EP4221662A1 - Reinigungstücher getränkt mit tränkungsmitteln basierend auf einer öl-in-wasser-emulsion - Google Patents
Reinigungstücher getränkt mit tränkungsmitteln basierend auf einer öl-in-wasser-emulsionInfo
- Publication number
- EP4221662A1 EP4221662A1 EP21763388.2A EP21763388A EP4221662A1 EP 4221662 A1 EP4221662 A1 EP 4221662A1 EP 21763388 A EP21763388 A EP 21763388A EP 4221662 A1 EP4221662 A1 EP 4221662A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oil
- impregnating agent
- weight
- agent according
- cleaning agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 238000004140 cleaning Methods 0.000 title abstract description 52
- 239000007764 o/w emulsion Substances 0.000 title abstract description 5
- 238000005470 impregnation Methods 0.000 title description 8
- 239000012459 cleaning agent Substances 0.000 claims description 32
- 239000000126 substance Substances 0.000 claims description 29
- 239000003995 emulsifying agent Substances 0.000 claims description 23
- 239000003921 oil Substances 0.000 claims description 23
- 235000019198 oils Nutrition 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000000839 emulsion Substances 0.000 claims description 17
- -1 fatty acid triglycerides Chemical class 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 230000000694 effects Effects 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 12
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 11
- 229960005323 phenoxyethanol Drugs 0.000 claims description 11
- 238000004321 preservation Methods 0.000 claims description 9
- 229920000297 Rayon Polymers 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 8
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- 239000010696 ester oil Substances 0.000 claims description 7
- YSRSBDQINUMTIF-SNVBAGLBSA-N (2r)-decane-1,2-diol Chemical compound CCCCCCCC[C@@H](O)CO YSRSBDQINUMTIF-SNVBAGLBSA-N 0.000 claims description 6
- ANZUDYZHSVGBRF-UHFFFAOYSA-N 3-ethylnonane-1,2,3-triol Chemical compound CCCCCCC(O)(CC)C(O)CO ANZUDYZHSVGBRF-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
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- 230000008719 thickening Effects 0.000 claims description 5
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 claims description 4
- TXFPEBPIARQUIG-UHFFFAOYSA-N 4'-hydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1 TXFPEBPIARQUIG-UHFFFAOYSA-N 0.000 claims description 4
- SASYSVUEVMOWPL-NXVVXOECSA-N decyl oleate Chemical compound CCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC SASYSVUEVMOWPL-NXVVXOECSA-N 0.000 claims description 4
- 229940089456 isopropyl stearate Drugs 0.000 claims description 4
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 claims description 4
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 claims description 4
- ZPWFUIUNWDIYCJ-UHFFFAOYSA-N propan-2-yl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(C)C ZPWFUIUNWDIYCJ-UHFFFAOYSA-N 0.000 claims description 4
- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 claims description 3
- NKEQOUMMGPBKMM-UHFFFAOYSA-N 2-hydroxy-2-[2-(2-hydroxy-3-octadecanoyloxypropoxy)-2-oxoethyl]butanedioic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CC(O)(C(O)=O)CC(O)=O NKEQOUMMGPBKMM-UHFFFAOYSA-N 0.000 claims description 3
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- 229920003086 cellulose ether Polymers 0.000 claims description 3
- 150000001983 dialkylethers Chemical class 0.000 claims description 3
- XJFGDLJQUJQUEI-UHFFFAOYSA-N dodecyl decanoate dodecyl octanoate Chemical compound CCCCCCCCCCCCOC(=O)CCCCCCC.CCCCCCCCCCCCOC(=O)CCCCCCCCC XJFGDLJQUJQUEI-UHFFFAOYSA-N 0.000 claims description 3
- PMMXXYHTOMKOAZ-UHFFFAOYSA-N hexadecyl 7-methyloctanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCC(C)C PMMXXYHTOMKOAZ-UHFFFAOYSA-N 0.000 claims description 3
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 claims description 3
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- 239000000312 peanut oil Substances 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 claims description 2
- 229940015975 1,2-hexanediol Drugs 0.000 claims description 2
- 229940043375 1,5-pentanediol Drugs 0.000 claims description 2
- SAMYFBLRCRWESN-UHFFFAOYSA-N 16-methylheptadecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC(C)C SAMYFBLRCRWESN-UHFFFAOYSA-N 0.000 claims description 2
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 claims description 2
- CZVOIAOPRGNENY-UHFFFAOYSA-N 2-butyloctyl 2-hydroxybenzoate Chemical compound CCCCCCC(CCCC)COC(=O)C1=CC=CC=C1O CZVOIAOPRGNENY-UHFFFAOYSA-N 0.000 claims description 2
