EP4177604A1 - Verfahren und system zur bestimmung der qualität eines geschlossenzelligen schaums in bezug auf wärmedämmung - Google Patents
Verfahren und system zur bestimmung der qualität eines geschlossenzelligen schaums in bezug auf wärmedämmung Download PDFInfo
- Publication number
- EP4177604A1 EP4177604A1 EP21207259.9A EP21207259A EP4177604A1 EP 4177604 A1 EP4177604 A1 EP 4177604A1 EP 21207259 A EP21207259 A EP 21207259A EP 4177604 A1 EP4177604 A1 EP 4177604A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sensor
- foam
- value
- carbon dioxide
- dioxide concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 238000000034 method Methods 0.000 title claims abstract description 52
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- 238000005259 measurement Methods 0.000 claims abstract description 84
- 238000012545 processing Methods 0.000 claims abstract description 23
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 102
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 67
- 239000001569 carbon dioxide Substances 0.000 claims description 27
- 238000010438 heat treatment Methods 0.000 claims description 15
- 238000000691 measurement method Methods 0.000 claims description 8
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- 238000004364 calculation method Methods 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims description 6
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 3
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- 239000000428 dust Substances 0.000 claims description 3
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- 239000007789 gas Substances 0.000 description 21
- 239000003570 air Substances 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 12
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- 239000000203 mixture Substances 0.000 description 11
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 10
- 238000010586 diagram Methods 0.000 description 8
- 239000010410 layer Substances 0.000 description 7
- 239000003822 epoxy resin Substances 0.000 description 6
- 229920000647 polyepoxide Polymers 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 5
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 5
- 229920005862 polyol Polymers 0.000 description 5
- 150000003077 polyols Chemical class 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 239000004604 Blowing Agent Substances 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
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- 229910052799 carbon Inorganic materials 0.000 description 2
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- 230000007797 corrosion Effects 0.000 description 2
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- 238000001514 detection method Methods 0.000 description 2
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- -1 hydro fluoro olefins Chemical class 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- PGYPOBZJRVSMDS-UHFFFAOYSA-N loperamide hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(C=1C=CC=CC=1)(C(=O)N(C)C)CCN(CC1)CCC1(O)C1=CC=C(Cl)C=C1 PGYPOBZJRVSMDS-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
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- 229920005989 resin Polymers 0.000 description 2
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- 206010016334 Feeling hot Diseases 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
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- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000001303 quality assessment method Methods 0.000 description 1
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Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/44—Resins; Plastics; Rubber; Leather
- G01N33/445—Rubber
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N25/00—Investigating or analyzing materials by the use of thermal means
- G01N25/18—Investigating or analyzing materials by the use of thermal means by investigating thermal conductivity
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
- G01N33/004—CO or CO2
Definitions
- the invention relates to a method for determining the quality of a closed cell foam with respect to its thermal insulation, a system for carrying out the method and a thermally insulated pipe according to the independent claims.
- the invention can also be used for the detection of a leakage which might occur over time.
- the insulating foam is surrounded by a polyethylene jacket.
- a change in the ⁇ -value of the cell gas mixture can indicate such a damage afterwards and the respective pipe can be replaced.
- the sensor according to the invention may be identical for both parameters.
- An example for such a sensor by means of which both parameters are obtainable is given below. Therefore, in instances where multiple sensors are used, which will be described in the course of the following text, it is conceivable to use multiple sensors of which one or more may be used for obtaining one of said parameters and the other sensor(s) are used for obtaining the other parameter.
- the characteristic parameter is not limited to the two enumerated parameters. For example, humidity may be another valid parameter for the purposes of the invention.
- the sensing element is encapsulated in a diffusion-open casing.
- this allows gas to be analyzed to access the sensing element but at the same time protects the sensing element from contamination with solid particles like foam particles produced during the insertion of the sensor into the foam or with dust.
- the transient hot wire measurement method is used to measure the thermal conductivity by measuring a temperature gradient at a certain distance from a heated element.
- a description of this method can be found at https://www.tec-science.com/thermodynamics/heat/transient-hot-wire-method-method-for-determining-thermal-conductivity-thw.
- the advantage is that the measurements are fast as compared to other methods.
