EP4143263A1 - Composition pour le matage et la réduction des effets anti-empreintes de surfaces sur des matériaux support - Google Patents

Composition pour le matage et la réduction des effets anti-empreintes de surfaces sur des matériaux support

Info

Publication number
EP4143263A1
EP4143263A1 EP21725967.0A EP21725967A EP4143263A1 EP 4143263 A1 EP4143263 A1 EP 4143263A1 EP 21725967 A EP21725967 A EP 21725967A EP 4143263 A1 EP4143263 A1 EP 4143263A1
Authority
EP
European Patent Office
Prior art keywords
compound
general formula
resin
suspension according
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP21725967.0A
Other languages
German (de)
English (en)
Inventor
Andreas Gier
Norbert Kalwa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Flooring Technologies Ltd
Original Assignee
Flooring Technologies Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Flooring Technologies Ltd filed Critical Flooring Technologies Ltd
Publication of EP4143263A1 publication Critical patent/EP4143263A1/fr
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/006—Anti-reflective coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/42—Gloss-reducing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine

Definitions

  • the present invention relates to a composition for matting and reducing anti-fingerprint effects of surfaces on carrier materials, a method for its production, the use of this composition and carrier materials, such as paper layers or wood-based panels, with this composition.
  • the surface design is an important aspect in addition to the color design. Sometimes the two aspects complement each other, sometimes they are deliberately designed in opposition.
  • melamine surfaces however, it must be noted that they have a very high mechanical and chemical resistance, which gives them significant advantages over thermoplastic films or lacquers.
  • press plates that are used in the manufacture of the melamine resin-coated wood-based panels, almost any surface finish can be produced.
  • the present invention was therefore based on the technical problem of producing a surface with a low degree of gloss and simultaneous anti-fingerprint properties. It should be possible to fall back on the existing material systems. It should also be possible to use the existing systems. The resulting products should have the same surface properties as standard melamine surfaces.
  • a resin suspension based on a formaldehyde resin comprising a composition for matting and reducing anti-fingerprint effects of surfaces on carrier materials is provided, the composition being producible from
  • - X is H, OH or a hydrolyzable radical selected from the group comprising halogen, alkoxy, carboxy, amino, monoalkylamino or dialkylamino, aryloxy, acyloxy, alkylcarbonyl;
  • R 1 is an organic radical selected from the group comprising alkyl, aryl, cycloalkyl, and
  • R 1 has at least one functional group Qi which is selected from a group containing a hydroxy, amino, monoalkylamino, carboxy, mercapto, alkoxy, aldehyde, acrylic, acryloxy, methacrylic, methacryloxy -, cyano, isocyano and epoxy groups, and
  • R 2 is a non-hydrolysable organic radical R 2 is selected from the group comprising alkyl, aryl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl or perfluorinated alkyl and
  • At least one matting agent comprising polymers and silica.
  • the present composition comprises with the compounds of the general formula (I) and (II) a crosslinking, hydrophilic component and with the compound of the general formula (III) a hydrophobic component.
  • the silane compound of the formula (I) is used to build up an S1O2 network via condensation of the OH groups, attachment to melamine resin and matting agent.
  • the silane compound of the formula (II) binds to the melamine resin and matting agent via the functional groups.
  • the silane compound of the formula (III) enables a hydrophobic and oleophobic surface to be built up. In a polar medium, these functionalized silanes will align themselves to the air / layer interface and thus show an increased concentration on the surface.
  • the present composition can be added to coating or impregnating resins such as melamine resins and / or urea resins.
  • impregnation resins the present composition can be used after the core impregnation of paper layers (Decorative paper, overlay paper) is applied with the impregnating resins commonly used and intermediate drying on the top of the core-impregnated paper layer (impregnate).
  • the present composition can also be applied together or separately with a resin to a printed wood-based panel.
  • the use of the present composition offers several advantages. In this way, a matt surface with gloss points of less than 10, preferably less than 8, particularly preferably less than 5, can be produced.
  • the treated surface has anti-fingerprint properties and requires only little cleaning effort compared to conventional surfaces.