- UADWUILHKRXHMM-UHFFFAOYSA-N 2-ethylhexyl benzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1 UADWUILHKRXHMM-UHFFFAOYSA-N 0.000 claims description 2
- 229940106004 2-ethylhexyl benzoate Drugs 0.000 claims description 2
- LWLRMRFJCCMNML-UHFFFAOYSA-N 2-ethylhexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CC)CCCC LWLRMRFJCCMNML-UHFFFAOYSA-N 0.000 claims description 2
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 claims description 2
- MWKPHOIHTLQZIY-UHFFFAOYSA-N 2-hexyldecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC MWKPHOIHTLQZIY-UHFFFAOYSA-N 0.000 claims description 2
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 claims description 2
- RUDXBXPTJPNTSO-UHFFFAOYSA-N 2-octyldodecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC RUDXBXPTJPNTSO-UHFFFAOYSA-N 0.000 claims description 2
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 claims description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims description 2
- SJIDAAGFCNIAJP-UHFFFAOYSA-N 6-methylheptyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCC(C)C SJIDAAGFCNIAJP-UHFFFAOYSA-N 0.000 claims description 2
- XUVVLJKRLAXOKZ-UHFFFAOYSA-N 7-methyloctyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCC(C)C XUVVLJKRLAXOKZ-UHFFFAOYSA-N 0.000 claims description 2
- 244000198134 Agave sisalana Species 0.000 claims description 2
- 244000025254 Cannabis sativa Species 0.000 claims description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 2
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- 229910019142 PO4 Inorganic materials 0.000 claims description 2
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- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 claims description 2
- ULBTUVJTXULMLP-UHFFFAOYSA-N butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCC ULBTUVJTXULMLP-UHFFFAOYSA-N 0.000 claims description 2
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- 235000014692 zinc oxide Nutrition 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- AGNTUZCMJBTHOG-UHFFFAOYSA-N 3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]propane-1,2-diol Chemical class OCC(O)COCC(O)COCC(O)CO AGNTUZCMJBTHOG-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 244000144927 Aloe barbadensis Species 0.000 description 1
- 235000002961 Aloe barbadensis Nutrition 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- MOZDKDIOPSPTBH-UHFFFAOYSA-N Benzyl parahydroxybenzoate Chemical compound C1=CC(O)=CC=C1C(=O)OCC1=CC=CC=C1 MOZDKDIOPSPTBH-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 240000001548 Camellia japonica Species 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 240000006740 Cichorium endivia Species 0.000 description 1
- 235000018536 Cichorium endivia Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241001640753 Fibrella Species 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 229920000433 Lyocell Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000588770 Proteus mirabilis Species 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- FRGAIZLZPOROJH-BKIJVIAGSA-N [(2R,3S,4S,5R,6S)-3,4,5-trihydroxy-6-[2-hydroxy-3-[2-hydroxy-3-(2-hydroxy-3-octadecanoyloxypropoxy)propoxy]propoxy]oxan-2-yl]methyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COCC(O)CO[C@H]1O[C@H](COC(=O)CCCCCCCCCCCCCCCCC)[C@@H](O)[C@H](O)[C@H]1O FRGAIZLZPOROJH-BKIJVIAGSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001140 aloe barbadensis leaf extract Substances 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 235000019606 astringent taste Nutrition 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940034794 benzylparaben Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 229940067596 butylparaben Drugs 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 235000018597 common camellia Nutrition 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000009878 intermolecular interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- GJLNWLVPAHNBQN-UHFFFAOYSA-N phenyl 4-hydroxybenzoate Chemical compound C1=CC(O)=CC=C1C(=O)OC1=CC=CC=C1 GJLNWLVPAHNBQN-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000019640 taste Nutrition 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
Definitions
- the present invention relates to a cleaning cloth impregnated with an impregnating agent based on an oil-in-water emulsion (O/W emulsion).
- O/W emulsion oil-in-water emulsion
- Cleaning wipes are a special form of cleaning agent because the cleaning performance is based on the interaction of the wipe and the impregnating agent.
