JP2023539200A - Cosmetic composition, its kit, its manufacturing method and its usage method - Google Patents

Abstract

Cosmetic compositions, kits thereof, and methods of making and using such cosmetic compositions. A cosmetic composition comprising about 0.1 to about 25% by weight citric acid, about 0.2 to about 40% by weight of one or more urea compounds, and about 20% or more water, the composition comprising: Cosmetic compositions, all based on the total weight of the cosmetic composition. Furthermore, the cosmetic composition is typically formulated such that the molar ratio of (a) citric acid to (b) urea compound is 1 or less. [Selection diagram] None

Description

CROSS-REFERENCE TO RELATED APPLICATIONS This application is a reference to U.S. patent application no. 17/007,752, filed on August 31, 2020, and French patent application no. and which are hereby incorporated by reference in their entirety.

The present disclosure relates to cosmetic compositions and kits thereof. Aspects of the present disclosure also relate to methods of making such cosmetic compositions and methods of using such cosmetic compositions.

Consumers desire new and improved compositions for treating, caring for and/or conditioning keratinous substances such as skin or hair. Hair and skin are exposed to intrinsic and extrinsic influences such as environmental factors, mechanical factors, chemical factors, heat and aging.

For example, the action of external environmental factors such as light and bad weather, and also heat, such as brushing, combing, dyeing, bleaching, permanent waving and/or decurling, blow-drying, ironing, or even repeated hair washing; The effects of mechanical or chemical treatments can damage and weaken the hair fibers. Over time, the hair becomes dry, coarse, brittle or dull, especially in the brittle areas, which can eventually result in split ends.

Thus, in order to overcome these drawbacks, it is necessary to give it satisfactory cosmetic properties, especially in terms of smoothness, gloss, flexibility, compliance, lightness, natural feel and good unraveling properties. , it is common practice to rely on hair care products with compositions intended to condition the hair. Hair care compositions, such as hair conditioners and/or treatment compositions, are used to improve or restore hair to its natural luster, shine and flexibility, or to improve the feel, appearance and manageability of hair. It may also be used before and after washing the hair with shampoo and/or before and after applying chemical treatments to the hair.

It is understood that different forms of hair care and skin care compositions can provide different benefits.

However, there is still a need to provide improved hair manageability, such as improved hair alignment, reduced undesirable volume (particularly reduced frizz), and increased shine. In addition to the care and conditioning benefits, the product also provides other benefits such as styling, volumizing, shaping, curl definition (for curly or wavy hair), and restylability or reshaping. There is a need to develop cosmetic products that can simultaneously provide the following: (without the need for reapplication).

Aspects of the present disclosure relate to cosmetic compositions and kits thereof. Further aspects of the present disclosure relate to methods of making such cosmetic compositions and methods of using such cosmetic compositions.

The cosmetic compositions disclosed herein advantageously exhibit increased durability and/or strength, perceptible visible shine, fiber alignment, reduced frizz, and/or increased hair manageability. provide. Without being bound to any particular theory, the inventors believe that cosmetic compositions, particularly those containing certain deep eutectic solvent systems, can diffuse into the hair and form an extensive network. think. The extensive mesh can strengthen and/or stabilize the hair structure, ultimately reducing hair frizz associated with high humidity.

Furthermore, the cosmetic composition may be capable of self-association, usually through hydrogen bonding interactions, which may enable the cosmetic composition to strengthen and/or strengthen hair, especially damaged hair. In some embodiments, the cosmetic composition restores damaged hair. The inventors have also surprisingly discovered that the cosmetic composition can increase the straightness of hair without the use of heat from, for example, irons, hair dryers, etc.

The cosmetic composition typically comprises (a) about 0.1 to about 25% by weight citric acid;
(b) about 0.2 to about 40% by weight of one or more urea compounds; and (c) about 20% or more of water;
The weight ratio of (a) citric acid to (b) urea compound is less than or equal to 1, and all weight percentages are based on the total weight of the cosmetic composition.

The cosmetic composition may include an amount of a deep eutectic solvent. Preferably, the amount of deep eutectic solvent is greater than or equal to 1% by weight. The deep eutectic solvent may include (a) a urea compound and (b) citric acid.

Preferably, the urea compound is selected from dimethylurea, hydroxylethylurea, urea and mixtures thereof. In some cases, the weight ratio of (a) citric acid to (b) urea compound is about 1:1 to 1:8. In further instances, the weight ratio of (a) citric acid to (b) urea compound is about 1:1 to 1:6.

In at least one embodiment, the cosmetic composition comprises from about 2.5 to about 40% by weight of one or more urea compounds and from about 1.5 to about 25% by weight citric acid. In at least one other embodiment, the cosmetic composition comprises about 20 to about 40% by weight of one or more urea compounds and about 15 to about 25% by weight citric acid.

The cosmetic composition may further include from about 0.1 to about 10% by weight of one or more cationic surfactants. The one or more cationic surfactants include cetrimonium chloride, stearimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium methosulfate. Monium chloride, arachidotrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetyldimonium chloride, oleamidepropyldimethylamine, linolamidepropyldimethylamine, stearamidepropyldimethylamine, oleylhydroxyethylimidazoline, stearamide Propyl dimethylamine, behenamidopropyl dimethylamine, behenamidopropyl diethylamine, behenamide ethyl diethylamine, behenamide ethyl dimethylamine, arachidamide propyl dimethylamine, arachidamide propyl diethylamine, arachidamide ethyl diethylamine, arachidamide ethyl dimethyl It may be selected from amines and mixtures thereof.

In some cases, the cosmetic composition includes from about 0.1% to about 25% by weight of one or more aliphatic compounds. The aliphatic compound may be selected from aliphatic alcohols, fatty acid esters, aliphatic ethers, fatty acids, waxes, oils, derivatives thereof and mixtures thereof.

Additionally or alternatively, the cosmetic composition may contain from about 20 to about 95% by weight polyol. Suitable polyols include ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, pentylene glycol, diethylene glycol, dipropylene glycol, 1,3 propanediol, glycerin, polyethylene glycol or mixtures thereof.

The cosmetic composition may contain from about 0.1 to about 20% by weight of a thickening agent. Thickeners include polyacrylate crosspolymers or crosslinked polyacrylate polymers, cationic acrylate copolymers, anionic acrylic or carboxylic acid polymers, polyacrylamide polymers, polysaccharides, rubbers, polyquaternium, vinylpyrrolidone homopolymers/copolymers, It may be selected from C8-24 hydroxyl substituted fatty acids, C8-24 conjugated fatty acids, sugar fatty acid esters, polyglyceryl esters and mixtures thereof.

Aspects of the present disclosure relate to methods of manufacturing cosmetic compositions. The method of manufacturing a cosmetic composition typically includes:
(I)
(a) about 0.1 to about 25% by weight citric acid; and (b) about 0.2 to about 40% by weight of one or more urea compounds selected from dimethylurea, hydroxylethylurea, or combinations thereof. producing a deep eutectic solvent system, wherein the weight ratio of (a) citric acid to (b) urea compound is 1 or less;
(II) adding the deep eutectic solvent system of (I) to the base composition to produce a cosmetic composition.

The method includes the steps of mixing (a) citric acid and (b) a urea compound, and optionally, mixing (a) citric acid and (b) a urea compound at a temperature of about 70°C to about 90°C. The method may further include a step of heating.

Further aspects of the disclosure relate to cosmetic compositions prepared by the methods of making cosmetic compositions disclosed herein.

According to a further aspect, a method of treating hair is provided. Methods of treating hair typically include
(I) optionally applying shampoo to the hair;
(II) optionally rinsing the hair to remove at least a portion of the shampoo;
(III)
(a) about 0.1 to about 25% by weight citric acid; and (b) about 0.2 to about 40% by weight of one or more urea compounds selected from dimethylurea, hydroxylethylurea, or combinations thereof. applying a cosmetic composition comprising: a cosmetic composition in which the weight ratio of (a) citric acid to (b) urea compound is 1 or less;
(IV) optionally rinsing the hair to remove at least a portion of the cosmetic composition.

Implementations of the present technology will now be described by way of example only with reference to the accompanying figures.

1 is a photograph of a hair swatch treated with a composition according to the present disclosure and subjected to humidity according to embodiments of the disclosure. 1 is a photograph of a hair swatch treated with a composition according to the present disclosure and subjected to humidity according to embodiments of the disclosure. 1 is a bar graph illustrating the durability of hair swatches after treatment with exemplary cosmetic compositions according to disclosed embodiments. 1 is a bar graph depicting the denaturation temperature of a hair swatch following treatment with an exemplary cosmetic composition according to disclosed embodiments. 1 is a bar graph illustrating the durability of hair swatches after treatment with comparative and exemplary cosmetic compositions according to disclosed embodiments. 1 is a bar graph depicting the denaturation temperature of hair swatches after treatment with comparative and exemplary cosmetic compositions according to disclosed embodiments. 1 is a bar graph depicting Young's modulus of hair swatches after treatment with comparative and exemplary cosmetic compositions according to embodiments of the disclosure. 1 is a bar graph depicting break elongation of hair swatches after treatment with comparative and exemplary cosmetic compositions according to disclosed embodiments.

It is to be understood that the various aspects are not limited to the arrangements and instrumentality shown in the drawings.

Aspects of the present disclosure relate to cosmetic compositions and kits thereof. Further aspects of the present disclosure relate to methods of making such cosmetic compositions and methods of using such cosmetic compositions. The cosmetic compositions disclosed herein advantageously exhibit increased durability and/or strength, perceptible visible shine, fiber alignment, reduced frizz, and/or increased hair manageability. provide.

The inventors have surprisingly discovered that certain ratios of compounds make it possible to provide improved durability and strength to cosmetic compositions in combination with reduced hair frizz. Without being bound to any particular theory, the inventors believe that cosmetic compositions, particularly those containing certain deep eutectic solvent (DES) systems, diffuse into the hair and form an extensive network. We believe that it is possible to form a The extensive mesh can strengthen and/or stabilize the hair structure, ultimately reducing hair frizz associated with high humidity.

Cosmetic compositions, and/or their ingredients, typically have the ability to self-associate through non-covalent interactions (i.e. hydrogen bonding, ionic and van der Waals interactions), thereby making the cosmetic composition may make it possible to strengthen and/or strengthen hair, especially damaged hair. In some embodiments, the cosmetic composition restores damaged hair. Furthermore, the inventors have surprisingly discovered that such cosmetic compositions can increase the straightness/alignment of hair fibers without the use of heat from, for example, irons, hair dryers, etc. Cosmetic compositions such as those containing the DES system have also shown evidence of shine benefits that are currently being investigated.

Cosmetic compositions according to disclosed embodiments typically include:
(a) about 0.1 to about 25% by weight citric acid;
(b) about 0.2 to about 40% by weight of one or more urea compounds; and (c) about 20% or more of water;
The weight ratio of (a) citric acid to (b) urea compound is less than or equal to 1, and all weight percentages are based on the total weight of the cosmetic composition.

The cosmetic composition may include an amount of a deep eutectic solvent system (“DES”). In some cases, the amount of deep eutectic solvent is about 1% or more, preferably about 2% or more, about 3% or more, about 4% or more, about 5% by weight or more, about 6% by weight or more, about 7% by weight or more, about 8% by weight or more, about 9% by weight or more, about 10% by weight or more, about 12% by weight or more, about 14% by weight or more, about 16% by weight % or more, about 18 wt% or more, about 20 wt% or more, about 22 wt% or more, about 24 wt% or more, about 26 wt% or more, about 28 wt% or more, about 30 wt% or more, about 32 wt% or more , about 34% by weight or more, about 36% by weight or more, about 40% by weight or more, about 45% by weight or more, about 50% by weight or more, or about 60% by weight or more.

The cosmetic composition may be formulated to have a weight ratio of (i) citric acid to (ii) urea compound which may be from about 10:1 to about 2:10. In some instances, the cosmetic composition has a composition of about 10:1 to about 0.5:10, about 9:1 to about 0.5:10, about 8:1 to about 0.5:10, about 7:1 1 to about 0.5:10, about 6:1 to about 0.5:10, about 5:1 to about 0.5:10, about 4:1 to about 0.5:10, about 3:1 to about About 0.5:10; 10:1 to about 1:10, about 9:1 to about 1:10, about 8:1 to about 1:10, about 7:1 to about 1:10, about 6:1 ～about 1:10, about 5:1～about 1:10, about 4:1～about 1:10, about 3:1～about 1:10; 10:1～about 2:10, about 9:1～ Approximately 2:10, approximately 8:1 to approximately 2:10, approximately 7:1 to approximately 2:10, approximately 6:1 to approximately 2:10, approximately 5:1 to approximately 2:10, approximately 4:1 to Approximately 2:10, approximately 3:1 to approximately 2:10; approximately 10:1 to approximately 2:8, approximately 9:1 to approximately 2:8, approximately 8:1 to approximately 2:8, approximately 7:1 to Approximately 2:8, approximately 6:1 to approximately 2:8, approximately 5:1 to approximately 2:8, approximately 4:1 to approximately 2:8, approximately 3:1 to approximately 2:8; approximately 10:1 to Approximately 2:6, approximately 9:1 to approximately 2:6, approximately 8:1 to approximately 2:6, approximately 7:1 to approximately 2:6, approximately 6:1 to approximately 2:6, approximately 5:1 to Approximately 2:6, approximately 4:1 to approximately 2:6, approximately 3:1 to approximately 2:6; approximately 3:1 to approximately 1:10, approximately 3:1 to approximately 1:9, approximately 3:1 to approximately Approximately 1:8, approximately 3:1 to approximately 1:7, approximately 3:1 to approximately 1:6, approximately 3:1 to approximately 2:10, approximately 3:1 to approximately 2:9, approximately 3:1 to about 2:8, about 3:1 to about 2:7, about 3:1 to about 2:6, about 3:1 to about 2:5, about 3:1 to about 2:4, or about 3:1 ～about 2:3, about 2:1 to about 2:10, about 1:1 to about 2:10, about 3:1 to about 2:9, about 3:1 to about 2:8, about 3:1 ~2:7, between about 3:1 and about 2:6, between about 3:1 and about 2:5, between about 3:1 and about 2:4, or between about 3:1 and about 2:3. including ranges and subranges (e.g., about 3:1 to about 2:5, about 2:1 to about 2:5, about 1:1 to about 2:5, about 1:1 to about 2:4, etc.) It may be formulated to have a weight ratio of citric acid to urea compound(s).

