EP4154970A1 - Emulsifier and emulsion composition containing same - Google Patents

Emulsifier and emulsion composition containing same Download PDF

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Publication number
EP4154970A1
EP4154970A1 EP21809241.9A EP21809241A EP4154970A1 EP 4154970 A1 EP4154970 A1 EP 4154970A1 EP 21809241 A EP21809241 A EP 21809241A EP 4154970 A1 EP4154970 A1 EP 4154970A1
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EP
European Patent Office
Prior art keywords
group
formula
represented
carbon atoms
general formula
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EP21809241.9A
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German (de)
French (fr)
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EP4154970A4 (en
Inventor
Taro Imai
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Shin Etsu Chemical Co Ltd
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Shin Etsu Chemical Co Ltd
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Publication of EP4154970A1 publication Critical patent/EP4154970A1/en
Publication of EP4154970A4 publication Critical patent/EP4154970A4/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/54—Silicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/893—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/068—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/10—General cosmetic use
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

Definitions

  • the present invention relates to an emulsifier exhibiting a high preservation stability and having an excellent emulsifying capability in a wide range of emulsification compositions, particularly to a (meth)acryl silicone-based diblock copolymer.
  • silicone oils are often used as oil agents; however, as for a water-in-oil type emulsion composition containing such silicone oil, it has been difficult to obtain an emulsion superior in stability even when using an emulsifier such as a polyoxyalkylene fatty acid ester-based emulsifier that has been conventionally used.
  • emulsifier used as a surfactant (emulsifier) is a polyoxyalkylene-modified organopolysiloxane (polyether-modified silicone) having a favorable compatibility to a silicone oil (e.g. Patent documents 1 to 5).
  • a large amount of a thickener or a gelator will actually lead to a loss of wateriness, and thereby contribute to a sticky texture. Further, there has been a downside where a poor extensibility is observed when applied to the skin, which leads to an insufficient smooth texture. Thus, desired is an emulsifier allowing there to be stably contained a large amount of water without adding a thickener or a gelator.
  • an emulsifier exhibiting a high preservation stability and having an excellent emulsifying capability in a wide range of emulsification compositions, particularly an emulsifier suitable for producing a water-in-oil type emulsion composition capable of containing a large amount of a water phase component. Further, it is also an object of the present invention to provide an emulsion composition using such emulsifier.
  • the inventor of the present invention diligently conducted a series of studies to achieve the above object, and completed the invention as follows. That is, the inventors found that the aforementioned problems can be solved by a diblock copolymer having, as its structural components, a hydrophobic silicone graft copolymer block, and a polar copolymer block having a particular polar group(s) serving as a functional group.
  • the present invention is to provide an emulsifier comprised of the following diblock copolymer.
  • the emulsifier comprised of the diblock copolymer of the present invention has, as its structural components, a hydrophobic silicone graft copolymer block (segment [I]), and a polar copolymer block having a particular polar group(s) serving as a functional group (segment [II]).
  • a hydrophobic silicone graft copolymer block (segment [I])
  • a polar copolymer block having a particular polar group(s) serving as a functional group (segment [II]).
  • (meth)acryl used in this specification refers to methacryl and acryl.
  • (meth)acrylate used in this specification refers to methacrylic acid ester and acrylic acid ester.
  • a diblock copolymer of the present invention as an emulsifier has, in its main chain, a silicone graft copolymer block unit represented by the following formula [I] (segment [I]) and a polar copolymer block unit represented by the following formula [II] (segment [II]), where one end structure of the main chain is a structure represented by the following formula [III], and the other end structure of the main chain is a structure represented by the following formula [IV].
  • R 1 represents a hydrogen atom or a methyl group.
  • A represents an organopolysiloxane-containing group represented by the following general formula (1), or an organopolysiloxane-containing group represented by the following general formula (2).
  • n 1 represents a number of the repeating units; n 1 is 1 to 50, preferably 1 to 20, more preferably 3 to 10.
  • the organopolysiloxane-containing group represented by the general formula (1) is a group having a linear organopolysiloxane structure where a repeating unit number m of a diorganosiloxy group is 0 to 100.
  • Z represents a divalent organic group, preferably a saturated hydrocarbon group having 2 to 12 carbon atoms, more preferably a propylene group.
  • Each R 2 independently represents a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group, preferably a saturated hydrocarbon group having 1 to 5 carbon atoms, more preferably a methyl group.
  • R 3 represents a saturated hydrocarbon group having 1 to 10 carbon atoms, preferably a saturated hydrocarbon group having 1 to 5 carbon atoms, more preferably a methyl group.
  • m is a number of 0 to 100, preferably a number of 1 to 60, more preferably a number of 5 to 30.
  • the organopolysiloxane-containing group represented by the general formula (2) is a group having a dendritically branched structure(s), where the number of such branched structures (hierarchical number c) is an integer of 1 to 10, preferably an integer of 1 to 6, more preferably an integer of 1 to 4. [Chemical formula 10] -O-L i (2)
  • i represents a number of each hierarchy of the dendritic structure, and is each integer from 1 to c.
  • L' is a silylorgano group represented by the general formula (3), and a hierarchy i in the general formula (2) is 1.
  • Z represents a divalent organic group, preferably a saturated hydrocarbon group having 2 to 12 carbon atoms, more preferably a propylene group.
  • R 4 represents a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group, preferably a saturated hydrocarbon group having 1 to 5 carbon atoms, more preferably a methyl group.
  • Each R 5 independently represents an alkyl group having 1 to 8 carbon atoms or a phenyl group, preferably an alkyl group having 1 to 3 carbon atoms, more preferably a methyl group.
  • Z, R 4 and R 5 are each identical to those described above, and each of a 1 , a 2 and a 3 is a number of 0 to 3.
  • R 1 represents a hydrogen atom or a methyl group.
  • B is any group selected from -OB', -NH 2 and -OH (B' represents a monovalent hydrocarbon group that has 1 to 20 carbon atoms, and has at least one kind of divalent group selected from a polyoxyalkylene group having 1 to 20 carbon atoms, -C(O)-, -O-, -S- and -NR- (R represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 20 carbon atoms)), and is preferably a group represented by a general formula (8') or (9').
  • n 2 represents a number of the repeating units; n 2 is 1 to 50, preferably 1 to 20, more preferably 3 to 10.
  • each R 7 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.
  • R 3 represents a saturated hydrocarbon group having 1 to 10 carbon atoms, n 3 represents a number of the repeating units, provided that 1 ⁇ n 3 ⁇ 10.
  • R 6 represents an alkyl group having 1 to 4 carbon atoms, preferably a methyl group.
  • R 7 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, preferably a methyl group.
  • R 1 represents a hydrogen atom or a methyl group.
  • X represents the group represented by A in the formula [I] or the group represented by B in the formula [II].
  • Each of the segments [I] and [II] may be composed of at least one kind of unit expressed by the formula [I] or at least one kind of unit expressed by the formula [II], or be composed of multiple kinds of units expressed by the formula [1] or multiple kinds of units expressed by the formula [II]. Further, the segments [I] and [II] that are sandwiched between the end structures [III] and [IV] are in a random order.
  • a diblock copolymer refers to a copolymer linking the segment [I] and the segment [II] as two segments having different physical properties such as polarity, water solubility, and presence or absence of affinity for powder. That is, the diblock copolymer of the present invention is a copolymer linking together the segments [I] and [II] of which the segment [I] is composed of consecutive units expressed by the formula [I], and the segment [II] is composed of consecutive units expressed by the formula [II].
  • the segment [I] may have a block structure in which units expressed by an identical formula [I] are present in a consecutive manner, or a random structure in which units expressed by different formulae [I] are arranged randomly.
  • the segment [II] may have a block structure in which units expressed by an identical formula [II] are present in a consecutive manner, or a random structure in which units expressed by different formulae [II] are arranged randomly.
  • the number average molecular weight (Mn) thereof is 2,000 to 25,000, preferably 2,000 to 20,000, more preferably 3,000 to 15,000. Further, the polydispersity (Mw/Mn) thereof is 1.00 to 3.00, preferably 1.00 to 2.00, more preferably 1.05 to 1.60.
  • repeating unit number of each of the segments [I] and [II] is 1 to 50, preferably 1 to 20, more preferably 3 to 10.
  • a ratio between the repeating unit number of the segment [I] and the repeating unit number of the segment [II] i.e. a ratio of n 2 /n 1 which is a ratio between a polymerization degree n 1 of the segment [I] and a polymerization degree n 2 of the segment [II] is preferably 0.02 to 10, more preferably 0.05 to 5.
  • the molecular weight is a number average molecular weight measured by gel permeation chromatography (GPC) under the following conditions, using polystyrene as a reference substance.
  • the diblock copolymer of the present invention as an emulsifier can be produced by a method having a step of performing group transfer polymerization on a monomer represented by a general formula (5), and a step of performing group transfer polymerization on a polar monomer represented by a general formula (6), using a compound represented by the following general formula (4) as an initiator.
  • the diblock copolymer of the present invention can be synthesized by sequentially performing group transfer polymerization on the monomer represented by the general formula (5) and on the polar monomer represented by the general formula (6), using the compound represented by the general formula (4) as an initiator; the monomer represented by the general formula (5) and the polar monomer represented by the general formula (6) can be subjected to group transfer polymerization in any order.
  • each R 6 independently represents an alkyl group having 1 to 4 carbon atoms; each R 7 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.
  • R 1 and A are defined as above in the formula [I].
  • R 1 and B are defined as above in the formula [II].
  • the initiator represented by the general formula (4) the following compounds may for example be used.
  • the initiator usable in the production method of the diblock copolymer of the present invention shall not be limited to the initiators exemplified below.
  • Me represents a methyl group
  • Et represents an ethyl group
  • nPr represents a n-propyl group
  • iPr represents an isopropyl group
  • nBu represents a n-butyl group.
  • the monomer represented by the general formula (5) there may be used for example the following monomers.
  • the monomer usable in the production method of the diblock copolymer of the present invention shall not be limited to the monomers exemplified below.
  • a in the general formula (5) is the organopolysiloxane-containing group represented by the general formula (1)
  • a in the general formula (5) is the organopolysiloxane-containing group represented by the general formula (2)
  • polar monomer represented by the general formula (6) there may be used for example the following polar monomers.
  • the polar monomer usable in the production method of the diblock copolymer of the present invention shall not be limited to the polar monomers exemplified below.
