EP4125789A1 - Hair care compositions comprising polyol, c2-6 monoalcohol and cationic surfactant - Google Patents
Hair care compositions comprising polyol, c2-6 monoalcohol and cationic surfactantInfo
- Publication number
- EP4125789A1 EP4125789A1 EP21719011.5A EP21719011A EP4125789A1 EP 4125789 A1 EP4125789 A1 EP 4125789A1 EP 21719011 A EP21719011 A EP 21719011A EP 4125789 A1 EP4125789 A1 EP 4125789A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- hair
- fatty
- esters
- carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 344
- 229920005862 polyol Polymers 0.000 title claims abstract description 47
- 150000003077 polyols Chemical class 0.000 title claims abstract description 47
- 239000003093 cationic surfactant Substances 0.000 title claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 55
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 29
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 28
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims abstract description 27
- 150000001983 dialkylethers Chemical class 0.000 claims abstract description 26
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 21
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000839 emulsion Substances 0.000 claims abstract description 15
- 229960000541 cetyl alcohol Drugs 0.000 claims abstract description 11
- 229940043348 myristyl alcohol Drugs 0.000 claims abstract description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 63
- -1 cycohexanol Chemical compound 0.000 claims description 41
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 32
- 229920001577 copolymer Polymers 0.000 claims description 29
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- 229930006000 Sucrose Natural products 0.000 claims description 27
- 239000005720 sucrose Substances 0.000 claims description 27
- 150000002148 esters Chemical class 0.000 claims description 26
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 24
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 17
- 239000002562 thickening agent Substances 0.000 claims description 16
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 15
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 12
- 229920000058 polyacrylate Polymers 0.000 claims description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 10
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 239000000194 fatty acid Substances 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 10
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 10
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 10
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 9
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 9
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 8
- PKPOVTYZGGYDIJ-UHFFFAOYSA-N dioctyl carbonate Chemical compound CCCCCCCCOC(=O)OCCCCCCCC PKPOVTYZGGYDIJ-UHFFFAOYSA-N 0.000 claims description 8
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 8
- 229920000289 Polyquaternium Polymers 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 claims description 7
- 229940075506 behentrimonium chloride Drugs 0.000 claims description 7
- 229960002788 cetrimonium chloride Drugs 0.000 claims description 7
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 7
- 229920006037 cross link polymer Polymers 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical group CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 claims description 6
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 claims description 6
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 6
- 229940095077 behentrimonium methosulfate Drugs 0.000 claims description 6
- 230000003745 detangling effect Effects 0.000 claims description 6
- QIVLQXGSQSFTIF-UHFFFAOYSA-M docosyl(trimethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C QIVLQXGSQSFTIF-UHFFFAOYSA-M 0.000 claims description 6
- 229940051250 hexylene glycol Drugs 0.000 claims description 6
- 229940049292 n-(3-(dimethylamino)propyl)octadecanamide Drugs 0.000 claims description 6
- WWVIUVHFPSALDO-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C WWVIUVHFPSALDO-UHFFFAOYSA-N 0.000 claims description 6
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 5
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 5
- 229940035437 1,3-propanediol Drugs 0.000 claims description 5
- 229940043375 1,5-pentanediol Drugs 0.000 claims description 5
- AKLBQZCEYQQQPR-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O.CCC(C)(C)O AKLBQZCEYQQQPR-UHFFFAOYSA-N 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 5
- 229940035429 isobutyl alcohol Drugs 0.000 claims description 5
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- YLXASPMPBDPQLL-MURFETPASA-N (9z,12z)-n-[3-(dimethylamino)propyl]octadeca-9,12-dienamide Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(=O)NCCCN(C)C YLXASPMPBDPQLL-MURFETPASA-N 0.000 claims description 4
- UCWYGNTYSWIDSW-QXMHVHEDSA-N (z)-n-[3-(dimethylamino)propyl]octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCCN(C)C UCWYGNTYSWIDSW-QXMHVHEDSA-N 0.000 claims description 4
- WGTDLPBPQKAPMN-KTKRTIGZSA-N 2-[2-[(z)-heptadec-8-enyl]-4,5-dihydroimidazol-1-yl]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCC1=NCCN1CCO WGTDLPBPQKAPMN-KTKRTIGZSA-N 0.000 claims description 4
- DIJXCGXVGCADCI-UHFFFAOYSA-N 3-(docosanoylamino)propyl-trimethylazanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCCCCCC(=O)NCCC[N+](C)(C)C DIJXCGXVGCADCI-UHFFFAOYSA-N 0.000 claims description 4
- 229940069025 behenamidopropyltrimonium methosulfate Drugs 0.000 claims description 4
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 claims description 4
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 4
- 229940073551 distearyldimonium chloride Drugs 0.000 claims description 4
- 229940046306 linoleamidopropyl dimethylamine Drugs 0.000 claims description 4
- KHPAAXRLVYMUHU-UHFFFAOYSA-N n-[2-(diethylamino)ethyl]docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCN(CC)CC KHPAAXRLVYMUHU-UHFFFAOYSA-N 0.000 claims description 4
- NZXVYLJKFYSEPO-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]-16-methylheptadecanamide Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)NCCCN(C)C NZXVYLJKFYSEPO-UHFFFAOYSA-N 0.000 claims description 4
- MNAZHGAWPCLLGX-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C MNAZHGAWPCLLGX-UHFFFAOYSA-N 0.000 claims description 4
- HJXPIPGLPXVLGN-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]icosanamide Chemical compound CCCCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C HJXPIPGLPXVLGN-UHFFFAOYSA-N 0.000 claims description 4
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 claims description 4
- FAGMGMRSURYROS-UHFFFAOYSA-M trihexadecyl(methyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(CCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCC FAGMGMRSURYROS-UHFFFAOYSA-M 0.000 claims description 4
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 claims description 4
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 claims description 3
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 claims description 3
- HANWHVWXFQSQGJ-UHFFFAOYSA-N 1-tetradecoxytetradecane Chemical compound CCCCCCCCCCCCCCOCCCCCCCCCCCCCC HANWHVWXFQSQGJ-UHFFFAOYSA-N 0.000 claims description 3
- YUDHLDPCTPRMRB-UHFFFAOYSA-N 4-propyldecan-4-yl hydrogen carbonate Chemical compound CCCCCCC(CCC)(CCC)OC(=O)O YUDHLDPCTPRMRB-UHFFFAOYSA-N 0.000 claims description 3
- QCDJXLSJVLOQDQ-UHFFFAOYSA-N 7-methyl-1-(7-methyloctoxy)octane Chemical compound CC(C)CCCCCCOCCCCCCC(C)C QCDJXLSJVLOQDQ-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 3
- PLQLENYNNIFMNL-UHFFFAOYSA-N [1-(3,5-dimethoxyphenyl)-2-oxo-2-phenylethyl] ethyl carbonate Chemical compound C=1C(OC)=CC(OC)=CC=1C(OC(=O)OCC)C(=O)C1=CC=CC=C1 PLQLENYNNIFMNL-UHFFFAOYSA-N 0.000 claims description 3
- PXTQQOLKZBLYDY-UHFFFAOYSA-N bis(2-ethylhexyl) carbonate Chemical compound CCCCC(CC)COC(=O)OCC(CC)CCCC PXTQQOLKZBLYDY-UHFFFAOYSA-N 0.000 claims description 3
- OKQDSOXFNBWWJL-UHFFFAOYSA-N dihexyl carbonate Chemical compound CCCCCCOC(=O)OCCCCCC OKQDSOXFNBWWJL-UHFFFAOYSA-N 0.000 claims description 3
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 3
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 claims description 3
- 229940085632 distearyl ether Drugs 0.000 claims description 3
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 150000002194 fatty esters Chemical class 0.000 claims description 2
- 150000004676 glycans Chemical class 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 229920001282 polysaccharide Polymers 0.000 claims description 2
- 239000005017 polysaccharide Substances 0.000 claims description 2
- 230000003648 hair appearance Effects 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 abstract description 18
- 239000002453 shampoo Substances 0.000 description 28
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 24
- 238000011282 treatment Methods 0.000 description 24
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 18
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 18
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 18
- 150000003839 salts Chemical class 0.000 description 18
- 229920002125 Sokalan® Polymers 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 14
- 235000010980 cellulose Nutrition 0.000 description 13
- 229920002678 cellulose Polymers 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 13
- 239000001913 cellulose Substances 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 5
- 150000007942 carboxylates Chemical class 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000002537 cosmetic Substances 0.000 description 5