- Cleaning wipes are characterized by the fact that it is a cleaning agent that is ready to use. No additional solvent, especially water, is required to develop the effect. Also, no solvent, especially water, is needed to wash away dirt. Cleaning wipes can be used conveniently on the go and when traveling or simply in between.
- cleaning cloths are used in a variety of ways, for example in leather and floor care, in the hygiene sector, in intimate and body care.
- cleansing wipes are also advantageously used for baby care, face and body cleansing, cleaning of the skin in the diaper area, and as toilet paper to promote toilet training in young children.
- facial cleansing When cleaning the face, dirt that has gotten onto the skin from the outside, dead cells and excess sebum must be removed. The dirt that has got onto the skin from the outside also includes make-up that has to be removed again.
- inorganic pigments such as silicates [magnesium silicate (talc), aluminum silicate (kaolin)] and metal oxides (chromium, iron, manganese, titanium and zinc oxides) organic color pigments are also used.
- silicates magnesium silicate (talc), aluminum silicate (kaolin)
- metal oxides chromium, iron, manganese, titanium and zinc oxides
- organic color pigments are also used.
- Stearic acid esters, lanolin alcohol and acetate are used as binding agents.
- Waxes such as beeswax or carnauba wax and oils such as paraffin oils, silicone oils or castor oil are used in many formulations.
- decorative cosmetics can contain preservatives, antioxidants, thickeners and other additives.
- Cleaning wipes have proven to be well suited for this purpose because the wiping motion of the wipes supports the cleaning effect of the surface-active substances and/or oils contained in the impregnating agent.
- DE 10157543 discloses emulsion-impregnated wipes, the emulsion containing chitosan and/or lecithin. This allows the content of emulsifiers and preservatives to be reduced.
- the document EP 1496853 describes cleaning wipes which are impregnated with an impregnating agent which contains starch-containing compounds.
- the incorporation of these starch-containing compounds leads to a particularly pleasant, smooth, velvety feeling on the skin.
- EP 1405632 discloses the incorporation of zinc oxide particles of a specific size into the impregnating agent and the possibility of applying this impregnating agent to the cloths.
- the document DE 102012200383 discloses cleaning cloths which have a rough surface. This leads to a peeling effect. In order to be able to control the strength of the peeling effect, different amounts of the impregnating agent are applied.
- Document DE 202004007851 describes colored cleaning cloths and impregnating agents. The dyes and impregnating agents used are selected in such a way that the color remains on the cloth and does not transfer into the impregnating agent.
- compositions containing lipids for impregnating wipes are described in document
- WO 2005/044220 A1 discloses.
- the effect of these impregnating agents is that cleaning articles impregnated with these agents have not only high cleaning power but also high refatting power.
- Classic cleaning cloths can therefore be impregnated with impregnating agents that dispense with the incorporation of “classic” surfactants, such as alkyl ether sulfates, which are generally used in liquid cleaning preparations. This can lead to reduced cleaning performance.
- Cleaning wipes containing oil are often used to remove waterproof make-up preparations. These cleaning cloths containing oil have the disadvantage that oils can get into the eye due to their varying degrees of spreading ability. This leads to reduced tolerability of these products.
- an oily residue often remains on the skin, which many users find unpleasant.
- the StdT also discloses cleaning wipes which have good cleaning performance and are well tolerated.
- the document DE 102015212822 A1 is mentioned as an example.
- the soaking agent has micelles.
- DE 102015212822 A1 is characterized in that it contains a mixture of different surfactants, anionic surfactants in the form of sodium acylglutamates, nonionic surfactants in the form of block polymers and alkyl polyglycosides.
- Cleansing wipes are intended to be used for cleaning, preferably for cleaning human skin and hair.
- dirt that has gotten onto the skin from the outside, dead cells and excess sebum must be removed.
- the dirt that has got onto the skin from the outside also includes make-up that has to be removed again.
- silicone compounds are a wish that is often expressed by consumers.
- microplastics are very important for consumers. However, there is no generally binding definition of what is meant by microplastics.
- the United Nations Environmental Program (UNEP) defines microplastics as solid, particulate materials below 5 nm in size that are not water-soluble, non-degradable and consist of plastic.
- UDP Environmental Program
- This group also includes, for example, representatives of polymers that are based on acrylate and also do not have good biodegradability.
- the ingredients of the saturant and the wipe material are as biodegradable as possible.