  • an oxyalkylene-substituted (meth)acrylate such as tetrahydrofurfuryl (meth)acrylate, di(ethyleneglycol)monomethylether (meth)acrylate, furfuryl (meth)acrylate, 2-methoxyethyl (meth)acrylate, 2-butoxyethyl (meth)acrylate, 2-ethoxyethyl (meth)acrylate, 2-(methoxyethoxy)ethyl (meth)acrylate, allyloxyethyl (meth)acrylate, 1-ethoxybutyl (meth)acrylate, tetrahydro-4H-pyranyl-2 (meth)acrylate, ethyltriglycol (meth)acrylate, butyldiglycol (meth)acrylate, poly(propyleneglycol)dimethylether (meth)acrylate and poly(ethyleneglycol)alkylether (meth)acryl
  • R 1 represents a hydrogen atom or a methyl group, preferably a methyl group.
  • Each R 7 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, preferably a methyl group and an ethyl group.
  • R 1 represents a hydrogen atom or a methyl group, preferably a methyl group.
  • R 3 represents a saturated hydrocarbon group having 1 to 10 carbon atoms, preferably a saturated hydrocarbon group having 1 to 5 carbon atoms, more preferably a methyl group.
  • n 3 represents a number of the repeating units, provided that 1 ⁇ n 3 ⁇ 10, preferably 2 ⁇ n 3 ⁇ 8.
  • polar monomer represented by the general formula (6) particularly preferred is a 2-(dimethylamino)ethyl methacrylate represented by a formula (8-1).
  • group transfer polymerization is performed via the following two stages.
  • a first stage any one of the monomer represented by the general formula (5) and the polar monomer represented by the general formula (6) is to be polymerized (the monomer to be polymerized in the first stage is referred to as a first monomer hereunder); subsequently, in a second stage, any one of the monomer represented by the general formula (5) and the polar monomer represented by the general formula (6), that was not polymerized in the first stage, is to be polymerized (the monomer to be polymerized in the second stage is referred to as a second monomer hereunder).
  • the first stage of the three components which are the compound represented by the general formula (4) and serving as an initiator, a catalyst, and the first monomer, two components are to be mixed together in advance, followed by adding and mixing the remaining one component thereinto so as to allow the polymerization of the first monomer to start taking place at first.
  • the second monomer will be added to the reaction system so as to allow the polymerization of the second monomer to start taking place.
  • reaction terminator After confirming that the polymerization reaction of the second monomer has stopped, a reaction terminator will be added so as to end the reaction.
  • the diblock copolymer as the target product can be obtained by performing purification in a conventional manner where, for example, a solvent and the unreacted monomer are to be distilled away under a reduced pressure.
  • a catalyst is put into a thoroughly dried triple-necked flask, followed by adding a solvent thereto. Moreover, after adding and mixing the initiator represented by the general formula (4) thereinto, a dropping funnel is then used to deliver the first monomer by drops while performing stirring. The reaction solution is cooled according to the extent of heat generation so that the reaction solution will be maintained at an appropriate temperature. After the first monomer was delivered by drops, stirring will be performed continuously until the first monomer has been consumed, where the termination of the polymerization reaction of the first monomer will then be confirmed by confirming, via gel permeation chromatography (GPC) analysis or the like, an increase in molecular weight according to a preparation ratio between the initiator and the first monomer.
  • GPC gel permeation chromatography
  • the second monomer will be delivered into this reaction system by drops while performing stirring.
  • the reaction solution is cooled according to the extent of heat generation so that the reaction solution will be maintained at an appropriate temperature.
  • stirring will be performed continuously until the second monomer dropped has been consumed, where a reaction terminator will be added in the end so as to end the reaction.
  • the diblock copolymer as the target product can be obtained by performing purification in a conventional manner where, for example, the solvent and the unreacted monomer are to be distilled away under a reduced pressure.
  • reaction solvent there may be used an aprotic organic solvent.
  • aprotic organic solvent there may be listed ethyl acetate, propionitrile, toluene, xylene, bromobenzene, dimethoxyethane, diethoxyethane, diethyl ether, tetramethylene sulfone, N,N-dimethylformamide, N,N-dimethylacetamide, N-methylpyrrolidone, anisole, 2-butoxyethoxytrimethylsilane, cellosolve acetate, crown ether, acetonitrile and tetrahydrofuran (THF).
  • dichloromethane toluene, acetonitrile and tetrahydrofuran, of which tetrahydrofuran is more preferred.
  • a reaction temperature for the group transfer polymerization reaction is -100 to 150°C, preferably 0 to 50°C, more preferably 10 to 30°C.
  • a temperature at the time of distilling away the solvent and unreacted monomer under a reduced pressure is 80 to 300°C, preferably 100 to 200°C, more preferably 120 to 180°C. Further, a pressure at the time of performing stripping is not higher than 1 atm, preferably not higher than 0.1 atm, more preferably not higher than 0.007 atm.
  • the catalyst there may be generally used one selected from an anionic catalyst, a Lewis acid catalyst and an organic molecular catalyst that are known as catalysts for group transfer polymerization.
  • anionic catalyst examples include tris(dimethylamino)sulfonium difluorotrimethylsilicate, tris(dimethylamino)sulfonium cyanide, tetraphenylarsonium cyanide, tris(dimethylamino)sulfonium azide, tetraethylammonium azide, bis(dialkylaluminum)oxide, borontrifluoride etherate, alkali metal fluoride, alkali metal cyanide, alkali metal azide, tris(dimethylamino)sulfonium difluorotriphenylstanate, tetrabutylammonium fluoride, tetramethylammonium fluoride, tetraethylammonium cyanide, tetrabutylammonium benzoate, tetrabutylammonium bibenzoate, and tetrabutylammonium m-chlor
  • Lewis acid catalyst examples include zinc iodide, zinc bromide, zinc chloride, mono and dialkylaluminum halides, and dialkylaluminum oxide.
  • organic molecular catalyst examples include 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, 1,3-diisopropylimidazol-2-ylidene, 1,3-di-tert-butylimidazol-2-ylidene, 1,8-diazabicyclo[5.4.0]-7-undecene, 2,8,9-trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane, 1-tert-butyl-2,2,4,4,4-pentakis(dimethylamino)-2 ⁇ 5 ,4 ⁇ 5 -catenadi(phosphazene), 1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)
  • reaction terminator a compound capable of donating protons is used.
  • examples thereof include methanol, isopropyl alcohol, n-butyl alcohol and water.
  • An emulsion composition of the present invention contains the above diblock copolymer as an emulsifier, a water phase component, and an oil phase component. There are contained 0.1 to 10% by mass of the emulsifier, 5 to 90% by mass of the water phase component, and 5 to 60% by mass of the oil phase component, with respect to the total mass of the emulsion composition; in a wide range of emulsification compositions, the emulsion composition of the present invention is an emulsion composition superior in dispersion stability over time, and it is particularly preferred that the emulsion composition be a water-in-oil type emulsion composition.
  • water phase component and oil phase component that are to be contained in the emulsion composition, they can be appropriately selected depending on the use and purpose of the composition, examples of which may include later-described components known as cosmetic material components.
  • the water phase component contained in the emulsion composition contains water as its main component, and further contains various water-soluble components.
  • oil phase component contained in the emulsion composition examples include a silicone oil, a hydrocarbon oil, a higher fatty acid, a polar oil such as an ester oil and a natural animal or vegetable oil, a semisynthetic oil, and/or a fluorine-based oil, of which a polar oil and a silicone oil are preferred.
  • the diblock copolymer of the present invention as an emulsifier can be used for various purposes; particularly, the diblock copolymer is preferable as a cosmetic raw material, and can be added to, for example, a basic cosmetic material such as a milky lotion, a cream, a beauty lotion, a facial pack, a dispersion liquid and a cleansing material; a makeup cosmetic material such as a foundation, a face powder, a lipstick, a blusher, an eyeshadow, an eyeliner and a mascara; and a hair cosmetic material such as a shampoo, a hair conditioner, a hair treatment agent and a hair styling material.
  • a basic cosmetic material such as a milky lotion, a cream, a beauty lotion, a facial pack, a dispersion liquid and a cleansing material
  • a makeup cosmetic material such as a foundation, a face powder, a lipstick, a blusher, an eyeshadow, an eyeliner and a mascara
  • a hair cosmetic material such as a shampoo, a hair
  • the diblock copolymer of the present invention as an emulsifier be added to the cosmetic material by an amount of 0.01 to 10% by mass.
  • An amount of less than 0.01% by mass shall make it difficult for a satisfactory emulsifying capability to be exerted; further, an amount of greater than 10% by mass is not preferable because a poor feeling of use will be incurred as extensibility dulls due to an increased viscosity.
  • the diblock copolymer of the present invention as an emulsifier in a cosmetic material, there are no particular restrictions on other cosmetic material components; there may be added cosmetic material components that are normally employed depending on the type of a product or a certain cosmetic purpose.
  • Such cosmetic material components include an oil agent raw material such as a fat and oil, a wax, a hydrocarbon, a silicone oil, a fatty acid, an alcohol, an ester and a lanolin; a powder raw material such as a white pigment, a coloring pigment, an extender pigment, a photoluminescent pigment, an organic powder and a hydrophobized pigment; a metallic soap; a surfactant; a multivalent alcohol; a polymer compound; water; an antioxidant; an ultraviolet absorber; a preservative; a tar pigment; a natural pigment; a beauty component; and a perfume.
  • These cosmetic material components may be appropriately added on the premise that the effects of the present invention will not be impaired.
  • An emulsion composition obtained using the diblock copolymer of the present invention as an emulsifier and a cosmetic material containing such emulsion composition are also part of the embodiment of the present invention.
  • the number average molecular weight of the diblock copolymer of the synthesis example 1, the polydispersity of the molecular weight thereof, and a polymerization degree ratio between each monomer were as follows.
  • A represents a residue of the silicone macromer (a)
  • B represents a residue of 2-(dimethylamino)ethylmethacrylate.
  • the product obtained was a diblock copolymer.
  • the number average molecular weight of the diblock copolymer of the synthesis example 2 the polydispersity of the molecular weight thereof, and a polymerization degree ratio between each monomer were as follows.
  • A represents a residue of the silicone macromer (a)
  • B represents a residue of the monomer (b).
  • the product obtained was a diblock copolymer.
  • the number average molecular weight of the diblock copolymer of the synthesis example 3 and the polydispersity of the molecular weight thereof were as follows.
  • A represents a residue of the silicone macromer (a)
  • B represents a residue of the monomer (c).
  • This reaction solution was then stirred at room temperature for an hour, followed by adding 10 mL of methanol thereinto so as to terminate the reaction.
  • the reaction solution after the termination of the reaction was then subjected to stripping at 105°C and a reduced pressure of lower than 0.007 atm for an hour, thereby obtaining a target random copolymer.
  • the number average molecular weight of the random copolymer of the comparative synthesis example 1 and the polydispersity of the molecular weight thereof were as follows.
  • A represents a residue of the silicone macromer (a)
  • B represents a residue of 2-(dimethylamino)ethylmethacrylate.
  • An emulsion composition was produced in accordance with the compositions shown in Table 1; the preservation stability of the emulsion composition obtained was then evaluated under the following criteria based on, for example, the presence or non-presence of phase separation and a gel-like substance after being stored at 40°C for three days.
  • the diblock copolymer of the present invention has an excellent emulsifying capability and is capable of providing an emulsion composition superior in stability. Further, it became clear that there can be provided a stable emulsion composition with a wider range of allowable water content as compared to a polyether-modified silicone.