The cosmetic composition may be formulated to have a molar ratio of (i) citric acid to (ii) urea compound which may be from about 10:1 to about 0.5:10. In some instances, the cosmetic composition has a 10:1 to about 0.5:10, about 9:1 to about 0.5:10, about 8:1 to about 0.5:10, about 7:1 - about 0.5:10, about 6:1 - about 0.5:10, about 5:1 - about 0.5:10, about 4:1 - about 0.5:10, about 3:1 - about 0.5:10; 10:1 to about 1:10, about 9:1 to about 1:10, about 8:1 to about 1:10, about 7:1 to about 1:10, about 6:1 to Approximately 1:10, approximately 5:1 to approximately 1:10, approximately 4:1 to approximately 1:10, approximately 3:1 to approximately 1:10; approximately 10:1 to approximately 2:10, approximately 9:1 to Approximately 2:10, approximately 8:1 to approximately 2:10, approximately 7:1 to approximately 2:10, approximately 6:1 to approximately 2:10, approximately 5:1 to approximately 2:10, approximately 4:1 to Approximately 2:10, approximately 3:1 to approximately 2:10; approximately 10:1 to approximately 2:8, approximately 9:1 to approximately 2:8, approximately 8:1 to approximately 2:8, approximately 7:1 to Approximately 2:8, approximately 6:1 to approximately 2:8, approximately 5:1 to approximately 2:8, approximately 4:1 to approximately 2:8, approximately 3:1 to approximately 2:8; approximately 10:1 to Approximately 2:6, approximately 9:1 to approximately 2:6, approximately 8:1 to approximately 2:6, approximately 7:1 to approximately 2:6, approximately 6:1 to approximately 2:6, approximately 5:1 to Approximately 2:6, approximately 4:1 to approximately 2:6, approximately 3:2 to approximately 2:6; approximately 2:1 to approximately 2:10, approximately 1:1 to approximately 2:10, approximately 3:2 to Approximately 2:9, approximately 3:2 to approximately 2:8, approximately 3:2 to approximately 2:7, approximately 3:2 to approximately 2:6, approximately 3:2 to approximately 2:5, approximately 3:2 to approximately about 2:4, about 3:2 to about 2:3, about 1:1 to about 1:4, about 1:1 to about 1:3, about 1:1 to about 1:2, or about 1:1 .3 to about 1:1.6, and ranges and subranges therebetween (e.g., about 3:2 to about 2:5, about 2:1 to about 2:5, about 1:1 to about 2:5, about The citric acid to urea compound(s) may be formulated to have a weight ratio of citric acid to urea compound(s) comprising 1:1 to about 2:4, etc.).

Preferably, the DES system includes citric acid and one or more urea compounds. In some cases, the DES system is formed from citric acid and one or more urea compounds, such as those selected from dimethylurea, hydroxylethylurea, urea, and mixtures thereof.

Additionally or alternatively, the combination of citric acid and urea compound(s) is in the form of a DES system prior to inclusion in the base of the cosmetic composition. The base of the cosmetic composition may be a composition of one or more ingredients of the cosmetic composition. For example, in some instances, the base composition may include all of the ingredients of the cosmetic composition apart from citric acid and urea compound(s). After the DES system has been incorporated into the base cosmetic composition, the cosmetic composition may at least partially contain the DES system.

Additionally or alternatively, the cosmetic composition may include arginine. In some cases, the arginine is l-arginine, d-arginine, and/or may be a racemic mixture.

Suitable ingredients, such as those listed below, may depend on the particular combination of other ingredients, the form of the cosmetic composition, and/or the use of the formulation (e.g., aqueous solution, lotion, gel, cream, spray, etc.). , which may be included or excluded from formulations for cosmetic compositions. Cosmetic compositions may be formulated, for example, as hair care compositions and/or hair cosmetic compositions and/or hair treatment compositions and/or skin care compositions and/or scalp care compositions for use on hair and/or skin. may be done.

Citric Acid Cosmetic compositions typically contain citric acid in an amount of about 0.1 to about 25% by weight, based on the total weight of the cosmetic composition. For example, the amount of citric acid present in the cosmetic composition may range from about 0.1% to about 25%, from about 0.1% to about 22%, from about 0.1% to about 20% by weight, about 0.1 to about 18% by weight, about 0.1 to about 16% by weight, about 0.1 to about 14% by weight, about 0.1 to about 12% by weight, about 0.1 to about 10% by weight, about 0.1 to about 9% by weight, about 0.1 to about 8% by weight, about 0.1 to about 7% by weight, about 0.1 to about 6% by weight, about 0.1 to about 5% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight, about 0.1 to about 2% by weight, about 0.1 to about 1% by weight; about 0.5 to about 25% by weight, about 0.5 to about 22% by weight, about 0.5 to about 20% by weight, about 0.5 to about 18% by weight, about 0.5 to about 16% by weight, about 0.5 to about 14% by weight, about 0.5 to about 12%, about 0.5 to about 10%, about 0.5 to about 9%, about 0.5 to about 8%, about 0.5 to about 7% by weight, about 0.5 to about 6%, about 0.5 to about 5%, about 0.5 to about 4%, about 0.5 to about 3%, about 0.5 to about 2% by weight, about 0.5 to about 1% by weight; about 1 to about 25% by weight, about 1 to about 22% by weight, about 1 to about 20% by weight, about 1 to about 18% by weight, about 1 to about 16% by weight, about 1 to about 14% by weight, about 1 to about 12% by weight, about 1 to about 10% by weight, about 1 to about 9% by weight, about 1 to about 8% by weight, about 1 to about 7% by weight %, about 1 to about 6%, about 1 to about 5%, about 1 to about 4%, about 1 to about 3%, about 1 to about 2%; about 3 to about 25%, about 1 to about 22% by weight, about 3 to about 20% by weight, about 3 to about 18% by weight, about 3 to about 16% by weight, about 3 to about 14% by weight, about 3 to about 12% by weight, about 3 ~ about 10% by weight, about 3 to about 9% by weight, about 3 to about 8% by weight, about 3 to about 7% by weight, about 3 to about 6% by weight, about 3 to about 5% by weight; about 5 to about 25% by weight, about 5 to about 22% by weight, about 5 to about 20% by weight, about 5 to about 18% by weight, about 5 to about 16% by weight, about 5 to about 14% by weight, about 5 to about 12% by weight %, about 5 to about 10%, about 5 to about 9%, about 5 to about 8%, about 5 to about 7%; about 10 to about 25%, about 10 to about 22%, about 10 to about 20% by weight, about 10 to about 18% by weight, about 10 to about 16% by weight, about 10 to about 14% by weight, about 10 to about 12% by weight; about 15 to about 25% by weight, about 15% by weight to about 22%, about 15 to about 20%, about 15 to about 18%; may be about 20 to about 25%, or about 20 to about 22%, including ranges and subranges thereof. include.

urea compound(s)
Cosmetic compositions typically include one or more urea compound(s) in an amount of about 0.2 to about 40% by weight, based on the total weight of the cosmetic composition. For example, the amount of one or more urea compound(s) present in the cosmetic composition may range from about 0.2% to about 35%, from about 0.2% to about 32% by weight, based on the total weight of the cosmetic composition. wt%, about 0.2 to about 30 wt%, about 0.2 to about 28 wt%, about 0.2 to about 26 wt%, about 0.2 to about 24 wt%, about 0.2 to about 22 wt%, about 0.2 to about 20 wt%, about 0.2 to about 18 wt%, about 0.2 to about 16 wt%, about 0.2 to about 14 wt%, about 0.2 to about 12 wt%, about 0.2 to about 10 wt%, about 0.2 to about 9 wt%, about 0.2 to about 8 wt%, about 0.2 to about 7 wt%, about 0.2 to about 6 wt%, about 0.2 to about 5 wt%, about 0.2 to about 4 wt%, about 0.2 to about 3 wt%, about 0.2 to about 2 wt%, about 0.2 to about 1 Weight%: about 0.5 to about 40 weight%, about 0.5 to about 35 weight%, about 0.5 to about 32 weight%, about 0.5 to about 30 weight%, about 0.5 to about 28 wt%, about 0.5 to about 26 wt%, about 0.5 to about 24 wt%, about 0.5 to about 22 wt%, about 0.5 to about 20 wt%, about 0.5 to about 18 wt%, about 0.5 to about 16 wt%, about 0.5 to about 14 wt%, about 0.5 to about 12 wt%, about 0.5 to about 10 wt%, about 0.5 to about 9 wt% wt%, about 0.5 to about 8 wt%, about 0.5 to about 7 wt%, about 0.5 to about 6 wt%, about 0.5 to about 5 wt%, about 0.5 to about 4 % by weight, about 0.5 to about 3%, about 0.5 to about 2%, about 0.5 to about 1%; about 1 to about 40%, about 1 to about 35%, about 1 to about 32% by weight, about 1 to about 30% by weight, about 1 to about 28% by weight, about 1 to about 26% by weight, about 1 to about 24% by weight, about 1 to about 22% by weight, about 1 to about 28% by weight about 20% by weight, about 1 to about 18% by weight, about 1 to about 16% by weight, about 1 to about 14% by weight, about 1 to about 12% by weight, about 1 to about 10% by weight, about 1 to about 9% by weight wt%, about 1 to about 8 wt%, about 1 to about 7 wt%, about 1 to about 6 wt%, about 1 to about 5 wt%, about 1 to about 4 wt%, about 1 to about 3 wt% , about 1 to about 2% by weight; about 3 to about 40% by weight, about 3 to about 35% by weight, about 3 to about 32% by weight, about 3 to about 30% by weight, about 3 to about 28% by weight, about 3 to about 26% by weight, about 3 to about 24% by weight, about 3 to about 22% by weight, about 3 to about 20% by weight, about 3 to about 18% by weight, about 3 to about 16% by weight, about 3 to about about 14% by weight, about 3 to about 12% by weight, about 3 to about 10% by weight, about 3 to about 9% by weight, about 3 to about 8% by weight, about 3 to about 7% by weight, about 3 to about 6% by weight wt%, about 3 to about 5 wt%; about 5 to about 40 wt%, about 5 to about 35 wt%, about 5 to about 32 wt%, about 5 to about 30 wt%, about 5 to about 28 wt% , about 5 to about 26%, about 5 to about 24%, about 5 to about 22%, about 5 to about 20%, about 5 to about 18%, about 5 to about 16%, about 5 to about 14% by weight, about 5 to about 12% by weight, about 5 to about 10% by weight, about 5 to about 9% by weight, about 5 to about 8% by weight, about 5 to about 7% by weight; about 10 to about about 40% by weight, about 10 to about 35% by weight, about 10 to about 32% by weight, about 10 to about 30% by weight, about 10 to about 28% by weight, about 10 to about 26% by weight, about 10 to about 24% by weight wt%, about 10 to about 22 wt%, about 10 to about 20 wt%, about 10 to about 18 wt%, about 10 to about 16 wt%, about 10 to about 14 wt%, about 10 to about 12 wt% about 15 to about 40% by weight, about 15 to about 35% by weight, about 15 to about 32% by weight, about 15 to about 30% by weight, about 15 to about 28% by weight, about 15 to about 26% by weight, about 15 to about 24% by weight, about 15 to about 22% by weight, about 15 to about 20% by weight, about 15 to about 18% by weight; about 20 to about 40% by weight, about 20 to about 35% by weight, about 20 to about about 32% by weight, about 20 to about 30% by weight, about 20 to about 28% by weight, about 20 to about 26% by weight, about 20 to about 24% by weight; about 25 to about 40% by weight, about 25 to about 35% by weight % by weight, from about 25 to about 32%, from about 25 to about 30%; from about 30 to about 40%, or from about 30 to about 35%, including ranges and subranges thereof.

［式中、Ｒ_１、Ｒ_２、Ｒ_３及びＲ_４は、水素、Ｃ_４～Ｃ_１０非置換アリール、Ｃ_４～Ｃ_１０置換アリール、Ｃ_２～Ｃ_１０非置換複素環、Ｃ_２～Ｃ_１０置換複素環、Ｃ_１～Ｃ_１０非置換アルキル、Ｃ_１～Ｃ_１０置換アルキル、Ｃ_３～Ｃ_１０非置換シクロアルキル及びＣ_３～Ｃ_１０置換シクロアルキルから独立して選択される］
による構造を有していてもよい。 The urea compound has the following formula:

[Wherein R ₁ , R ₂ , R ₃ and R ₄ are hydrogen, C ₄ to C ₁₀ unsubstituted aryl, C ₄ to C ₁₀ substituted aryl, C ₂ to C ₁₀ unsubstituted heterocycle, C ₂ to C 10 independently selected from _10- substituted heterocycle, C ₁ -C ₁₀ unsubstituted alkyl, C ₁ -C ₁₀ substituted alkyl, C ₃ -C ₁₀ unsubstituted cycloalkyl and C ₃ -C ₁₀ substituted cycloalkyl]
It may have a structure according to.

The urea compound is preferably selected from dimethylurea, hydroxyethylurea, urea or mixtures thereof. Non-limiting examples of urea compounds include urea, urea derivatives, imidazolidinyl urea, diazolidinyl urea, m-dimethylaminophenyl urea, dimethyl urea, hydroxyethyl urea, N-(2-hydroxyethyl) urea; N-(2- hydroxypropyl)urea; N-(3-hydroxypropyl)urea; N-(2,3-dihydroxypropyl)urea; N-(2,3,4,5,6-pentahydroxyhexyl)urea; N-methyl- N-(1,3,4,5,6-pentahydroxy-2-hexyl)urea; N-methyl-N'-(1-hydroxy-2-methyl-2-propyl)urea; N-(1-hydroxy -2-methyl-2-propyl)urea; N-(1,3-dihydroxy-2-propyl)urea; N-(tris-hydroxymethylmethyl)urea; N-ethyl-N'-(2-hydroxyethyl) Urea; N,N-bis(2-hydroxyethyl)urea; N,N'-bis(2-hydroxyethyl)urea; N,N-bis(2-hydroxypropyl)urea; N,N'-bis(2-hydroxyethyl)urea; -hydroxypropyl)urea; N,N-bis(2-hydroxyethyl)-N'-propylurea; N,N-bis(2-hydroxypropyl)-N'-(2-hydroxyethyl)urea; N-tert -Butyl-N'-(2-hydroxyethyl)-N'-(2-hydroxypropyl)urea; N-(1,3-dihydroxy-2-propyl)-N'-(2-hydroxyethyl)urea; N , N-bis(2-hydroxyethyl). -N',N'-dimethylurea; N,N,N',N'-tetrakis(2-hydroxyethyl)urea; N',N'-bis(2-hydroxyethyl)-N' and N'-bis Contains (2-hydroxypropyl)-urea.

Water The total amount of water in the cosmetic composition can vary, but is typically about 20% or more by weight based on the total weight of the cosmetic composition. In some instances, the total amount of water is about 20 to about 99%, about 20 to about 95%, about 20 to about 90%, about 20 to about 80% by weight, based on the total weight of the cosmetic composition. %, about 20 to about 70% by weight, about 20 to about 60% by weight, about 20 to about 50% by weight, about 20 to about 40% by weight; about 30 to about 99% by weight, about 30 to about 95% by weight, about 30 to about 90% by weight, about 30 to about 80% by weight, about 30 to about 70% by weight, about 30 to about 60% by weight, about 30 to about 50% by weight, about 30 to about 40% by weight; about 40 ~99% by weight, about 40 to about 95% by weight, about 40 to about 90% by weight, about 40 to about 80% by weight, about 40 to about 70% by weight, about 40 to about 60% by weight, about 40 to about 50% by weight; about 50 to about 99% by weight, about 50 to about 95% by weight, about 50 to about 90% by weight, about 50 to about 80% by weight, about 50 to about 70% by weight, about 50 to about 60% by weight %; about 60 to about 99% by weight, about 60 to about 95% by weight, about 60 to about 90% by weight, about 60 to about 80% by weight, about 60 to about 70% by weight; about 70 to about 99% by weight, about 70 to about 95% by weight, about 70 to about 90% by weight, about 70 to about 80% by weight; about 80 to about 99% by weight, about 80 to about 95% by weight, about 80 to about 90% by weight; about 90 to about 99%, about 90 to about 95%; or about 95 to about 99%, including ranges and subranges therebetween.