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 5
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 5
- ZPVGIKNDGJGLCO-VGAMQAOUSA-N [(2s,3r,4s,5s,6r)-2-[(2s,3s,4s,5r)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] hexadecanoate Chemical group CCCCCCCCCCCCCCCC(=O)O[C@@]1([C@]2(CO)[C@H]([C@H](O)[C@@H](CO)O2)O)O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O ZPVGIKNDGJGLCO-VGAMQAOUSA-N 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 4
- 229920000591 gum Polymers 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 229940070765 laurate Drugs 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 238000012216 screening Methods 0.000 description 4
- 206010019049 Hair texture abnormal Diseases 0.000 description 3
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 229920000688 Poly[(2-ethyldimethylammonioethyl methacrylate ethyl sulfate)-co-(1-vinylpyrrolidone)] Polymers 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 150000001253 acrylic acids Chemical class 0.000 description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 description 3
- 229940071160 cocoate Drugs 0.000 description 3
- 229940100463 hexyl laurate Drugs 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229940117958 vinyl acetate Drugs 0.000 description 3
- HXQHFNIKBKZGRP-URPRIDOGSA-N (5Z,9Z,12Z)-octadecatrienoic acid Chemical compound CCCCC\C=C/C\C=C/CC\C=C/CCCC(O)=O HXQHFNIKBKZGRP-URPRIDOGSA-N 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical class CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 2
- IZHVBANLECCAGF-UHFFFAOYSA-N 2-hydroxy-3-(octadecanoyloxy)propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCCCCCC IZHVBANLECCAGF-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- JBYXPOFIGCOSSB-GOJKSUSPSA-N 9-cis,11-trans-octadecadienoic acid Chemical compound CCCCCC\C=C\C=C/CCCCCCCC(O)=O JBYXPOFIGCOSSB-GOJKSUSPSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 229920002148 Gellan gum Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 229920000161 Locust bean gum Polymers 0.000 description 2
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- CNVZJPUDSLNTQU-UHFFFAOYSA-N Petroselaidic acid Natural products CCCCCCCCCCCC=CCCCCC(O)=O CNVZJPUDSLNTQU-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- UWHZIFQPPBDJPM-FPLPWBNLSA-M Vaccenic acid Natural products CCCCCC\C=C/CCCCCCCCCC([O-])=O UWHZIFQPPBDJPM-FPLPWBNLSA-M 0.000 description 2
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- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- BEKZXQKGTDVSKX-UHFFFAOYSA-N propyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCC BEKZXQKGTDVSKX-UHFFFAOYSA-N 0.000 description 1
- DPBVJRXPSXTHOL-UHFFFAOYSA-N propyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCC DPBVJRXPSXTHOL-UHFFFAOYSA-N 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical compound CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 1
- DCBSHORRWZKAKO-UHFFFAOYSA-N rac-1-monomyristoylglycerol Chemical compound CCCCCCCCCCCCCC(=O)OCC(O)CO DCBSHORRWZKAKO-UHFFFAOYSA-N 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- JIWBIWFOSCKQMA-UHFFFAOYSA-N stearidonic acid Natural products CCC=CCC=CCC=CCC=CCCCCC(O)=O JIWBIWFOSCKQMA-UHFFFAOYSA-N 0.000 description 1
- 150000003445 sucroses Chemical class 0.000 description 1
- 235000010491 tara gum Nutrition 0.000 description 1
- 239000000213 tara gum Substances 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- CRDAMVZIKSXKFV-UHFFFAOYSA-N trans-Farnesol Natural products CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 description 1
- AQWHMKSIVLSRNY-UHFFFAOYSA-N trans-Octadec-5-ensaeure Natural products CCCCCCCCCCCCC=CCCCC(O)=O AQWHMKSIVLSRNY-UHFFFAOYSA-N 0.000 description 1
- ZHYZQXUYZJNEHD-UHFFFAOYSA-N trans-geranic acid Natural products CC(C)=CCCC(C)=CC(O)=O ZHYZQXUYZJNEHD-UHFFFAOYSA-N 0.000 description 1
- UWHZIFQPPBDJPM-BQYQJAHWSA-N trans-vaccenic acid Chemical compound CCCCCC\C=C\CCCCCCCCCC(O)=O UWHZIFQPPBDJPM-BQYQJAHWSA-N 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 229940081851 triarachidin Drugs 0.000 description 1
- 229940098780 tribehenin Drugs 0.000 description 1
- 229940093633 tricaprin Drugs 0.000 description 1
- 229940093609 tricaprylin Drugs 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- PJHKBYALYHRYSK-UHFFFAOYSA-N triheptanoin Chemical compound CCCCCCC(=O)OCC(OC(=O)CCCCCC)COC(=O)CCCCCC PJHKBYALYHRYSK-UHFFFAOYSA-N 0.000 description 1
- 229940078561 triheptanoin Drugs 0.000 description 1
- 229940116962 triisononanoin Drugs 0.000 description 1
- 229940098385 triisostearin Drugs 0.000 description 1
- 229940081852 trilinolein Drugs 0.000 description 1
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 1
- 229940113164 trimyristin Drugs 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 229940117972 triolein Drugs 0.000 description 1
- 229960001947 tripalmitin Drugs 0.000 description 1
- SKGWNZXOCSYJQL-UHFFFAOYSA-N tripalmitoleoyl-sn-glycerol Natural products CCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCC)COC(=O)CCCCCCCC=CCCCCCC SKGWNZXOCSYJQL-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-VBJOUPRGSA-N triricinolein Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/C[C@H](O)CCCCCC)COC(=O)CCCCCCC\C=C/C[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-VBJOUPRGSA-N 0.000 description 1
- 229940057402 undecyl alcohol Drugs 0.000 description 1
- 239000010913 used oil Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
Definitions
- the present disclosure relates to hair care and treatment compositions and to methods for caring for and providing cosmetic benefits to the hair using the compositions.
- Dryness and damage can occur due to several factors including weather exposure, mechanical treatments (e.g. brushing hair), excessive treatments using chemicals, dying hair, heat styling, etc.
- mechanical treatments e.g. brushing hair
- cleansing products that can be excessively stripping of hair's natural oils, can also lead to split ends, dull hair, and exacerbate dry hair.
- oil treatments, conditioner, hair masks, and chemical treatments are commonly used.
- oils for dry hair treatments have increased due to their effectiveness and simplicity.
- Commonly used oils include olive oil, mineral oil, avocado oil, apricot kernel oil, rice bran oil, and coconut oil.
- effects are not usually seen after more than several hours (e.g. 8 hours) of treatment and several treatments are usually required, making it time consuming and labor intensive.
- a variety of approaches have been developed to condition the hair.
- a common method of providing conditioning benefit is through the use of rinse- off and leave-on hair conditioners and masks containing conditioning agents such as cationic surfactants and polymers, high melting point fatty compounds, low melting point oils, silicone compounds, and mixtures thereof.
- conditioning agents such as cationic surfactants and polymers, high melting point fatty compounds, low melting point oils, silicone compounds, and mixtures thereof.
- Such products typically contain a substantial amount of water or are in the form of emulsions.
- the instant disclosure relates to hair care and treatment compositions; and to methods for conditioning and caring for the hair using the compositions.
- the compositions are transparent and are anhydrous or substantially anhydrous (i.e., the amount of water can be about 10 wt.% or less).
- the composition forms an emulsion in a lamellar phase stucture, which surprisingly enhances the delivery of conditioning active agents such as cationic surfactants, emollients, and fatty compounds onto a surface such as hair.
- conditioning active agents such as cationic surfactants, emollients, and fatty compounds onto a surface such as hair.
- the deposition of these conditioning active agents impart a smoothing and lubricating effect to the hair, resulting in the hair having a shiny and healthy appearance and tactile repairing sensation.
- the hair is easily detangled and dryness and frizziness are reduced or minimized.
- the compositions typically include:
- composition of the present disclosure is transparent and is solubilized, non- emulsified until applied to wet or damp hair or put in contact with extraneous water, whereupon the composition forms an opaque emulsion.
- the resulting opaque emulsion has a lamellar phase structure.
- compositions of the present disclosure can be applied immediately after shampooing the hair, for example, in place of a conditioner.
- the compositions can also be applied on hair immediately after shampooing and conditioning the hair, for example, as a rinse-off or leave-in treatment.
- the compositions can also be applied before shampooing the hair as pre-shampoo treatment compositions.
- the compositions can also be used on hair by themselves, without requiring the use of any other hair product.
- the compositions are applied directly to wet or damp hair and massaged into the hair to ensure uniform coverage.
- the compositions can also first be combined with a small amount of extraneous water, with the resulting mixture being applied immediately onto hair and massaged into the hair to ensure uniform coverage.
- compositions After application to the hair, the hair may be rinsed with water, dried, and styled as desired.
- Another unique aspect of the compositions is that they may be used as a leave-on product.
- the compositions can be applied to wet or damp hair or first mixed with a small amount of extraneous water, and allowed to remain on the hair indefinitely, i.e., the hair composition is not removed or rinsed from the hair prior to drying and/or shaping or styling the hair.