  • the hydrolyzable radical X is advantageously selected from a group containing H, OH, fluorine, chlorine, bromine, iodine, Ci- 6 -alkoxy, in particular methoxy, ethoxy, n-propoxy and butoxy, Ce-io-aryloxy, in particular phenoxy, C 2- acyloxy, especially acetoxy or propionoxy, C2-7-alkylcarbonyl, especially acetyl, monoalkylamino or dialkylamino with Ci to C12, especially Ci to C 6 .
  • the compound of the general formula (I) corresponds to the formula S1X 4 , where the radical X is OH or alkoxy, in particular methoxy, ethoxy, n-propoxy or i-propoxy.
  • the compounds tetramethoxysilane and tetraethoxysilane are particularly preferred.
  • the organic radical R 1 of the compound of the general formula (II) is preferably selected from a group comprising C 1 -C 3 o-alkyl, in particular C 5 -C 2 5 -alkyl, C 2 -C 6 -alkenyl, C 3 -C 8 - Cycloalkyl and C 3 -C 8 cycloalkenyl.
  • the organic R 1 is selected from the group comprising methyl, ethyl, n-propyl, isopropyl, n-butyl, s-butyl, t-butyl, pentyl, hexyl, cyclohexyl, vinyl, 1-propenyl, 2-propenyl , Butenyl, acetylenyl, propargyl, butadienyl or cyclohexadienyl, preferably methyl, ethyl, propyl or vinyl.
  • the at least one functional group Q 1 of the compound of the general formula (II) is selected from a group containing epoxy, hydroxy, ether, acrylic, acryloxy, methacrylic, methacryloxy, amino , Alkoxy, cyano and / or isocyano group.
  • the functional group Q 1 can therefore advantageously have a radical with a double bond or an epoxy group, which can be activated and polymerized by means of UV radiation.
  • compounds of the general formula (II) according to R 1 a SiX (4 a) , in particular R 1 SiX 3 , with a functional group Q1 can be selected from methacryloxypropyltrimethoxysilane (MPTS), aminoethyl aminopropyltrimethoxysilane, silanes with a Epoxy functionalization such as glycidyl oxypropyltriethoxysilane, or silanes with a vinyl functionalization such as vinyltrimethoxysilane.
  • MPTS methacryloxypropyltrimethoxysilane
  • aminoethyl aminopropyltrimethoxysilane aminoethyl aminopropyltrimethoxysilane
  • silanes with a Epoxy functionalization such as glycidyl oxypropyltriethoxysilane
  • silanes with a vinyl functionalization such as vinyltrimethoxysilane.
  • the radical R 1 can have at least one functional group Q 1 .
  • the R 1 radical can also be substituted by other radicals.
  • substituted in use with “alkyl”, “alkenyl”, “aryl”, etc., denotes the substitution of one or more atoms, usually H atoms, by one or more of the following substituents, preferably by one or two of the following substituents: halogen, hydroxy, protected hydroxy, oxo, protected oxo, C 3 -C 7 cycloalkyl, bicyclic alkyl, phenyl, naphthyl, amino, protected amino, monosubstituted amino, protected monosubstituted amino, disubstituted amino, guanidino, protected Guanidino, a heterocyclic ring, a substituted heterocyclic ring, imidazolyl, indolyl, pyrrolidinyl, CrCi 2 alkoxy, Ci-Ci 2 acyl, CrCi 2 acyloxy, acryloyloxy, nitro, carboxy, protected carboxy, carbamoyl,
  • alkynyl denotes a radical of the formula B-OXO-, in particular a “C 2 -C 6 alkynyl”.
  • Examples of C 2 -C 6 alkynyls include ethynyl, propynyl, 2-butynyl, 2-pentynyl, 3-pentynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, vinyl, and di- and triynes of straight lines and branched alkyl chains.
  • aryl denotes aromatic hydrocarbons, for example phenyl, benzyl, naphthyl, or anthryl.
  • Substituted aryl groups are aryl groups which, as defined above, are substituted with one or more substituents as defined above.
  • cycloalkyl includes the groups cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl and cycloheptyl.
  • the non-hydrolyzable organic radical R 2 of the compound according to the formula (III) is selected from a group comprising C1 -C15 alkyl, in particular C1 -C10 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl and C 6 -Cio aryl. These can be unsubstituted or substituted with a further hydrophobic group.
  • non-hydrolyzable organic radical R 2 of the compound of the general formula (III) is selected from the group comprising methyl, ethyl, n-propyl, isopropyl, n-butyl, s-butyl, t-butyl, pentyl , Hexyl, heptyl, octyl, nonyl, cyclohexyl, vinyl, 1 - propenyl, 2-propenyl, butenyl, acetylenyl, propargyl, phenyl and naphthyl. Methyl, ethyl, propyl, pentyl, octyl or phenyl radicals are particularly preferred.
  • non-hydrolyzable organic radical is to be understood in the context of the present invention as an organic radical which, in the presence of water, does not lead to the formation of an OH group or an NH 2 group linked to the Si atom.
  • the compound of the general formula (III) can in particular comprise one of the following formulas:
  • the present composition has at least one compound of the general formula (I), at least one compound of the general formula (II) and at least two compounds of the general formula (III).
  • it can also contain at least one compound of the general formula (I) and at least two, preferably at least three compounds of the general formula (II) and at least two, preferably at least three compounds of the general formula (III). Any combination is conceivable here.