- cleaning wipes are to be provided which take account of the consumer's desire for increased compatibility and improved biodegradability, in particular with regard to the wipe material. Nevertheless, the cleaning performance should correspond to that of conventional cloths.
- a cleaning agent consisting of a cloth and an impregnating agent.
- the cloth is characterized by being made of fibers of natural origin and biodegradable.
- the impregnation agent is characterized in that it is in the form of an O/W emulsion, is free of silicones, parabens and acrylate-based polymers and
- Phenoxyethanol at least two substances that simultaneously have a caring effect and support preservation and contain at least one O/W emulsifier.
- This cleaning agent is preferably used on the human body, it is preferably a cosmetic cleaning agent.
- the cleaning agents should also be suitable in particular for cleaning the skin of the face and there in particular for the sensitive area around the eyes.
- the impregnating agent contains water.
- the water content is advantageously 80 to 99% by weight, particularly advantageously 85 to 95% by weight, based on the total weight of the impregnating agent.
- Phenoxyethanol is particularly effective in acidic and neutral environments, but also in alkaline environments and is completely non-toxic. Adequate preservation of cosmetic products can already be achieved by using low concentrations. Because of its neutral taste, phenoxyethanol quickly found its way into the pharmaceutical and cosmetics industries. Its action is directed against Gram-positive and Gram-negative bacteria such as Escherichia coli, Pseudomonas aeruginosa, Proteus mirabilis, Staphylococcus aureus, and against yeasts such as Candida albicans and other microorganisms. Phenoxyethanol is a viscous liquid with a faint, slightly pleasant odor and an astringent taste. It has been found in nature in tropical fruits, in Cichorium endivia and in green tea (Camellia sinesis). It has a mild, rose-like flavor
- Fragrance and is also used as a fixative for perfume compositions. It is miscible with acetone, ethyl alcohol and glycerin, soluble in and fats, e.g. olive and peanut oil, but slightly soluble in water.
- the impregnating agent according to the invention contains phenoxyethanol in a content of 0.5 to 0.95% by weight, preferably 0.6 to 0.9% by weight, based on the total weight of the impregnating agent.
- the impregnating agent according to the invention contains at least two substances which at the same time have a caring effect and support the preservation. These substances are not included in the list of permitted preservatives (Cosmetics Ordinance Annex 6; Regulation (EC) No. 1223/2009, Annex V), but they have a stabilizing effect on the respective cosmetic preparations and, when used together with preservatives, they promote it the stability of the respective preparations. This phenomenon can thus be described as preservation-supportive.
- Such substances can be selected from the group consisting of propylene glycol, ethylhexylglycerol, 1,2-hexanediol, methylpropanediol, butylene glycol, caprylyl glycol, decylene glycol, hydroxyacetophenone and/or pentylene glycol.
- the impregnating agent according to the invention contains the at least two substances, which simultaneously have a caring effect and support the preservation, with a total content of 0.15 to 3.0% by weight, preferably 0.35 to 2.0% by weight, based on the total weight of the soaking agent.
- Combinations of phenoxyethanol and at least two substances selected from ethylhexylglycerol, hydroxyacetophenone and decylene glycol are preferred, and the combination of phenoxyethanol, ethylhexylglycerol and decylene glycol is more preferred.
- the impregnating agent according to the invention can contain perfume.
- the perfume used is advantageously a mixture of perfume raw materials.
- the perfume is mainly included to give a pleasant smell to the impregnation agent and also to the whole product after the impregnation process. Furthermore, it is also known from selected perfume raw materials that they can develop an antimicrobial effect or can also support the effect of conventional preservatives.
- perfume is contained in the impregnating agent according to the invention, the perfume is present in a content of 0.05 to 1.0% by weight, in particular 0.14 to 0.4% by weight, based on the total weight of the impregnating agent.
- the impregnating agents according to the invention are free from parabens.
- the cleaning cloth, the cosmetic product consisting of the impregnating agent and cloth, and the packaging unit for the cleaning cloth are also free of parabens.
- R denotes an alkyl side chain which can consist of a straight or branched chain of 1 to 5 carbon atoms or of aromatic radicals.
- Known parabens are methyl, ethyl, propyl, butylparaben, as well as isopropyl, isobutyl, pentyl, and phenylparaben.
- Benzylparaben is not permitted as a preservative in cosmetic products.
- the preparations according to the invention are free from parabens.