- the present disclosure relates to a hair care composition
- a hair care composition comprising:
- the composition of the present disclosure is transparent and in solubilized, non-emulsified until applied to wet or damp hair or put in contact with extraneous water, whereupon the composition forms an opaque emulsion.
- the composition forms an emulsion that is a lamellar phase in situ when it comes in contact with water present on wet or damp hair.
- the weight ratio of the polyol(s) to the monoalcohols (polyols: monoalcohols) in the compositions of the present disclosure is from about 20:1 to about 1 :1.
- the one or more polyol(s) is selected from ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, pentylene glycol, diethylene glycol, dipropylene glycol, 1 ,3 propanediol, glycerin, or mixtures thereof.
- the one or more polyol(s) is not butylene glycol.
- the one or more monoalcohols is selected from ethanol, butanol, pentanol, hexanol, isopropyl alcohol, cycohexanol, isobutyl alcohol, 2-methyl-2- butanol (2-methylbutan-2-ol), and a mixture thereof.
- the one or more polyol(s) is selected from propylene glycol and the one or more monoalcohols is selected from ethanol wherein the weight ratio of propylene glycol to ethanol (propylene glycol: ethanol) is from about 15:1 to about 1 :1 or from about 10:1 to about 1.5:1 or from about 8:1 to about 2:1 or from about 5:1 to about 2:1.
- the weight ratio of the one or more fatty alcohols to the one or more cationic surfactant is from about 2:1 to about 1 :1 , about 2:1 to about 1.1 :1 , about 2:1 to about 1 .2:1 , about 2:1 to about 1 .3:1 , about 2:1 to about 1 .4:1 , about 2:1 to about 1 .5:1 , about 2:1 to about 1 .6:1 , or about 2:1 to about
- the weight ratio of the one or more fatty carbonate esters to one or more dialkyl ethers is from about 2:1 to 1 :1 , about 2:1 to 1.1 :1 , about 2:1 to 1 .2:1 , about 2;1 to 1 .3:1 , about 2:1 to 1 .4:1 , about 2:1 to 1 .5:1 , about 2:1 to 1 .6:1 , about 2:1 to 1 :7:1 , or about 2:1 to 1 .8:1 .
- the composition further comprises one or more isopropyl esters.
- the composition further comprises one or more additional esters other than isopropyl esters.
- the composition further comprises one or more isopropyl esters and one or more additional esters other than isopropyl esters.
- the present disclosure also relates to methods of treating or caring for the hair comprising applying onto hair the hair care compositions of the present disclosure.
- compositions of the present disclosure provide to hair one or more of improved shine, detangling, ease of combing, smoothness, sleekness, shape, discipline, sealed ends of the hair, desirable volume, weightless feel (does not weigh the hair down), and curl care and definition (for curly or wavy hair).
- transparent with respect to a transparent composition indicates that the composition has transmittance of at least 80% at a wavelength of 600 nm, for example measured using a Lambda 40 UV-visible spectrometer.
- the compositions may have, for example, a transmittance of at least 80%, at least 90%, or at least 95% at a wavelength of 600 nm, measured, for example, using a Lambda 40 UV-visible spectrometer.
- transparent is interchangeable with the term “clear” for purposes of the instant disclosure.
- transparent can also mean that an article is visible to the human eye when looking through the composition contained in a clear glass bottle.
- compositions can be substantially anhydrous.
- substantially anhydrous is interchangeable with the phrase “essentially free of water” or “substantially free of water.”
- a substantially anhydrous composition may include up to 10 wt.% of water regardless of whether the water is added to the composition or part of a raw material. Nonetheless, the substantially anhydrous composition may include less than 9 wt.%, less than 8 wt.%, less than 7 wt.%, less than 6 wt.%, less than 5 wt.%, less than 4 wt.%, less than 3 wt.%, less than 2 wt.%, less than 1 wt.%, or less than 0.5 wt.% of water.
- compositions can be anhydrous, that is, they do not contain water or are free of water (added water or part of a raw material).
- compositions of the instant disclosure typically have a viscosity at 25°C of about 10 mPa.s to about 10,000 mPa.s or about 10 mPa.s to about 8,000 mPa.s, or about 10 mPa.s to about 6,000 mPa.s, or about 10 mPa.s to about 4,000 mPa.s, or about 10 mPa.s to about 2,000 mPa.s, or about 10 mPa.s to about 1 ,000 mPa.s, or about 10 mPa.s to about 800mPa.s, or about 10 mPa.s to about 600 mPa.s, or about 10 mPa.s to about 500 mPa.s, or about 10 mPa.s to ⁇ 500 mPa.s, including ranges and sub-ranges there between.
- the viscosity measurements can be carried out, for example, using a Broooksfield viscometer, Model RVT (Brookfield Engineering Laboratories, Inc.) at about 20 revolutions per minute (RPM), at ambient room temperature of about 20 to 25°C; spindle sizes may be selected in accordance with the standard operating recommendations form the manufacturer, ranging from disk spindle No. 1 to No. 4.
- RVT Brookfield Engineering Laboratories, Inc.
- RPM revolutions per minute
- the cosmetic composition when combined with the extraneous water, forms an emulsion, which typically is opaque and has a viscosity that is greater than that of the solubilized, non-emulsified, transparent composition prior to combination with the extraneous water.
- the cosmetic composition when combined with the extraneous water, forms an emulsion, in situ (either on the hair or on skin or other parts of the body), which typically is opaque and has a viscosity that is greater than that of the solubilized, transparent composition prior to combination with the extraneous water.
- PolvoKs a viscosity that is greater than that of the solubilized, transparent composition prior to combination with the extraneous water.
- the hair care compositions include one or more polyols, e.g., such as those chosen from ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, pentylene glycol, diethylene glycol, dipropylene glycol, 1 ,3 propanediol, glycerin, diglycerin, and a mixture thereof.
- the amount of polyol(s) present in the hair care composition typically ranges from about 20 wt.% or higher, based on the total weight of the hair treatment composition.
- the amount of polyol(s) in the hair care composition may be about 20 to about 95 wt.%, about 20 to about 85 wt.%, about 20 to about 80 wt.%, about 20 to about 75 wt.%, about 20 to about 70 wt.%, about 20 to about 65 wt.%, about 20 to about 60 wt.%, about 20 to about 55 wt.%, about 20 to about 50 wt.%, about 20 to about 45 wt.%, about 20 to about 40 wt.%, about 20 to about 35 wt.%, about 20 to about 30 wt.%; about 25 to about 88 wt.%, about 25 to about 85 wt.%, about 25 to about 80 wt.%, about 25 to about 75 wt.%, about 25 to about 70 wt.%, about 25 to about 65 wt.%, about 25 to about 60 wt.%, about 25 to about 55 wt.%, about 25 to about
- polyol should be understood as meaning, within the meaning of the present disclosure, an organic molecule comprising at least two free hydroxyl groups.
- the polyols of the hair care composition may be glycols or compounds with numerous hydroxyl groups.
- the one or more polyols is/are selected from the group consisting of C2-C32 polyols.
- the one or more polyols may be liquid at ambient temperature (25°C).
- the one or more polyols may have from 2 to 32 carbon atoms, from 3 to 16 carbon atoms, or from 3 to 12 carbon atoms.
- Polyols that may be included in the hair care composition include ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, pentylene glycol, 1 ,3-propanediol, dipropylene glycol, caprylyl glycol, glycerin, diglycerin, diethylene glycol, and dipropylene glycol, and mixtures thereof.
- the polyol is propylene glycol.
- the polyol is one or both of propylene glycol and butylene glycol.
- the hair care composition comprises at least propylene glycol, and optionally one or more polyols other than propylene glycol.
- Non-limiting examples of polyols that may be included in the hair care composition include and/or may be chosen from alkanediols such as glycerin, 1 ,2,6-hexanetriol, trimethylolpropane, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, dipropylene glycol, 2-butene-1 ,4-diol, 2-ethyl- 1 ,3-hexanediol, 2-methyl-2,4-pentanediol, caprylyl glycol, 1 ,2-hexanediol, 1 ,2- pentanediol, and 4-methyl-1 ,2-pentanediol; glycol ethers such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate,
- the one or more polyols may, optionally, be glycols or glycol ethers such as, e.g., monomethyl, monoethyl and monobutyl ethers of ethylene glycol, propylene glycol or ethers thereof such as, e.g., monomethyl ether of propylene glycol, butylene glycol, hexylene glycol, dipropylene glycol as well as alkyl ethers of diethylene glycol, e.g., monoethyl ether or monobutyl ether of diethylene glycol.