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Abstract

Provided are an emulsifier exhibiting a high preservation stability and having an excellent emulsifying capability in a wide range of emulsification compositions; and an emulsion composition containing such emulsifier. The emulsifier is comprised of a diblock copolymer whose main chain is comprised of a silicone graft copolymer block represented by a formula [I] and a polar copolymer block represented by a formula [II], wherein one end structure of the main chain is represented by a formula [III], and the other end structure of the main chain is represented by a formula [IV], the formulae [I] to [IV] being expressed aswherein R<sup>1</sup> represents a hydrogen atom or a methyl group; A represents an organopolysiloxane-containing group; n<sup>1</sup> satisfies 1≤ n<sup>1</sup> ≤50; B represents a polar groupcontaining monovalent hydrocarbon group having 1 to 20 carbon atoms, an amino group or a hydroxyl group; n<sup>2</sup> satisfies 1≤ n<sup>2</sup>≤50; R<sup>6</sup> represents an alkyl group having 1 to 4 carbon atoms; each R<sup>7</sup> independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; X represents the group represented by A in the formula [I] or the group represented by B in the formula [II].

Description

    TECHNICAL FIELD
  • The present invention relates to an emulsifier exhibiting a high preservation stability and having an excellent emulsifying capability in a wide range of emulsification compositions, particularly to a (meth)acryl silicone-based diblock copolymer.
    • BACKGROUND ART
  • Generally, in the case of a water-in-oil type emulsion composition, in order to obtain an emulsion composition that is smooth, has a little stickiness and is superior in water repellency, silicone oils are often used as oil agents; however, as for a water-in-oil type emulsion composition containing such silicone oil, it has been difficult to obtain an emulsion superior in stability even when using an emulsifier such as a polyoxyalkylene fatty acid ester-based emulsifier that has been conventionally used. Here, with regard to an emulsion whose oil phase is a silicone oil, there are widely known methods in which used as a surfactant (emulsifier) is a polyoxyalkylene-modified organopolysiloxane (polyether-modified silicone) having a favorable compatibility to a silicone oil (e.g. Patent documents 1 to 5).
  • However, even when using a polyether-modified silicone, if adding a large amount of a water phase component to achieve a wateriness, the stability of an emulsion may be impaired whereby the oil phase and water phase may be separated over time, or the emulsion may not be able to be obtained in the first place. Here, in general, there is now considered a method for achieving a stability of an emulsion by either increasing the viscosity of the oil phase or turning it into a gel.
  • However, a large amount of a thickener or a gelator will actually lead to a loss of wateriness, and thereby contribute to a sticky texture. Further, there has been a downside where a poor extensibility is observed when applied to the skin, which leads to an insufficient smooth texture. Thus, desired is an emulsifier allowing there to be stably contained a large amount of water without adding a thickener or a gelator.
    • PRIOR ART DOCUMENTS Patent documents
    • Patent document 1: JP-A-Sho 61-293903
    • Patent document 2: JP-A-Sho 61-293904
    • Patent document 3: JP-A-Sho 62-187406
    • Patent document 4: JP-A-Sho 62-215510
    • Patent document 5: JP-A-Sho 62-216635
    SUMMARY OF THE INVENTION Problems to be solved by the invention
  • Thus, it is an object of the present invention to provide an emulsifier exhibiting a high preservation stability and having an excellent emulsifying capability in a wide range of emulsification compositions, particularly an emulsifier suitable for producing a water-in-oil type emulsion composition capable of containing a large amount of a water phase component. Further, it is also an object of the present invention to provide an emulsion composition using such emulsifier.
    • Means to solve the problems
  • The inventor of the present invention diligently conducted a series of studies to achieve the above object, and completed the invention as follows. That is, the inventors found that the aforementioned problems can be solved by a diblock copolymer having, as its structural components, a hydrophobic silicone graft copolymer block, and a polar copolymer block having a particular polar group(s) serving as a functional group.
  • Thus, the present invention is to provide an emulsifier comprised of the following diblock copolymer.
    1. [1] An emulsifier comprised of a diblock copolymer whose main chain is comprised of a silicone graft copolymer block represented by a formula [I] and a polar copolymer block represented by a formula [II], wherein one end structure of the main chain is represented by a formula [III], and the other end structure of the main chain is represented by a formula [IV], the formula [I] being expressed as
      Figure imgb0001
      Figure imgb0002
      • wherein R1 represents a hydrogen atom or a methyl group,
        • A represents an organopolysiloxane-containing group represented by a general formula (1) or an organopolysiloxane-containing group represented by a general formula (2),
        • n1 represents a number of repeating units and satisfies 1≤ n1 ≤50,
      • wherein the general formula (1) is expressed as
        Figure imgb0003
      • wherein the organopolysiloxane-containing group represented by the general formula (1) has a linear organopolysiloxane structure where a repeating unit number m is 0 to 100,
        • Z represents a divalent organic group,
        • each R2 independently represents a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group,
        • R3 represents a saturated hydrocarbon group having 1 to 10 carbon atoms,
        • m is a number of 0 to 100, and
      • wherein the general formula (2) is expressed as

                [Chemical formula 3]     -O-Li (2)

      • wherein the organopolysiloxane-containing group represented by the general formula (2) has a dendritic organopolysiloxane structure whose hierarchical number c is 1 to 10,
        • L' is a silylorgano group represented by a general formula (3),
        • i represents a number of each hierarchy of the dendritic structure and is each integer from 1 to c in both the general formulae (2) and (3), and is 1 in the general formula (2),
      • wherein the general formula (3) is expressed as
        Figure imgb0004
      • wherein Z represents a divalent organic group,
        • R4 represents a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group,
        • each R5 independently represents an alkyl group having 1 to 8 carbon atoms or a phenyl group,
        • Li+1 is the silylorgano group Li represented by the general formula (3) when the hierarchy i is lower than c (lower than the uppermost hierarchy); and is a hydrogen atom, a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group, when the hierarchy i is i=c (the uppermost hierarchy),
        • a' represents the number of OR4 groups in the hierarchy i and is a number of 0 to 3; the formula [II] being expressed as
          Figure imgb0005
      • wherein R1 represents a hydrogen atom or a methyl group,
        • B is any group selected from -OB', -NH2 and -OH (B' represents a monovalent hydrocarbon group that has 1 to 20 carbon atoms, and has at least one kind of divalent group selected from a polyoxyalkylene group having 1 to 20 carbon atoms, -C(O)-, -O-, -S- and -NR-(R represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 20 carbon atoms)),
        • n2 represents a number of repeating units and satisfies 1≤ n2≤50; the formula [III] being expressed as
          Figure imgb0006
      • wherein R6 represents an alkyl group having 1 to 4 carbon atoms,
        each R7 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; the formula [IV] being expressed as
        Figure imgb0007
      • wherein R1 represents a hydrogen atom or a methyl group,
        X represents the group represented by A in the formula [I] or the group represented by B in the formula [II].
    2. [2] The emulsifier comprised of the diblock copolymer according to [1], wherein the diblock copolymer has a number average molecular weight of 2,000 to 25,000 in terms of polystyrene when measured by gel permeation chromatography.
    3. [3] An emulsion composition comprising the emulsifier according to [1] or [2], a water phase component and an oil phase component.
    4. [4] The emulsion composition according to [3], wherein
      • the emulsifier is in an amount of 0.1 to 10% by mass,
      • the water phase component is in an amount of 5 to 90% by mass, and
      • the oil phase component is in an amount of 5 to 60% by mass, with respect to a total mass of the emulsion composition.
    5. [5] A cosmetic material comprising the emulsion composition according to [3] or [4].
    Effects of the invention
  • The emulsifier comprised of the diblock copolymer of the present invention has, as its structural components, a hydrophobic silicone graft copolymer block (segment [I]), and a polar copolymer block having a particular polar group(s) serving as a functional group (segment [II]). When preparing a water-in-oil type emulsion composition using such diblock copolymer, the interaction between the polar group(s) and a water phase and the interaction between the silicone moiety and an oil agent will turn into a stronger and more efficient interaction derived from the block structure, thereby allowing there to be obtained an emulsion composition having an excellent temporal stability in a wide range of emulsification compositions.
    • MODE FOR CARRYING OUT THE INVENTION
  • The present invention is described in detail hereunder. Further, the term "(meth)acryl " used in this specification refers to methacryl and acryl. Similarly, the term "(meth)acrylate" used in this specification refers to methacrylic acid ester and acrylic acid ester.
    • [Emulsifier]
  • A diblock copolymer of the present invention as an emulsifier has, in its main chain, a silicone graft copolymer block unit represented by the following formula [I] (segment [I]) and a polar copolymer block unit represented by the following formula [II] (segment [II]), where one end structure of the main chain is a structure represented by the following formula [III], and the other end structure of the main chain is a structure represented by the following formula [IV].
    • Segment [I]
  • Figure imgb0008
  • In the formula [I], R1 represents a hydrogen atom or a methyl group. A represents an organopolysiloxane-containing group represented by the following general formula (1), or an organopolysiloxane-containing group represented by the following general formula (2). n1 represents a number of the repeating units; n1 is 1 to 50, preferably 1 to 20, more preferably 3 to 10.
  • The organopolysiloxane-containing group represented by the general formula (1) is a group having a linear organopolysiloxane structure where a repeating unit number m of a diorganosiloxy group is 0 to 100.
    Figure imgb0009
  • In the general formula (1), Z represents a divalent organic group, preferably a saturated hydrocarbon group having 2 to 12 carbon atoms, more preferably a propylene group. Each R2 independently represents a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group, preferably a saturated hydrocarbon group having 1 to 5 carbon atoms, more preferably a methyl group. R3 represents a saturated hydrocarbon group having 1 to 10 carbon atoms, preferably a saturated hydrocarbon group having 1 to 5 carbon atoms, more preferably a methyl group. m is a number of 0 to 100, preferably a number of 1 to 60, more preferably a number of 5 to 30.
  • The organopolysiloxane-containing group represented by the general formula (2) is a group having a dendritically branched structure(s), where the number of such branched structures (hierarchical number c) is an integer of 1 to 10, preferably an integer of 1 to 6, more preferably an integer of 1 to 4.
    [Chemical formula 10]