- free from parabens means that no parabens are added to the preparations and no parabens are introduced via preserved ingredients. This is equivalent to saying that the preparations according to the invention do not contain any parabens.
- free from means that less than 0.001% by weight, preferably less than 0.0001% by weight, particularly preferably 0% by weight, of the respective substances, based on the total weight of the preparation, are present.
- the impregnating agent is in the form of an O/W emulsion.
- Emulsions are generally understood as meaning heterogeneous systems which consist of two liquids which are immiscible or only partially miscible with one another and which are usually referred to as phases.
- one of the two liquids is dispersed in the other liquid in the form of very fine droplets.
- the liquids pure or as solutions
- the two liquids are water and oil and oil droplets are finely distributed in the water, then it is an oil-in-water emulsion (O/W emulsion, e.g. milk).
- O/W emulsion oil-in-water emulsion
- the basic character of an O/W emulsion for example electrical conductivity, sensory properties, dyeability of the continuous phase, is shaped by the water.
- a water-in-oil emulsion (W/O emulsion, eg butter) is the reverse of the principle, with the basic character being determined by the oil.
- emulsions For their formation and for stabilization, emulsions generally require one or more emulsifiers, optionally also thickeners and/or consistency factors, in order to be stable over a cosmetically acceptable period of time.
- Emulsifiers ensure that two immiscible liquids (e.g. oil in water) can be mixed into an emulsion. Due to their amphiphilic character, they penetrate the oil with their fat-soluble part. The hydrophilic part allows the oil droplets formed by stirring or homogenization to be dispersed in the aqueous environment. Emulsifiers primarily have no washing-active, surface-active character.
- Emulsifiers reduce the interfacial tension between the two phases and, in addition to reducing the interfacial work, also stabilize the emulsion formed. They stabilize the emulsion formed by interfacial films and by forming steric or electrical barriers, which prevents the emulsified particles from flowing together (coalescence).
- a structural feature of such compounds is their amphiphilic molecular structure.
- the molecule of such a compound has at least one group with affinity for substances of strong polarity (polar group) and at least one group with affinity for non-polar substances (apolar group).
- polar group substances of strong polarity
- apolar group non-polar substance
- HLB value HLB value
- HLB 20 ⁇ (1-Miipophii/M), where Miipophii stands for the molar mass of the lipophilic portion in the emulsifier and M for the molar mass of the emulsifier as a whole.
- emulsifiers with an HLB value of up to approx. 8 are W/O emulsifiers.
- O/W emulsifiers have HLB values of more than 8 to about 15. Substances with HLB values greater than 15 are often referred to as solubilizers.
- hydrophilic emulsifiers are advantageously selected, ie those which have an HLB value of >10.
- the emulsifiers polyglyceryl-3-methylglucose distearate and/or glyceryl stearate citrate are also advantageously selected.
- the emulsifiers mentioned can be obtained under the trade name Tego Care 450 from Evonik (polyglyceryl-3-methylglucose distearate) and Imwitor 370 from Hüls (glyceryl stearate citrate).
- the impregnating agent according to the invention contains at least one emulsifier with a total content of 0.15 to 1.0% by weight, preferably 0.3 to 0.65% by weight, based on the total weight of the impregnating agent.
- At least one substance with a thickening effect can advantageously also be present.
- Thickeners are understood to mean macromolecules which have a largely linear, partly also crosslinked structure and have intermolecular interaction forces which enable secondary and main valence bonds between the individual molecules and thus the formation of a network-like structure.
- These can be partially water-soluble or water-swellable natural polymers or polymers based on natural starting polymers that form gels or viscous solutions in aqueous systems. They increase the viscosity of the water either by binding water molecules (hydration) or by absorbing and enveloping the water in their intertwined macromolecules, while at the same time restricting the mobility of the water.
- a prerequisite for solubility or swellability in water or aqueous media is that these polymers have a sufficient number of hydrophilic groups and are not excessively crosslinked.
- the hydrophilic groups can be nonionic, anionic or cationic in nature.
- the group of polymeric thickeners which are often used in cosmetics, but also in dermatology, includes natural polymers or polymers based on natural polymers:
- organic, natural polymers such as carrageenan, xanthan gum, tragacanth, alginates, pectins, polyoses, locust bean gum, starch and derivatives of starch, microcrystalline cellulose, dextrins, • organic, modified natural substances, such as. B. carboxymethyl cellulose and other cellulose ethers, hydroxyethyl and hydroxypropyl cellulose and the like,
- inorganic compounds such as. B. polysilicic acids, clay minerals such as montmorillonites, zeolites, silicic acids.