- glycols or glycol ethers such as, e.g., monomethyl, monoethyl and monobutyl ethers of ethylene glycol, propylene glycol or ethers thereof such as, e.g., monomethyl ether of propylene glycol, butylene glycol, hexylene glycol, dipropylene glycol as well as alkyl ethers of diethylene glycol, e
- the hair care compositions include monoalcohol(s), such as those having from 2 to 6 carbon atom.
- the amount of monoalcohol present in the hair treatment composition may range from about 5 to about 50 wt.%, based on the total weight of the hair treatment composition.
- the hair care composition may have monoalcohol in an amount of about 5 to about 50 wt.%, about 5 to about 45 wt.%, about 5 to about 40 wt.%, about 5 to about 35 wt.%, about 5 to about 30 wt.%, about 5 to about 25 wt.%; about 10 to about 50 wt.%, about 10 to about 45 wt.%, about 10 to about 40 wt.%, about 10 to about 35 wt.%, about 10 to about 30 wt.%, about 10 to about 25 wt.%; about 15 to about 50 wt.%, about 15 to about 45 wt.%, about 15 to about 40 wt.%, about 15 to about 35 wt.%, about 15 to about 30 wt.%, or about 15 to about 25 wt.% including all ranges and sub-ranges there between, based on the total weight of the hair care composition.
- the one or more monoalcohols of the hair care composition may be chosen from ethanol, propanol, butanol, pentanol, hexanol, isopropyl alcohol, cycohexanol, isobutyl alcohol, 2-methyl-2-butanol (2-methylbutan-2-ol), and a mixture thereof.
- the one or more monoalcohol(s) includes or consists of ethanol.
- the total amount of polyol(s) is typically at least the same or higher than the total amount of the monoalcohol(s) having from 2 to 6 carbon atoms in the compositions.
- the compositions include more polyol(s) than monoalcohol(s) having from 2 to 6 carbon atoms, i.e., a higher weight percent of the composition is a polyol(s) than monoalcohols having from 2 to 6 carbon atoms.
- the ratio of polyol(s) to the total amount of monoalcohol(s) having from 2 to 6 carbon atoms may be from 20:1 to 1 :1.
- the ratio is from 20:1 to 1.1 :1 , 20:1 to 1 .5:1 , or 20:1 to 2:1 , including ranges and sub-ranges there between.
- the ratio is from about 18:1 to 1 :1 , about 18:1 to 1 .1 , about 18:1 to 1 .5:1 , about 18:1 to 2:1 , about 15:1 to 2:1 , about 12:1 to 2:1 , about 10:1 to 2.5:1 , about 8:1 to 2.5:1 , about 5:1 to 2.5:1 , or about 5:1 to 3:1 , including ranges and sub-ranges there between.
- the total amount of the one or more fatty alcohols selected from cetyl alcohol and myristyl alcohol in the compositions may vary but is typically about 2 wt.% or less, such as from about 0.1 to about 2 wt.%, based on the total weight of the composition.
- the total amount of fatty alcohols selected from cetyl alcohol and myristyl alcohol may be from about 0.1 to about 1.9 wt.%, about 0.1 to about 1.8 wt.%, about 0.1 to about 1.7 wt.%, about 0.5 to about 1 .7 wt.%, about 0.5 to about 1 .6 wt.%, about 0.5 to about 1 .5 wt.%, or about 0.5 to about 2 wt.%, about 0.6 to 2 wt.%, about 0.8 to about 2 wt.%, about 0.9 to about 2 wt.%, about 1 to about 2 wt.%, about 1 .1 to about 2 wt.%, about 1 .2 to about 2 wt.%, about 1 .4 to about 2 wt.%, or about 1 .5 to about 2 wt.%, including ranges and sub ranges there between, based on the total weight of the composition.
- fatty alcohol means an alcohol comprising at least one hydroxyl group (OH), and comprising at least 8 carbon atoms, and which is neither oxyalkylenated (in particular neither oxyethylenated nor oxypropylenated) nor glycerolated.
- the fatty alcohols can be represented by: R-OH, wherein R denotes a saturated (alkyl) or unsaturated (alkenyl) group, linear or branched, optionally substituted with one or more hydroxyl groups, comprising from 8 to 40 carbon atoms, preferably 10 to 30 carbon atoms, more preferably 12 to 24 carbon atoms, and even more preferably 14 to 22 carbon atoms.
- compositions of the instant disclosure may optionally include one or more of additional fatty alcohols such as decyl alcohol, undecyl alcohol, dodecyl alcohol, cetearyl alcohol (mixture of cetyl alcohol and stearyl alcohol), stearyl alcohol, isostearyl alcohol, isocetyl alcohol, behenyl alcohol, linalool, oleyl alcohol, cis4-t-butylcyclohexanol, isotridecyl alcohol, myricyl alcohol and a mixture thereof.
- additional fatty alcohols such as decyl alcohol, undecyl alcohol, dodecyl alcohol, cetearyl alcohol (mixture of cetyl alcohol and stearyl alcohol), stearyl alcohol, isostearyl alcohol, isocetyl alcohol, behenyl alcohol, linalool, oleyl alcohol, cis4-t-butylcyclohexanol, isotridecyl alcohol, myricyl alcohol
- Cationic Surfactant means a surfactant that may be positively charged when it is contained in the compositions according to the disclosure. This surfactant may bear one or more positive permanent charges or may contain one or more functional groups that are cationizable in the composition according to the disclosure.
- Non-limiting examples of cationic surfactants include cetrimonium chloride, stearimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylmonium chloride, oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethyl-amine, behenamidoethyldimethylamine, arachidamidoprop
- the cationic surfactant is preferably selected from cetrimonium chloride, stearimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylmonium chloride, oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethyl-amine, behenamidoethyldimethylamine, arachida
- the cationic surfactant is most preferably cetrimonium chloride, behentrimonium chloride, or a mixture thereof.
- the total amount of cationic surfactant(s) in the composition can vary but is typically from about 0.1 to about 5 wt.%, based on the total weight of the composition. In some cases, the total amount of cationic surfactant(s) is from about 0.1 to about 4 wt.%, about 0.1 to about 3 wt.%, about 0.1 to about 2 wt.%, about 0.5 to about 5 wt.%, about 0.5 to about 4 wt.%, about 0.5 to about 3 wt.%, or about 0.5 to about 2 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- the total amount of fatty alcohol(s) is typically at least the same or higher than the total amount of the cationic surfactants in the compositions.
- the compositions include more fatty alcohols than cationic surfactants i.e., a higher weight percent of the composition is a fatty alcohol than cationic surfactants.
- the ratio of fatty alcohol(s) to the total amount of cationic surfactants may be from about 2:1 to 1 :1 , about 2:1 to 1.1 :1 , about 2:1 to 1 .2:1 , about 2:1 to 1 .3:1 , about 2:1 to 1 .4:1 , about 2:1 to 1 .5:1 , about 2:1 to 1 .6:1 , or about 2:1 to 1 .7:1 , including ranges and sub-ranges there between.
- compositions of the instant disclosure include one or more fatty carbonate esters (also referred to as “fatty carbonates”).
- Fatty carbonate esters include dialkyl carbonates.
- the total amount of the one or more fatty carbonate ester(s) in the composition can vary but is typically about 1 wt% or less, based on the total weight of the composition.
- the total amount of fatty carbonate ester(s) is from about 0.05 to about 1 wt.%, about 0.07 to about 1 wt.%, about 0.08 to about 1 wt.%, about 0.1 to about 0.9 wt.%, about 0.2 to about 0.7 wt.%, about 0.3 to about 0.6 wt.%, or about 0.3 to about 0.5 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- the total amount of the one or more fatty carbonate ester(s) in the composition is about 1 wt,%, 0.9 wt,%, 0.8 wt,%. 0.7 wt,%, 0.6 wt,%, 0.5 wt,%, 0.4 wt,%, 0.3 wt,%, 0.2 wt,%, 0.1 wt,%, 0.08 wt,%, 0.07 wt,%, 0.06 wt,%, 0.05 wt,%, 0.04 wt,%, 0.03 wt,%, 0.02 wt,%, or 0.01 wt,%, based on the total weight of the composition.
- compositions of the instant disclosure include one or more dialkyl ethers.
- dialkyl ethers include dicaprylyl ether, dicetyl ether, dodecyl ether, dilauryl ether, dimyristyl ether, distearyl ether, diisononyl ether, and a mixture thereof.