Cationic surfactant(s)
The cosmetic composition may optionally include cationic surfactant(s). The amount of cationic surfactant(s) may be from about 0.1 to about 10% by weight of the total weight of the cosmetic composition. In some instances, the cationic surfactant(s) is about 0.1% to about 10%, about 0.1% to about 8%, about 0.1% by weight, based on the total weight of the cosmetic composition. 1 to about 6% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight; about 0.2 to about 10% by weight, about 0.2 to about 8% by weight, about 0. 2 to about 6% by weight, about 0.2 to about 4% by weight, about 0.2 to about 3% by weight; about 0.5 to about 10% by weight, about 0.5 to about 8% by weight, about 0. 5 to about 6% by weight, about 0.5 to about 4% by weight, about 0.5 to about 3% by weight; about 1 to about 10% by weight, about 1 to about 8% by weight, about 1 to about 6% by weight , about 1 to about 4% by weight, about 1 to about 3% by weight; about 1.5 to about 10% by weight, about 1.5 to about 8% by weight, about 1.5 to about 6% by weight, about 1. 5 to about 4% by weight, about 1.5 to about 3% by weight; about 2 to about 10% by weight, about 2 to about 8% by weight, about 2 to about 6% by weight, about 2 to about 4% by weight, about Amounts ranging from 2 to about 3% by weight, including ranges and subranges therebetween.

In certain embodiments, the cationic surfactant is cetrimonium chloride, steartrimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachid Trimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetyldimonium chloride, oleamidepropyldimethylamine, linolamidepropyldimethylamine, isostearamidepropyldimethylamine, oleylhydroxyethylimidazoline, stearamidepropyldimethylamine , behenamide propyl dimethylamine, behenamide propyl diethylamine, behenamide ethyl diethylamine, behenamide ethyl dimethylamine, arachidamide propyl dimethylamine, arachidamide propyl diethylamine, arachidamide ethyl diethylamine, arachidamide ethyl dimethylamine and the like or selected from.

Additional non-limiting examples of cationic surfactants include behenarkonium chloride, benzethonium chloride, cetylpyridinium chloride, lauralkonium chloride, cetalkonium chloride, cetrimonium bromide, cetrimonium chloride, cetylamine. Hydrofluoride, chloralyl methenamine chloride (quaternium-15), distearyldimonium chloride (quaternium-5), dodecyldimethylethylbenzyl ammonium chloride (quaternium-14), quaternium-22, quaternium-26, quaternium-18 hecto Wright, dimethylaminoethyl chloride hydrochloride, cysteine hydrochloride, diethanolammonium POE (10) olethyl ether phosphate, diethanolammonium POE (3) oleyl ether phosphate, tallow alkonium chloride, dimethyldioctadecylammonium bentonite, stearalkonium chloride, Domiphene bromide, denatonium benzoate, myristalkonium chloride, laurtrimonium chloride, ethylenediamine dihydrochloride, guanidine hydrochloride, pyridoxine hydrochloride, iofetamine hydrochloride, meglumine hydrochloride, methylbenzethonium chloride, miltrimonium bromide, oleyltrimonium chloride, polyquaternium-1, procaine hydrochloride, cocobetaine, stearalkonium bentonite, stearalkonium hektonite, stearyltrihydroxyethylpropylenediamine dihydrofluoride, tallow trimonium chloride, and hexadecyltrimethylammonium brolide and mixtures thereof. Can be mentioned.

The cationic surfactant(s) also optionally include polyoxyalkylenated, primary, secondary or tertiary aliphatic amines or salts thereof, and quaternary ammonium salts, and It may also be selected from mixtures thereof. In some cases, it is useful to use salts, such as chloride salts of quaternary ammonium compounds.

［式中、Ｒ_８～Ｒ_１１基は、同一でも異なっていてもよく、１～３０炭素原子を含む、直鎖若しくは分岐、飽和若しくは不飽和の脂肪族基、又はアリール若しくはアルキルアリールなどの芳香族基を表し、Ｒ_８～Ｒ_１１基の少なくとも１つは、８～３０炭素原子、好ましくは１２～２４炭素原子を含む基を示す］
に対応するものを含む。脂肪族基は、殊に酸素、窒素、硫黄及びハロゲンなどのヘテロ原子を含んでいてもよい。脂肪族基は例えば、Ｃ_１～Ｃ_３０アルキル、Ｃ_２～Ｃ_３０アルケニル、Ｃ_１～Ｃ_３０アルコキシ、ポリオキシ（Ｃ_２～Ｃ_６）アルキレン、Ｃ_１～Ｃ_３０アルキルアミド、（Ｃ_１２～Ｃ_２２）アルキルアミド（Ｃ_２～Ｃ_６）アルキル、（Ｃ_１２～Ｃ_２２）アルキルアセテート及びＣ_１～Ｃ_３０ヒドロキシアルキル基から選ばれ；Ｘ^－は、ハライド、ホスフェート、アセテート、ラクテート、（Ｃ_１～Ｃ_４）アルキルサルフェート、及び（Ｃ_１～Ｃ_４）アルキル－又は（Ｃ_１～Ｃ_４）アルキルアリールスルホネートの群から選ばれる陰イオンである。 Aliphatic amines generally contain at least one C ₈ -C ₃₀ hydrocarbon chain. For example, quaternary ammonium salts that may be incorporated in certain instances have the following general formula:

[In the formula, the R ₈ to R ₁₁ groups may be the same or different, and are straight chain or branched, saturated or unsaturated aliphatic groups containing 1 to 30 carbon atoms, or aromatic groups such as aryl or alkylaryl. At least one of the R ₈ to R ₁₁ groups represents a group containing 8 to 30 carbon atoms, preferably 12 to 24 carbon atoms]
Including those corresponding to. Aliphatic groups may also contain heteroatoms such as oxygen, nitrogen, sulfur and halogen, among others. Aliphatic groups are, for example, C ₁ -C ₃₀ alkyl, C ₂ -C ₃₀ alkenyl, C ₁ -C ₃₀ alkoxy, polyoxy(C ₂ -C ₆ )alkylene, C ₁ -C ₃₀ alkylamide, (C ₁₂ -C 30 ₂₂ ) alkylamido selected from ( _C2 - _C6 ⁾ alkyl, _{( C12} - _C22 ) alkyl acetate and C1 _{- C30} hydroxyalkyl groups; -C ₄ )alkyl sulfate, and (C ₁ -C ₄ )alkyl- or (C ₁ -C ₄ )alkylaryl sulfonate.

On the other hand, among the quaternary ammonium salts having the structure according to the above general formula (III), tetraalkylammonium salts, such as dialkyldimethylammonium salts or alkyltrimethylammonium salts in which the alkyl group contains approximately 12 to 22 carbon atoms, For example, behenyltrimethylammonium salts, distearyldimethylammonium salts, cetyltrimethylammonium salts or benzyldimethylstearylammonium salts, or on the other hand oleocetyldimethylhydroxyethylammonium salts, palmitylamidopropyltrimethylammonium salts, stearamidopropyltrimethylammonium salts and Stearamidopropyldimethylcetearylammonium salt is preferred.

［式中、Ｒ_１２は、例えば獣脂脂肪酸に由来する８～３０炭素原子を含むアルケニル又はアルキル基を表し、Ｒ_１３は水素原子、Ｃ_１～Ｃ_４アルキル基又は８～３０炭素原子を含むアルキル若しくはアルケニル基を表し、Ｒ_１４はＣ_１～Ｃ_４アルキル基を表し、Ｒ_１５は水素原子又はＣ_１～Ｃ_４アルキル基を表し、Ｘ^－は、ハライド、ホスフェート、アセテート、ラクテート、アルキルサルフェート、アルキル又はアルキルアリールスルホネートの群から選ばれる陰イオンであり、アルキル及びアリール基は、好ましくはそれぞれ１～２０炭素原子及び６～３０炭素原子を含む］
による構造を有するものを含む。Ｒ_１２及びＲ_１３は、好ましくは、例えば、獣脂脂肪酸に由来する、１２～２１炭素原子を含有するアルケニル又はアルキル基の混合物を示し、Ｒ_１４は好ましくはメチル基を示し、Ｒ_１５は好ましくは水素原子を示す。そのような製品は、例えば、Ｒｅｗｏ社によって名称ＲＥＷＯＱＵＡＴ Ｗ ７５の下で販売されている。 Examples of quaternary ammonium salts of imidazolines that may be incorporated in certain instances include the general formula given below:

[In the formula, R ₁₂ represents an alkenyl or alkyl group containing 8 to 30 carbon atoms derived from, for example, tallow fatty acid, and R ₁₃ is a hydrogen atom, a C ₁ -C ₄ alkyl group, or an alkyl group containing 8 to 30 carbon atoms. or represents an alkenyl group, R ₁₄ represents a C ₁ to C ₄ alkyl group, R ₁₅ represents a hydrogen atom or a C ₁ to C ₄ alkyl group, and X ⁻ represents a halide, phosphate, acetate, lactate, alkyl sulfate, an anion selected from the group of alkyl or alkylaryl sulfonates, where the alkyl and aryl groups preferably contain from 1 to 20 carbon atoms and from 6 to 30 carbon atoms, respectively]
Including those with a structure according to R ₁₂ and R ₁₃ preferably represent a mixture of alkenyl or alkyl groups containing 12 to 21 carbon atoms, for example derived from tallow fatty acids, R ₁₄ preferably represents a methyl group and R ₁₅ preferably Indicates a hydrogen atom. Such a product is, for example, sold under the name REWOQUAT W 75 by the company Rewo.

［式中、Ｒ_１６は、任意選択的に、ヒドロキシル化された、及び／又は１個又は複数の酸素原子が介在する、およそ１６～３０炭素原子を含むアルキルラジカルを示し、Ｒ_１７は、水素又は１～４炭素原子を含むアルキルラジカル又は水素及び１～４炭素原子を含むアルキルラジカルから選ばれる同一でも異なってもよい、（Ｒ_１６ａ）（Ｒ_１７ａ）（Ｒ_１８ａ）Ｎ－（ＣＨ_２）_３、Ｒ_１６ａ、Ｒ_１７ａ、Ｒ_１８ａ、Ｒ_１８、Ｒ_１９、Ｒ_２０及びＲ_２１基から選ばれ；Ｘ^－は、ハライド、アセテート、ホスフェート、ニトレート及びメチルサルフェートの群から選ばれる陰イオンである］
による構造を有するものを含む。そのような化合物は、例えばＦｉｎｅｔｅｘ社によって販売されているＦｉｎｑｕａｔ ＣＴＰ（クオタニウム８９）、及びＦｉｎｅｔｅｘ社によって販売されているＦｉｎｑｕａｔ ＣＴ（クオタニウム７５）である。 Examples of quaternary diammonium or triammonium salts that may be incorporated in certain instances include the following general formula:

[wherein R ₁₆ represents an alkyl radical containing approximately 16 to 30 carbon atoms, optionally hydroxylated and/or intervening with one or more oxygen atoms, and R ₁₇ is hydrogen or (R _16a )(R _17a )(R _18a )N-(CH ₂ ) which may be the same or different selected from alkyl radicals containing 1 to 4 carbon atoms or hydrogen and alkyl radicals containing 1 to 4 carbon atoms. ₃ , R _16a , R _17a , R _18a , R ₁₈ , R ₁₉ , R ₂₀ and R ₂₁ groups; X ⁻ is an anion selected from the group of halide, acetate, phosphate, nitrate and methyl sulfate ]
Including those with a structure according to Such compounds are, for example, Finquat CTP (Quaternium 89), sold by Finetex, and Finquat CT (Quaternium 75), sold by Finetex.

から選択され、
Ｂは

から選択され、ここで、Ｒ_６及びＲ_７は同一又は異なり、Ｈ又は１～４個のＣ原子を有するアルキル鎖、１～４個のＣ原子を有するヒドロキシルアルキル鎖及び２～４個のＣ原子を有するジヒドロキシルアルキル鎖であり、

Ｒ_８及びＲ_９は同一又は異なり、１～４個のＣ原子を有するアルキル鎖、１～４個のＣ原子を有するヒドロキシルアルキル鎖及び２～４個のＣ原子を有するジヒドロキシルアルキル鎖であり、Ｒ_１０は１～４個のＣ原子を有するアルキル鎖、１～４個のＣ原子を有するヒドロキシルアルキル鎖又は２～４個のＣ原子を有するジヒドロキシルアルキル鎖である］
による構造を有するものを含む。 Examples of cationic/cationic surfactants that may be incorporated in certain instances include the general formula given below:
R4-A-R5--B
[wherein R4 is a saturated or unsaturated, straight or branched alkyl chain with 8 to 24 C atoms, R5 is a straight or branched alkyl chain with 1 to 4 C atoms, A is

selected from
B is

wherein R ₆ and R ₇ are the same or different and are selected from H or an alkyl chain with 1 to 4 C atoms, a hydroxylalkyl chain with 1 to 4 C atoms and a hydroxylalkyl chain with 2 to 4 C atoms. is a dihydroxylalkyl chain having atoms;

R ₈ and R ₉ are the same or different and are an alkyl chain with 1 to 4 C atoms, a hydroxylalkyl chain with 1 to 4 C atoms and a dihydroxylalkyl chain with 2 to 4 C atoms; , R ₁₀ is an alkyl chain with 1 to 4 C atoms, a hydroxylalkyl chain with 1 to 4 C atoms or a dihydroxylalkyl chain with 2 to 4 C atoms]
Including those with a structure according to

In some instances, R ₄ is a saturated or unsaturated, straight or branched alkyl chain having 10 to 24 C atoms, more preferably 12 to 22 C atoms, and R ₅ has 1 to 4 C atoms. It is a straight chain or branched alkyl group having a C atom, and A, B, and R ₆ to R ₁₀ are the same as above.