  • the composition can contain tetraethoxysilane as the compound of the formula (I), glycidyloxypropyltriethoxysilane as the compound of the formula (II) and octyltriethoxysilane and pentyltriethoxysilane as the compounds of the formula (III).
  • the composition can contain tetraethoxysilane as the compound of the formula (I), glycidyloxypropyltriethoxysilane as the compound of the formula (II) and octyltriethoxysilane and tridecafluorooctyltriethoxysilane as the compounds of the formula (III).
  • the range of the molar amount given for the compound of the general compound (III) can relate to one compound or to the sum of two compounds or three compounds of the general formula (III).
  • the ratio of the silane compound of the formula (I) to the silane compounds of the formula (II) and (III) is preferably between 40/20/40.
  • the at least one matting agent comprises polymers and silica.
  • a possible matting agent is known, for example, under the name Deuteron MM 659, which is a composite of polyurethane, e.g. polyurethane balls and silica. It is important that the particle size distribution of the matting agent is appropriate for the application of the layer. Other materials such as pure silica particles such as Syloid 244, a synthetic, amorphous silica, or Tospeals (monodisperse polysiloxane particles) would also be possible.
  • the matting agent should not increase the viscosity too much. All of the particles mentioned here show a high level of light stability.
  • the present composition can contain inorganic particles, in particular Si0 2 , Al 2 0 3 , Zr0 2 , Ti0 2 particles.
  • the particles preferably used here have a size between 2 and 400 nm, preferably between 2 to 100 nm, particularly preferably between 2 to 50 nm.
  • the addition of the inorganic particles increases the solids content of the composition, which improves the application behavior of the composition.
  • the addition of inorganic particles also prevents shrinkage and cracking.
  • the inorganic Particles can be used in a quantity range of 0.1 to 25% by weight, preferably 5 to 20% by weight, based on the solids content of the silane material (sol-gel material).
  • a synthetic, amorphous SiO2 is known under the trade name SYLOID 244, for example.
  • the present composition is preferably used in aqueous form.
  • the present composition contains only alcohol and little or no water, i.e. the silane compounds can be used in an alcoholic form.
  • composition used herein can be prepared in a process comprising the following steps:
  • Inorganic and / or organic acids suitable as catalysts are selected from a group comprising phosphoric acid, acetic acid, p-toluenesulfonic acid, hydrochloric acid, formic acid or sulfuric acid.
  • Ammonium salts such as ammonium sulfate, which react as weak acids, are also suitable.
  • p-Toluenesulfonic acid is particularly preferred.
  • the method comprises the following steps:
  • an alcoholic aqueous suspension in particular an ethanolic aqueous suspension, containing at least one compound of the general formula (I), at least one compound of the general formula (II) and at least one, preferably two compounds of the general formula (III);
  • the inorganic particles are preferably used in an amount between 0.1 to 15% by weight, preferably 0.5 to 10% by weight, particularly preferably between 1 to 5% by weight.
  • Phenoxyethanol for example, can be used as the alcohol to be added to the aqueous mixture with the matting agent.
  • phenoxyethanol has a high flash point of 126 ° C, which is important for process reliability, also with regard to drying out too quickly.
  • Other alcohols are also technically possible.
  • an ether such as dipropylene glycol monomethyl ether can also be used in this process step.
  • Acetate such as n-butyl acetate
  • n-butyl acetate has shown itself to be very positive in terms of production time and subsequent stability in an aqueous medium.
  • 1-methoxy-2-propanol could also be used.
  • the aqueous suspension of the composition produced in this way can be stirred into aqueous resins of all kinds, e.g. formaldehyde resins such as melamine resins, and used to produce a matt and at the same time hydrophobic and oleophobic surface.
  • aqueous resins of all kinds e.g. formaldehyde resins such as melamine resins
  • At least one silicone-containing additive such as BYK-306, can be added as a leveling agent to the aqueous suspension. This additive reduces the surface tension and serves as a good mediator between the present composition with the silane compounds and an aqueous resin or water is used.
  • the recipe will be modified.
  • the silanes are provided in a suspension with a reduced water content (e.g. 10 g water and 80 g 1-methoxy-2-propanol) (other alcohols are also possible).