- the total amount of the one or more dialkyl ether(s) in the composition can vary but is typically about 1 wt% or less, based on the total weight of the composition. In some cases, the total amount of dialkyl ether(s)is from about 0.05 to about 1 wt.%, about 0.07 to about 1 wt.%, about 0.08 to about 1 wt.%, about 0.1 to about 0.9 wt.%, about 0.2 to about 0.7 wt.%, about 0.3 to about 0.6 wt.%, or about 0.3 to about 0.5 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- the total amount of the one or dialkyl ether(s)) in the composition is about 1 wt,%, 0.9 wt,%, 0.8 wt,%. 0.7 wt,%, 0.6 wt,%, 0.5 wt,%, 0.4 wt,%, 0.3 wt,%, 0.2 wt,%, 0.1 wt,%, 0.08 wt,%, 0.07 wt,%, 0.06 wt,%, 0.05 wt,%, 0.04 wt,%, 0.03 wt,%, 0.02 wt,%, or 0.01 wt,%, based on the total weight of the composition.
- the total amount of fatty carbonate ester(s) is typically at least the same or higher than the total amount of the dialkyl ether(s) in the compositions.
- the compositions may include more fatty carbonate ester(s) than dialkyl ether(s), i.e., a higher weight percent of the composition is a fatty carbonate ester(s) than dialkyl ether(s).
- the ratio of fatty carbonate ester(s) to the total amount of dialkyl ether(s) may be from about 2:1 to 1 :1 , about 2:1 to 1.1 :1 , about 2:1 to 1 .2:1 , about 2;1 to 1 .3:1 , about 2:1 to 1 .4:1 , about 2:1 to 1 .5:1 , about 2:1 to 1 .6:1 , about 2:1 to 1 :7:1 , or about 2:1 to 1 .8:1 , including ranges and sub-ranges there between.
- the hair care compositions may be devoid of added water, i.e., the compositions do not contain water that is added to the composition or present in a raw material.
- the hair care composition can comprise from 0 up to about 10 wt.% of water.
- the amount of water present in the composition prior to combination with extraneous water may be from about 0.01 to about 10 wt.% or about 0.05 to about 9 wt.%, or about 0.1 to about 8 wt.% or about 0.2 to about 7 wt.% or about 0.3 to about 6 wt.% or about 0.5 to about 5 wt.% or about 0.6 to about 4 wt.% or about 0.7 to about 3 wt.% or about 0.5 to about 2 wt.% or about 0.5 to about 1 wt.% or less than 2 wt.%, or less than 1 wt.%, or less than 0.5 wt.% or less than 0.3 wt.%, including ranges and sub-ranges there between, based on the total weight of the hair care composition.
- the water present in the hair care composition prior to combination with extraneous water is added to the composition (“added water”).
- the water present in the cosmetic composition prior to combination with extraneous water is not “added water,” i.e., it is present in the hair care composition as part of a raw material that is included in the composition.
- the hair care composition may include water prior to the combination of extraneous water, in some embodiments the hair care composition is anhydrous or devoid of water.
- compositions of the instant disclosure may optionally include an isopropyl ester. More specific non-limiting examples include isopropyl isostearate, isopropyl myristate, isopropyl palmitate, diisopropyl sebacate, diisopropyl dimer dilinoleate, and mixtures thereof
- compositions of the instant disclosure may also optionally include one or more of additional esters other than isopropyl esters.
- additional esters other isopropyl esters include glycerol fatty esters, sucrose fatty esters, sorbitan fatty ester, fatty acid esters, or mixtures thereof.
- Additional non-limiting examples are esters of C6-22 fatty acids with a monohydric alcohol and/or esters of C6-22 fatty alcohols with a monocarboxylic acid.
- More specific non-limiting examples include n-propyl myristate, hexyl laurate, hexadecyl isostearate, hexydecyl laurate, hexyldecyl octanoate, n-propyl palmitate, and mixtures thereof.
- the one or more additional esters is a glycerol ester of fatty acids or glyceryl esters (or glycerol fatty esters), for example, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl isostearate, glyceryl monooleate, glyceryl dioleate, glyceryl distearate, glyceryl laurate, trilaurin, triarachidin, tribehenin, tricaprin, tricaprylin, caprylic/capric triglyceride, trierucin, triheptanoin, triheptylundecanoin, triisononanoin, triisopalmitin, triisostearin, trilinolein, trimyristin, trioctanoin, triolein, tripalmitin, tripalmitolein, tristearin,
- additional esters include diisobutyl adipate, 2- hexyldecyl adipate, di-2-heptylundecyl adipate, monoisostearic acid N-alkyl glycol, isocetyl isostearate, trimethylolpropane triisostearate, ethylene glycol di-2- ethylhexanoate, cetyl 2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octanoate, octyldodecyl gum ester, oleyl oleate, octyldodecyl oleate, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 2- e
- the additional esters are selected from sucrose fatty esters.
- a non-limiting but preferred example is sucrose palmitate.
- Additional examples include sucrose cocoate, sucrose monooctanoate, sucrose monodecanoate, sucrose mono- or dilaurate, sucrose monomyristate, sucrose mono- or dipalmitate, sucrose mono- and distearate, sucrose mono-, di- or trioleate, sucrose mono- or dilinoleate, sucrose pentaoleate, sucrose hexaoleate, sucrose heptaoleate or sucrose octooleate, and mixed esters, such as sucrose palmitate/stearate.
- the one or more additional esters other than isopropyl esters include Ethylhexyl Palmitate, Ethylhexyl Stearate, Hexyl Laurate, Coco- Caprylate/Caprate, Cetearyl Ethylhexanoate, Propylene Glycol Dicaprylate/ Dicaprate, and mixtures thereof.
- the total amount of estersin the composition may vary but is typically from about 0.1 to about 2 wt.%, based on the total weight of the composition. In some instances, the total amount of esters is from about 0.1 to about 2 wt.%, about 0.1 to about 1.8 wt.%, about 0.1 to about 1.6 wt.%, about 0.1 to about 1.5 wt.%, about 0.2 to about 1 .5 wt.%, about 0.3 to about 1 .2 wt.%, about 0.4 to about 1 wt.%, about 0.4 to about 0.8 wt.%, or about 0.5 to about 0.7 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- One or more alkanes such as undecane, tridecane or a mixture thereof can be included in the compositions of the instant disclosure.
- the total amount of the one or more alkanes may vary but is typically from about 0.1 to about 10 wt.%, based on the total weight of the composition. In some instances, the total amount of the one or more alkanes is from about 0.1 to about 9 wt.%, about 0.1 to about 8 wt.%, about 0.1 to about 6wt.%, about 0.1 to about 5 wt.%, about 0.2 to about 4 wt.%, about 0.3 to about 3 wt.%, about 0.4 to about 2 wt.%, about 0.4 to about 1 .5 wt.%, or about 0.4 to about 1 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- Thickening agents can optionally be included in the compositions of the instant disclosure.
- Thickening agents may be referred to as “thickeners” or “viscosity modifying agents.” Thickening agents are typically included to increase the viscosity of the compositions. Nonetheless, in some instances, certain thickening agents provide additional, surprising benefits to the compositions.
- Non-limiting examples of thickening agents include polyacrylate crosspolymers or crosslinked polyacrylate polymers, cationic acrylate copolymers, anionic acrylic or carboxylic acid polymers, polyacrylamide polymers, polysaccharides such as cellulose derivatives, gums, polyquaterniums, vinylpyrrolidone homopolymers/copolymers, C8-24 hydroxyl substituted aliphatic acid, C8-24 conjugated aliphatic acid, sugar fatty esters, polyglyceryl esters, and a mixture thereof.
- Particular types of thickening agents that may be mentioned include the following: a.
- Carboxylic acid or carboxylate based homopolymer or co-polymer which can be linear or crosslinked: These polymers contain one or more monomers derived from acrylic acid, substituted acrylic acids, and salts and esters of these acrylic acids (acrylates) and the substituted acrylic acids.
- Commercially available polymers include those sold under the trade names CARBOPOL, ACRYSOL, POLYGEL, SOKALAN, CARBOPOL ULTREZ, and POLYGEL.
- Examples of commercially available carboxylic acid polymers include the carbomers, which are homopolymers of acrylic acid crosslinked with allyl ethers of sucrose or pentaerytritol. The carbomers are available as the CARBOPOL 900 series from B.F.
- carboxylic acid polymeric agents include ULTREZ 10 (B.F. Goodrich) and copolymers of C10-30 alkyl acrylates with one or more monomers of acrylic acid, methacrylic acid, or one of their short chain (i.e., C1 -4 alcohol) esters, wherein the crosslinking agent is an allyl ether of sucrose or pentaerytritol.
- ULTREZ 10 B.F. Goodrich
- These copolymers are known as acrylates/C10-C30 alkyl acrylate crosspolymers and are commercially available as CARBOPOL 1342, CARBOPOL 1382, PEMULEN TR-1 , and PEMULEN TR-2
- carboxylic acid or carboxylate polymeric agents include copolymers of acrylic acid and alkyl C5-C10 acrylate, copolymers of acrylic acid and maleic anhydride, and polyacrylate crosspolymer-6.