- the transient line source method is used to measure the thermal conductivity by measuring a temperature gradient, where a suitable sensor and a heated element are arranged in a same rod.
- a description of this method can be found at https://thermtest.com/tls-100.
- An advantage of this method is the small size of the sensor arrangement as compared to other methods, while yielding a measurement result within ca. 1 min.
- replacement value is understood in general as a value used for the quality assessment which was not directly measured but derived from a directly measured value.
- the heat conductivity starts at the level of about 26 mW/m*K because of the outside air introduced into the hole during insertion of the sensor package.
- the heat conductivity drops over time, as does the relative humidity.
- the apparent CO 2 -concentration is increasing.
- the explanation for that is as follows:
- the sensor STC31 is commercially available and used for the detection of the CO 2 concentration in air. Air has a ⁇ -value of 26 mW/m*K, CO 2 has a ⁇ -value of 16 mW/m*K.
- a decreasing heat conductivity is interpreted as an increasing CO 2 concentration because only CO 2 with its low heat conductivity can explain that outcome within the logical framework of the algorithm.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials Using Thermal Means (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP21207259.9A EP4177604A1 (de) | 2021-11-09 | 2021-11-09 | Verfahren und system zur bestimmung der qualität eines geschlossenzelligen schaums in bezug auf wärmedämmung |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP21207259.9A EP4177604A1 (de) | 2021-11-09 | 2021-11-09 | Verfahren und system zur bestimmung der qualität eines geschlossenzelligen schaums in bezug auf wärmedämmung |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4177604A1 true EP4177604A1 (de) | 2023-05-10 |
Family
ID=78820881
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP21207259.9A Pending EP4177604A1 (de) | 2021-11-09 | 2021-11-09 | Verfahren und system zur bestimmung der qualität eines geschlossenzelligen schaums in bezug auf wärmedämmung |
Country Status (1)
Country | Link |
---|---|
EP (1) | EP4177604A1 (de) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2091880A (en) * | 1981-01-22 | 1982-08-04 | Insapipe Ind Ltd | Water penetration sensor for thermally insulated conduits |
US20070235440A1 (en) * | 2006-04-05 | 2007-10-11 | Youfan Gu | Multiple heater control system with expandable modular functionality |
US20090115433A1 (en) * | 2005-07-13 | 2009-05-07 | Gunther Bier | Method for Locating Leaks In Pipes |
JP2009281908A (ja) * | 2008-05-23 | 2009-12-03 | Panasonic Corp | 熱物性測定装置 |
US20130085708A1 (en) * | 2011-09-30 | 2013-04-04 | Drager Medical Gmbh | Device and process for determining the body core temperature |
US20190234903A1 (en) * | 2018-02-01 | 2019-08-01 | Ppg Industries Ohio, Inc. | Complex impedance moisture sensor and sensing method |
KR102287882B1 (ko) * | 2020-02-26 | 2021-08-09 | 부산대학교 산학협력단 | 극저온 유체 단열 저장 시스템의 성능시험 장치 및 방법 |
-
2021
- 2021-11-09 EP EP21207259.9A patent/EP4177604A1/de active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2091880A (en) * | 1981-01-22 | 1982-08-04 | Insapipe Ind Ltd | Water penetration sensor for thermally insulated conduits |
US20090115433A1 (en) * | 2005-07-13 | 2009-05-07 | Gunther Bier | Method for Locating Leaks In Pipes |
US20070235440A1 (en) * | 2006-04-05 | 2007-10-11 | Youfan Gu | Multiple heater control system with expandable modular functionality |
JP2009281908A (ja) * | 2008-05-23 | 2009-12-03 | Panasonic Corp | 熱物性測定装置 |
US20130085708A1 (en) * | 2011-09-30 | 2013-04-04 | Drager Medical Gmbh | Device and process for determining the body core temperature |
US20190234903A1 (en) * | 2018-02-01 | 2019-08-01 | Ppg Industries Ohio, Inc. | Complex impedance moisture sensor and sensing method |
KR102287882B1 (ko) * | 2020-02-26 | 2021-08-09 | 부산대학교 산학협력단 | 극저온 유체 단열 저장 시스템의 성능시험 장치 및 방법 |
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