  • the composition in a resin suspension can be used to coat carrier materials, in particular paper layers, such as decorative paper layers or overlay paper layers, or in particular wood-based panels, such as medium-density fiber (MDF), high-density fiber (HDF) or coarse chipboard (OSB) panels, plywood panels or a Plastic composite panels (WPC) or stone-plastic composite panels (SPC) can be used.
  • carrier materials in particular paper layers, such as decorative paper layers or overlay paper layers, or in particular wood-based panels, such as medium-density fiber (MDF), high-density fiber (HDF) or coarse chipboard (OSB) panels, plywood panels or a Plastic composite panels (WPC) or stone-plastic composite panels (SPC) can be used.
  • paper layers such as decorative paper layers or overlay paper layers
  • wood-based panels such as medium-density fiber (MDF), high-density fiber (HDF) or coarse chipboard (OSB) panels, plywood panels or a Plastic composite panels (WPC) or stone-plastic composite panels (SPC)
  • the resin suspension is typically applied to a wood-based panel using rollers, and the resin suspension is applied to a layer of paper using a grid system,
  • wood-based panels are provided coated with the present composition and paper layers, preferably decorative paper layer or overlay paper layer, coated with the present composition, which have a reduced degree of gloss.
  • the surfaces of the wood-based panels and paper layers coated with the present composition have degrees of gloss of less than 10, preferably less than 8, particularly preferably less than 5. Gloss degrees of less than 4, for example 3.1, 3.4 or 3, can even be used , 8 can be achieved.
  • the present composition can be applied to a paper layer, with already impregnated paper layers (impregnates) being particularly preferred.
  • impregnated paper layers impregnates
  • the term “impregnation” is to be understood as meaning complete or partial impregnation of the paper layer with the resin.
  • Such impregnations can be applied, for example, in an impregnation bath, by rolling, by anilox rollers, by doctoring or also by spraying.
  • Overlay papers, decorative papers, or kraft papers are used as the paper layers.
  • Overlay papers are thin papers, which typically come with a conventional one Melamine resin have been impregnated.
  • Overlay papers are also available in which abrasion-resistant particles, such as corundum particles, are mixed into the resin of the overlay in order to increase the abrasion resistance.
  • Decor papers are special papers for the surface refinement of wood-based materials, which enable a wide variety of decorations. In addition to the typical imprints of various wooden structures, further imprints of geometric shapes or artistic products are available. There is in fact no restriction in the choice of motif. In order to ensure optimal printability, the paper used must have good smoothness and dimensional stability and also be suitable for penetration of a necessary synthetic resin impregnation.
  • Kraft papers have high strength and consist of cellulose fibers to which starch, alum and glue are added to achieve surface effects and increases in strength.
  • the paper layers are treated as follows: First, the back of the paper layer (e.g. in a soaking tub) is impregnated with a resin with a solids content between 50 and 70% by weight, preferably 60% by weight. After passing through a breathing section, immersion impregnation with a resin takes place. Excess resin is removed in a doctor blade system / squeegee roller pair, and abrasion-resistant particles are optionally scattered onto the impregnated paper layer. After a drying step, the resin suspension with a solids content between 50 and 70% by weight, preferably 55% by weight, comprising the matting composition according to the invention is then applied. Another drying step takes place to a residual moisture content of approx. 6%. The impregnate can then be pressed in the usual way with a wood-based panel, e.g. in a short-cycle press.
  • the composition is applied to a printed wood-based panel.
  • a wood-based panel or carrier plate is first provided with a resin primer on which at least one primer layer is applied.
  • the primer layer preferably used here comprises a composition of casein or soy protein as a binder and inorganic pigments, in particular inorganic color pigments.
  • White pigments such as titanium dioxide or other colored pigments such as calcium carbonate, barium sulfate or barium carbonate can be used as color pigments in the primer layer.
  • the primer can also contain water as a solvent. It is likewise preferred if the pigmented base layer applied consists of at least one, preferably of at least two, particularly preferably of at least four applied in succession Layers or orders, the order quantity between the layers or orders can be the same or different.
  • a primer layer is applied to the primer, preferably as a single application with subsequent drying.
  • the primer layer is particularly useful in the case of a subsequent gravure printing process (with rollers), whereas this is not absolutely necessary when using a digital printing process.