- the at least one thickening substance is particularly advantageously selected from the group consisting of xanthan gum, carrageenan, cellulose ether, sclerotium gum, -dehydroxanthan gum, succinoglycan gum, hydroxypropyl starch phosphate, cellulose gum, microcrystalline cellulose and/or alginates.
- the at least one thickening substance has a total content of 0.01 to 2.0% by weight, preferably 0.05 to 1.5% by weight, particularly preferably 0.1 to 1.0% by weight % contained, based on the total weight of the impregnating agent.
- the impregnating agent according to the invention is free from acrylate-based polymers.
- acrylate-based polymers are polymers which contain (meth)acrylic acid and derivatives of these acids as monomer building blocks.
- Derivatives are structural analogues in the form of esters, ethers, amides, hydroxyl compounds and/or salts.
- the impregnating agent according to the invention in the form of an O/W emulsion contains an oil phase.
- This oil phase contains at least one lipophilic component which can be selected from the group of oils, the term oils often being understood to mean liquids which cannot be mixed with water and which evaporate with more difficulty than water. Their chemical composition is very different. Oils can be divided into the following groups: fatty oils, essential oils, mineral oils and silicone oils. Of the oils mentioned, silicone oils are not included in the present invention.
- fatty oils is usually understood to mean fatty acid triglycerides that are liquid at room temperature. These include fatty acid triglycerides, ie triglycerol esters of saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acids with a chain length of 8 to 24, in particular 12 to 18, carbon atoms.
- the fatty acid triglycerides can, for example, be chosen advantageously from the group of synthetic, semi-synthetic and natural oils, such as. B.
- cocoglyceride olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grape seed oil, safflower oil, evening primrose oil, macadamia nut oil and the like more.
- the impregnating agent according to the invention can contain at least one further lipophilic component, advantageously selected from the group of polar oils, which in turn are selected from monoesters of saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acids with a chain length of 3 to 30 C -Atoms and saturated and/or unsaturated, branched and/or unbranched alcohols with a chain length of 3 to 30 carbon atoms and/or from the group of esters of aromatic carboxylic acids and saturated and/or unsaturated, branched and/or unbranched alcohols with a chain length from 3 to 30 carbon atoms.
- polar oils advantageously selected from the group of polar oils, which in turn are selected from monoesters of saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acids with a chain length of 3 to 30 C -Atoms and saturated and/or unsaturated, branched and/or unbranched alcohols with
- ester oils can then advantageously be selected from the group consisting of 2-ethylhexyl benzoate, 2-ethylhexyl hydroxystearate benzoate, 2-ethylhexyl laurate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, 2-hexyldecyl stearate, 2-octyldodecyl palmitate, butyloctyl salicylate, C12- 15 Alkyl Benzoate, Castor Oil Benzoate, Cetearyl Isononanoate, Coco Caprylate/Caprate, Decyl Oleate, Diethylhexyl Adipate, Dipropylene Glycol Dibenzoate, Ethylhexyl Cocoate, Glyceryl Caprate, Glyceryl Isostearate, Isononyl Isononanoate, Isononyl Stearate, Isooctyl Stearate
- the lipophilic component can be advantageously selected on the other hand from the group of dialkyl ethers and dialkyl carbonates.
- a combination of at least one vegetable oil and at least one ester oil is contained, more particularly preferably of a vegetable oil and an ester oil, for example isopropyl stearate and almond oil.
- the at least one lipophilic component is advantageously present in the impregnating agent according to the invention with a total content of 0.01 to 10.0% by weight, preferably 0.01 to 8.0% by weight, based on the total weight of the impregnating agent.
- Substances or mixtures of substances are understood to be further humectants which give cosmetic preparations the property of positively influencing and/or regulating the moisture content of the skin, in particular of the epidermis, after application or distribution on the skin.
- Other advantageous humectants within the meaning of the present invention are, for example, glycerin, lactic acid, urea, aloe barbadensis (INCI: Aloe Barbadensis Leaf Juice) and/or sorbitol, in particular glycerin.
- the total content of the at least one humectant is 0.005 to 10% by weight, preferably 0.01 to 5.0% by weight, based on the total weight of the impregnating agent.