Suitable non-limiting examples are stearyloxypropylamine, palmityloxypropylamine, stearyloxypropyldimethylamine, stearyloxypropyldiethylamine, stearyloxyethylyldimethylamine, stearyloxyethylamine, myristyloxypropylamine, myristyloxypropyl Dimethylamine, palmitamidopropylamine, palmitamidopropylmethylamine, palmitamidopropyl diethylamine, palmitamidopropyl dibutylamine, palmitamidopropyl butylamine, palmitamidopropyl dipropylamine, palmitamidopropylpropylamine, Palmitamidopropyldihydroxylethylamine, palmitamidopropylhydroxyethylamine, palmitamidopropyldihydroxylpropylamine, palmitamidopropylhydroxypropylamine, lauramidepropylamine, lauramidepropylmethylamine, lauramidepropyldiethylamine, lauramide Propyldibutylamine, lauramidepropylbutylamine, lauramidepropyldipropylamine, lauramidepropylpropylamine, lauramidepropyldihydroxylethylamine, lauramidepropylhydroxyethylamine, lauramidepropyldihydroxylpropylamine, lauramidepropylhydroxypropylamine, Stearamidepropylamine, stearamidepropyldimethylamine, stearamidepropyldiethylamine, stearamidepropyldibutylamine, stearamidepropylbutylamine, stearamidepropyldipropylamine, betenamidepropylpropylamine, betenamidepropyldihydroxylethylamine, bete Namidopropylhydroxyethylamine, betenamidopropyldihydroxylpropylamine, betenamidopropylhydroxypropylamine, betenamidepropylamine, betenamidepropylmethylamine, betenamidepropyldiethylamine, betenamidepropyldibutylamine, Betenamidopropyldibutylamine Namidopropylbutylamine, betenamidepropyldipropylamine, betenamidepropylpropylamine, betenamidepropyldihydroxylethylamine, betenamidepropylhydroxyethylamine, betenamidepropyldihydroxylpropylamine, betenamidepropylhydroxypropyl Amine, Dipalmitamidepropylmethylamine, Dipalmitamidepropylethylamine, Dipalmitamidepropylbutylamine, Dipalmitamidepropylpropylamine, Dipalmitamidepropylhydroxyethylamine, Dipalmitamidepropylhydroxypropylamine, Lauramidopropylamine, dilauramidepropylmethylamine, dilauramidepropylbutylamine, dilauramidepropylhydroxyethylamine, dilauramidepropylhydroxypropylamine, distearamidepropylamine, distearamidepropylmethylamine, dibehenamidepropyl Propylamine, dibehenamidepropylhydroxyethylamine, palmitamidopropyltrimethylammonium chloride, stearamidepropyltrimethylammonium chloride, betenamidepropyltrihydroxyethalmonium chloride, distearylamidepropyldimethylammonium chloride, dicetylamide dihydroxy Ethylammonium chloride, palmitoylpropylamine, palmitoylpropylmethylamine, palmitoylpropyldiethylamine, palmitoylpropyldibutylamine, palmitoylpropylbutylamine, palmitoylpropyldipropylamine, palmitoylpropylpropylamine, palmitoylpropyldihydroxylethylamine, palmitoylpropylhydroxyethylamine, palmitoylpropyl Dihydroxylpropylamine, palmitoylpropylhydroxypropylamine, myristoylpropylamine, myristoylpropylmethylamine, myristoylpropyldiethylamine, myristoylpropyldibutylamine, myristoylpropylbutylamine, myristoylpropyldipropylamine, myristoylpropylpropylamine, myristoylpropyldihydroxylethylamine, myristoylpropylhydroxyethylamine, myristoylpropyldihydroxylpropylamine, myristoylpropylhydroxypropylamine, stearoylpropylamine, stearoylpropylmethylamine, stearoylpropyldiethylamine, stearoylpropyldibutylamine, stearoylpropylbutylamine, stearoylpropyldipropylamine, behenylpropylpropylamine , behenylpropyldihydroxylethylamine, behenylpropylhydroxyethylamine, behenylpropyldihydroxylpropylamine, behenylpropylhydroxypropylamine, behenylpropylamine, behenylpropylmethylamine, behenylpropyldiethylamine, behenylpropyldibutylamine, behenylpropylbutylamine, behenylpropyldibutylamine Propylamine, Behenylpropylpropylamine, Behenylpropyldihydroxylethylamine, Behenylpropylhydroxyethylamine, Behenylpropyldihydroxylpropylamine, Behenylpropylhydroxypropylamine, Dipalmitoylpropylmethylamine, Dipalmitoylpropylethylamine, Dipalmitylpropylbutylamine, Palmitylpropylpropylamine, dipalmitylpropylhydroxyethylamine, dipalmitylpropylhydroxypropylamine, dilauroylpropylamine, dilauroylpropylmethylamine, dilauroylpropylbutylamine, dilauroylpropylhydroxyethylamine, dilauroylpropylhydroxypropylamine, Distearylpropylamine, distearylpropylmethylamine, dibehenylpropylpropylamine, dibehenylpropylhydroxyethylamine, palmitylpropyltrimethylammonium chloride, stearylpropyltrimethylammonium chloride, behenylpropyltrihydroxyethalmonium chloride, distearylpropyl Dimethylammonium chloride, dicetyldihydroxyethylammonium chloride, dioleoylethylhydroxyethylmonium methosulfate, and dicocoylethylhydroxyethylmonium methosulfate It is.

The cationic surfactant may be selected from aliphatic alkylamines, preferably aliphatic dialkylamines. Non-limiting examples include dimethyl lauramine, dimethyl behine amine, dimethyl cocamine, dimethyl myristamine, dimethyl palmitamine, dimethyl stearamine, dimethyl tallow amine, dimethyl soiamine and mixtures thereof.

Aliphatic dialkylamines include aliphatic amidoamine compounds, salts thereof and mixtures thereof. Non-limiting examples include oleamidopropyl dimethylamine, linolamidopropyl dimethylamine, isostearamidopropyl dimethylamine, stearamidopropyl dimethylamine, oleylhydroxyethylimidazoline, stearamidopropyl dimethylamine, behenamidopropyl dimethylamine, Henamidopropyldiethylamine, behenamideethyldiethylamine, behenamideethyldimethylamine, arachidamidepropyldimethylamine, arachidamidepropyldiethylamine, arachidamideethyldiethylamine, arachidamideethyldimethylamine, brassicamidopropyldimethylamine, lauramidopropyldimethyl amines, myristamidopropyl dimethylamine, dilinolamidopropyl dimethylamine, and palmitamidopropyl dimethylamine.

Non-polymeric, mono-, di- and/or tricarboxylic acids may be used to "neutralize" the aliphatic dialkylamine. In some cases, the one or more non-polymeric mono-, di- and/or tricarboxylic acids include at least one dicarboxylic acid. Non-limiting examples are lactic acid, oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, maleic acid, sebacic acid, azelaic acid, dodecanedioic acid, phthalic acid. , isophthalic acid, terephthalic acid, 2,6-naphthalene dicarboxylic acid, benzoic acid and mixtures thereof. In particular, lactic acid or tartaric acid or mixtures thereof are particularly useful in combination with aliphatic dimethylamines, such as stearamidopropyl dimethylamine.

In embodiments, the cosmetic composition may be formulated with a cationic surfactant selected from behentrimonium chloride, cetrimonium chloride, behentrimonium methosulfate, or mixtures thereof.

Cosmetic compositions may be formulated such that two or more cationic surfactants are associated with the same or different balancing anionic ions. For example, at least one of the two or more cationic surfactants may contain chloride ions and/or sulfate ions. In some instances, the two or more cationic surfactants include cetrimonium chloride and one or both of behentrimonium methosulfate and behentrimonium chloride. In a further example, the two or more cationic surfactants include behentrimonium chloride and one or both of behentrimonium methosulfate and cetrimonium chloride.

In yet another example, the cationic surfactant(s) are cetrimonium chloride, steartrimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyl Trimonium chloride, arachidotrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylamonium chloride, oleamidepropyldimethylamine, linolamidepropyldimethylamine, stearamidepropyldimethylamine, oleylhydroxyethylimidazoline, Aramidopropyl dimethylamine, behenamide propyl dimethylamine, behenamide propyl diethylamine, behenamide ethyl diethylamine, behenamide ethyl dimethylamine, arachidamide propyl dimethylamine, arachidamide propyl diethylamine, arachidamide ethyl diethylamine, arachidamide ethyl selected from dimethylamine and mixtures thereof.

aliphatic compound(s)
The cosmetic composition contains variable amounts of one or more fatty compound(s), but typically from about 0.1 to about 20% by weight based on the total weight of the cosmetic composition. . In some instances, the amount of aliphatic compound present in the cosmetic composition is about 0.1% to 20%, about 0.1% to about 18%, about 0% by weight, based on the total weight of the cosmetic composition. .1 to about 16% by weight, about 0.1 to about 14% by weight, about 0.1 to about 12% by weight, about 0.1 to about 10% by weight, about 0.1 to about 8% by weight, about 0 .1 to about 7% by weight, about 0.1 to about 6% by weight, about 0.1 to about 5% by weight; about 0.5 to 20% by weight, about 0.5 to about 18% by weight, about 0. 5 to about 16% by weight, about 0.5 to about 14% by weight, about 0.5 to about 12% by weight, about 0.5 to about 10% by weight, about 0.5 to about 8% by weight, about 0. 5 to about 7% by weight, about 0.5 to about 6% by weight, about 0.5 to about 5% by weight; about 1 to about 20% by weight, about 1 to about 18% by weight, about 1 to about 16% by weight , about 1 to about 14%, about 1 to about 12%, about 1 to about 10%, about 1 to about 8%, about 1 to about 7%, about 1 to about 6%, about 1 to about 5% by weight; about 2 to about 20% by weight, about 2 to about 18% by weight, about 2 to about 16% by weight, about 2 to about 14% by weight, about 2 to about 12% by weight, about 2 to about about 10% by weight, about 2 to about 8% by weight, about 2 to about 7% by weight, about 2 to about 6% by weight, about 2 to about 5% by weight; about 3 to about 20% by weight, about 3 to about 18% by weight wt%, about 3 to about 16 wt%, about 3 to about 14 wt%, about 3 to about 12 wt%, about 3 to about 10 wt%, about 3 to about 8 wt%, about 3 to about 7 wt% , about 3 to about 6%, about 3 to about 5%; about 4 to about 20%, about 4 to about 18%, about 4 to about 16%, about 4 to about 14%, about 4 to about 12% by weight, about 4 to about 10% by weight, about 4 to about 8% by weight; about 4 to about 7% by weight, about 4 to about 6% by weight, about 4 to about 5% by weight; about 5 to about 20% by weight, about 5 to about 18%, about 5 to about 16%, about 5 to about 14%, about 5 to about 12%, about 5 to about 10%, or about 5 to about 8%. %, about 5 to about 7%, or about 5 to about 6% by weight, including all ranges and subranges therebetween.

Examples of fatty compound(s) that may be incorporated into the cosmetic composition include fatty alcohols, fatty acid esters, fatty ethers, fatty acids, waxes, oils, derivatives thereof and mixtures thereof. Additional examples of aliphatic compounds worth mentioning are oils, mineral oils, alkanes (paraffins), fatty alcohol derivatives, fatty acid derivatives, esters of fatty alcohols, hydroxy-substituted fatty acids, waxes and triglyceride compounds, lanolin, and the like. Contains a mixture of.

Fatty acid ester(s)
The cosmetic composition may include one or more fatty compound(s) that are fatty acid esters. For example, the aliphatic compound(s) may have the formula: R ₁ O(C=O)R ₂ where R ₁ and R ₂ independently have 1 to 30 carbon atoms, or or is a straight or branched, saturated or unsaturated alkyl chain having 4 to 25 carbon atoms or 6 to 22 carbon atoms], preferably C14-15 dialkyl carbonate, dicaprylyl carbonate , diethyl carbonate, dihexyl carbonate, diethylhexyl carbonate, dimethoxyphenylphenyloxoethyl ethyl carbonate, dimethyl carbonate, dipropyl carbonate, dipropylheptyl carbonate, dioctyl carbonate and mixtures thereof. You may be

Additionally or alternatively, fatty acid esters include cetyl ester, parcellin oil (cetearyl octoate), isopropyl myristate, isopropyl palmitate, _C12 - _C15 alkyl benzoate, 2-ethylphenyl benzoate, isopropyl lanolin fatty acid, laurin hexyl acid, diisopropyl adipate, isononyl isononanoate, oleyl erucate, 2-ethylhexyl palmitate, isostearyl isostearate, diisopropyl sebacate, octanoate, decanoate or ricinoleate of alcohols or polyalcohols, hydroxylated esters and carbonic acid dicaprylyl, pentaerythritol ester, diisostearyl malate, neopentyl glycol dioctoate, dibutyl sebacate, di- _C12-13 alkyl malate, dicetearyl dimer dilinoleate, dicetyl adipate, diisocetyl adipate, diisononyl adipate, selected from diisostearyl dimer dilinoleate, diisostearyl fumarate and mixtures thereof. Other fatty acid esters worth mentioning are polyglyceryl-10 oleate, polyglyceryl-10 dioleate, polyglyceryl-6 stearate, polyglyceryl-6 distearate, polyglyceryl-10 stearate, polyglyceryl-10 distearate, dipalmitic acid Contains polyglyceryl-8, polyglyceryl-10 dipalmitate, polyglyceryl-10 behenate, and polyglyceryl-12 trilaurate.

aliphatic alcohol(s)
Suitable aliphatic alcohols, when present, have more than 8 carbon atoms, 8 to 50 carbon atoms, 8 to 40 carbon atoms, 8 to 30 carbon atoms, 8 to 22 carbon atoms, 12 to 22 carbon atoms, or 12 to 18 carbon atoms. Includes those having aliphatic groups containing carbon chains, including all ranges and subranges therebetween, of carbon atoms. In some instances, the aliphatic group of the aliphatic alcohol has a carbon chain of 10-20 carbon atoms or 10-18 carbon atoms. The aliphatic alcohol may be selected from polyethylene glycol ethers such as those having aliphatic alcohol groups containing a carbon chain of 12 to 16 or 12 to 14 carbon atoms.

The fatty alcohol moiety is preferably hydrogenated (eg stearyl, lauryl, cetyl, cetearyl); however, the fatty alcohol may contain one or more double bonds (eg oleyl). Non-limiting examples of aliphatic alcohols include decyl alcohol, undecyl alcohol, dodecyl alcohol, myristyl alcohol, lauryl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol (cetyl alcohol and stearyl alcohol), isostearyl alcohol, isocetyl Alcohols include behenyl alcohol, linalool, oleyl alcohol, cis-4-t-butylcyclohexanol, isotridecyl alcohol, myricyl alcohol and mixtures thereof. In some cases, the aliphatic alcohol includes at least one of myristyl alcohol, lauryl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, isostearyl alcohol, oleyl alcohol, isotridecyl alcohol, and mixtures thereof; or may be selected from them.

Aliphatic alcohols may be saturated or unsaturated. Exemplary saturated liquid aliphatic alcohols may be branched and optionally include at least one aromatic or non-aromatic ring in their structure. However, in some instances, the aliphatic alcohol is acyclic. Non-limiting examples of liquid saturated aliphatic alcohols include octyldodecanol, isostearyl alcohol, and 2-hexyldecanol.

Exemplary unsaturated liquid aliphatic alcohols may contain at least one double or triple bond in their structure. For example, the aliphatic alcohol may contain several double bonds (such as 2 or 3 double bonds), which may be conjugated or unconjugated. Unsaturated aliphatic alcohols may be linear or branched, acyclic, or contain at least one aromatic or non-aromatic ring in their structure. The liquid unsaturated aliphatic alcohol may include or be selected from oleyl alcohol, linoleyl alcohol, linolenyl alcohol, and undecylenyl alcohol.

The aliphatic alcohol can be, for example, an alkoxylated aliphatic alcohol having from about 1 to about 100 moles of alkylene oxide per mole of alkoxylated aliphatic alcohol. For example, the alkoxylated fatty alcohol may be about 1 to about 80 moles, about 2 to about 50, about 5 to about 45 moles, about 10 to about 40 moles, or 15 to about 35 moles per mole of alkoxylated fatty alcohol. may be alkoxylated with alkylene oxides, including all ranges and subranges therebetween.