  • the amount of the applied liquid primer is between 10 and 30 g / m 2 , preferably between 15 and 20 g / m 2 .
  • Polyurethane-based compounds are preferably used as primers.
  • Rotogravure and digital printing processes are advantageously used as direct printing processes for printing the wood-based panel.
  • the first resin layer having a solids content between 60 and 80% by weight, preferably 65% by weight, and containing glass spheres as spacers;
  • the fourth resin layer having a solids content between 50 and 70% by weight, preferably 60% by weight;
  • glass spheres can be applied, which act as spacers.
  • the glass spheres that are preferably used have a diameter of 80-100 ⁇ m.
  • the amount of glass spheres is 10 to 50 g / m 2 , preferably 10 to 30 g / m 2 , particularly preferably 15 to 25 g / m 2 .
  • the approach preferably consists of approx. 40 kg of liquid resin plus glass beads and auxiliary materials.
  • the glass beads can also be present in silanized form. By silanizing the glass beads, the embedding of the glass beads in the resin matrix is improved.
  • abrasion-resistant particles such as corundum (aluminum oxide), boron carbide, silicon dioxide, silicon carbide particles can be sprinkled onto the wood-based panel.
  • Corundum particles are particularly preferred. This is preferably a high-grade corundum (white) with a high level of transparency, so that the visual effect of the underlying decoration is adversely affected as little as possible.
  • the amount of abrasion-resistant particles scattered on is 10 to 50 g / m 2 , preferably 10 to 30 g / m 2 , particularly preferably 15 to 25 g / m 2 .
  • the amount of abrasion-resistant particles scattered on depends on the abrasion class to be achieved and the grain size.
  • the amount of abrasion-resistant particles in the case of abrasion class AC3 is in the range between 10 to 15 g / m 2 , in abrasion class AC4 between 15 to 20 g / m 2 and in abrasion class AC5 between 20 to 35 g / m 2 when used the grit F200.
  • the finished panels preferably have abrasion class AC4.
  • Abrasion-resistant particles with grain sizes in classes F180 to F240, preferably F200, are used.
  • the grain size of class F180 covers a range from 53 - 90 ⁇ m, F220 from 45-75 mhi, F230 34-82 mhi, F240 28-70 mhi (FEPA standard).
  • white aluminum oxide F230 is used as the abrasion-resistant particles.
  • the resin layers are dried at dryer temperatures between 150 and 220 ° C., preferably between 180 and 210 ° C., in particular in a convection dryer.
  • the temperature is adapted to the respective resin layers and can vary in the individual convection dryers. Instead of convection dryers, however, other dryers can also be used.
  • the layer structure is pressed under the influence of pressure and temperature in a short-cycle press at temperatures between 150 and 250 ° C., preferably at 160 ° C. and a pressure between 30 and 60 kg / cm 2 .
  • the pressing time is between 10 and 20 seconds, preferably between 12 and 14 seconds.
  • the coated wood-based panel is aligned in the short-cycle press with a structured press plate located in the short-cycle press using markings on the wood-based panel, so that congruence between the decoration on the wood-based panel and the structure of the press panel to be embossed is produced.
  • a structured press plate located in the short-cycle press using markings on the wood-based panel, so that congruence between the decoration on the wood-based panel and the structure of the press panel to be embossed is produced.
  • This enables the creation of a decor-synchronous structure.
  • the melamine resin layers melt and a laminate is formed as a result of the condensation reaction.
  • Embodiment 1 a) Production of a first matting composition
  • the above formulation is modified for incorporation into acrylate, epoxy or urethane resins on an alcoholic basis or 100% systems.
  • the amount of water in the examples is replaced by 10 g of water and 80 g of 1-methoxy-2-propanol). Other alcohols are also possible.
  • the addition of the second amount of water (10 g) is retained.
  • the rotary evaporation step to remove the ethanol may now be omitted.
  • you could add a higher-boiling alcohol such as dipropylene glycol monomethyl ether and remove the lower-boiling alcohols, so that the flash point is raised further.
  • Embodiment 2 Application of the composition according to the invention to a decorative paper
  • a decorative paper (grammage: 80 g / m 2 ) is unrolled from an unwinder in an impregnation channel.
  • the decor paper is first placed in a soaking tub on the back with a Impregnated melamine resin.
  • the melamine resin has a solids content of approx. 60% by weight and contains the usual auxiliaries such as hardeners and wetting agents. Release agents, etc. After passing through the breathing path, immersion impregnation also takes place with a melamine resin.
  • the decorative paper runs through nip rollers in which the resin application is set to approx. 125 g liquid / m 2 .
