EP4137535A1 - Procédé de fabrication d'un polymère superabsorbant - Google Patents

Procédé de fabrication d'un polymère superabsorbant Download PDF

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Publication number
EP4137535A1
EP4137535A1 EP21900895.0A EP21900895A EP4137535A1 EP 4137535 A1 EP4137535 A1 EP 4137535A1 EP 21900895 A EP21900895 A EP 21900895A EP 4137535 A1 EP4137535 A1 EP 4137535A1
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EP
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Prior art keywords
polymer
water
superabsorbent polymer
chemical formula
surface crosslinking
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EP21900895.0A
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German (de)
English (en)
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EP4137535A4 (fr
Inventor
Ji Hong Min
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LG Chem Ltd
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LG Chem Ltd
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Priority claimed from KR1020210159519A external-priority patent/KR20220077867A/ko
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Publication of EP4137535A1 publication Critical patent/EP4137535A1/fr
Publication of EP4137535A4 publication Critical patent/EP4137535A4/fr
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/075—Macromolecular gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/265—Synthetic macromolecular compounds modified or post-treated polymers
    • B01J20/267—Cross-linked polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/008—Treatment of solid polymer wetted by water or organic solvents, e.g. coagulum, filter cakes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/26—Treatment of polymers prepared in bulk also solid polymers or polymer melts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/245—Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/68—Superabsorbents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2305/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2301/00 or C08J2303/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof

Definitions

  • the present invention relates to a method of preparing a superabsorbent polymer, in which an interpenetrating polymer network (IPN) is formed on the surface of the superabsorbent polymer.
  • IPN interpenetrating polymer network
  • a superabsorbent polymer is a synthetic polymeric material capable of absorbing moisture from 500 to 1000 times its own weight.
  • SAM Super Absorbency Material
  • AGM Absorbent Gel Material
  • SAM Super Absorbency Material
  • AGM Absorbent Gel Material
  • these superabsorbent polymers have been widely used in the field of hygienic materials such as diapers, sanitary pads, etc.
  • the superabsorbent polymer is generally contained in a state of being spread in the pulp.
  • continuous efforts have been made to provide hygienic materials such as diapers having a thinner thickness.
  • pulpless diapers and the like in which the content of pulp is reduced or pulp is not used at all is being actively advanced.
  • a superabsorbent polymer is contained at a relatively high ratio and these superabsorbent polymer particles are inevitably contained in multiple layers in the hygienic materials.
  • the superabsorbent polymer In order for the whole superabsorbent polymer particles contained in the multiple layers to more efficiently absorb a liquid such as urine, etc., it is necessary for the superabsorbent polymer to basically exhibit high absorption performance and absorption rate. For this purpose, a method of crosslinking the surface of the superabsorbent polymer is used.
  • the surface crosslinking of the superabsorbent polymer is to form a surface-crosslinked layer by binding functional groups such as a carboxyl group, etc. present on the surface of the superabsorbent polymer, and this surface crosslinking may improve physical properties of the superabsorbent polymer.
  • the surface-crosslinked layer is formed by this method, the physical strength may increase, but the absorption rate of the superabsorbent polymer may decrease. Therefore, there is a need for a method of forming the surface-crosslinked layer without impairing the intrinsic physical properties of the superabsorbent polymer.
  • IPN interpenetrating polymer network
  • the method of preparing a superabsorbent polymer largely includes a step of carrying out a polymerization of a water-soluble ethylene-based unsaturated monomer to form a water-containing gel polymer, and a step of pulverizing the water-containing gel polymer. Further, to improve various physical properties of the superabsorbent polymer, a method of crosslinking the surface of the prepared superabsorbent polymer is used.
  • the surface crosslinking of the superabsorbent polymer is formed by binding functional groups with each other, such as hydroxyl groups, etc., which are present on the surface of the superabsorbent polymer. Since the functional groups present in the superabsorbent polymer are chemically reacted, some physical properties of the superabsorbent polymer may deteriorate.
  • the present invention instead of the functional groups such as hydroxyl groups, etc. present on the surface of the superabsorbent polymer, a new polymer chain is introduced as an interpenetrating polymer network (IPN) on the surface of the superabsorbent polymer to form a surface-crosslinked layer. Therefore, the present invention is characterized in that the surface-crosslinked layer is formed without deteriorating the intrinsic physical properties of the superabsorbent polymer, and consequently, various physical properties of the superabsorbent polymer are improved.