Examples of alkoxylated fatty alcohols include steareth (such as steareth-2, steareth-20 and steareth-21), laureth (such as laureth-4, and laureth-12), ceteth (such as ceteth-10 and ceteth-20), and Mention may be made of ceteares (eg ceteares-2, ceteares-10 and ceteares-20). In at least one example, the one or more alkoxylated aliphatic alcohols include Steareth-20. In some instances, the one or more alkoxylated aliphatic alcohols may be exclusively steareth-20.

Additional aliphatic alcohol derivatives which are optionally suitable include methyl stearyl ether; 2-ethylhexyl dodecyl ether; stearyl acetate; cetyl propionate; ceteth-1 to ceteth-45, which are ethylene glycol ethers of cetyl alcohol Compounds of the Steareth series (where the numerical designation indicates the number of ethylene glycol moieties present); Steareth-1 to 10, which are ethylene glycol ethers of steareth alcohols (where the numerical designation indicates the number of ethylene glycol moieties present); indicates the number of ethylene glycol moieties present); ceteareth-1 to ceteareth-10 (where the number The notation indicates the number of ethylene glycol moieties present); C1-C30 alkyl ethers of the ceteth, steareth, and ceteareth compounds just described; octyldodecyl alcohol, dodecylpentadecyl alcohol, hexyldecyl alcohol, and isostearyl alcohol, etc. polyoxyethylene ethers of branched alcohols; polyoxyethylene ethers of behenyl alcohol; PPG ethers such as PPG-9-steareth-3, PPG-11 stearyl ether, PPG8 ceteth-1 and PPG-10 cetyl ether; and mixtures thereof. include.

aliphatic ether(s)
The aliphatic compound may be selected from aliphatic ethers. For example, the cosmetic composition may contain polyoxyethylene cetyl/stearyl ether, polyoxyethylene cholesterol ether, polyoxyethylene laurate or polyoxyethylene dilaurate, polyoxyethylene stearate or polyoxyethylene distearate, polyoxyethylene lauryl ether or It may include polyoxyethylene stearyl ether, dicaprylyl ether, dicetyl ether distearyl ether, dodecyl ether, dilauryl ether, dimyristyl ether, diisononyl ether, or mixtures thereof. Non-limiting examples of suitable polyoxyethylene aliphatic ethers are polyoxyethylene cetyl/stearyl ether, polyoxyethylene cholesterol ether, polyoxyethylene laurate or dilaurate, polyoxyethylene stearate or polyoxyethylene distearate. , polyoxyethylene lauryl ether or polyoxyethylene stearyl ether, and mixtures thereof, where the polyoxyethylene head groups range from about 2 to about 100. In certain embodiments, polyoxyethylene aliphatic ethers include polyoxyethylene stearyl ether, polyoxyethylene myristyl ether, polyoxyethylene lauryl ether, and mixtures thereof having about 3 to about 10 oxyethylene units.

fatty acid(s)
In some instances, the aliphatic compound may be selected from fatty acids, fatty acid derivatives, esters of fatty acids, hydroxyl-substituted fatty acids, and alkoxylated fatty acids. Fatty acids may be straight chain or branched chain acids and/or saturated or unsaturated. Non-limiting examples of fatty acids include diacids, triacids and other polyhydric acids, and salts of these fatty acids. For example, fatty acids may optionally include or be selected from lauric acid, palmitic acid, stearic acid, behenic acid, arachidonic acid, oleic acid, isostearic acid, sebacic acid, and mixtures thereof. In some cases, the fatty acid is selected from the group consisting of palmitic acid, stearic acid, and mixtures thereof.

［式中、ｎの平均値は約３であり、Ｒ^１、Ｒ^２及びＲ^３はそれぞれ独立して脂肪酸部分又は水素であってもよく、ただし、Ｒ^１、Ｒ^２及びＲ^３の少なくとも１つは脂肪酸部分である］
のものを含む。例えば、Ｒ^１、Ｒ^２及びＲ^３は飽和又は不飽和、直鎖又は分岐であってよく、Ｃ_１～Ｃ_４０、Ｃ_１～Ｃ_３０、Ｃ_１～Ｃ_２５又はＣ_１～Ｃ_２０、Ｃ_１～Ｃ_１６又はＣ_１～Ｃ_１０の長さを有する。 Non-limiting examples of polyglycerol esters of fatty acids have the following formula:

[wherein the average value of n is about 3, R ¹ , R ² and R ³ may each independently be a fatty acid moiety or hydrogen, provided that at least one of R ¹ , R ² and R ³ One is the fatty acid part]
including those of For example, R ¹ , R ² and R ³ may be saturated or unsaturated, linear or branched, C ₁ -C ₄₀ , C ₁ -C ₃₀ , C ₁ -C ₂₅ or C ₁ -C ₂₀ , C ₁ to C ₁₆ or C ₁ to C ₁₀ .

Fatty acid derivatives are herein defined as fatty acid esters of fatty alcohols as defined above, fatty acid esters of fatty alcohol derivatives as defined above (if such fatty alcohol derivatives have a hydroxyl group that can be esterified). ), fatty acid esters of alcohols other than those described above, aliphatic alcohols and aliphatic alcohol derivatives, hydroxy-substituted fatty acids, and mixtures thereof. Non-limiting examples of fatty acid derivatives include ricinoleic acid, glycerol monostearate, 12-hydroxystearic acid, ethyl stearate, cetyl stearate, cetyl palmitate, polyoxyethylene cetyl ether stearate, polyoxyethylene stearyl stearate. Ether, polyoxyethylene lauryl ether stearate, ethylene glycol monostearate, polyoxyethylene monostearate, polyoxyethylene distearate, propylene glycol monostearate, propylene glycol distearate, trimethylolpropane distearate, sorbitan stearate, Polyglyceryl stearate, dimethyl sebacate, PEG-15 cocoate, PPG-15 stearate, glyceryl monostearate, glyceryl distearate, glyceryl tristearate, PEG-8 laurate, PPG-2 isostearate, PPG-laurate 9, and mixtures thereof. Glycerol monostearate, 12-hydroxystearic acid and mixtures thereof are preferred for use herein.

Wax The aliphatic compound, in some instances, includes or is selected from one or more waxes. Non-limiting examples of waxes within this category include, for example, synthetic waxes, ceresin, paraffin, ozokerite, polyethylene wax, illipe butter, beeswax, carnauba wax, microcrystalline, lanolin, lanolin derivatives, candelia, cocoa butter, shellac. Wax, spermaceti, bran wax, kapok wax, sugarcane wax, montan wax, whale wax, bayberry wax, wattles wax, vegetable waxes (sunflower seed helianthus annuus, carnauba wax, candelia, auricularis or wood) (such as wax or cork fiber or sugar cane wax) or mixtures thereof.

Oil agent(s)
In some instances, the aliphatic compound may include or be selected from one or more oil agent(s). Suitable oils include synthetic oils such as silicone oil; natural oils such as coconut oil; hydrocarbons such as mineral oil and hydrogenated polyisobutene; aliphatic alcohols such as octyldodecanol; C ₁₂ -C ₁₅ alkyl benzoates and the like. diesters such as propylene dipelargonate; and triesters such as glyceryl trioctanoate. Non-limiting examples of oils that may optionally be included in the cosmetic composition include isotridecyl isononanoate, PEG-4 diheptanoate, isostearyl neopentanoate, tridecyl neopentanoate, cetyl octoate, cetyl palmitate. , cetyl ricinoleate, cetyl stearate, cetyl myristate, cocodi (caprylate/caprate), decyl isostearate, isodecyl oleate, isodecyl neopentanoate, isohexyl neopentanoate, octyl palmitate, dioctyl malate, tridecyl octoate , myristyl myristate, octododecanol, or a combination of octyldodecanol, acetylated lanolin alcohol, cetyl acetate, isodocanol, polyglyceryl-3-diisostearate, castor oil, lanolin and lanolin derivatives, triisocetyl citrate, sesquioleic acid Sorbitan, _C10 - _C18 triglycerides, caprylic/capric/triglycerides, coconut oil, corn oil, cottonseed oil, glyceryl triacetyl hydroxystearate, glyceryl triacetyl ricinolate, glyceryl trioctanoate, hydrogenated castor oil, linseed oil, mink Oil, olive oil, coconut oil, illipe butter, rapeseed oil, soybean oil, sunflower oil, tallow, tricaprin, trihydroxystearin, triisostearin, trilaurin, trilinolein, trimyristin, triolein, tripalmitin, tristearin, walnut oil , wheat germ oil, cholesterol, or a combination thereof.

polyol(s)
Optionally, the cosmetic composition includes one or more polyols. The amount of polyol(s) present in the cosmetic composition typically ranges from about 20% by weight or more based on the total weight of the cosmetic composition. For example, the amount of polyol(s) in the cosmetic composition may be from about 20 to about 87%, from about 20 to about 85%, from about 20 to about 80%, about 20 to about 75% by weight, about 20 to about 70% by weight, about 20 to about 65% by weight, about 20 to about 60% by weight, about 20 to about 55% by weight, about 20 to about 50% by weight, about 20 to about about 45% by weight, about 20 to about 40% by weight, about 20 to about 35% by weight, about 20 to about 30% by weight; about 30 to about 87% by weight, about 30 to about 85% by weight, about 30 to about 80 wt%, about 30 to about 75 wt%, about 30 to about 70 wt%, about 30 to about 65 wt%, about 30 to about 60 wt%, about 30 to about 55 wt%, about 30 to about 50 wt% , about 30 to about 45% by weight, about 30 to about 40% by weight; about 40 to about 87% by weight, about 40 to about 85% by weight, about 40 to about 80% by weight, about 40 to about 75% by weight, about 40 to about 70% by weight, about 40 to about 65% by weight, about 40 to about 60% by weight, about 40 to about 55% by weight, about 40 to about 50% by weight; about 50 to about 87% by weight, about 50 to about about 85% by weight, about 50 to about 80% by weight, about 50 to about 75% by weight, about 50 to about 70% by weight, about 50 to about 65% by weight, about 50 to about 60% by weight; about 60 to about 87 wt%, about 60 to about 85 wt%, about 60 to about 80 wt%, about 60 to about 75 wt%, about 60 to about 70 wt%; about 65 to about 87 wt%, about 65 to about 85 wt% , about 65 to about 80%, about 65 to about 75%; about 70 to about 87%, about 70 to about 85%, about 70 to about 75%, and ranges and sub-ranges therebetween. Includes all ranges.

The term "polyol" is to be understood within the meaning of the present disclosure as an organic molecule containing at least two free hydroxyl groups. The polyol of the cosmetic composition may be a glycol or compound having a large number of hydroxyl groups. In some cases, the one or more polyols are selected from the group consisting of C ₂ -C ₃₂ polyols. The polyol or polyols may be liquid at ambient temperature (25°C). The polyol or polyols may have 2 to 32 carbon atoms, 3 to 16 carbon atoms, or 3 to 12 carbon atoms.

In certain instances, the polyols that may be included in the cosmetic composition include ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, glycerin, diglycerin, diethylene glycol and dipropylene glycol, polyethylene glycol, and mixtures thereof. include. In some cases, the polyol is propylene glycol. In some further cases, the polyol is one or both of propylene glycol and butylene glycol. Additionally, in some cases, the cosmetic composition includes at least propylene glycol, and optionally one or more polyols other than propylene glycol.

Non-limiting examples of polyols that may optionally be included in cosmetics include glycerin, 1,2,6-hexanetriol, trimethylolpropane, ethylene glycol, propylene glycol, butylene glycol, pentylene glycol, Xylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, dipropylene glycol, 2-butene-1,4-diol, 2-ethyl-1,3-hexanediol, 2-methyl-2,4- Alkanediols such as pentanediol caprylyl glycol, 1,2-hexanediol, 1,2-pentanediol, and 4-methyl-1,2-pentanediol; ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol mono Butyl ether, ethylene glycol monomethyl ether acetate, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol mono-n-propyl ether, ethylene glycol mono-iso-propyl ether, diethylene glycol mono-iso-propyl ether, ethylene glycol mono-n-butyl ether, Ethylene glycol mono-t-butyl ether, diethylene glycol mono-t-butyl ether, 1-methyl-1-methoxybutanol, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol mono-t-butyl ether, propylene glycol mono-n-propyl Ethers, glycol ethers such as propylene glycol mono-iso-propyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol mono-n-propyl ether, dipropylene glycol mono-iso-propyl ether, sorbitol, It may include and/or be selected from sorbitan, triacetin and mixtures thereof.

The one or more polyols are optionally glycols or glycol ethers such as the monomethyl, monoethyl and monobutyl ethers of ethylene glycol, propylene glycol, or ethers thereof such as propylene glycol, butylene glycol, hexylene glycol, dipropylene glycol. Monomethyl ether and the like, as well as alkyl ethers of diethylene glycol, such as monoethyl ether or monobutyl ether of diethylene glycol. In some cases, the one or more polyols are ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, pentylene glycol, 1,3-propanediol, diethylene glycol, dipropylene glycol, 1,4-butanediol, It may include or be selected from 1,5-pentanediol, hexane-1,6-diol, glycerin, diglycerin, caprylyl glycol and mixtures thereof.

Thickener(s)
The cosmetic compositions described herein may optionally include a thickening agent. The amount of thickener can vary, but is usually from about 0.01 to about 20% by weight, based on the total weight of the cosmetic composition. In some instances, the amount of aliphatic compound present in the cosmetic composition is about 0.1% to 20%, about 0.1% to about 18%, about 0% by weight, based on the total weight of the cosmetic composition. .1 to about 16% by weight, about 0.1 to about 14% by weight, about 0.1 to about 12% by weight, about 0.1 to about 10% by weight, about 0.1 to about 8% by weight, about 0 .1 to about 7% by weight, about 0.1 to about 6% by weight, about 0.1 to about 5% by weight; about 0.5 to 20% by weight, about 0.5 to about 18% by weight, about 0. 5 to about 16% by weight, about 0.5 to about 14% by weight, about 0.5 to about 12% by weight, about 0.5 to about 10% by weight, about 0.5 to about 8% by weight, about 0. 5 to about 7% by weight, about 0.5 to about 6% by weight, about 0.5 to about 5% by weight; about 1 to about 20% by weight, about 1 to about 18% by weight, about 1 to about 16% by weight , about 1 to about 14%, about 1 to about 12%, about 1 to about 10%, about 1 to about 8%, about 1 to about 7%, about 1 to about 6%, about 1 to about 5% by weight; about 2 to about 20% by weight, about 2 to about 18% by weight, about 2 to about 16% by weight, about 2 to about 14% by weight, about 2 to about 12% by weight, about 2 to about about 10% by weight, about 2 to about 8% by weight, about 2 to about 7% by weight, about 2 to about 6% by weight, about 2 to about 5% by weight; about 3 to about 20% by weight, about 3 to about 18% by weight wt%, about 3 to about 16 wt%, about 3 to about 14 wt%, about 3 to about 12 wt%, about 3 to about 10 wt%, about 3 to about 8 wt%, about 3 to about 7 wt% , about 3 to about 6% by weight, about 3 to about 5% by weight; about 4 to about 20% by weight, about 4 to about 18% by weight, about 4 to about 16% by weight, about 4 to about 14% by weight, about 4 to about 12% by weight, about 4 to about 10% by weight, about 4 to about 8% by weight; about 4 to about 7% by weight, about 4 to about 6% by weight, about 4 to about 5% by weight; about 5 to about 20% by weight, about 5 to about 18%, about 5 to about 16%, about 5 to about 14%, about 5 to about 12%, about 5 to about 10%, or about 5 to about 8% by weight %, about 5 to about 7%, or about 5 to about 6% by weight, including all ranges and subranges therebetween.