  • the decor paper goes through a first flotation dryer in which the decor paper is dried to a residual moisture of 15-20%.
  • the upper side of the decorative paper is provided in a grid with a formulation of 100% by weight melamine resin (solids content: 55% by weight) and 95% by weight of the composition according to the invention (Inosil MM-32-x).
  • the amount applied was 50 g formulation / m 2 .
  • the impregnate is cut to size and stacked.
  • a press plate with a deckle structure was used.
  • Embodiment 3 Application of the composition according to the invention to an overlay paper
  • An overlay paper (grammage: 30 g / m 2 ) is unrolled from an unwinder in an impregnation channel.
  • the overlay paper is first impregnated on the back with a melamine resin in a soaking tub.
  • the melamine resin has a solids content of approx. 60% by weight and contains the usual auxiliaries such as hardeners and wetting agents. Release agents, etc.
  • immersion impregnation also takes place with a melamine resin.
  • the overlay paper runs through nip rollers in which the resin application is set to approx. 180 g liquid / m 2 .
  • the overlay paper is then sprinkled on top with about 20 g corundum / m 2 with the aid of a spreader (grain size: F230 according to the FEPA standard). Then this goes through Impregnate a first flotation dryer in which the overlay impregnate is dried to a residual moisture of 15-20%.
  • the back of the overlay paper is made in a grid with a formulation of 100% by weight melamine resin (solids content: 55% by weight) and 95% by weight of the composition according to the invention (Inosil MM-32-x).
  • the amount applied was 50 g formulation / m 2 . It is again dried in a flotation dryer. The residual moisture was then 6.0%.
  • the impregnate is cut to size and stacked. Then the pallet with the impregnates is turned (bottom side up). The impregnate was then pressed in a short-cycle press. The following structure was used: overlay impregnate - decor impregnate - HDF (fibreboard with increased bulk density) - counter-tension impregnate.
  • the impregnates are standard products that can be procured from contract impregnators for this application.
  • Embodiment 4 Application of the composition according to the invention to a wood-based panel
  • An HDF (format: 2800 x 2070 x 7 mm) is first primed with a melamine resin in a direct printing line (application quantity: approx. 20 g melamine resin liquid / m 2 , solids content: approx. 65% by weight).
  • the resin is dried in a circulating air dryer and then a colored primer consisting of titanium dioxide and casein is applied. This colored primer is applied up to seven times. The amount to be applied is 5 - 10 g of primer per application. Intermediate drying is carried out after each application with the aid of a circulating air and / or IR dryer. Then a primer is applied (Application quantity 10 - 20 g fl / m 2 ). This is also dried. A decoration is then printed onto this primer using the gravure or digital printing process.
  • a cover layer made of melamine resin is then applied (application quantity: 10-30 g melamine resin fluid / m 2 , solids content: 65% by weight).
  • the melamine resin contains glass spheres (diameter glass spheres: 80-100 gm, application quantity: 5 g glass spheres / m 2 ) as spacers.
  • the plates in turn pass through a dryer. Then they are cooled in a paternoster.
  • the panels are then coated on the upper side with melamine resin (application quantity: 60 g melamine resin fl./m 2 , solids: 65% by weight) on a production line.
  • melamine resin application quantity: 60 g melamine resin fl./m 2 , solids: 65% by weight
  • a melamine resin is applied to the back in the same amount as a counterbalance, also with the help of a roller.
  • corundum is sprinkled onto the top of the plate ( amount applied: 20 g corundum / m 2 , grain size: F230 according to the FEPA standard).
  • the structure is dried in a dryer with the help of IR radiators or circulating air.
  • 30 g of melamine resin fl./m 2 solids content: 60% by weight
  • Intermediate drying takes place after each application.
  • a formulation of 100% by weight of melamine resin (solids content: 55% by weight) and 95% by weight of the composition according to the invention (Inosil MM-32-x) is applied.
  • the amount applied was 50 g formulation / m 2 .
  • the plates are dried in a circulating air dryer.
  • a press plate with a deckle structure was used.
  • test area must be distinguished from the surrounding area when viewed from different directions, e.g. distance, gloss and color changes, there is no noticeable change in the surface
  • the coating has flaked off along the cut edges and / or at the intersections of the grid lines, flaked area greater than 5% but not greater than 15% of the cross-cut area
  • the coating has partially or completely flaked off along the cut edges and / or some squares have partially or completely flaked off, the flaked area is greater than 15% but not greater than 35% of the cross-cut area