  • IPN interpenetrating polymer network
  • the step 1 is a step of preparing a water-containing gel polymer, and specifically, a step of forming a water-containing gel polymer by carrying out a crosslinking polymerization of a monomer composition including a water-soluble ethylene-based unsaturated monomer having acidic groups which are at least partially neutralized.
  • the water-soluble ethylene-based unsaturated monomer may be any monomer commonly used in the preparation of superabsorbent polymers. Specifically, the water-soluble ethylene-based unsaturated monomer may be a compound represented by the following Chemical Formula 2: [Chemical Formula 2] R 1 -COOM 1 in Chemical Formula 2,
  • the water-soluble ethylene-based unsaturated monomer may include one or more selected from the group consisting of acrylic acid, methacrylic acid, and a monovalent metal salt thereof, a divalent metal salt thereof, an ammonium salt thereof, and an organic amine salt thereof.
  • acrylic acid or a salt thereof is used as the water-soluble ethylene-based unsaturated monomer, it is advantageous in terms of obtaining a superabsorbent polymer having improved absorbency.
  • the monomer may include one or more selected from the group consisting of an anionic monomer such as maleic anhydride, fumaric acid, crotonic acid, itaconic acid, 2-acryloyl ethane sulfonic acid, 2-methacryloyl ethane sulfonic acid, 2-(meth)acryloyl propane sulfonic acid, or 2-(meth)acrylamide-2-methylpropane sulfonic acid, and a salt thereof; a nonionic hydrophilic monomer such as (meth)acrylamide, N-substituted (meth)acrylate, 2-hydroxyethyl(meth)acrylate, 2-hydroxypropyl(meth)acrylate, methoxypolyethyleneglycol(meth)acrylate, or polyethyleneglycol(meth)acrylate; and an unsaturated monomer containing an amino group such as (N,N)-dimethylaminoethyl(meth)acrylate or (N,N)
  • the water-soluble ethylene-based unsaturated monomer may have an acidic group, in which at least a part of the acidic group is neutralized.
  • an alkaline substance such as sodium hydroxide, potassium hydroxide, ammonium hydroxide or the like may be used as the monomer.
  • the degree of neutralization of the monomer may be 40 mol% to 95 mol%, or 40 mol% to 80 mol%, or 45 mol% to 75 mol%.
  • the range of the degree of neutralization may vary depending on the final physical properties. An excessively high degree of neutralization causes the neutralized monomers to be precipitated, and thus polymerization may not readily occur. On the contrary, an excessively low degree of neutralization not only deteriorates the absorbency of the polymer but also endows the polymer with hard-to-handle properties, like elastic rubber.
  • the monomer composition may include a polymerization initiator commonly used in the preparation of superabsorbent polymers.
  • a thermal polymerization initiator As the polymerization initiator, a thermal polymerization initiator, a photopolymerization initiator or the like may be used depending on the polymerization method. However, even in the case of the photopolymerization method, a certain amount of heat is generated by ultraviolet irradiation, etc., and a certain amount of heat is generated in accordance with the progression of the polymerization reaction, which is an exothermic reaction, and therefore, a thermal polymerization initiator may be further included.
  • the photopolymerization initiator may include, for example, one or more compounds selected from the group consisting of benzoin ether, dialkyl acetophenone, hydroxyl alkyl ketone, phenyl glyoxylate, benzyl dimethyl ketal, acyl phosphine, and ⁇ -aminoketone.
  • benzoin ether dialkyl acetophenone
  • hydroxyl alkyl ketone e.glyoxylate
  • benzyl dimethyl ketal e.glyoxylate
  • benzyl dimethyl ketal e.glyoxylate
  • benzyl dimethyl ketal e.glyoxylate
  • benzyl dimethyl ketal e.glyoxylate
  • benzyl dimethyl ketal e.glyoxylate
  • benzyl dimethyl ketal e.glyoxylate
  • benzyl dimethyl ketal e.glyoxylate
  • thermal polymerization initiator one or more compounds selected from the group consisting of a persulfate-based initiator, an azo-based initiator, hydrogen peroxide, and ascorbic acid may be used.