The thickening agent(s) may be selected from xanthan gum, guar gum, biosaccharide gum, cellulose, gum arabic, gum sclerotium, agarose, pectin, gellan gum, hyaluronic acid. Additionally, the one or more thickening agents may include polyammonium acryloyl dimethyl taurate, ammonium acryloyl dimethyl taurate/VP copolymer, sodium polyacrylate, acrylate copolymer, polyacrylamide, carbomer, and acrylate/acrylic acid C10-30 alkyl cross. A polymeric thickener selected from the group consisting of polymers may also be included. In some cases, the composition includes ammonium polyacryloyl dimethyl taurate and/or sodium polyacrylate. Suitable thickening agents can be found in US patent application Ser. No. 16/731,654, which is incorporated herein in its entirety for all purposes.

Many thickeners are water-soluble and increase the viscosity of the water to form an aqueous gel when the cosmetic composition of the present invention is dispersed/dissolved in water. If necessary, the aqueous solution may be heated, cooled, or neutralized for gel formation. If the thickener is dispersed/dissolved in water, it may also be dispersed/dissolved in an aqueous solvent soluble in water, such as ethyl alcohol.

Particular types of thickeners that may be mentioned include:
One or more thickening agents can optionally be included in the cosmetic compositions of the present disclosure. Thickeners may also be referred to as "thickeners" or "viscosity modifiers." Thickeners are typically included to increase the viscosity of cosmetic compositions. Nevertheless, in some instances, certain thickeners provide additional surprising benefits to cosmetic compositions. Non-limiting examples of thickeners include polyacrylate crosspolymers or crosslinked polyacrylate polymers, cationic acrylate copolymers, anionic acrylic or carboxylic acid polymers, polyacrylamide polymers, polysaccharides such as cellulose derivatives, rubbers, Includes polyquaternium, vinylpyrrolidone homopolymers/copolymers, C8-24 hydroxyl substituted fatty acids and C8-24 conjugated fatty acids, sugar fatty acid esters, polyglyceryl esters and mixtures thereof. Particular types of thickeners that may be mentioned include:

Carboxylic acid- or carboxylate-based homopolymers or copolymers, which may be linear or cross-linked:
These polymers include one or more monomers derived from acrylic acid, substituted acrylic acids, and salts and esters of these acrylic acids and substituted acrylic acids (acrylates). Commercially available polymers include those sold under the trade names CARBOPOL, ACRYSOL, POLYGEL, SOKALAN, CARBOPOL ULTREZ and POLYGEL. Examples of commercially available carboxylic acid polymers include carbomers, which are homopolymers of acrylic acid crosslinked with allyl ethers of sucrose or pentaerythritol. Carbomer is B. F. Available as the CARBOPOL 900 series from Goodrich (eg CARBOPOL 954). Additionally, other suitable polymeric agents of carboxylic acids include ULTREZ 10 (B.F. Goodrich) and one, one or It comprises a copolymer of C10-30 alkyl acrylate with a plurality of monomers, where the crosslinker is sucrose or the allyl ether of pentaerythritol. These copolymers are known as acrylate/C10-C30 alkyl acrylate crosspolymers, and B. F. Commercially available from Goodrich as CARBOPOL 1342, CARBOPOL 1382, PEMULEN TR-1 and PEMULEN TR-2.

Other suitable carboxylic acid or carboxylate polymeric agents include copolymers of acrylic acid and alkyl C5-C10 acrylates, copolymers of acrylic acid and maleic anhydride, and polyacrylate crosspolymer-6. Polyacrylate crosspolymer-6 is available in a raw material known as SEPIMAX ZEN from Seppic.

Other suitable carboxylic acid or carboxylate polymeric agents include acrylamide propyltrimonium chloride/acrylate copolymers, cationic acrylate copolymers (or quaternary ammonium compounds), under the trade name SIMULQUAT HC 305 from Seppic. It is available as a known raw material.

In certain embodiments, the carboxylic acid or carboxylate polymer thickeners useful herein include carbomer, acrylate/C10-C30 alkyl acrylate crosspolymer, polyacrylate crosspolymer-6, acrylamide propyltrimonium chloride/acrylate copolymer , and mixtures thereof.

Polyquaternium compounds:
Non-limiting examples include polyquaternium-1, polyquaternium-2, polyquaternium-3, polyquaternium-4, polyquaternium-5, polyquaternium-6, polyquaternium -7, Polyquaternium-8, Polyquaternium-9, Polyquaternium-10, Polyquaternium-11, Polyquaternium-12, Polyquaternium-13, Polyquaternium- 14, Polyquaternium-15, Polyquaternium-16, Polyquaternium-17, Polyquaternium-18, Polyquaternium-19, Polyquaternium-20, Polyquaternium-21 , polyquaternium-22, polyquaternium-23, polyquaternium-24, polyquaternium-25, polyquaternium-26, polyquaternium-27, polyquaternium-28, Polyquaternium-29, Polyquaternium-30, Polyquaternium-40, Polyquaternium-41, Polyquaternium-42, Polyquaternium-43, Polyquaternium-44, Poly Quaternium-45, Polyquaternium-46, Polyquaternium-47, Polyquaternium-48, Polyquaternium-49, Polyquaternium-50, Polyquaternium-51, Polyquaternium Ternium-52, Polyquaternium-53, Polyquaternium-54, Polyquaternium-55, Polyquaternium-56, Polyquaternium-57, Polyquaternium-58, Polyquaternium Polyquaternium-59, Polyquaternium-60, Polyquaternium-61, Polyquaternium-62, Polyquaternium-63, Polyquaternium-64, Polyquaternium-65, Polyquaternium -66, polyquaternium-67, etc. In some cases, preferred polyquaternium compounds include polyquaternium-10, polyquaternium-11, polyquaternium-67, and mixtures thereof.

cellulose:
Non-limiting examples of cellulose include cellulose, carboxymethylhydroxyethylcellulose, cellulose acetate propionate carboxylate, hydroxyethylcellulose, hydroxyethylethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, methylhydroxyethylcellulose, microcrystalline cellulose, sodium cellulose Contains sulfates, and mixtures thereof. In some instances, the cellulose is selected from water-soluble cellulose derivatives (eg, carboxymethylcellulose, methylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, cellulose sulfate sodium salt). Additionally, in some instances, the cellulose is preferably hydroxypropylcellulose (HPC).

Polyvinylpyrrolidone (PVP) and copolymers:
Non-limiting examples include polyvinylpyrrolidone (PVP), polyvinylpyrrolidone (PVP)/vinyl acetate copolymer (PVP/VA copolymer), polyvinylpyrrolidone (PVP)/eicosene copolymer, PVP/hexadecene copolymer, and the like. Commercially available polyvinylpyrrolidones include LUVISKOL K30, K85, K90 available from BASF. Commercially available copolymers of vinylpyrrolidone and vinyl acetate include LUVISKOL VA37, VA64 available from BASF; copolymers of vinylpyrrolidone, methacrylamide and vinylimidazole (INCI name: VP/methacrylamide/vinylimidazole copolymer) available from BASF It is commercially available as LUVISET. In some instances, PVP and PVP/VA copolymers are preferred.

Sucrose ester:
Non-limiting examples are sucrose palmitate, sucrose cocoate, sucrose monooctanoate and sucrose monodecanoate, sucrose mono- or dilaurate, sucrose monomyristate, sucrose mono- or dipalmitate, sucrose mono- and distearate. , sucrose mono-, di-, or trioleate, sucrose mono- or dilinoleate, sucrose pentaoleate, sucrose hexaoleate, sucrose heptoleate or octooleate, and mixed esters such as sucrose palmitate/sucrose stearate; including mixtures thereof.

［式中、ｎは２～２０、２～１０若しくは２～５であり、又は２、３、４、５、６、７、８、９若しくは１０であり、Ｒ^１、Ｒ^２及びＲ^３はそれぞれ、独立して脂肪酸部分又は水素であってもよく、ただし、Ｒ^１、Ｒ^２及びＲ^３の少なくとも１つは脂肪酸部分である］
のものを含む。例えば、Ｒ^１、Ｒ^２及びＲ^３は飽和又は不飽和、直鎖又は分岐であってもよく、Ｃ_１～Ｃ_４０、Ｃ_１～Ｃ_３０、Ｃ_１～Ｃ_２５、又はＣ_１～Ｃ_２０、Ｃ_１～Ｃ_１６、又はＣ_１～Ｃ_１０の長さを有する。さらに、脂肪酸の非イオン性ポリグリセロールエステルの非限定的な例は、カプリル酸塩／カプリン酸ポリグリセリル－４、カプリル酸／カプリン酸ポリグリセリル－１０、カプリン酸ポリグリセリル－４、カプリン酸ポリグリセリル－１０、ラウリン酸ポリグリセリル－４、ラウリン酸ポリグリセリル－５、ラウリン酸ポリグリセリル－６、ラウリン酸ポリグリセリル－１０、ココ酸ポリグリセリル－１０、ミリスチン酸ポリグリセリル－１０、オレイン酸ポリグリセリル－１０、ステアリン酸ポリグリセリル－１０、及びそれらの混合物を含む。 Polyglyceryl ester:
Non-limiting polyglycerol esters (polyglyceryl esters) of fatty acids have the following formula:

[where n is 2 to 20, 2 to 10 or 2 to 5, or 2, 3, 4, 5, 6, 7, 8, 9 or 10, and R ¹ , R ² and R ³ are Each may independently be a fatty acid moiety or hydrogen, provided that at least one of R ¹ , R ² and R ³ is a fatty acid moiety]
including those of For example, R ¹ , R ² and R ³ may be saturated or unsaturated, linear or branched, C ₁ -C ₄₀ , C ₁ -C ₃₀ , C ₁ -C ₂₅ , or C ₁ -C ₂₀ , C ₁ to C ₁₆ , or C ₁ to C ₁₀ . Additionally, non-limiting examples of non-ionic polyglycerol esters of fatty acids include polyglyceryl-4 caprylate/polyglyceryl-10 caprylate, polyglyceryl-4 caprate, polyglyceryl-10 caprate, laurin polyglyceryl-4 acid, polyglyceryl-5 laurate, polyglyceryl-6 laurate, polyglyceryl-10 laurate, polyglyceryl-10 cocoa acid, polyglyceryl-10 myristate, polyglyceryl-10 oleate, polyglyceryl-10 stearate, and their Contains mixtures.

Rubber:
Non-limiting examples of gums include gum arabic, gum tragacanth, gum karaya, guar gum, gellan gum, cod gum, locust bean gum, tamarind gum, xanthan gum, locust bean gum, acacia gum, sclerotium gum, gellan gum, and the like.

Water-soluble solvent(s)
Cosmetic compositions may include one or more water-soluble solvents. The amount of water-soluble solvent in the cosmetic composition, if present, may range from about 1 to about 35% by weight, based on the total weight of the cosmetic composition. For example, the cosmetic composition may be about 1% to about 35%, about 1% to about 30%, about 1% to about 25%, about 1% to about 20%, about 1% by weight, based on the total weight of the cosmetic composition. to about 18% by weight, about 1 to about 16% by weight, about 1 to about 14% by weight, about 1 to about 12% by weight, about 1 to about 10% by weight; about 5 to about 35% by weight, about 5 to about 30% by weight, about 5 to about 25% by weight, about 5 to about 20% by weight, about 5 to about 18% by weight, about 5 to about 16% by weight, about 5 to about 14% by weight, about 5 to about 12% by weight %, about 5 to about 10% by weight; about 10 to about 35% by weight, about 10 to about 30% by weight, about 10 to about 25% by weight, about 10 to about 20% by weight, about 10 to about 18% by weight, about 10 to about 16% by weight, about 10 to about 14% by weight; about 12 to about 35% by weight, about 12 to about 30% by weight, about 12 to about 25% by weight, about 12 to about 20% by weight, about 12 to about 18% by weight, about 12 to about 16% by weight; about 14 to about 35% by weight, about 14 to about 30% by weight, about 14 to about 25% by weight, about 14 to about 20% by weight, about 14 to about 18% by weight; about 16 to about 35% by weight, about 16 to about 30% by weight, about 16 to about 25% by weight, about 16 to about 20% by weight; about 18 to about 35% by weight, about 18 to about 30% by weight %, about 18 to about 25%, or about 18 to about 20% by weight, including ranges and subranges thereof.

The term "water-soluble solvent" is interchangeable with the term "water-miscible solvent" and refers to a compound that is liquid at 25° C. and atmospheric pressure (760 mmHg), which has at least 50% concentration in water under these conditions. Has solubility. In some cases, the aqueous solvent has a solubility of at least 60%, 70%, 80% or 90%. Non-limiting examples of water-soluble solvents include, for example, glycerin, alcohols (eg C _1-30 , C _1-15 , C _1-10 or C _1-4 alcohols), organic solvents, polyols (polyhydric alcohols), Including glycols (eg, butylene glycol, caprylyl glycol, etc.) and mixtures thereof.

In some cases, the water-soluble solvent is a monoalcohol. Non-limiting examples of monoalcohols are ethanol, propanol, butanol, pentanol, hexanol, isopropyl alcohol, cyclohexanol, isobutyl alcohol, 2-methyl-2-butanol (2-methylbutan-2-ol) and mixtures thereof. including. In some instances, the monoalcohol includes or is selected from ethanol, propanol, butanol, pentanol, isomers thereof, or combinations thereof. In a further example, the one or more monoalcohol(s) comprises or consists of ethanol.

Examples of organic solvents include, but are not limited to, monoalcohols and polyols such as ethyl alcohol, isopropyl alcohol, propyl alcohol, benzyl alcohol and phenylethyl alcohol, or glycols or glycol ethers (e.g. ethylene glycol, monomethyl of propylene glycol, monoethyl and monobutyl ether) or their ethers (e.g. monomethyl ether of propylene glycol, butylene glycol, hexylene glycol, dipropylene glycol, etc.) and alkyl ethers of diethylene glycol (e.g. monoethyl ether or monobutyl ether of diethylene glycol). can. The water-soluble solvent may be an organic solvent which may be a volatile compound or a non-volatile compound.