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La présente invention concerne une suspension de résine à base d'une résine de formaldéhyde comprenant une composition pour le matage et la réduction des effets anti-empreintes de surfaces sur des matériaux support, en particulier des couches de papier et des panneaux en matériau dérivé du bois, la composition comprenant des composés silane et au moins un agent de matage. L'invention concerne en outre un procédé de fabrication de cette composition, l'utilisation de cette composition ainsi que des matériaux support, tels que des couches de papier ou des panneaux en matériau dérivé du bois, contenant cette composition.
EP21725967.0A 2020-04-30 2021-04-27 Composition pour le matage et la réduction des effets anti-empreintes de surfaces sur des matériaux support Pending EP4143263A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP20172323.6A EP3904463A1 (fr) 2020-04-30 2020-04-30 Composition permettant de matage et de réduction des effets anti-empreintes des surfaces sur des matières porteuses
PCT/EP2021/060988 WO2021219640A1 (fr) 2020-04-30 2021-04-27 Composition pour le matage et la réduction des effets anti-empreintes de surfaces sur des matériaux support

Publications (1)

Publication Number Publication Date
EP4143263A1 true EP4143263A1 (fr) 2023-03-08

Family

ID=70482329

Family Applications (2)

Application Number Title Priority Date Filing Date
EP20172323.6A Pending EP3904463A1 (fr) 2020-04-30 2020-04-30 Composition permettant de matage et de réduction des effets anti-empreintes des surfaces sur des matières porteuses
EP21725967.0A Pending EP4143263A1 (fr) 2020-04-30 2021-04-27 Composition pour le matage et la réduction des effets anti-empreintes de surfaces sur des matériaux support

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP20172323.6A Pending EP3904463A1 (fr) 2020-04-30 2020-04-30 Composition permettant de matage et de réduction des effets anti-empreintes des surfaces sur des matières porteuses

Country Status (4)

Country Link
US (1) US20230174791A1 (fr)
EP (2) EP3904463A1 (fr)
CN (1) CN115485339B (fr)
WO (1) WO2021219640A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4382576A1 (fr) * 2022-12-05 2024-06-12 Flooring Technologies Ltd. Composition pour le scellement et le revêtement des bords et/ou des chanfreins de panneaux en bois
EP4417750A1 (fr) * 2023-02-17 2024-08-21 Flooring Technologies Ltd. Procédé de préparation d'un matériau composite exempt de résine mélamine-formaldéhyde
WO2024206607A1 (fr) * 2023-03-28 2024-10-03 Henkel Ag & Co. Kgaa Revêtements anti-empreintes digitales non fluorés