- the impregnating agent according to the invention additionally contains at least one cosmetic active ingredient selected from the group of vitamins, plant extracts and/or individual active ingredients.
- the impregnation agent can additionally contain cosmetic auxiliaries such as are usually used in such agents, e.g. complexing agents and dyes, antioxidants and substances to adjust the pH.
- cosmetic auxiliaries such as are usually used in such agents, e.g. complexing agents and dyes, antioxidants and substances to adjust the pH.
- the impregnating agents according to the invention are free from silicones.
- the cleaning cloth, the cosmetic product consisting of the impregnating agent and cloth, and the packaging unit for the cleaning cloth are also free of silicone.
- Silicone compounds are characterized by the presence of silicon and oxygen atoms, which are linked to one another and can form a large number of different compounds.
- the term "free from” means that less than 0.001% by weight, preferably less than 0.0001% by weight, particularly preferably e% by weight of the respective substance(s), based on the total weight of the impregnating agent.
- the cloth material used for the cleaning cloths is characterized in that it consists of fibers that are of natural origin and biodegradable.
- the cloths mentioned can be smooth or surface-structured. Smooth cloths are preferred according to the invention.
- “dry” towels are preferably used in combination with the impregnating agents according to the invention, which are made of fleece, in particular of water-jet-bonded and/or water-jet-embossed fleece.
- Such webs can have macro embossing of any desired pattern.
- the selection to be made depends on the one hand on the impregnation to be applied and on the other hand on the field of application in which the cloth is later to be used.
- the cloth has a weight of 30 to 120 g/m 2 , preferably 35 to 80 g/m 2 , particularly preferably 40 to 65 g/m 2 (measured at 20°C ⁇ 2 °C and at a room humidity of 65% ⁇ 5% for 24 hours).
- a natural-based fibrous material is selected as the starting material for the non-woven fabric of the cloth.
- Examples include viscose, cotton, cellulose, jute, hemp, sisal, silk, and wool.
- the fibers consist of 100% viscose with different fineness.
- the fineness of the fibers is 1.0 dTex to 2.0 dTex, preferably 1.2 dTex to 1.8 dTex.
- Such cloths are available, for example, from Jacob Holm under the designation 10.040.007 or from Spuntech under the designation 13P46V100.
- Fibers made of viscose, lyocel, polylactic acid and cotton in different compositions are also advantageous, which are offered by the Lenzing company under the names LENZING TM Lyocell and LENZING TM Viscose or by the Suominen company under the names Biolace and Fibrella.
- the cleaning product according to the invention ie the cloth (biodegradable, non-woven, using the example of Jacob Holm cloth under the designation 10.040.007) impregnated with the impregnating agent according to Example 1, the biodegradability according to OECD Guideline 301 B was demonstrated.
- the biodegradability of a composition for example the impregnating agent, data from the OECD or equivalent methods for classifying the ingredients are used.
- the percentage of biodegradable ingredients in a composition is calculated by dividing the weight of biodegradable organic ingredients by the total weight of organic ingredients. Values such as XX% biodegradable composition result.
- a biodegradability of 99% was calculated for the impregnating agent according to example recipe D8.
- biodegradability describes the process of degradation of organic compounds by living beings, especially saprobionts. Ideally, inorganic substances such as CO2, O2 and ammonia are formed; Compounds that are used by plants and microorganisms to build organic compounds.
- OECD 301 Organic, chemical compounds that are easily biodegradable are classified according to OECD 301, for cosmetic compositions mostly according to OECD 301 B. These substances or compositions can be rapidly and completely degraded.
- the fibers can also be colored in order to be able to emphasize and/or increase the optical attractiveness of the fleece.
- the fibers can also contain UV stabilizers and/or preservatives.
- the weight ratio of the unimpregnated cloth to the impregnating agent is advantageously 1:1 to 1:5, particularly advantageously 1:1.5 to 1:4.5, particularly advantageously 2.0:3.5.
- the cleaning product consisting of the cloth according to the invention and the impregnating agent according to the invention, is advantageously offered in packaging which consists of 30%, preferably 45%, recycled plastic material.
- the packaging material also advantageously consists of a polyester and polyethylene composite.