- Polyacrylate Crosspolymer-6 is aviable in the raw material known as SEPIMAX ZEN from Seppic.
- Another suitable carboxylic acid or carboxylate polymeric agent includes acrylamidopropyltrimonium chloride/acrylates copolymer, a cationic acrylates copolymer (or a quaternary ammonium compound), available as a raw material known under the tradename of SIMULQUAT HC 305 from Seppic.
- the carboxylic acid or carboxylate polymer thickeners useful herein are those selected from carbomers, acrylates/C10-C30 alkyl acrylate crosspolymers, polyacrylate crosspolymer-6, acrylamidopropyltrimonium chloride/acrylates copolymer, and mixtures thereof. b.
- Non-limiting examples include polyquaternium-1 , polyquaternium-2, polyquaternium-3, polyquaternium-4, polyquaternium-5, polyquaternium-6, polyquaternium-7, polyquaternium-8, polyquaternium-9, polyquaternium-10, polyquaternium-11 , polyquaternium-12, polyquaternium-13, polyquaternium-14, polyquaternium-15, polyquaternium-16, polyquaternium-17, polyquaternium-18, polyquaternium-19, polyquaternium-20, polyquaternium-21 , polyquaternium-22, polyquaternium-23, polyquaternium-24, polyquaternium-25, polyquaternium-26, polyquaternium-27, polyquaternium-28, polyquaternium-29, polyquaternium-30, polyquaternium-40, polyquaternium-41, polyquaternium-42, polyquaternium-43, polyquaternium-44, polyquaternium-45, polyquaternium-46, polyquaternium-
- preferred polyquaternium compounds include polyquaternium-10, polyquaternium-11 , polyquaternium-67, and a mixture thereof.
- Celluloses Non-limiting examples of celluloses include cellulose, carboxymethyl hydroxyethylcellulose, cellulose acetate propionate carboxylate, hydroxyethylcellulose, hydroxyethyl ethylcellulose, hydroxypropylcellulose, hydroxypropyl methylcellulose, methyl hydroxyethylcellulose, microcrystalline cellulose, sodium cellulose sulfate, and mixtures thereof.
- the cellulose is selected from water soluble cellulose derivatives (for example, carboxymethyl cellulose, methyl cellulose, methylhydroxypropyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, cellulose sulfate sodium salt). Furthermore, in some instance, the cellulose is preferably hydroxypropylcellulose (HPC). d.
- Polyvinylpyrrolidone (PVP) and co-polymers Non-limiting examples include Polyvinylpyrrolidone(PVP), Polyvinylpyrrolidone(PVP)/vinyl acetate copolymer (PVP/VA copolymer), polyvinylpyrrolidone (PVP)/eicosene copolymer, PVP/hexadecene copolymer, etc.
- Commercially available polyvinylpyrrolidone includes LUVISKOL K30, K85, K90 available from BASF.
- copolymers of vinylpyrrolidone and vinylacetate include LUVISKOL VA37, VA64 available from BASF; copolymers of vinylpyrrolidone, methacrylamide, and vinylimidazole (INCI: VP/Methacrylamide/Vinyl Imidazole Copolymer) is commercially available as LUVISET from BASF. In some instances, PVP and PVP/VA copolymer are preferred. e.
- Sucrose esters Non-limiting examples include sucrose palmitate, sucrose cocoate, sucrose monooctanoate, sucrose monodecanoate, sucrose mono- or dilaurate, sucrose monomyristate, sucrose mono- or dipalmitate, sucrose mono- and distearate, sucrose mono-, di- or trioleate, sucrose mono- or dilinoleate, sucrose pentaoleate, sucrose hexaoleate, sucrose heptaoleate or sucrose octooleate, and mixed esters, such as sucrose palmitate/stearate, and mixtures thereof.
- Polyglyceryl esters Non-limiting polyglycerol esters of fatty acids (polygylceryl esters) include those of the following formula:
- R , 1 -(0CH 2 - ICH-CH 2 0) radical-R 3 wherein n is from 2 to 20 or from 2 to 10 or from 2 to 5, or is 2, 3, 4, 5, 6, 7, 8, 9, or 10, and R 1 , R 2 and R 3 each may independently be a fatty acid moiety or hydrogen, provided that at least one of R 1 , R 2 , and R 3 is a fatty acid moiety.
- R 1 , R 2 and R 3 may be saturated or unsaturated, straight or branched, and have a length of Ci- C40, C1-C30, C1-C25, or C1-C20, C1-C16, or C1-C10.
- nonionic polyglycerol esters of fatty acids include polyglyceryl-4 caprylate/caprate, polyglyceryl-10 caprylate/caprate, polyglyceryl-4 caprate, polyglyceryl-10 caprate, polyglyceryl-4 laurate, polyglyceryl-5 laurate, polyglyceryl-6 laurate, polyglyceryl-10 laurate, polyglyceryl-10 cocoate, polyglyceryl-10 myristate, polyglyceryl-10 oleate, polyglyceryl-10 stearate, and mixtures thereof.
- Non-limiting examples include conjugated linoleic acid, cis-parinaric acid, trans-7- octadecenoic acid, cis-5,8,11 ,14,17-eicosapentanoic acid, cis-4,7,10,13,16,19- docosahexenoic acid, columbinic acid, linolenelaidic acid, ricinolaidic acid, stearidonic acid, 2-hydroxystearic acid, alpha-linolenic acid, arachidonic acid, cis-11 ,14- eicosadienoic acid, linolelaidic acid, monopetroselinic acid, petroselinic acid, ricinoleic acid, trans-vaccenic acid, cis-11 ,14,17-eicosatrienoic acid, cis-5-eicosenoic
- the aliphatic acid comprises 12-hydroxystearic acid, conjugated linoleic acid, or a mixture thereof.
- Gums Non-limiting examples of gums include gum arabic, tragacanth gum, karaya gum, guar gum, gellan gum, tara gum, locust bean gum, tamarind gum, xanthan gum, locust bean gum, Seneca gum, sclerotium gum, gellan gum, etc.
- the total amount of thickening agents can vary but is typically from about 0.01 to about 20 wt.%, based on the total weight of the composition. In some instances, the total amount of thickening agents is about 0.01 to about 15 wt.%, about 0.01 to about 10 wt.%, about 0.01 to about 0.01 to about 8 wt.%, about 0.01 to about 6 wt.%, about 0.01 to about 5 wt.%, about 0.1 to about 20 wt.%, about 0.1 to about 15 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, or about 0.1 to about 5 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- compositions include one or more polyacrylate crosspolymers, for example, polyacrylate crosspolymer-6.
- the total amount of the polyacrylate crosspolymer(s) can vary but may be from about 0.01 to about 10 wt.%, based on the total weight of the compositions.
- the total amount of polyacrylate crosspolymers is from about 0.01 to about 8 wt.%, about 0.01 to about 5 wt.%, about 0.01 to about 3 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, or about 0.1 to about 3 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- the compositions include one or more carbomers, which are polymeric materials composed of acrylic acid monomers.
- the total amount of carbomers may vary but may be from about 0.01 to about 10 wt.%, based on the total weight of the compositions. In some instances, the total amount of carbomers is from about 0.01 to about 8 wt.%, about 0.01 to about 5 wt.%, about 0.01 to about 3 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, or about 0.1 to about 3 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- the compositions include acrylamidopropyltrimonium chloride/acrylates copolymer, which is a copolymer of one or more of the monomers formed from the amide of acrylic acid, methacrylic acid and aminopropyltrimethyl- ammonium chloride and one or more monomers of acrylic acid, methacrylic acid or one of their esters.
- the total amount of acrylamidopropyltrimonium chloride/acrylates copolymer may vary but may be from about 0.01 to about 10 wt.%, based on the total weight of the compositions.
- the total amount of acrylamidopropyltrimonium chloride/acrylates copolymer is from about 0.01 to about 8 wt.%, about 0.01 to about 5 wt.%, about 0.01 to about 3 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, or about 0.1 to about 3 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- the compositions include one or more polyquaternium compounds.
- Non-limiting examples include polyquaternium-10, polyquaternium-11 , and polyquaternium-67.
- the total amount of polyquaternium compounds may vary but may be from about 0.01 to about 10 wt.%, based on the total weight of the compositions.
- the total amount of polyquaternium compounds is from about 0.01 to about 8 wt.%, about 0.01 to about 5 wt.%, about 0.01 to about 3 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, or about 0.1 to about 3 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- the compositions include one or more cellulose thickeners (e.g., microcrystalline cellulose, carboxymethylcellulose, hydroxymethylcellulose, and hydroxypropylcellulose).
- cellulose thickeners e.g., microcrystalline cellulose, carboxymethylcellulose, hydroxymethylcellulose, and hydroxypropylcellulose.
- the total amount of cellulose thickeners can vary but may be from about 0.01 to about 10 wt.%, based on the total weight of the compositions.