  • a persulfate-based initiator may include sodium persulfate (Na 2 S 2 O 8 ), potassium persulfate (K 2 S 2 O 8 ), ammonium persulfate ((NH 4 ) 2 S 2 O 8 ), etc.
  • examples of the azo-based initiator may include 2,2-azobis(2-amidinopropane)dihydrochloride, 2,2-azobis-(N,N-dimethylene)isobutyramidine dihydrochloride, 2-(carbamoylazo)isobutylonitrile, 2,2-azobis[2-(2-imidazolin-2-yl)propane]dihydrochloride, 4,4-azobis-(4-cyanovaleric acid), etc. More various thermal polymerization initiators are well disclosed in " Principle of Polymerization(Wiley, 1981)" written by Odian, p 203 , the content of which is incorporated herein by reference.
  • the polymerization initiator may be included at a concentration of about 0.001% by weight to about 1% by weight, or 0.005% by weight to about 0.1% by weight, based on the monomer composition.
  • concentration of the polymerization initiator when the concentration of the polymerization initiator is too low, the polymerization rate may become slow and a large amount of residual monomer may be extracted in the final product, which is not preferred.
  • concentration of the polymerization initiator is too high, polymer chains constituting the network become short, and thus the content of water-soluble components is increased and physical properties of the polymer may deteriorate, such as a reduction in absorbency under pressure, which is not preferred.
  • the polymerization of the monomer composition may be carried out in the presence of a crosslinking agent ("internal crosslinking agent") in order to improve physical properties of the polymer by polymerization of the water-soluble ethylene-based unsaturated monomer.
  • the crosslinking agent is used for internal crosslinking of the water-containing gel polymer, and may be used, separately from "a surface crosslinking agent” described below.
  • the internal crosslinking agent may be any compound, as long as it enables introduction of crosslinking during the polymerization of the water-soluble ethylene-based unsaturated monomer.
  • multifunctional crosslinking agents such as N,N'-methylenebisacrylamide, trimethylolpropane tri(meth)acrylate, ethylene glycol di(meth)acrylate, polyethylene glycol di(meth)acrylate, propylene glycol di(meth)acrylate, polypropylene glycol di(meth)acrylate, butanediol di(meth)acrylate, butylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, hexanediol di(meth)acrylate, triethylene glycol di(meth)acrylate, tripropylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, dipentaerythritol pentaacrylate, g
  • the internal crosslinking agent may be added at a concentration of 0.001 % by weight to 1% by weight, or 0.01 % by weight to 0.8% by weight, or 0.1% by weight to 0.7% by weight, based on the monomer composition.
  • concentration of the internal crosslinking agent when the concentration of the internal crosslinking agent is too low, the absorption rate of the polymer is lowered and gel strength may become weak, which is not preferred.
  • concentration of the internal crosslinking agent is too high, the absorption capacity of the polymer is lowered, which is not preferred for an absorbent.
  • crosslinking polymerization of the monomer composition may be carried out in the presence of a foaming agent, depending on the need and degree of improvement of the absorption rate.
  • This foaming agent is decomposed during the crosslinking polymerization reaction to generate gas, and therefore, pores may be formed inside the water-containing gel polymer.
  • a foaming agent is additionally used, a more developed porous structure is formed inside the superabsorbent polymer, and the absorption rate of the superabsorbent polymer may be further improved.
  • Non-limiting examples of the foaming agent may include one or more compounds selected from the group consisting of sodium bicarbonate, sodium carbonate, potassium bicarbonate, potassium carbonate, calcium bicarbonate, calcium carbonate, magnesium bicarbonate, magnesium carbonate, azodicarbonamide (ADCA), dinitroso pentamethylene tetramine (DPT), p,p'-oxybis(benzenesulfonyl hydrazide) (OBSH), p-toluenesulfonyl hydrazide (TSH), sucrose stearate, sucrose palmitate, and sucrose laurate.
  • ADCA azodicarbonamide
  • DPT dinitroso pentamethylene tetramine
  • OBSH p,p'-oxybis(benzenesulfonyl hydrazide)
  • TSH p-toluenesulfonyl hydrazide
  • sucrose stearate sucrose palmitate
  • sucrose laurate
  • the foaming agent may be preferably present in an amount of 1000 ppmw to 4000 ppmw, and more specifically, in an amount of 1000 ppm or more, or 1100 ppmw or more, or 1200 ppmw or more; and 4000 ppmw or less, or 3500 ppmw or less, or 3000 ppmw or less in the monomer composition.