            -O-Li     (2)
    Figure imgb0010
  • In the general formulae (2) and (3), i represents a number of each hierarchy of the dendritic structure, and is each integer from 1 to c.
  • In the general formula (2), L' is a silylorgano group represented by the general formula (3), and a hierarchy i in the general formula (2) is 1.
  • In the general formula (3), Z represents a divalent organic group, preferably a saturated hydrocarbon group having 2 to 12 carbon atoms, more preferably a propylene group. R4 represents a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group, preferably a saturated hydrocarbon group having 1 to 5 carbon atoms, more preferably a methyl group. Each R5 independently represents an alkyl group having 1 to 8 carbon atoms or a phenyl group, preferably an alkyl group having 1 to 3 carbon atoms, more preferably a methyl group. Li+1 is the silylorgano group L' represented by the general formula (3) when the hierarchy i is lower than c (lower than the uppermost hierarchy); and is a hydrogen atom, a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group, when the hierarchy i is i=c (the uppermost hierarchy). As L' when i=c (the uppermost hierarchy), preferred is a saturated hydrocarbon group having 1 to 8 carbon atoms, more preferred is a saturated hydrocarbon group having 1 to 4 carbon atoms, a' represents the number of the OR4 groups in the hierarchy i, and is a number of 0 to 3.
  • A dendritic organopolysiloxane of a hierarchical number 1 (c=1) is expressed by the following general formula (3-1) wherein L2 represents a hydrogen atom, a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group.
    Figure imgb0011
  • A dendritic organopolysiloxane of a hierarchical number 2 (c=2) is expressed by the following general formula (3-2) wherein L3 represents a hydrogen atom, a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group.
    Figure imgb0012
  • A dendritic organopolysiloxane of a hierarchical number 3 (c=3) is expressed by the following general formula (3-3) wherein L3 represents a hydrogen atom, a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group.
    Figure imgb0013
    Figure imgb0014
  • In the general formulae (3-1) to (3-3), Z, R4 and R5 are each identical to those described above, and each of a1, a2 and a3 is a number of 0 to 3.
    • Segment [II]
  • Figure imgb0015
  • In the formula [II], R1 represents a hydrogen atom or a methyl group. B is any group selected from -OB', -NH2 and -OH (B' represents a monovalent hydrocarbon group that has 1 to 20 carbon atoms, and has at least one kind of divalent group selected from a polyoxyalkylene group having 1 to 20 carbon atoms, -C(O)-, -O-, -S- and -NR- (R represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 20 carbon atoms)), and is preferably a group represented by a general formula (8') or (9'). Further, n2 represents a number of the repeating units; n2 is 1 to 50, preferably 1 to 20, more preferably 3 to 10.
    [Chemical formulae 16]

            -O-CH2-CH2-N(R7)2     (8')

            -O-(C2H4O)n3-R3     (9')