- the cleaning performance and also the mildness of a cleaning agent according to the invention were tested in a PIU (Product In Use Test). Both with regard to the cleaning performance and the mildness of the cleaning agent according to the invention, it was confirmed that they are on the same level as the cleaning performance and mildness of a cleaning cloth consisting of a paraben-containing impregnation medium and a non-biodegradable fleece.
- test participants were users of waterproof makeup products, including waterproof mascara.
- the impregnating agents according to D2 and D8 have the following composition, the information is given in % by weight and relates to the active content: for adjusting the pH value, pH value range 5.0-6.0
- cleaning agent D2 the cloth consists of a mixture of 60% polyester and 40% viscose fibres
- cleaning agent D7 the cloth consists of 100% viscose fibres.
- D8 represents a cleaning product according to the invention.
- the results show that the cleaning product according to the invention is rated better than a conventional product in terms of thorough cleaning.
- the removal of waterproof make-up, the care of the skin and the suitability for sensitive skin are rated a little less well compared to the conventional product.
- the cleaning performance of the product according to the invention is almost as good or better than that of the conventional product.
- a tolerability test was carried out at the same time under the observation of a general practitioner and an ophthalmologist. 34 of the participants in the product-in-use test described above also took part in the tolerability test.
- the cleaning agent (D8) according to the invention very good skin acceptance for the face, the area around the eyes and lips and very good eye compatibility were attested.
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102020212222.9A DE102020212222A1 (de) | 2020-09-29 | 2020-09-29 | Reinigungstücher getränkt mit Tränkungsmitteln basierend auf einer Öl-in-Wasser-Emulsion |
PCT/EP2021/073765 WO2022069124A1 (de) | 2020-09-29 | 2021-08-27 | Reinigungstücher getränkt mit tränkungsmitteln basierend auf einer öl-in-wasser-emulsion |
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EP4221662A1 true EP4221662A1 (de) | 2023-08-09 |
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EP21763388.2A Pending EP4221662A1 (de) | 2020-09-29 | 2021-08-27 | Reinigungstücher getränkt mit tränkungsmitteln basierend auf einer öl-in-wasser-emulsion |
Country Status (4)
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EP (1) | EP4221662A1 (de) |
BR (1) | BR112023005763A2 (de) |
DE (1) | DE102020212222A1 (de) |
WO (1) | WO2022069124A1 (de) |
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DE10157543A1 (de) | 2001-11-23 | 2003-06-12 | Beiersdorf Ag | Emulsionsgetränkte Tücher |
DE10216511A1 (de) | 2002-04-11 | 2003-10-23 | Beiersdorf Ag | Stärkehaltige kosmetische Tücher |
DE10219638B4 (de) | 2002-05-02 | 2005-05-04 | Beiersdorf Ag | Hautreinigungstuch |
DE10246160A1 (de) | 2002-10-02 | 2004-04-15 | Beiersdorf Ag | Mit Befeuchtungsmitteln getränkte Tücher, welche Zinkoxid einer Partikelgröße von 20 bis 100 mm enthalten |
DE10352370A1 (de) | 2003-11-10 | 2005-06-23 | Beiersdorf Ag | Lipidhaltiges Substrat |
DE202004007851U1 (de) | 2004-05-13 | 2004-08-05 | Beiersdorf Ag | Kosmetisch oder dermatologisch getränktes Tuch |
DE102012200383A1 (de) | 2012-01-12 | 2013-07-18 | Beiersdorf Ag | Hautreinigungstuch mit einstellbaren Peelingeigenschaften |
DE102015212822A1 (de) | 2015-07-09 | 2017-01-12 | Beiersdorf Ag | Reinigungstücher getränkt mit Tränkungsmitteln basierend auf einer Mizellentechnologie |
DE102017209649A1 (de) * | 2017-06-08 | 2018-12-13 | Beiersdorf Ag | Alkandiole in salzhaltigen kosmetischen Zubereitungen |
DE102018220913A1 (de) * | 2018-12-04 | 2020-06-04 | Beiersdorf Ag | O/W-Emulsion mit Rhamnolipiden |
-
2020
- 2020-09-29 DE DE102020212222.9A patent/DE102020212222A1/de active Pending
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2021
- 2021-08-27 EP EP21763388.2A patent/EP4221662A1/de active Pending
- 2021-08-27 BR BR112023005763A patent/BR112023005763A2/pt unknown
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BR112023005763A2 (pt) | 2023-04-25 |
WO2022069124A1 (de) | 2022-04-07 |
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