by using a polyvinyl-alcohol-based film.

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US20230034095A1 (en) * 2021-07-16 2023-02-02 The Procter & Gamble Company Liquid hand dishwashing cleaning composition
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US20230018865A1 (en) * 2021-07-16 2023-01-19 The Procter & Gamble Company Liquid hand dishwashing cleaning composition
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DE102004051011A1 (de) * 2004-10-20 2005-06-23 Clariant Gmbh Flüssigwaschmittel enthaltend sekundäres Alkansulfonat und Farbfixiermittel
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