  • (In the formula (8'), each R7 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms. In the formula (9'), R3 represents a saturated hydrocarbon group having 1 to 10 carbon atoms, n3 represents a number of the repeating units, provided that 1≤n3≤10.)
    • End structure [III]
  • Figure imgb0016
  • In the formula [III], R6 represents an alkyl group having 1 to 4 carbon atoms, preferably a methyl group. Each R7 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, preferably a methyl group.
    • End structure [IV]
  • Figure imgb0017
  • In the formula [IV], R1 represents a hydrogen atom or a methyl group. X represents the group represented by A in the formula [I] or the group represented by B in the formula [II].
  • Each of the segments [I] and [II] may be composed of at least one kind of unit expressed by the formula [I] or at least one kind of unit expressed by the formula [II], or be composed of multiple kinds of units expressed by the formula [1] or multiple kinds of units expressed by the formula [II]. Further, the segments [I] and [II] that are sandwiched between the end structures [III] and [IV] are in a random order.
  • In the present invention, a diblock copolymer refers to a copolymer linking the segment [I] and the segment [II] as two segments having different physical properties such as polarity, water solubility, and presence or absence of affinity for powder. That is, the diblock copolymer of the present invention is a copolymer linking together the segments [I] and [II] of which the segment [I] is composed of consecutive units expressed by the formula [I], and the segment [II] is composed of consecutive units expressed by the formula [II]. If the segment [I] is composed of multiple kinds of units expressed by the formula [I], the segment [I] may have a block structure in which units expressed by an identical formula [I] are present in a consecutive manner, or a random structure in which units expressed by different formulae [I] are arranged randomly. Similarly, if the segment [II] is composed of multiple kinds of units expressed by the formula [II], the segment [II] may have a block structure in which units expressed by an identical formula [II] are present in a consecutive manner, or a random structure in which units expressed by different formulae [II] are arranged randomly.
  • In the case of the diblock copolymer of the present invention as an emulsifier, the number average molecular weight (Mn) thereof is 2,000 to 25,000, preferably 2,000 to 20,000, more preferably 3,000 to 15,000. Further, the polydispersity (Mw/Mn) thereof is 1.00 to 3.00, preferably 1.00 to 2.00, more preferably 1.05 to 1.60.
  • Further, the repeating unit number of each of the segments [I] and [II] is 1 to 50, preferably 1 to 20, more preferably 3 to 10.
  • A ratio between the repeating unit number of the segment [I] and the repeating unit number of the segment [II] i.e. a ratio of n2/n1 which is a ratio between a polymerization degree n1 of the segment [I] and a polymerization degree n2 of the segment [II] is preferably 0.02 to 10, more preferably 0.05 to 5.
  • In the present invention, the molecular weight is a number average molecular weight measured by gel permeation chromatography (GPC) under the following conditions, using polystyrene as a reference substance.
    • [Measurement conditions]
    • Measuring instrument: HLC-8320GPC (by Tosoh Corporation)
    • Developing solvent: Tetrahydrofuran (THF)
    • Flow rate: 0.600 mL/min
    • Detector: Refractive index detector (RI)
    • Column: TSK Guardcolumn Super H-H
      • (4.6 mm I.D. × 35 mm)
      • TSK gel Super H2500
      • (Filler particle size: 3.0 µm, 6 mm I.D. × 150 mm)
      • TSK gel Super HM-N
      • (Filler particle size: 3.0 µm, 6 mm I.D. × 150 mm)
      • (All manufactured by Tosoh Corporation)
    • Column temperature: 40°C
    • Sample injection volume: 50 µL (THF solution with a concentration of 0.3% by mass)
  • The diblock copolymer of the present invention as an emulsifier can be produced by a method having a step of performing group transfer polymerization on a monomer represented by a general formula (5), and a step of performing group transfer polymerization on a polar monomer represented by a general formula (6), using a compound represented by the following general formula (4) as an initiator. That is, the diblock copolymer of the present invention can be synthesized by sequentially performing group transfer polymerization on the monomer represented by the general formula (5) and on the polar monomer represented by the general formula (6), using the compound represented by the general formula (4) as an initiator; the monomer represented by the general formula (5) and the polar monomer represented by the general formula (6) can be subjected to group transfer polymerization in any order.
    Figure imgb0018
  • In the general formula (4), each R6 independently represents an alkyl group having 1 to 4 carbon atoms; each R7 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.
    Figure imgb0019
  • In the general formula (5), R1 and A are defined as above in the formula [I].
    Figure imgb0020
  • In the general formula (6), R1 and B are defined as above in the formula [II].
  • As the initiator represented by the general formula (4), the following compounds may for example be used. The initiator usable in the production method of the diblock copolymer of the present invention shall not be limited to the initiators exemplified below.
    Figure imgb0021
  • In these formulae, Me represents a methyl group, Et represents an ethyl group, nPr represents a n-propyl group, iPr represents an isopropyl group, and nBu represents a n-butyl group.
  • As the monomer represented by the general formula (5), there may be used for example the following monomers. The monomer usable in the production method of the diblock copolymer of the present invention shall not be limited to the monomers exemplified below.
  • When A in the general formula (5) is the organopolysiloxane-containing group represented by the general formula (1)
    Figure imgb0022
    Figure imgb0023
  • When A in the general formula (5) is the organopolysiloxane-containing group represented by the general formula (2)
    Figure imgb0024
    Figure imgb0025
  • As the polar monomer represented by the general formula (6), there may be used for example the following polar monomers. The polar monomer usable in the production method of the diblock copolymer of the present invention shall not be limited to the polar monomers exemplified below.
  • Specifically, there may be listed, for example, an oxyalkylene-substituted (meth)acrylate such as tetrahydrofurfuryl (meth)acrylate, di(ethyleneglycol)monomethylether (meth)acrylate, furfuryl (meth)acrylate, 2-methoxyethyl (meth)acrylate, 2-butoxyethyl (meth)acrylate, 2-ethoxyethyl (meth)acrylate, 2-(methoxyethoxy)ethyl (meth)acrylate, allyloxyethyl (meth)acrylate, 1-ethoxybutyl (meth)acrylate, tetrahydro-4H-pyranyl-2 (meth)acrylate, ethyltriglycol (meth)acrylate, butyldiglycol (meth)acrylate, poly(propyleneglycol)dimethylether (meth)acrylate and poly(ethyleneglycol)alkylether (meth)acrylate; an aminoalkyl (meth)acrylate such as dimethylaminoethyl methacrylate and diethylaminoethyl methacrylate; and a (meth)acrylamide such as (meth)acrylamide, 4-(meth)acryloylmorpholine, N-tert-butyl (meth)acrylamide, N,N-dimethyl (meth)acrylamide, N,N-diethyl (meth)acrylamide, N-(butoxymethyl) (meth)acrylamide, N-[3-(dimethylamino)propyl] (meth)acrylamide, N-dodecyl (meth)acrylamide and N-isopropyl (meth)acrylamide.
  • As the polar monomer represented by the general formula (6), preferred is a polar monomer represented by the following general formula (8) or (9).
    Figure imgb0026
     In the general formula (8), R1 represents a hydrogen atom or a methyl group, preferably a methyl group. Each R7 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, preferably a methyl group and an ethyl group.
    Figure imgb0027
     In the general formula (9), R1 represents a hydrogen atom or a methyl group, preferably a methyl group. R3 represents a saturated hydrocarbon group having 1 to 10 carbon atoms, preferably a saturated hydrocarbon group having 1 to 5 carbon atoms, more preferably a methyl group. n3 represents a number of the repeating units, provided that 1≤n3≤10, preferably 2≤n3≤8.
  • As the polar monomer represented by the general formula (6), particularly preferred is a 2-(dimethylamino)ethyl methacrylate represented by a formula (8-1).
    Figure imgb0028
  • In the production method of the diblock copolymer of the present invention, group transfer polymerization is performed via the following two stages. In a first stage, any one of the monomer represented by the general formula (5) and the polar monomer represented by the general formula (6) is to be polymerized (the monomer to be polymerized in the first stage is referred to as a first monomer hereunder); subsequently, in a second stage, any one of the monomer represented by the general formula (5) and the polar monomer represented by the general formula (6), that was not polymerized in the first stage, is to be polymerized (the monomer to be polymerized in the second stage is referred to as a second monomer hereunder).