- the total amount of cellulose thickeners is from about 0.01 to about 8 wt.%, about 0.01 to about 5 wt.%, about 0.01 to about 3 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, or about 0.1 to about 3 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- compositions include polyvinylpyrrolidone (PVP) and/or polyvinylpyrrolidone/vinyl acetate (VP/VA) copolymer.
- PVP polyvinylpyrrolidone
- VP/VA polyvinylpyrrolidone/vinyl acetate copolymer
- the total amount of PVP and/or VP/VA copolymer can vary but may be from about 0.01 to about 10 wt.%, based on the total weight of the compositions.
- the total amount of PVP and/or VP/VA copolymer is from about 0.01 to about 8 wt.%, about 0.01 to about 5 wt.%, about 0.01 to about 3 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 8 wt.%, about 0.1 to about 6 wt.%, about 0.1 to about 5 wt.%, or about 0.1 to about 3 wt.%, including ranges and sub-ranges there between, based on the total weight of the composition.
- the compositions are free or essentially free of silicones.
- the compositions include less than about 3 wt.%, 2 wt.%, 1 wt.%, or 0.5 wt.% of silicones, or preferably, do not containsilicones.
- the compositions comprise silicones.
- Non-limiting examples of silicones include amine-functionalized silicones (e.g., amodimethicone), dimethicone, bis-aminopropyl dimethicone, trimethyl silylamodimethicon, etc.
- compositions of the instant disclosure are useful for conditioning and/or managing the hair.
- a “lamellar phase” refers generally to packing of polar-headed long chain nonpolar-tail molecules in an environment of bulk polar liquid (i.e., water from the hair), as sheets of bilayers separated by bulk liquid.
- the compositions can be applied to the wet or damp hair and may be massaged into the hair, for example, with the hands, and/or spread throughout the hair with a comb or brush. This results in a smoothing and softening of the hair, which reduces frizz, dryness, and unwanted volume, and increases shine.
- the compositions can remain in the hair or can optionally be rinsed from the hair prior to drying and/or styling of the hair.
- compositions may be used as a leave-on product.
- the compositions can be applied to wet or damp hair and allowed to remain on the hair indefinitely, i.e., the hair composition is not removed or rinsed from the hair prior to styling the hair.
- the methods of treating hair according to the disclosure also include methods according to various routines.
- the compositions may be mixed with a shampoo (or conditioner) prior to application to the hair.
- the composition may be layered on top of (or lathered into) hair to which the shampoo (or conditioner) is already applied.
- the composition may be applied separate from the shampoo (or conditioner), i.e., applied to the hair after the shampoo (or conditioner) has been rinsed from the hair.
- kits may include at least one composition according to the instant disclosure and one or more additional compositions, for example, a shampoo, a conditioner, etc.
- additional compositions for example, a shampoo, a conditioner, etc.
- the various compositions are separately contained in the kits.
- the kits include one or more compositions according the instant disclosure, a shampoo, and/or a conditioner, all of which are separately contained.
- the kits may also include one or more compositions according the instant disclosure, a shampoo, and a conditioner. Instructions, mixing components, brushes, gloves, measuring tools, etc., may also optionally be included in the kits.
- compositions may be packaged in a variety of different containers, such as, for example, a ready-to-use container.
- useful packaging include tubes, jars, caps, unit dose packages, and bottles, including squeezable tubes and bottles.
- the packaging may be configured so that it can be attached to a wall, such as a wall in a bathroom, including walls of a shower or tub.
- the packaging can be a container that is configured to attach to a wall, such that when pressure is applied to the container, the composition contained therein is expelled from one or more openings in the container.
- the packaging is a tube, such as a tube with two compartments, or dual tubes, each forming a separate compartment. Each compartment may include a different composition.
- one tube or compartment may include a composition according to the instant disclosure, and the other tube may include a composition to be used with the composition, for example, a shampoo, a conditioner, an all-in-one shampoo/conditioner (i.e., a conditioning shampoo; also referred to as a “co wash”).
- a composition to be used with the composition for example, a shampoo, a conditioner, an all-in-one shampoo/conditioner (i.e., a conditioning shampoo; also referred to as a “co wash”).
- Methods of treating hair according to the disclosure may vary but typically include applying a composition of the instant disclosure to the hair, allowing the composition to remain on the hair for a sufficient amount of time, and rinsing the compositions from the hair.
- the composition may be applied to the hair in a sequence with other compositions.
- the compositions may be applied to the hair before shampooing the hair, after shampooing the hair, before conditioning the hair, and/or after conditioning the hair.
- the compositions are not required to be used in a sequence.
- the compositions are used in conjunction with additional hair- treatment compositions in a routine, for example, during an individual’s normal showering/bathing routine.
- the composition may be applied to the hair individually or may be combined with one or more additional compositions.
- Combining the compositions with one or more additional compositions can be useful for eliminating multiple steps from a routine.
- the composition may be mixed with a shampoo (or conditioner) prior to application to the hair.
- the mixture of the shampoo (or conditioner) and the composition are simultaneously applied to the hair during the cleansing or conditioning process and simultaneously rinsed from the hair.
- the composition may be layered on top of (or lathered into) hair to which a shampoo (or conditioner) has already been applied or vice versa.
- the composition may be applied to the hair and without rinsing it from the hair, a shampoo (or conditioner) is then subsequently applied to the hair.
- the shampoo (or conditioner) may be first applied to the hair and without rinsing the shampoo (or conditioner) from the hair, the hair-treatment composition is also applied to the hair.
- the composition When used in conjunction with a shampoo and/or a conditioner, the composition may be mixed or used with the shampoo and/or conditioner in a ratio of about 1 :10 to about 10:1 , about 1 :5 to about 5:1 , about 1 :3 to about 3:1 , about 1 :2 to about 2:1 , about 1 :1 to about 4:1 , about 1 :1 to about 3:1 , or about 1 :1 to about 2:1 (hair-treatment composition of the instant disclosure: shampoo/conditioner, etc.).
- compositions of the instant disclosure may be allowed to remain on the hair for a minimum amount of time before being rinsed from the hair, but it is not necessary to allow the composition to remain on the hair for an extended period of time.
- the compositions can be applied and allowed to remain on the hair for a period of time that is typical for regular shampooing and/or conditioning.
- the composition (whether combined with another hair-treatment composition such as a shampoo or conditioner) may be applied to the hair and allowed to remain on the hair for a few seconds (1 , 2, 3, or 5 seconds) up to about 1 , about 2, about 5, about 10, about 15, about 20, about 25, or about 30 minutes.
- the composition When the composition is not being mixed with another composition prior to application to the hair, the composition may be applied to the hair immediately after or before the hair it treated with another composition (e.g., a shampoo and/or a conditioner).
- another composition e.g., a shampoo and/or a conditioner
- the hair-treatment compositions may be applied to the hair within about 1 , 2, 5, 10, or 20 minutes before or after a shampoo and/or a conditioner is applied to the hair.
- compositions of the present disclosure can be mixed with a shampoo prior to application to hair; or layered onto hair with a shampoo; or applied to hair after a shampoo has been rinsed from the hair; or layered onto hair with a conditioner; or mixed with a conditioner prior to application to hair; or applied to hair after a conditioner has been rinsed from the hair.
- compositions of the instant disclosure are unique in their ability to provide hair with improved manageability, long-lasting style and frizz control, and smoothness. Accordingly, the instant disclosure relates to methods for treating hair, for example, for improving the manageability of hair, for imparting lasting style and frizz control, and for imparting smoothness. More specifically, the compositions may be used in methods for conditioning the hair, providing curl definition to the hair, providing frizz control to the hair, improving ease of compatibility and detangling, and providing smoothness.
- compositions of the instant disclosure are transparent and substantially anhydrous cosmetic composition comprising:
- cationic surfactants selected from cetrimonium chloride, stearimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylmonium chloride, oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldimethylamine, be
- dialkyl ethers preferably selected from dicaprylyl ether, dicetyl ether, dodecyl ether, dilauryl ether, dimyristyl ether, distearyl ether, diisononyl ether, and a mixture thereof; wherein preferably, the weight ratio of the one or more fatty carbonate esters to one or more dialkyl ethers (fatty carbonate esters: dialkyl ether) is from about 2:1 to 1 :1 ; and
- esters comprising one or more isopropyl ester, one or more additional esters other than isopropyl ester, and a mixture thereof; wherein the composition is a transparent and non-emulsified composition until applied to the wet or damp hair or put in contact with extraneous water, whereupon the composition forms an opaque emulsion which in one embodiment, is in lamellar phase; and all percentages by weight are based on the total weight of the composition.
- the instant disclosure is directed to methods of treating hair comprising applying the hair care compositions to wet or damp hair and forming opaque emulsion in situ.