  • the monomer composition may further include additives such as a thickener, a plasticizer, a preservation stabilizer, an antioxidant, etc., as needed.
  • additives such as a thickener, a plasticizer, a preservation stabilizer, an antioxidant, etc., as needed.
  • Such monomer composition may be prepared in the form of a solution in which raw materials, such as the above-described water-soluble ethylene-based unsaturated monomer, polymerization initiator, internal crosslinking agent, foaming agent, etc., are dissolved in a solvent.
  • any solvent may be used without limitations in the constitution as long as it is able to dissolve the above raw materials.
  • the solvent water, ethanol, ethylene glycol, diethylene glycol, triethylene glycol, 1,4-butanediol, propylene glycol, ethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, methyl ethyl ketone, acetone, methyl amyl ketone, cyclohexanone, cyclopentanone, diethylene glycol monomethyl ether, diethylene glycol ethylether, toluene, xylene, butyrolactone, carbitol, methyl cellosolve acetate, N,N-dimethylacetamide, or a mixture thereof may be used.
  • Formation of the water-containing gel polymer through polymerization of the monomer composition may be carried out by a common polymerization method, and a process thereof is not particularly limited.
  • the polymerization method is largely classified into thermal polymerization and photopolymerization according to a polymerization energy source.
  • the thermal polymerization may be carried out in a reactor like a kneader equipped with agitating spindles.
  • the photopolymerization may be carried out in a reactor equipped with a movable conveyor belt.
  • the monomer composition is injected to the reactor like the kneader equipped with the agitating spindles, and thermal polymerization is carried out by providing hot air thereto or by heating the reactor, thereby obtaining the water-containing gel polymer.
  • the water-containing gel polymer may be obtained as particles having a size of centimeters or millimeters when it is discharged from an outlet of the reactor, according to the type of agitating spindles equipped in the reactor.
  • the water-containing gel polymer may be obtained in various forms according to a concentration of the monomer composition fed thereto, a feeding speed or the like, and the water-containing gel polymer having a (weight average) particle size of 2 mm to 50 mm may be generally obtained.
  • the water-containing gel polymer may be obtained in a sheet-type.
  • the thickness of the sheet may vary according to the concentration of the monomer composition fed thereto and the feeding speed.
  • the sheet is preferably controlled to have a thickness of 0.5 cm to 10 cm in order to assure the production speed while allowing the entire sheet to be uniformly polymerized.
  • the water-containing gel polymer formed by the method may exhibit a water content of 40% by weight to 80% by weight.
  • the water content means a weight occupied by water with respect to the total weight of the water-containing gel polymer, which may be a value obtained by subtracting the weight of the dried polymer from the weight of the water-containing gel polymer.
  • the water content may be defined as a value calculated by measuring the weight loss due to evaporation of moisture in the polymer during the process of drying by raising the temperature of the polymer through infrared heating.
  • the drying conditions may be determined as follows: the drying temperature is increased from room temperature to about 180°C and then the temperature is maintained at 180°C, and the total drying time is set to 20 minutes, including 5 minutes for the temperature rising step.
  • the step 2 of the present invention is a step of gel-pulverizing the water-containing gel polymer prepared in the previous step 1.
  • the pulverizing may increase the drying efficiency of the water-containing gel polymer, and may also influence morphology of the superabsorbent polymer, thereby influencing various physical properties of the superabsorbent polymer, such as absorption rate.
  • the present invention includes a step of pulverizing the water-containing gel polymer before drying. In order to distinguish this pulverizing from the pulverizing of the step 4 to be described below, it may be referred to as the term 'coarsely pulverizing' for convenience in the present invention.
  • a pulverizer used for the pulverizing is not limited by its configuration, and specifically, it may include any one selected from the group consisting of a vertical pulverizer, a turbo cutter, a turbo grinder, a rotary cutter mill, a cutter mill, a disc mill, a shred crusher, a crusher, a chopper, and a disc cutter, but is not limited to the above-described examples.
  • the step of coarsely pulverizing may be carried out such that a particle size of the water-containing gel polymer becomes about 2 mm to about 10 mm. Pulverizing of the water-containing gel polymer into a particle size of less than 2 mm is not technically easy due to its high water content, and an agglomeration phenomenon between the pulverized particles may occur. Meanwhile, when the polymer is pulverized into a particle size of greater than 10 mm, the effect of increasing the efficiency in the subsequent step of drying may be insignificant.