  • In the first stage, of the three components which are the compound represented by the general formula (4) and serving as an initiator, a catalyst, and the first monomer, two components are to be mixed together in advance, followed by adding and mixing the remaining one component thereinto so as to allow the polymerization of the first monomer to start taking place at first.
  • Next, after confirming that the polymerization reaction of the first monomer has stopped, the second monomer will be added to the reaction system so as to allow the polymerization of the second monomer to start taking place.
  • After confirming that the polymerization reaction of the second monomer has stopped, a reaction terminator will be added so as to end the reaction.
  • After the reaction was over, the diblock copolymer as the target product can be obtained by performing purification in a conventional manner where, for example, a solvent and the unreacted monomer are to be distilled away under a reduced pressure.
  • In the group transfer polymerization reactions of the first and second stages, it is preferred that a solvent be used.
  • As an example of a more specific production method, there may be employed the following method.
  • A catalyst is put into a thoroughly dried triple-necked flask, followed by adding a solvent thereto. Moreover, after adding and mixing the initiator represented by the general formula (4) thereinto, a dropping funnel is then used to deliver the first monomer by drops while performing stirring. The reaction solution is cooled according to the extent of heat generation so that the reaction solution will be maintained at an appropriate temperature. After the first monomer was delivered by drops, stirring will be performed continuously until the first monomer has been consumed, where the termination of the polymerization reaction of the first monomer will then be confirmed by confirming, via gel permeation chromatography (GPC) analysis or the like, an increase in molecular weight according to a preparation ratio between the initiator and the first monomer. Next, the second monomer will be delivered into this reaction system by drops while performing stirring. The reaction solution is cooled according to the extent of heat generation so that the reaction solution will be maintained at an appropriate temperature. After the second monomer was delivered by drops, stirring will be performed continuously until the second monomer dropped has been consumed, where a reaction terminator will be added in the end so as to end the reaction. After the reaction was over, the diblock copolymer as the target product can be obtained by performing purification in a conventional manner where, for example, the solvent and the unreacted monomer are to be distilled away under a reduced pressure.
  • As the reaction solvent, there may be used an aprotic organic solvent. For example, there may be listed ethyl acetate, propionitrile, toluene, xylene, bromobenzene, dimethoxyethane, diethoxyethane, diethyl ether, tetramethylene sulfone, N,N-dimethylformamide, N,N-dimethylacetamide, N-methylpyrrolidone, anisole, 2-butoxyethoxytrimethylsilane, cellosolve acetate, crown ether, acetonitrile and tetrahydrofuran (THF). In terms of reaction efficiency, preferred are dichloromethane, toluene, acetonitrile and tetrahydrofuran, of which tetrahydrofuran is more preferred.
  • A reaction temperature for the group transfer polymerization reaction is -100 to 150°C, preferably 0 to 50°C, more preferably 10 to 30°C.
  • A temperature at the time of distilling away the solvent and unreacted monomer under a reduced pressure is 80 to 300°C, preferably 100 to 200°C, more preferably 120 to 180°C. Further, a pressure at the time of performing stripping is not higher than 1 atm, preferably not higher than 0.1 atm, more preferably not higher than 0.007 atm.
  • As the catalyst, there may be generally used one selected from an anionic catalyst, a Lewis acid catalyst and an organic molecular catalyst that are known as catalysts for group transfer polymerization.
  • Examples of the anionic catalyst include tris(dimethylamino)sulfonium difluorotrimethylsilicate, tris(dimethylamino)sulfonium cyanide, tetraphenylarsonium cyanide, tris(dimethylamino)sulfonium azide, tetraethylammonium azide, bis(dialkylaluminum)oxide, borontrifluoride etherate, alkali metal fluoride, alkali metal cyanide, alkali metal azide, tris(dimethylamino)sulfonium difluorotriphenylstanate, tetrabutylammonium fluoride, tetramethylammonium fluoride, tetraethylammonium cyanide, tetrabutylammonium benzoate, tetrabutylammonium bibenzoate, and tetrabutylammonium m-chlorobenzoate.
  • Examples of the Lewis acid catalyst include zinc iodide, zinc bromide, zinc chloride, mono and dialkylaluminum halides, and dialkylaluminum oxide.
  • Examples of the organic molecular catalyst include 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, 1,3-diisopropylimidazol-2-ylidene, 1,3-di-tert-butylimidazol-2-ylidene, 1,8-diazabicyclo[5.4.0]-7-undecene, 2,8,9-trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane, 1-tert-butyl-2,2,4,4,4-pentakis(dimethylamino)-2λ5,4λ5-catenadi(phosphazene), 1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)-phosphoranilidenamino]-2λ5,4λ5-catenadi(phosphazene), tris(2,4,6-trimethoxyphenyl)phosphine, tris-(pentafluorophenyl)borane, triethylsilyl trifluoromethanesulfonate, triphenylcarbenium tetrakis(pentafluorophenyl)borate, trifluoromethanesulfonimide, and 1-[bis(trifluoromethanesulfonyl)methyl]-2,3,4,5,6-pentafluorobenzene.
  • As the reaction terminator, a compound capable of donating protons is used. Examples thereof include methanol, isopropyl alcohol, n-butyl alcohol and water.
    • [Emulsion composition]
  • An emulsion composition of the present invention contains the above diblock copolymer as an emulsifier, a water phase component, and an oil phase component. There are contained 0.1 to 10% by mass of the emulsifier, 5 to 90% by mass of the water phase component, and 5 to 60% by mass of the oil phase component, with respect to the total mass of the emulsion composition; in a wide range of emulsification compositions, the emulsion composition of the present invention is an emulsion composition superior in dispersion stability over time, and it is particularly preferred that the emulsion composition be a water-in-oil type emulsion composition.
  • As the water phase component and oil phase component that are to be contained in the emulsion composition, they can be appropriately selected depending on the use and purpose of the composition, examples of which may include later-described components known as cosmetic material components.
  • The water phase component contained in the emulsion composition contains water as its main component, and further contains various water-soluble components.
  • Examples of the oil phase component contained in the emulsion composition include a silicone oil, a hydrocarbon oil, a higher fatty acid, a polar oil such as an ester oil and a natural animal or vegetable oil, a semisynthetic oil, and/or a fluorine-based oil, of which a polar oil and a silicone oil are preferred.
  • Utilizing its emulsifying capability, the diblock copolymer of the present invention as an emulsifier can be used for various purposes; particularly, the diblock copolymer is preferable as a cosmetic raw material, and can be added to, for example, a basic cosmetic material such as a milky lotion, a cream, a beauty lotion, a facial pack, a dispersion liquid and a cleansing material; a makeup cosmetic material such as a foundation, a face powder, a lipstick, a blusher, an eyeshadow, an eyeliner and a mascara; and a hair cosmetic material such as a shampoo, a hair conditioner, a hair treatment agent and a hair styling material. In such case, it is preferred that the diblock copolymer of the present invention as an emulsifier be added to the cosmetic material by an amount of 0.01 to 10% by mass. An amount of less than 0.01% by mass shall make it difficult for a satisfactory emulsifying capability to be exerted; further, an amount of greater than 10% by mass is not preferable because a poor feeling of use will be incurred as extensibility dulls due to an increased viscosity.
  • Further, if using the diblock copolymer of the present invention as an emulsifier in a cosmetic material, there are no particular restrictions on other cosmetic material components; there may be added cosmetic material components that are normally employed depending on the type of a product or a certain cosmetic purpose. Examples of such cosmetic material components include an oil agent raw material such as a fat and oil, a wax, a hydrocarbon, a silicone oil, a fatty acid, an alcohol, an ester and a lanolin; a powder raw material such as a white pigment, a coloring pigment, an extender pigment, a photoluminescent pigment, an organic powder and a hydrophobized pigment; a metallic soap; a surfactant; a multivalent alcohol; a polymer compound; water; an antioxidant; an ultraviolet absorber; a preservative; a tar pigment; a natural pigment; a beauty component; and a perfume. These cosmetic material components may be appropriately added on the premise that the effects of the present invention will not be impaired.