- the instant disclosure is directed to methods of treating hair comprising: (i) putting the transparent compositions in contact with an amount of extraneous water such that an opaque emulsion in lamellar phase is formed; and (ii) applying the resulting mixture onto hair.
- compositions of the present disclosure were found to remain clear within a broad range of temperatures such as from room temperature to about 6°C or less than 6°C.
- Two-grams of platinum bleached hair swatches were first washed with a conventional sulfate-based shampoo and rinsed off with water. The swatches were then treated with invention formulas by massaging 0.8 grams of product onto each hair swatch for 30 seconds. The swatches were then rinsed with water for 30 seconds and then allowed to air dry.
- the dry treated swatches were evaluated by five experts for sensory feel. Four out of the five experts selected invention formulas A and B as providing a better sensorial effect of smooth feel on the treated hair as compared to comparative formula P.
- the professional salon hair dressers evaluated the treated hair and found that the attributes of overall cosmeticity, care, and manageability such as, - detangling, combing, smoothness, conditioning feel, shape, discipline, and sealed ends were found to be noticeably better on the hair treated with the invention formula than on the hair treated with comparative formula X.
- compositions and methods of the present disclosure can comprise, consist of, or consist essentially of the essential elements and limitations of the disclosure described herein, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful.
- compositions described throughout this disclosure may be a “leave-on” product.
- a “leave-on” (also called leave-in) product refers to a hair treatment composition that is applied to hair and is not subjected to immediate rinsing and/or washing for at least 4 hours or for a period of time ranging from 4 hours up to 72 hours, from 4 hours up to 48 hours, or from 8 hours up to 36 hours, or from 8 hours up to 24 hours.
- the product is applied to the hair and remains on the hair, as styled, i.e., it is not removed from the hair prior to styling the hair.
- any value or point described herein that falls within a range described herein can serve as a minimum or maximum value to derive a sub-range, etc.
- all ranges provided are meant to include every specific range within, and combination of sub ranges between, the given ranges.
- a range from 1 -5 includes specifically 1 , 2, 3, 4 and 5, as well as sub ranges such as 2-5, 3-5, 2-3, 2-4, 1 -4, etc.
- active material as used herein with respect to the percent amount of an ingredient or raw material, refers to 100% activity of the ingredient or raw material.
- Cosmetically acceptable means that the item in question is compatible with a keratinous substrate such as skin and hair.
- a “cosmetically acceptable carrier” means a carrier that is compatible with a keratinous substrate such as skin and hair.
- hair care is interchangeable with the term “hair treatment” for purposes of the instant disclosure.
- a mixture thereof also relates to “mixtures thereof.”
- A-F represent the elements: “one or more elements selected from the group consisting of A, B, C, D, E, F, and a mixture thereof.”
- A-F represent the elements: “one or more elements selected from the group consisting of A, B, C, D, E, F, and a mixture thereof.”
- the term, “a mixture thereof” does not require that the mixture include all of A, B, C, D, E, and F (although all of A, B, C, D, E, and F may be included). Rather, it indicates that a mixture of any two or more of A, B, C, D, E, and F can be included. In other words, it is equivalent to the phrase “one or more elements selected from the group consisting of A, B, C, D, E, F, and a mixture of any two or more of A, B, C, D, E, and F.”
- a salt thereof also relates to “salts thereof.”
- the disclosure refers to “an element selected from the group consisting of A, B, C, D, E, F, a salt thereof, and a mixture thereof,” it indicates that that one or more of A, B, C, D, and F may be included, one or more of a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included, or a mixture of any two of A, B, C, D, E, F, a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included.
- the salts referred to throughout the disclosure may include salts having a counter ion such as an alkali metal, alkaline earth metal, or ammonium counter-ion. This list of counter-ions, however, is non-limiting.
- Volatile as used herein, means having a flash point of less than about 100 Q C.
- Non-volatile as used herein, means having a flash point of greater than about
- polymers include homopolymers and copolymers formed from at least two different types of monomers.
- ranges provided are meant to include every specific range within, and combination of sub ranges between, the given ranges.
- a range from 1 - 5 includes specifically 1 , 2, 3, 4 and 5, as well as sub ranges such as 2-5, 3-5, 2-3, 2-4,
- compositions (nanoemulsions) of the instant disclosure can be free or essentially free of all components and elements positively recited throughout the instant disclosure.
- an overlapping compound does not represent more than one component.
- a fatty acid may be characterized as both a nonionic surfactant and a fatty compound. If a particular composition includes both a nonionic surfactant and a fatty compound, a single fatty acid will serve as only the nonionic surfactant or as only the fatty compound (the single fatty acid does not serve as both the nonionic surfactant and the fatty compound).
Abstract
Description
Claims
Applications Claiming Priority (3)
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US202063002820P | 2020-03-31 | 2020-03-31 | |
FR2006214A FR3111270B1 (en) | 2020-06-15 | 2020-06-15 | HAIR CARE COMPOSITIONS |
PCT/US2021/025077 WO2021202656A1 (en) | 2020-03-31 | 2021-03-31 | Hair care compositions comprising polyol, c2-6 monoalcohol and cationic surfactant |
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EP4125789A1 true EP4125789A1 (en) | 2023-02-08 |
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EP21719011.5A Pending EP4125789A1 (en) | 2020-03-31 | 2021-03-31 | Hair care compositions comprising polyol, c2-6 monoalcohol and cationic surfactant |
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CN (1) | CN115551469A (en) |
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DE102020123257A1 (en) * | 2020-09-07 | 2022-03-10 | Henkel Ag & Co. Kgaa | CLEAR LIQUID HAIR MASK WITH CONSISTENCY TRANSFORMATION AND IMMEDIATE EFFECT DURING APPLICATION |
FR3124949A1 (en) * | 2021-07-09 | 2023-01-13 | L'oreal | compositions for the hair |
EP4329715A1 (en) | 2021-04-29 | 2024-03-06 | L'oreal | Hair compositions comprising at least 50% polyol |
FR3124081B1 (en) * | 2021-06-21 | 2023-12-29 | Oreal | Cosmetic composition comprising at least one polar oil, a polyol and at least one hydrophilic active ingredient |
CN114344176A (en) * | 2022-01-25 | 2022-04-15 | 广东柏俐臣生物科技有限公司 | DIY essence cream-changeable hair care cream and preparation method thereof |
WO2023172867A1 (en) * | 2022-03-10 | 2023-09-14 | The Procter & Gamble Company | Hair conditioning composition |
DE102022202842A1 (en) * | 2022-03-23 | 2023-09-28 | Henkel Ag & Co. Kgaa | Hair conditioning agent for straightening hair |
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US4954335A (en) * | 1989-05-31 | 1990-09-04 | Helene Curtis, Inc. | Clear conditioning composition and method to impart improved properties to the hair |
DE19962879A1 (en) * | 1999-12-24 | 2001-06-28 | Henkel Kgaa | Skin or hair care composition includes a combination of a dialkyl carbonate and a dialkyl ether to improve hair compatibility, feel and split repair |
DE10103093A1 (en) * | 2001-01-24 | 2002-07-25 | Beiersdorf Ag | Stable self-heating aqueous hair-treatment compositions, used as e.g. conditioners, contain a polyalcohol with negative dissolution enthalpy on moist hair, together with quaternary ammonium compounds |
US8349301B2 (en) * | 2002-06-04 | 2013-01-08 | The Procter & Gamble Company | Shampoo containing a gel network |
MX2008000049A (en) * | 2005-07-07 | 2008-03-19 | Procter & Gamble | Conditioning compositions comprising coacervate and gel matrix. |
KR101774460B1 (en) * | 2011-10-27 | 2017-09-06 | 애경산업(주) | Hair Conditioning Composition |
JP2014122191A (en) * | 2012-12-21 | 2014-07-03 | L'oreal Sa | Cosmetic composition comprising oil, nonionic surfactant and jasmonic acid derivative |
FR3064475B1 (en) * | 2017-03-31 | 2020-10-23 | Oreal | COSMETIC TREATMENT PROCESS FOR KERATINIC FIBERS INCLUDING THE APPLICATION OF A BASIC COMPOSITION AND OF A COMPOSITION CONTAINING A POLYOL |
US20200206112A1 (en) * | 2018-12-31 | 2020-07-02 | L'oreal | Hair coloring compositions and methods of use |
JP7241890B2 (en) * | 2018-12-31 | 2023-03-17 | ロレアル | Hair care and conditioning compositions |
BR112021023766A2 (en) * | 2019-06-28 | 2022-01-11 | Oreal | Cosmetic compositions and hair care method |
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- 2021-03-31 EP EP21719011.5A patent/EP4125789A1/en active Pending
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WO2021202656A1 (en) | 2021-10-07 |
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