  • the step 3 of the present invention is a step of drying, pulverizing, and size-sorting the gel-pulverized water-containing gel polymer of the step 2 to form a base polymer powder.
  • the drying may be carried out at a temperature of 120°C to 250°C, or 140°C to 200°C, or 150°C to 190°C.
  • the drying temperature may be defined as a temperature of a heating medium provided for drying, or an internal temperature of a drying reactor including the heating medium and the polymer during the drying process. If the drying temperature is low, and therefore, the drying time becomes long, the process efficiency may be decreased. In order to prevent this problem, the drying temperature is preferably 120°C or higher. In addition, when the drying temperature is higher than necessary, the surface of the water-containing gel polymer is excessively dried, and thus there is a concern about generation of fine particles during the subsequent pulverization process and deterioration of the physical properties of a final polymer. In order to prevent this problem, therefore, the drying temperature is preferably 250°C or lower.
  • the drying time in the drying step is not particularly limited, but may be controlled to 20 minutes to 90 minutes at the above drying temperature, in view of process efficiency and physical properties of the polymer.
  • the drying may be carried out by using a general medium, and for example, the pulverized water-containing gel polymer may be supplied with hot air, or irradiated with infrared rays, microwaves, ultraviolet rays, or the like.
  • the drying as above is performed such that the dried polymer may preferably have the water content of about 0.1% by weight to about 10% by weight.
  • the water content of the dried polymer is less than 0.1% by weight, production costs may be increased and degradation of the crosslinked polymer may undesirably occur due to excessive drying.
  • the water content of the dried polymer is more than 10% by weight, defects may occur in the subsequent process, which is not preferred.
  • the dried water-containing gel polymer may be pulverized. This is a step of optimizing the surface area of the base polymer powder and the superabsorbent polymer.
  • the pulverization may be carried out such that the particle size of the pulverized polymer is 150 ⁇ m to 850 ⁇ m.
  • a pulverizer applicable herein may include a pin mill, a hammer mill, a screw mill, a roll mill, a disc mill, a jog mill, or the like which is commonly used.
  • a step of selectively size-sorting particles having a particle size of 150 ⁇ m to 850 ⁇ m from the polymer particles obtained through the pulverization step may be further carried out.
  • the base polymer powder may be obtained through the above-described size-sorting process.
  • the base polymer powder thus obtained may have a particle size of 150 ⁇ m to 850 ⁇ m, and may include fine powder having a particle size of less than 150 ⁇ m in an amount of 2% by weight or less, or 1% by weight or less.
  • the step 4 of the present invention is a step of reacting the base polymer powder prepared in the step 3 with a surface crosslinking solution to form an interpenetrating polymer network on the surface of the base polymer powder.
  • the present invention is characterized by forming an interpenetrating polymer network (IPN) on the surface of the superabsorbent polymer.
  • IPN interpenetrating polymer network
  • the surface crosslinking solution is characterized by including a monomer having an amine group and a compound represented by Chemical Formula 1.
  • the compound represented by Chemical Formula 1 includes an aldehyde group in its chemical structure, and thus it is reacted with the monomer having an amine group on the surface of the base polymer powder to form an interpenetrating polymer network, and consequently, a surface-crosslinked layer may be formed.
  • the monomer having an amine group is chitosan, or cyclodextrin.
  • the cyclodextrin means that the amine group is substituted.
  • a solvent of the surface crosslinking solution may be water, methanol, cyclohexane, or a combination thereof, and most preferably, water may be used.
  • the solvent may be used in an amount of 5 parts by weight to 50 parts by weight, based on 100 parts by weight of the base polymer powder.
  • pH of the surface crosslinking solution is 1 to 3.
  • the reaction of chitosan and the compound represented by Chemical Formula 1 may be effectively induced.
  • the pH may be adjusted using an acidic material without limitation. For example, hydrochloric acid, sulfuric acid, etc. may be used.
  • a concentration of chitosan in the surface crosslinking solution is 1 N to 10 N.
  • a concentration of the compound represented by Chemical Formula 1 is preferably 1 N to 10 N.