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005052939A1 (de) * 2005-11-03 2007-05-10 Degussa Gmbh Herstellung von beschichteten Substraten
DE102007008468A1 (de) * 2007-02-19 2008-08-21 Clariant International Ltd. Laminate enthaltend Metalloxid-Nanopartikel
KR101043527B1 (ko) * 2007-12-05 2011-06-23 엘지전자 주식회사 내지문 코팅층을 갖는 가전제품의 스테인리스 스틸 외부 케이스
DE102008041920A1 (de) * 2008-09-09 2010-03-11 Evonik Degussa Gmbh Neue Katalysatoren für die Vernetzung von funktionellen Silanen oder funktionellen Siloxanen, insbesondere mit Substraten
JP5293534B2 (ja) * 2009-09-25 2013-09-18 パナソニック株式会社 耐指紋性塗膜形成品及び耐指紋性コーティング材組成物
PL2447332T3 (pl) * 2010-10-27 2014-06-30 SWISS KRONO Tec AG Klej hybrydowy i jego zastosowanie w płytach drewnopochodnych
KR101800743B1 (ko) * 2011-01-10 2017-11-24 삼성전자주식회사 지문 돋보임 방지 피막용 조성물, 상기 조성물을 이용한 지문 돋보임 방지 피막, 및 상기 피막을 포함하는 물품
DE102011084183A1 (de) * 2011-03-25 2012-09-27 Evonik Degussa Gmbh Wässrige Korrosionsschutzformulierung auf Silanebasis
US20160032146A1 (en) * 2013-03-08 2016-02-04 National Institute Of Advanced Industrial Science And Technology Organic/inorganic transparent hybrid films and a process for producing the same
KR101384424B1 (ko) * 2013-12-20 2014-04-14 김병만 지문 방지 코팅액 조성물 및 그 제조방법과 지문 방지 코팅액 제조용 중공체 입자의 제조방법
CN105482574B (zh) * 2014-10-13 2017-08-25 立邦工业涂料(上海)有限公司 一种氟碳自清洁涂料及制备方法
EP3020524B1 (fr) * 2014-11-13 2018-10-31 SWISS KRONO Tec AG Procédé de fabrication de panneaux en bois, notamment de panneaux en bois OSB, et panneaux en bois pouvant être fabriqués selon ce procédé
PT3231596T (pt) * 2016-04-12 2019-01-17 SWISS KRONO Tec AG Material de suporte com camada de resina modificada e preparação do mesmo
PL3231519T3 (pl) * 2016-04-12 2020-06-01 Flooring Technologies Ltd. Płyta drewnopochodna ze zmodyfikowaną warstwą żywiczną i sposób jej produkcji
PT3597706T (pt) * 2018-07-16 2020-10-30 Flooring Technologies Ltd Composição para o revestimento e vedação de bordos de placas de fibras de madeira

Also Published As

Publication number Publication date
CN115485339A (zh) 2022-12-16
US20230174791A1 (en) 2023-06-08
WO2021219640A1 (fr) 2021-11-04
CN115485339B (zh) 2023-11-28
EP3904463A1 (fr) 2021-11-03

Similar Documents

Publication Publication Date Title
DE102005006599B4 (de) Holzwerkstoffplatte mit einer mindestens abschnittweise aufgetragenen Oberflächenbeschichtung
EP4143263A1 (fr) Composition pour le matage et la réduction des effets anti-empreintes de surfaces sur des matériaux support
EP1549511B8 (fr) Pellicule de revetement decorative en forme de feuille ou de bande et procede de fabrication
EP3442791B1 (fr) Un matériau de support avec une couche de résine modifiée, et sa production.
WO2014075804A1 (fr) Matière de surface pour le revêtement de stratifiés en résine de mélamine
EP2920232B1 (fr) Matière de surface pour le revêtement de stratifiés en résine de mélamine
AT405265B (de) Dekorlaminat und verfahren zu seiner herstellung
EP3351682B1 (fr) Matiere en couche destine au revetement d'un materiau en bois en forme de plaque et procede de fabrication de la matiere en couche
EP2219883B1 (fr) Plaque composite multicouche
EP1319524B1 (fr) Feuilles décoratives à haute dureté de surface et à résistance améliorée à la rayure et à l'abrasion, ainsi que leur procédé de fabrication
DE102013002457A1 (de) Abriebfestes Oberflächenmaterial
EP2730430B1 (fr) Procédé de traitement d'un panneau de matière dérivée du bois et panneau de construction avec un noyau à base de matière dérivée du bois
EP3964553B1 (fr) Procédé de fabrication d'un support pourvu d'un revêtement antiviral
EP3718768B1 (fr) Imprégnat aux propriétés antistatiques
WO2009133144A1 (fr) Stratifié et son procédé de fabrication
EP3878648B1 (fr) Matériau composite doté d'un film thermoplastique destiné à être utilisé dans un panneau de plancher et son procédé de fabrication
EP3013581B1 (fr) Stratifié comportant un revêtement contenant de la résine aminoplaste
EP3049570B1 (fr) Dispersion servant à produire des surfaces résistantes à l'abrasion
WO2024170681A1 (fr) Procédé de fabrication d'un matériau composite exempt de résine de mélamine-formaldéhyde
DE202007017966U1 (de) Mehrschichtiger Verbundwerkstoff

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: UNKNOWN

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20221128

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)