  • An emulsion composition obtained using the diblock copolymer of the present invention as an emulsifier and a cosmetic material containing such emulsion composition are also part of the embodiment of the present invention.
    • WORKING EXAMPLES
  • The present invention is described in greater detail hereunder with reference to working examples; however, the present invention shall not be limited to these working examples. Here, in the examples below, unless otherwise noted, "%" in composition refers to % by mass.
    • [Synthesis example 1]
  • Here, 19.9 mg of a tetrabutylammonium m-chlorobenzoate that had been dried under a reduced pressure was dissolved in 25 mL of THF. Under a nitrogen atmosphere, 436.0 mg of 1-methoxy-1-(trimethylsiloxy)-2-methyl-1-propene as an initiator was added to such THF solution of tetrabutylammonium m-chlorobenzoate, followed by spending 30 min delivering 7.5 g of the following silicone macromer (a) thereinto by drops so as to prepare a reaction solution. This reaction solution was further stirred at room temperature for another two hours. Next, 5 min were spent delivering 7.5 g of 2-(dimethylamino)ethylmethacrylate by drops into this reaction solution, and the solution was then stirred at room temperature for an hour, followed by adding 10 mL of methanol thereinto so as to terminate the reaction. The reaction solution after the termination of the reaction was then subjected to stripping at 105°C and a reduced pressure of lower than 0.007 atm for an hour, thereby obtaining a target diblock copolymer.
  • Here, gel permeation chromatography (GPC) analysis was conducted at two time points which were the time point at which the group transfer polymerization of the silicone macromer (a) had finished; and a time point after the reaction was over. As a result, at each stage, there was confirmed an increase in molecular weight according to the preparation ratio between the initiator and monomer, and it was confirmed that the target diblock copolymer had been obtained.
  • The number average molecular weight of the diblock copolymer of the synthesis example 1, the polydispersity of the molecular weight thereof, and a polymerization degree ratio between each monomer were as follows.
  • Number average molecular weight (Mn)=5025, Polydispersity (Mw/Mn)=1.19, Polymerization degree ratio (n2/n1)=5.34
    Figure imgb0029
    Figure imgb0030
  • (A represents a residue of the silicone macromer (a), and B represents a residue of 2-(dimethylamino)ethylmethacrylate. The average polymerization degree q of the silicone macromer (a) is q=3.5, and the average polymerization degree p of 2-(dimethylamino)ethylmethacrylate is p=18.4.)
    • [Synthesis example 2]
  • Here, 19.9 mg of a tetrabutylammonium m-chlorobenzoate that had been dried under a reduced pressure was dissolved in 25 mL of THF. Under a nitrogen atmosphere, 436.0 mg of 1-methoxy-1-(trimethylsiloxy)-2-methyl-1-propene as an initiator was added to such THF solution of tetrabutylammonium m-chlorobenzoate, followed by spending 30 min delivering 11.76 g of the silicone macromer (a) thereinto by drops so as to prepare a reaction solution. This reaction solution was further stirred at room temperature for another hour. Next, 15 min were spent delivering 3.24 g of the following monomer (b) by drops into this reaction solution, and the solution was then stirred at room temperature for three hours, followed by adding 10 mL of methanol thereinto so as to terminate the reaction. The reaction solution after the termination of the reaction was then subjected to stripping at 105°C and a reduced pressure of lower than 0.007 atm for an hour, thereby obtaining a target diblock copolymer.
  • In a similar manner as the synthesis example 1, it was confirmed that the product obtained was a diblock copolymer. The number average molecular weight of the diblock copolymer of the synthesis example 2, the polydispersity of the molecular weight thereof, and a polymerization degree ratio between each monomer were as follows.
  • Number average molecular weight (Mn)=9318, Polydispersity (Mw/Mn)=1.21, Polymerization degree ratio (n2/n1)=1.00
    Figure imgb0031
    Figure imgb0032
  • (A represents a residue of the silicone macromer (a), and B represents a residue of the monomer (b). The average polymerization degree q of the silicone macromer (a) is q=7.9, and the average polymerization degree p of the monomer (b) is p=7.9.)
    • [Synthesis example 3]
  • Here, 19.9 mg of a tetrabutylammonium m-chlorobenzoate that had been dried under a reduced pressure was dissolved in 25 mL of THF. Under a nitrogen atmosphere, 436.0 mg of 1-methoxy-1-(trimethylsiloxy)-2-methyl-1-propene as an initiator was added to such THF solution of tetrabutylammonium m-chlorobenzoate, followed by spending an hour delivering 9.67 g of the silicone macromer (a) thereinto by drops so as to prepare a reaction solution. This reaction solution was further stirred at room temperature for another two hours. Next, 30 min were spent delivering 5.33 g of the following monomer (c) by drops into this reaction solution, and the solution was then stirred at room temperature for five hours, followed by adding 10 mL of methanol thereinto so as to terminate the reaction. The reaction solution after the termination of the reaction was then subjected to stripping at 105°C and a reduced pressure of lower than 0.007 atm for an hour, thereby obtaining a target diblock copolymer.
  • In a similar manner as the synthesis example 1, it was confirmed that the product obtained was a diblock copolymer. The number average molecular weight of the diblock copolymer of the synthesis example 3 and the polydispersity of the molecular weight thereof were as follows.
  • Number average molecular weight (Mn)=9327, Polydispersity (Mw/Mn)=1.24, Polymerization degree ratio (n2/n1)=0.73
    Figure imgb0033
    Figure imgb0034
    Figure imgb0035
  • (A represents a residue of the silicone macromer (a), and B represents a residue of the monomer (c). The average polymerization degree q of the silicone macromer (a) is q=7.4, and the average polymerization degree p of the monomer (c) is p=5.4.)
    • [Comparative synthesis example 1]
  • Here, 19.9 mg of a tetrabutylammonium m-chlorobenzoate that had been dried under a reduced pressure was dissolved in 25 mL of THF. Under a nitrogen atmosphere, 436.0 mg of 1-methoxy-1-(trimethylsiloxy)-2-methyl-1-propene as an initiator was added to such THF solution of tetrabutylammonium m-chlorobenzoate, followed by spending 30 min delivering 7.5 g of the silicone macromer (a) and 7.5 g of 2-(dimethylamino)ethylmethacrylate thereinto by drops so as to prepare a reaction solution. This reaction solution was then stirred at room temperature for an hour, followed by adding 10 mL of methanol thereinto so as to terminate the reaction. The reaction solution after the termination of the reaction was then subjected to stripping at 105°C and a reduced pressure of lower than 0.007 atm for an hour, thereby obtaining a target random copolymer. The number average molecular weight of the random copolymer of the comparative synthesis example 1 and the polydispersity of the molecular weight thereof were as follows.
  • Number average molecular weight (Mn)=5302, Polydispersity (Mw/Mn)=1.32
    Figure imgb0036
  • (A represents a residue of the silicone macromer (a), and B represents a residue of 2-(dimethylamino)ethylmethacrylate. The average polymerization degree q of the silicone macromer (a) is q=2.9, and the average polymerization degree p of 2-(dimethylamino)ethylmethacrylate is p=16.9.)
    • [Stability evaluation of emulsion composition]
  • An emulsion composition was produced in accordance with the compositions shown in Table 1; the preservation stability of the emulsion composition obtained was then evaluated under the following criteria based on, for example, the presence or non-presence of phase separation and a gel-like substance after being stored at 40°C for three days.
    • ∘: Phase separation was not observed at all, and a gel-like substance was not observed either.
    • ×: Liquid was separated, or a gel-like substance was generated.
    Figure imgb0037
    Figure imgb0038
    Figure imgb0039
  • As is clear from the results shown in Table 1, when compared to the random copolymer (comparative synthesis example 1) synthesized using the same monomer, the diblock copolymer of the present invention has an excellent emulsifying capability and is capable of providing an emulsion composition superior in stability. Further, it became clear that there can be provided a stable emulsion composition with a wider range of allowable water content as compared to a polyether-modified silicone.