  • a weight ratio of the chitosan and the compound represented by Chemical Formula 1 in the surface crosslinking solution is 1:1 to 5:1, and more preferably 1:1 to 3:1.
  • n in Chemical Formula 1 is 2 to 4. More preferably, n in Chemical Formula 1 is 3.
  • the compound represented by Chemical Formula 1 is preferably glutaraldehyde.
  • the surface crosslinking solution may include an inorganic filler.
  • the inorganic filler may include silica, aluminum oxide, or silicate.
  • the inorganic filler may be included in an amount of 0.01 part by weight to 0.5 parts by weight, based on 100 parts by weight of the base polymer powder.
  • the surface crosslinking solution may further include a thickener.
  • a thickener one or more selected from polysaccharides and a hydroxy-containing polymers may be used.
  • the polysaccharides may include gum-type thickeners, cellulose-type thickeners, etc.
  • Specific examples of the gum-type thickeners include xanthan gum, arabic gum, karaya gum, tragacanth gum, ghatti gum, guar gum, locust bean gum, psyllium seed gum, etc.
  • cellulose-type thickeners include hydroxypropylmethyl cellulose, carboxymethyl cellulose, methylcellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxyethylmethyl cellulose, hydroxymethylpropyl cellulose, hydroxyethylhydroxypropyl cellulose, ethylhydroxyethyl cellulose, methylhydroxypropyl cellulose, etc.
  • hydroxy-containing polymer may include polyethylene glycol, polyvinyl alcohol, etc.
  • a method of placing the surface crosslinking solution and the base polymer in a reaction tank and mixing them, a method of spraying the surface crosslinking solution onto the base polymer, a method of mixing the base polymer and the surface crosslinking solution while continuously feeding them to a mixer which is continuously operated, etc. may be used.
  • the step 4 may be carried out at a temperature of 20°C to 90°C. Further, the step 4 may be carried out for 10 minutes to 24 hours.
  • the present invention provides a superabsorbent polymer prepared according to the above-described preparation method of the present invention.
  • the superabsorbent polymer includes a base polymer powder including a crosslinked polymer of a water-soluble ethylene-based unsaturated monomer having acidic groups which are at least partially neutralized; and a surface-crosslinked layer which is formed on the base polymer powder and includes an interpenetrating polymer network. Further, the superabsorbent polymer is obtained as particles having a particle size of 150 ⁇ m to 850 ⁇ m.
  • the superabsorbent polymer has excellent CRC and gel strength.
  • CRC Chiptrifugal Retention Capacity
  • water retention capacity refers to an amount of a solution absorbed under no load.
  • the CRC may be measured in accordance with EDANA WSP 241.3, and a specific measurement method will be described in Example below.
  • CRC of the superabsorbent polymer is 30 g/g to 40 g/g.
  • CRC of the superabsorbent polymer is 30.5 g/g or more, 31.0 g/g or more, 31.5 g/g or more, or 32.0 g/g or more, and 39 g/g or less, 38 g/g or less, 37 g/g or less, 36 g/g or less, or 35 g/g or less.
  • the term "gel strength" refers to a degree to which absorbency and water retention capacity of the superabsorbent polymer are maintained even under an external pressure, in other words, a degree to which the superabsorbent polymer maintains its shape well even after absorbing water. A specific method of measuring the gel strength will be described in Example below.
  • the gel strength of the superabsorbent polymer is 1.50 N to 3.00 N.
  • the gel strength of the superabsorbent polymer is 1.55 N or more, 1.60 N or more, 1.65 N or more, or 1.70 N or more, and 2.90 N or less, 2.80 N or less, 2.70 N or less, 2.60 N or less, 2.50 N or less, 2.40 N or less, 2.30 N or less, 2.20 N or less, 2.10 N or less, or 2.00 N or less.
  • a method of preparing a superabsorbent polymer according to the present invention is characterized in that an interpenetrating polymer network is formed on the surface of the superabsorbent polymer during formation of a surface-crosslinked layer of the superabsorbent polymer, thereby improving physical properties of the superabsorbent polymer.
  • the solution was poured in a tray (15 cm in width x 15 cm in length) installed in a square polymerizer which had a UV irradiation device installed at the top and was preheated to 80°C, and polymerization was initiated by UV irradiation.
  • a sheet-type polymer thus prepared was cut in a size of 5 cm x 5 cm, and then injected to a meat chopper to pulverize the polymer.
  • water-containing particles having a size of 1 mm to 10 mm were obtained.
  • the crumbs were dried in an oven capable of shifting airflow up and down.
  • the crumbs were uniformly dried by flowing hot air at 180°C or higher from the bottom to the top for 15 minutes and from the top to the bottom for 15 minutes.
  • the dried product had a water content of 2% or less.
  • the product was pulverized using a pulverizer and sorted by size, and a size of about 150 to about 850 ⁇ m was selected to prepare a base polymer.
  • Chitosan (0.05 g) and glutaraldehyde (0.025 mL) were added to a 0.1 N HCl aqueous solution (10 ml), and stirred to prepare a surface crosslinking solution.
  • the surface crosslinking solution was sprayed onto 100 g of the base polymer prepared in Preparation Example, and uniformly mixed, and then a reaction was allowed at 25°C for 40 minutes to prepare a superabsorbent polymer.
  • Each superabsorbent polymer was prepared in the same manner as in Example 1, except that the composition of the surface crosslinking solution was changed as in Table 1, below.
  • each polymer size-sorted using #30-50 sieve was obtained.
  • Each polymer W 0 (g) (about 2.0 g) was uniformly placed into a nonwoven-fabric-made bag, followed by sealing. Then, the bag was immersed in a physiological saline solution (0.9% by weight) at room temperature. After 30 minutes, the bag was drained at 250 G for 3 minutes with a centrifuge, and the weight W 2 (g) of the bag was then measured. Further, the same procedure was carried out using no polymer, and the resultant weight W 1 (g) was measured.
  • CRC (g/g) was calculated from the obtained weights according to the following Equation:
  • CRC g / g W 2 g ⁇ W 1 g / W 0 g ⁇ 1
  • each polymer size-sorted using #30-50 sieve was obtained, and 1 g thereof was weighed.
  • the weighed samples were sufficiently immersed and swelled in 100 g of a physiological saline solution for 1 hour. Thereafter, the solvent not absorbed therein was removed by using an aspirator for 4 minutes, and the solvent left on the surface of the same was evenly distributed and wiped once with a filter paper.
  • 2.5 g of the swelled superabsorbent polymer was positioned between two plates (a diameter of 25 mm, with a wall of about 2 mm at the bottom for preventing the sample from leaking) of a rheometer, and the gap between the two plates was adjusted to 1 mm (At this time, when the sample is hard and thus it is difficult to adjust the gap to 1 mm, the gap between the plates was properly adjusted by pressing the plates with a force of about 3 N such that the swelled superabsorbent polymer sample was contacted evenly at the face of the plates).
  • the superabsorbent polymers of Examples 1 to 4 according to the present invention showed the similar levels of CRC, but showed the increased gel strength, as compared with the superabsorbent polymers of Comparative Examples 1 and 2.
  • the superabsorbent polymers of Comparative Examples 1 and 2 also had the surface-crosslinked layer of a network structure by surface crosslinking, but the superabsorbent polymers of Examples 1 to 4 according to the present invention had a structure in which, in addition to the network structure, additional crosslinking occurred, and thus another network structure was formed, thereby having the improved gel strength.

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EP21900895.0A 2020-12-02 2021-11-23 Procédé de fabrication d'un polymère superabsorbant Pending EP4137535A4 (fr)

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US6222091B1 (en) * 1997-11-19 2001-04-24 Basf Aktiengesellschaft Multicomponent superabsorbent gel particles
EP1140229B1 (fr) * 1998-12-16 2010-10-06 Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO Polysaccharides superabsorbants acides
US6998367B2 (en) * 2001-12-06 2006-02-14 Kimberly-Clark Worldwide, Inc. Absorbent composition containing transitional crosslinking points
JP2004285548A (ja) * 2003-01-30 2004-10-14 Toyobo Co Ltd 機能性繊維、その繊維構造物、および吸収性物品
WO2005097313A1 (fr) * 2004-03-31 2005-10-20 Nippon Shokubai Co., Ltd. Un agent absorbant de liquides aqueux et procédé pour la fabrication de celui-ci
KR20120066369A (ko) * 2010-12-14 2012-06-22 강원대학교산학협력단 글루타알데히드로 가교된 키토산 마이크로겔 및 그 제조방법
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