Claims (5)

  1. An emulsifier comprised of a diblock copolymer whose main chain is comprised of a silicone graft copolymer block represented by a formula [I] and a polar copolymer block represented by a formula [II], wherein one end structure of the main chain is represented by a formula [III], and the other end structure of the main chain is represented by a formula [IV], the formula [I] being expressed as
    Figure imgb0040
     wherein R1 represents a hydrogen atom or a methyl group,
    A represents an organopolysiloxane-containing group represented by a general formula (1) or an organopolysiloxane-containing group represented by a general formula (2),
    n1 represents a number of repeating units and satisfies 1≤ n1 ≤50,
    wherein the general formula (1) is expressed as
    Figure imgb0041
     wherein the organopolysiloxane-containing group represented by the general formula (1) has a linear organopolysiloxane structure where a repeating unit number m is 0 to 100,
    Z represents a divalent organic group,
    each R2 independently represents a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group,
    R3 represents a saturated hydrocarbon group having 1 to 10 carbon atoms,
    m is a number of 0 to 100, and
    wherein the general formula (2) is expressed as

            [Chemical formula 3]     -O-Li (2)

    wherein the organopolysiloxane-containing group represented by the general formula (2) has a dendritic organopolysiloxane structure whose hierarchical number c is 1 to 10,
    L' is a silylorgano group represented by a general formula (3),
    i represents a number of each hierarchy of the dendritic structure and is each integer from 1 to c in both the general formulae (2) and (3), and is 1 in the general formula (2),
    wherein the general formula (3) is expressed as
    Figure imgb0042
     wherein Z represents a divalent organic group,
    R4 represents a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group,
    each R5 independently represents an alkyl group having 1 to 8 carbon atoms or a phenyl group,
    Li+1 is the silylorgano group L' represented by the general formula (3) when the hierarchy i is lower than c (lower than the uppermost hierarchy); and is a hydrogen atom, a saturated hydrocarbon group having 1 to 10 carbon atoms or a phenyl group, when the hierarchy i is i=c (the uppermost hierarchy),
    a' represents the number of OR4 groups in the hierarchy i and is a number of 0 to 3; the formula [II] being expressed as
    Figure imgb0043
    Figure imgb0044
    wherein R1 represents a hydrogen atom or a methyl group,
    B is any group selected from -OB', -NH2 and -OH (B' represents a monovalent hydrocarbon group that has 1 to 20 carbon atoms, and has at least one kind of divalent group selected from a polyoxyalkylene group having 1 to 20 carbon atoms, -C(O)-, -O-, -S- and -NR-(R represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 20 carbon atoms)),
    n2 represents a number of repeating units and satisfies 1≤ n2≤50; the formula [III] being expressed as
    Figure imgb0045
    wherein R6 represents an alkyl group having 1 to 4 carbon atoms,

    each R7 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; the formula [IV] being expressed as
    Figure imgb0046
     wherein R1 represents a hydrogen atom or a methyl group,
    X represents the group represented by A in the formula [I] or the group represented by B in the formula [II].
  2. The emulsifier comprised of the diblock copolymer according to claim 1, wherein the diblock copolymer has a number average molecular weight of 2,000 to 25,000 in terms of polystyrene when measured by gel permeation chromatography.
  3. An emulsion composition comprising the emulsifier according to claim 1 or 2, a water phase component and an oil phase component.
  4. The emulsion composition according to claim 3, wherein
    the emulsifier is in an amount of 0.1 to 10% by mass,
    the water phase component is in an amount of 5 to 90% by mass, and
    the oil phase component is in an amount of 5 to 60% by mass, with respect to a total mass of the emulsion composition.
  5. A cosmetic material comprising the emulsion composition according to claim 3 or 4.
EP21809241.9A 2020-05-22 2021-05-11 Emulsifier and emulsion composition containing same Pending EP4154970A4 (en)

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JPS61293903A (en) 1985-05-20 1986-12-24 Shiseido Co Ltd Water-in-oil type emulsion cosmetic
JPS61293904A (en) 1985-05-20 1986-12-24 Shiseido Co Ltd Water-in-oil type emulsion cosmetic
JPS62187406A (en) 1986-02-13 1987-08-15 Shiseido Co Ltd W/o-type emulsified cosmetic
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US5057578A (en) * 1990-04-10 1991-10-15 E. I. Du Pont De Nemours And Company Silicone-containing block copolymers and macromonomers
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