Further non-limiting examples of water-soluble solvents include alkanediols such as glycerin, 1,2,6-hexanetriol, trimethylolpropane, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 2-butene -1,4-diol pentaethylene glycol (dipropylene glycol), 2-ethyl-1,3-hexanediol, 2-methyl-2,4-pentanediol (1,2-hexanediol) (caprylyl glycol) ( glycol ethers, methyl cellosolve, Ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol mono-n-propyl ether, ethylene glycol mono-iso-propyl ether, diethylene glycol mono-iso-propyl Ether, ethylene glycol mono-n-butyl ether, ethylene glycol mono-t-butyl ether, diethylene glycol mono-t-butyl ether, 1-methyl-1-methoxybutanol, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol mono-t -butyl ether, propylene glycol mono-n-propyl ether, propylene glycol mono-iso-propyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol mono-n-propyl ether, and dipropylene glycol mono- Iso-propyl ether; 2-pyrrolidone, N-methyl-2-pyrrolidone, 1,3-dimethyl-2-imidazolidinone, formamide, acetamide, dimethyl sulfoxide, sorbitol, sorbitan, acetin, diacetin, triacetin, sulfolane and their Contains mixtures.

silicone(s)
Cosmetic compositions typically include silicone(s) in an amount ranging from about 0.1 to about 10% by weight, based on the total weight of the cosmetic composition. For example, the amount of silicone(s) present in the cosmetic composition may range from about 0.1% to about 10%, from about 0.1% to about 8%, from about 0.1% to about 8%, by weight, based on the total weight of the cosmetic composition. 1 to about 6% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight; about 0.2 to about 10% by weight, about 0.2 to about 8% by weight, about 0. 2 to about 6% by weight, about 0.2 to about 4% by weight, about 0.2 to about 3% by weight; about 1 to about 10% by weight, about 1 to about 8% by weight, about 1 to about 6% by weight. , about 1 to about 4% by weight, about 1 to about 3% by weight; about 1.5 to about 10% by weight, about 1.5 to about 8% by weight, about 1.5 to about 6% by weight, about 1. 5 to about 4% by weight, about 1.5 to about 3% by weight; about 2 to about 10% by weight, about 2 to about 8% by weight, about 2 to about 6% by weight, about 2 to about 4% by weight, about It may range from 2 to about 3% by weight, including ranges and subranges therebetween.

The term "amino-functionalized silicone" or "amino silicone" means a silicone containing at least one primary amino, secondary amino, tertiary amino, and/or quaternary ammonium group. The structure of the amino-functionalized silicone may be linear or branched, cyclic or acyclic. The amino functionality may be located at any position in the silicone molecule, preferably at the end of the backbone (eg in the case of amodimethicone) and/or in the side chain.

Non-limiting examples of silicones include amine-functionalized silicones (e.g., amodimethicone), dimethicone, bisaminopropyl dimethicone, trimethylsilylamodimethicone, dimethicone copolyols, etc. Cosmetic compositions include, in some instances, polydimethylsiloxanes. (dimethicone), polydiethylsiloxane, polydimethylsiloxane with terminal hydroxyl groups (dimethiconol), polymethylphenylsiloxane, phenylmethylsiloxane, amino-functional polydimethylsiloxane (amodimethicone), bis-aminopropyl dimethicone, trimethylsilylamodimethicone, dimethicone It may include one or more silicones selected from copolyols, dimethicone copolyol esters, dimethicone copolyol quaternium nitrogen-containing compounds, dimethicone copolyol phosphate esters, and mixtures thereof. For example, the silicone or silicones may be or include one or more dimethicone copolyols. The copolyols are dimethicone adipate PEG-8, dimethicone benzoate PEG-8, dimethicone phosphate PEG-7, dimethicone phosphate PEG-10, dimethicone benzoate PEG/PPG-20/23, dimethicone phosphate PEG/PPG- 7/4, dimethicone phosphate PEG/PPG-12/4, PEG-3 dimethicone, PEG-7 dimethicone, PEG-8 dimethicone, PEG-9 dimethicone, PEG-10 dimethicone, PEG-12 dimethicone, PEG-14 dimethicone, PEG-17 dimethicone, PEG/PPG-3/10 dimethicone, PEG/PPG-4/12 dimethicone, PEG/PPG-6/11 dimethicone, PEG/PPG-8/14 dimethicone, PEG/PPG-14/4 dimethicone, PEG/PPG-15/15 dimethicone, PEG/PPG-16/2 dimethicone, PEG/PPG-17/18 dimethicone, PEG/PPG-18/18 dimethicone, PEG/PPG-19/19 dimethicone, PEG/PPG-20 /6 dimethicone, PEG/PPG-20/15 dimethicone, PEG/PPG-20/20 dimethicone, PEG/PPG-20/23 dimethicone, PEG/PPG-20/29 dimethicone, PEG/PPG-22/23 dimethicone, PEG /PPG-22/24 dimethicone, PEG/PPG-23/6 dimethicone, PEG/PPG-25/25 dimethicone, PEG/PPG-27/27 dimethicone and mixtures thereof.

The silicone(s) are optionally siloxanes having a methacrylic group at one of their molecular ends, polydimethylsiloxanes comprising a styryl group at one of their molecular ends, or similar silicone compounds containing unsaturated groups; Butadiene; vinyl chloride; vinylidene chloride; methacrylonitrile; dibutyl fumarate; maleic anhydride; succinic anhydride; methacryl glycidyl ether; organic salts of amines, ammonium salts, and methacrylic acid, itaconic acid, crotonic acid, maleic acid alkali metal salts of or of fumaric acid; radically polymerizable unsaturated monomers containing sulfonic acid groups, such as styrene sulfonic acid groups; It may include or be selected from quaternary ammonium salts; and methacrylic esters of alcohols containing tertiary amine groups, such as methacrylic esters of diethylamine.

In some cases, the silicone optionally comprises a siloxane having an organofunctional group such as a polyalkylsiloxane in which at least one alkyl radical is different from methyl, such as the INCI names stearyl dimethicone, cetyl dimethicone or C26-28 alkyl dimethicone. or organopolysiloxanes, such as polyarylsiloxanes and polyarylalkylsiloxanes, such as those having the INCI names phenyltrimethicone, trimethylsiloxyphenyl dimethicone or dimethylphenyl dimethicone, or, for example, aminopropyl, aminopropyl-aminoethyl, Organopolysiloxanes with organofunctional radicals such as aminopropyl-aminoisobutyl radicals, such as organopolysiloxanes with the INCI name amodimethicone, or organopolysiloxanes with, for example, polyethylene glycol or polyalkylene glycol radicals, such as the INCI name PEG-12. Contains or is selected from organopolysiloxanes having dimethicone PEG/PPG-25,25-dimethicone or cetyl PEG/PPG-15/15 butyl ether dimethicone.

［式中、各Ｒ^１は、Ｃ_１－３０アルキル基、Ｃ_１－３０アルコキシ基、Ｃ_５－３０アリール基、Ｃ_６－３０アラルキル基、Ｃ_６－３０アラルキルオキシ基、Ｃ_１－３０アルカリール基、Ｃ_１－３０アルコキシアリール基、及びヒドロキシ基から独立して選択され（好ましくは、各Ｒ^１は、Ｃ_１－３０アルキル基、Ｃ_１－３０アルコキシ基及びヒドロキシ基から独立して選択され）；
各Ｒ^２は独立して１～１０炭素原子を有する二価アルキレンラジカルである。（好ましくは、Ｒ^２は３～６炭素原子を有する二価アルキレンラジカルである）；
各Ｒ^３は、Ｃ_１－３０アルキル基、Ｃ_５－３０アリール基、Ｃ_６－３０アラルキル基及びＣ_１－３０アルカリール基から独立して選択され（好ましくは、各Ｒ^３は、Ｃ_１－３０アルキル基から独立して選択され）；
Ｑは－ＮＲ^４ _２及び－ＮＲ^４（ＣＨ_２）_ｘＮＲ^４ _２から選択される１価のラジカルであり；
各Ｒ^４は、水素及びＣ_１－４アルキル基から独立して選択され；
ｘは２～６であり；
ｚは０又は１であり；
ｎは２５～３，０００（好ましくは、２５～２，０００；より好ましくは、２５～１，０００；最も好ましくは、２５～５００）であり；
ｍは０～３，０００（好ましくは０～２，０００；より好ましくは０～１，０００；最も好ましくは０～１００）であり；
ただし、Ｒ^１及びＲ^３基の合計数の少なくとも５０ｍｏｌ％がメチルであり、ｍが０のとき、ｚは１である］
を有する化合物から選択される。 In some instances, the amino-functionalized silicone has the following formula:

[In the formula, each R ¹ is a C _1-30 alkyl group, a C _1-30 alkoxy group, a C _5-30 aryl group, a C _6-30 aralkyl group, a C _6-30 aralkyloxy group, or a C _1-30 alkyl group. independently selected from lyl, C _1-30 alkoxyaryl, and hydroxy (preferably each R ¹ is independently selected from C _1-30 alkyl, C _1-30 alkoxy, and hydroxy) );
Each R ² is independently a divalent alkylene radical having 1 to 10 carbon atoms. (preferably R ² is a divalent alkylene radical having 3 to 6 carbon atoms);
Each R ³ is independently selected from a C _1-30 alkyl group, a C _5-30 aryl group, a C _6-30 aralkyl group, and a C _1-30 alkaryl group (preferably, each R ³ is a C _{1-30 -30} alkyl groups);
Q is a monovalent radical selected from -NR ⁴ ₂ and -NR ⁴ (CH ₂ ) _x NR ⁴ ₂ ;
each R ⁴ is independently selected from hydrogen and C _1-4 alkyl groups;
x is 2 to 6;
z is 0 or 1;
n is 25 to 3,000 (preferably 25 to 2,000; more preferably 25 to 1,000; most preferably 25 to 500);
m is 0 to 3,000 (preferably 0 to 2,000; more preferably 0 to 1,000; most preferably 0 to 100);
However, when at least 50 mol% of the total number of R ¹ and R ³ groups is methyl, and m is 0, z is 1]
selected from compounds having

Preferred R ¹ groups include methyl, methoxy, ethyl, ethoxy, propyl, propoxy, isopropyl, isopropoxy, butyl, butoxy, isobutyl, isobutoxy, phenyl, xenyl, benzyl, phenylethyl, tolyl and hydroxy. Preferred R ² divalent alkylene radicals include trimethylene, tetramethylene, pentamethylene, -CH ₂ CH (CH ₃ )CH ₂ - and -CH ₂ CH ₂ CH (CH ₃ )CH ₂ -. Preferred ^R3 groups include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, phenyl, xenyl, benzyl, phenylethyl and tolyl. Preferred R ⁴ groups include methyl, ethyl, propyl, isopropyl, butyl and isobutyl. When z is 0, an amino-functionalized silicone has only pendant amine-functional substituents in the polymer chain. When z is 1, the amino-functional silicone may have only terminal amine-functional substituents (e.g., m=0), or it may have both terminal and pendant amine-functional substituents in the polymer chain. (for example, m>0). Preferably, n+m is 50 to 1,000. More preferably, n+m is 50-750. Still more preferably, n+m is from 50 to 500. Most preferably n+m is 50-250.

［式中、Ｒ_３はヒドロキシル又はＯＲ_５であり、Ｒ_５はＣ_１～Ｃ_４アルキル基であり、Ｒ_４は以下の式：

による構造を含む基であり、
Ｒ_６はＣ_１～Ｃ_４アルキルであり、ｎは１～４であり、ｘは上に記載の「ｎ」と同じであり、ｙは上に記載の「ｍ」と同じである］
の化合物から選択されてもよい。 In some instances, the amino-functionalized silicone is an alkoxylated and/or hydroxylated amino silicone. Suitable alkoxylated and/or hydroxylated amino silicones have the following formula:

[wherein R ₃ is hydroxyl or OR ₅ , R ₅ is a C ₁ -C ₄ alkyl group, and R ₄ is of the following formula:

It is a group containing the structure according to
R ₆ is C ₁ -C ₄ alkyl, n is 1-4, x is the same as "n" as described above, and y is the same as "m" as described above]
may be selected from the following compounds.

［式中、ｘ’及びｙ’は重量平均分子量（Ｍｗ）が約５０００から５００ ０００の間に含まれるような整数である］
に対応するポリシロキサン；
ｂ）以下の式：
Ｒ’_ａＧ_３－ａ－Ｓｉ（ＯＳｉＧ_２）_ｎ－（ＯＳｉＧ_ｂＲ’_２－ｂ）_ｍ－Ｏ－ＳｉＧ_３－ａ－Ｒ’_ａ
［式中、：
Ｇは、同一でも異なっていてもよく、水素原子、又はフェニル、ＯＨ又はＣ_１～Ｃ_８アルキル基、例えばメチル又はＣ_１～Ｃ_８アルコキシ、例えばメトキシを指し、
ａは、同一でも異なっていてもよく、数０又は１～３の整数、特に０を示し、
ｂは０又は１、特に１を示し、
ｍ及びｎは合計（ｎ＋ｍ）が１～２０００、特に５０～１５０の範囲となるような数であり、ｎが０～１９９９、特に４９～１４９の数を示し、ｍが１～２０００、特に１～１０の数を示すことができ、
Ｒ’は、同一でも異なっていてもよく、式－ＣｑＨ_２ｑＬ［式中、ｑは２～８の範囲の数であり、Ｌは以下：
－ＮＲ”－Ｑ－Ｎ（Ｒ”）_２
－Ｎ（Ｒ”）_２
－Ｎ＋（Ｒ”）_３Ａ－
－Ｎ＋Ｈ（Ｒ”）_２Ａ－
－Ｎ＋Ｈ_２（Ｒ”）Ａ－
－Ｎ（Ｒ”）－Ｑ－Ｎ＋Ｒ”Ｈ_２Ａ－
－ＮＲ”－Ｑ－Ｎ＋（Ｒ”）_２ＨＡ－
－ＮＲ”－ＱＮ＋（Ｒ”）_３Ａ、
［式中、Ｒ”は、同一でも異なっていてもよく、水素、フェニル、ベンジル又は飽和１価炭化水素系ラジカル、例えばＣ_１～Ｃ_２０アルキルラジカルを示し；Ｑは直鎖又は分岐ＣｒＨ_２ｒ基［ｒは２～６、好ましくは２～４の範囲の整数である］を示し；Ａ－は化粧品として許容されるイオン、特に、フルオリド、クロリド、ブロミド又はヨージドなどのハライドを表す］
を有する１価のラジカルを示す］
の基から選ばれる、任意選択的に、四級化されたアミノ基である］］
に対応するアミノシリコーン
であってもよい。 Silicone has the following formula:

[wherein x' and y' are integers such that the weight average molecular weight (Mw) is comprised between about 5,000 and 500,000]
Polysiloxane corresponding to;
b) The following formula:
R' _a G _3-a -Si(OSiG ₂ ) _n -(OSiG _b R' _2-b ) _m -O-SiG _3-a -R' _a
[In the formula:
G, which may be the same or different, refers to a hydrogen atom or a phenyl, OH or a C ₁ -C ₈ alkyl group, such as methyl or a C ₁ -C ₈ alkoxy, such as methoxy;
a may be the same or different, and represents the number 0 or an integer from 1 to 3, particularly 0;
b represents 0 or 1, especially 1,
m and n are numbers such that the total (n+m) is in the range of 1 to 2000, especially 50 to 150, n is 0 to 1999, especially 49 to 149, and m is 1 to 2000, especially 1 ～Can show the number 10,
R' may be the same or different and have the formula -CqH ₂ qL [where q is a number ranging from 2 to 8 and L is the following:
-NR”-Q-N(R”) ₂
-N(R”) ₂
-N+(R”) ₃ A-
-N+H(R”) ₂ A-
-N+H ₂ (R”)A-
-N(R”)-Q-N+R”H ₂ A-
-NR”-Q-N+(R”) ₂ HA-
-NR”-QN+(R”) ₃ A,
[wherein R'' may be the same or different and represents hydrogen, phenyl, benzyl or a saturated monovalent hydrocarbon radical, such as a C ₁ -C ₂₀ alkyl radical; Q is a linear or branched CrH _2r group; [r is an integer in the range from 2 to 6, preferably from 2 to 4]; A- represents a cosmetically acceptable ion, in particular a halide such as fluoride, chloride, bromide or iodide]
[indicates a monovalent radical having]
is an optionally quaternized amino group selected from the group ]]
It may also be an amino silicone corresponding to

［式中、：
ｍ及びｎは合計（ｎ＋ｍ）が１～１０００、特に５０～２５０、とりわけ１００～２００の範囲をとり得るような数であり、ｎは０～９９９、特に４９～２４９、とりわけ１２５～１７５の数を示すことが可能であり、ｍは１～１０００、特に１～１０、とりわけ１～５の数を示すことが可能であり、
Ｒ_１、Ｒ_２、Ｒ_３は、同一でも異なっていてもよく、ヒドロキシ又はＣ_１～Ｃ_４アルコキシラジカルを表し、ここでラジカルＲ_１～Ｒ_３の少なくとも１つはアルコキシラジカルを示す］
を有するシリコーンによって代表される。 Another group of amino silicones corresponding to this definition has the following formula:

[In the formula:
m and n are numbers such that the sum (n+m) can range from 1 to 1000, especially from 50 to 250, especially from 100 to 200, and n is a number from 0 to 999, especially from 49 to 249, especially from 125 to 175. m can represent a number from 1 to 1000, especially from 1 to 10, especially from 1 to 5,
R ₁ , R ₂ and R ₃ may be the same or different and represent hydroxy or a C ₁ to C ₄ alkoxy radical, where at least one of the radicals R ₁ to R ₃ represents an alkoxy radical]
typified by silicone with

The alkoxy radical is preferably a methoxy radical. The hydroxy/alkoxy molar ratio preferably ranges from 0.2:1 to 0.4:1, preferably from 0.25:1 to 0.35:1, in particular equal to 0.3:1. The weight average molecular weight (Mw) of the silicone is preferably in the range from 2,000 to 1,000,000, especially from 3,500 to 200,000.

［式中、
ｐ及びｑは、合計（ｐ＋ｑ）が１～１０００、特に５０～３５０、とりわけ１５０～２５０の範囲をとるような数であり、ｐは０～９９９、特に４９～３４９、とりわけ１５９～２３９の数を示すことが可能であり、ｑは１～１０００、特に１～１０、とりわけ１～５の数を示すことが可能であり、
Ｒ_１、Ｒ_２は、同じでも異なっていてもよく、ヒドロキシ又はＣ_１～Ｃ_４アルコキシラジカルを表し、ここでラジカルＲ_１又はＲ_２の少なくとも１つはアルコキシラジカルを示す］
によって表される。 Another group of amino silicones corresponding to this definition has the following formula:

[In the formula,
p and q are numbers such that the sum (p+q) ranges from 1 to 1000, especially from 50 to 350, especially from 150 to 250, and p is a number from 0 to 999, especially from 49 to 349, especially from 159 to 239. q can represent a number from 1 to 1000, especially from 1 to 10, especially from 1 to 5,
R ₁ and R ₂ may be the same or different and represent hydroxy or a C ₁ -C ₄ alkoxy radical, where at least one of the radicals R ₁ or R ₂ represents an alkoxy radical]
Represented by

The alkoxy radical is preferably a methoxy radical. The hydroxy/alkoxy molar ratio generally ranges from 1:0.8 to 1:1.1, preferably from 1:0.9 to 1:1, in particular equal to 1:0.95.

［式中、
ｍ及びｎは、合計（ｎ＋ｍ）が１～２０００、特に５０～１５０の範囲をとるような数であり、ｎは０～１９９９、特に４９～１４９の数を示すことが可能であり、ｍは１～２０００、特に１～１０の数を示すことが可能であり、
Ａは、４～８炭素原子、好ましくは４炭素原子を含有する直鎖又は分岐アルキレンラジカルを示す。このラジカルは好ましくは直鎖である］
によって表される。 Another group of amino silicones has the following formula:

[In the formula,
m and n are numbers such that the total (n+m) ranges from 1 to 2000, particularly from 50 to 150, n can represent a number from 0 to 1999, especially from 49 to 149, and m is It is possible to indicate a number from 1 to 2000, especially from 1 to 10,
A represents a straight-chain or branched alkylene radical containing 4 to 8 carbon atoms, preferably 4 carbon atoms. This radical is preferably linear]
Represented by

The weight average molecular weight (Mw) of this amino silicone is preferably in the range of 2,000 to 1,000,000, even more preferably 3,500 to 200,000.

［式中、
ｍ及びｎは、合計（ｎ＋ｍ）が１～２０００、特に５０～１５０の範囲をとるような数であり、ｎは０～１９９９、特に４９～１４９の数を示すことが可能であり、ｍは１～２０００、特に１～１０の数を示すことが可能であり、
Ａは、４～８炭素原子、好ましくは４炭素原子を含有する直鎖又は分岐アルキレンラジカルを示す。このラジカルは好ましくは分岐である］
によって表される。 Another group of amino silicones has the following formula:

[In the formula,
m and n are numbers such that the total (n+m) ranges from 1 to 2000, particularly from 50 to 150, n can represent a number from 0 to 1999, especially from 49 to 149, and m is It is possible to indicate a number from 1 to 2000, especially from 1 to 10,
A represents a straight-chain or branched alkylene radical containing 4 to 8 carbon atoms, preferably 4 carbon atoms. This radical is preferably branched]
Represented by

The weight average molecular weight (Mw) of this amino silicone is preferably in the range of 500 to 1,000,000, even more preferably 1000 to 200,000.

［式中、
Ｒ_５は、１～１８炭素原子を含有する１価の炭化水素系ラジカル、特にＣ_１～Ｃ_１８アルキル、又はＣ_２～Ｃ_１８アルケニルラジカル、例えばメチルを表し、
Ｒ_６は二価炭化水素系ラジカル、特にＣ_１～Ｃ_１８アルキレンラジカル又は二価Ｃ_１～Ｃ_１８、例えば、ＳｉＣ結合を介してＳｉに連結したＣ_１～Ｃ_８アルケノキシラジカルを表し、
Ｑ－は、ハライドイオン、特にクロリド又は有機酸塩（例えば酢酸塩）などの陰イオンであり、
ｒは、２～２０、特に２～８の統計的平均値を表し、
ｓは、２０～２００、特に２０～５０の統計的平均値を表す］
によって表される。 Another group of amino silicones has the following formula:

[In the formula,
R ₅ represents a monovalent hydrocarbon radical containing 1 to 18 carbon atoms, in particular a C ₁ to C ₁₈ alkyl, or a C ₂ to C ₁₈ alkenyl radical, for example methyl;
R ₆ represents a divalent hydrocarbon radical, in particular a C ₁ -C ₁₈ alkylene radical or a divalent C ₁ -C ₁₈ , for example a C ₁ -C ₈ alkenoxy radical linked to Si via a SiC bond;
Q- is a halide ion, especially an anion such as chloride or an organic acid salt (e.g. acetate);
r represents a statistical average value of 2 to 20, especially 2 to 8;
s represents a statistical average value of 20 to 200, particularly 20 to 50]
Represented by

Such aminosilicone is described, inter alia, in US Pat. No. 4,185,087.

［式中、
Ｒ_７は、同一でも異なっていてもよく、１～１８炭素原子を含む１価の炭化水素系ラジカル、特にＣ_１～Ｃ_１８アルキルラジカル、Ｃ_２～Ｃ_１８アルケニルラジカル又は５若しくは６個の炭素原子を含有する環、例えばメチルを表し、
Ｒ_６は、二価炭化水素系ラジカル、特にＣ_１～Ｃ_１８アルキレンラジカル、又はＳｉＣ結合を介してＳｉに連結した二価Ｃ_１～Ｃ_１８、例えばＣ_１～Ｃ_８アルケノキシラジカルを表し、
Ｒ_８は、同一でも異なっていてもよく、水素原子、１～１８炭素原子を含有する１価の炭化水素系ラジカル、特にＣ_１～Ｃ_１８アルキルラジカル、Ｃ_２～Ｃ_１８アルケニルラジカル又は－Ｒ_６－ＮＨＣＯＲ_７ラジカルを表し、
Ｘ－は、ハライドイオン、特にクロリド又は有機酸塩（例えば酢酸塩）などの陰イオンであり、
ｒは、２～２００、特に５～１００の統計的平均値を表す］
によって表される。これらのシリコーンは、例えば欧州特許出願公開第０５３０９７４号に記載されている。 The group of quaternary ammonium silicones has the following formula:

[In the formula,
R ₇ may be the same or different and represents a monovalent hydrocarbon radical containing 1 to 18 carbon atoms, in particular a C ₁ to C ₁₈ alkyl radical, a C ₂ to C ₁₈ alkenyl radical or a 5 or 6 carbon radical. represents a ring containing atoms, for example methyl,
R ₆ represents a divalent hydrocarbon radical, in particular a C ₁ -C ₁₈ alkylene radical, or a divalent C ₁ -C ₁₈ , for example C ₁ -C ₈ alkenoxy radical, linked to Si via a SiC bond; ,
R ₈ may be the same or different and represents a hydrogen atom, a monovalent hydrocarbon radical containing 1 to 18 carbon atoms, in particular a C ₁ to C ₁₈ alkyl radical, a C ₂ to C ₁₈ alkenyl radical or -R ₆ -NHCOR ₇ represents a radical,
X- is a halide ion, especially an anion such as chloride or an organic acid salt (e.g. acetate);
r represents a statistical average value of 2 to 200, particularly 5 to 100]
Represented by These silicones are described, for example, in European Patent Application No. 0530974.

［式中、
Ｒ_１、Ｒ_２、Ｒ_３及びＲ_４は、同一でも異なっていてもよく、Ｃ_１～Ｃ_４アルキルラジカル又はフェニル基を示し、
Ｒ_５はＣ_１～Ｃ_４アルキルラジカル又はヒドロキシル基を示し、
ｎは１～５の範囲の整数であり、
ｍは１～５の範囲の整数であり、
ｘはアミンの数が０．０１から１ｍｅｑ／ｇとなるように選ばれ、
Ａがポリシロキサンブロックであり、Ｂは少なくとも１個のアミン基を含むポリオキシアルキレン化ブロックである（ＡＢ）ｎ型の多重ブロックポリオキシアルキレン化アミノシリコーンである］
によって表される。 The group of quaternary ammonium silicones has the following formula:

[In the formula,
R ₁ , R ₂ , R ₃ and R ₄ may be the same or different and represent a C ₁ -C ₄ alkyl radical or a phenyl group,
R ₅ represents a C ₁ -C ₄ alkyl radical or a hydroxyl group,
n is an integer in the range of 1 to 5;
m is an integer in the range of 1 to 5;
x is selected such that the number of amines is from 0.01 to 1 meq/g,
A is a polysiloxane block and B is a polyoxyalkylenated block containing at least one amine group (AB) is an n-type multiblock polyoxyalkylenated amino silicone]
Represented by

The silicone preferably has the following general formula:
[-(SiMe ₂ O)xSiMe ₂ -RN(R")-R'-O(C ₂ H ₄ O) _a (C ₃ H ₆ O) b-R'-N(H)-R-]
or as an alternative [-(SiMe ₂ O)xSiMe ₂ -RN(R”)-R'-O(C ₂ H ₄ O) _a (C ₃ H ₆ O) b-]
[In the formula,
a is an integer equal to or greater than 1, preferably in the range 5 to 200, especially in the range 10 to 100;
b is an integer comprised between 0 and 200, preferably between 4 and 100, especially between 5 and 30;
x is an integer ranging from 1 to 10,000, especially from 10 to 5,000;
R" is a hydrogen atom or methyl,
R represents a divalent straight chain or branched C ₂ -C ₁₂ hydrocarbon radical which may be the same or different and optionally contains one or more heteroatoms such as oxygen; preferably R , an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, or a -CH ₂ CH ₂ CH ₂ OCH(OH)CH ₂ - radical; preferentially, R is -CH ₂ CH ₂ CH ₂ OCH(OH)CH ₂ - represents the radical,
R' may be the same or different and represents a divalent straight chain or branched C ₂ -C ₁₂ hydrocarbon radical optionally containing one or more heteroatoms such as oxygen; preferably R ' denotes an ethylene radical, a straight-chain or branched propylene radical, a straight-chain or branched butylene radical, or a -CH ₂ CH ₂ CH ₂ OCH(OH)CH ₂ - radical; preferentially R' represents -CH(CH ₃ )-CH ₂ -]
It is composed of repeating units with .

The siloxane blocks preferably represent between 50 and 95 mol%, in particular 70 to 85 mol%, of the total mass weight of the silicone.

The amine content is preferably between 0.02 and 0.5 meq/g of copolymer in a 30% solution of dipropylene glycol, especially between 0.05 and 0.2. The weight average molecular weight (Mw) of the silicone oil is preferably comprised between 5000 and 1,000,000, especially between 10,000 and 200,000.

The silicone may be selected from those having at least one quaternary ammonium group. Suitable non-limiting examples are Quaternium-80, Silicone Quaternium-1, Silicone Quaternium-2, Panthenylsuccinate Silicone Quaternium-2 Silicone Quaternium-3, Silicone Quaternium-4 , Silicone Quaternium-5, Silicone Quaternium-6, Silicone Quaternium-7, Silicone Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15, Silicone Quaternium-16, Silicone Quaternium-16/Glycidoxy Dimethicone Crosspolymer, Silicone Quaternium-17, Silicone Quaternium-18, Silicone They are Quaternium-20 and Silicone Quaternium-21. Quaternium-80, Silicone Quaternium-16, Silicone Quaternium-18, Silicone Quaternium-1, Silicone Quaternium-2, Silicone Quaternium-3, Silicone Quaternium-4, Silicone Quaternium -5, Silicone Quaternium-6, Silicone Quaternium-7, Silicone Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium- 12, Silicone Quaternium-15, Silicone Quaternium-17, Silicone Quaternium-20 and Silicone Quaternium-21 are preferred. Quaternium-80, Silicone Quaternium-16, Silicone Quaternium-18, Silicone Quaternium-3, Silicone Quaternium-4, Silicone Quaternium-5, Silicone Quaternium-6, Silicone Quaternium -7, Silicone Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15 and Silicone Quaternium- 17 is more preferred. Preferred are Quaternium-80, Silicone Quaternium-16, Silicone Quaternium-18, Silicone Quaternium-15 and mixtures thereof. In embodiments, one or more silicone oils of the present disclosure are non-amino silicone oils such as dimethicone.

Non-limiting examples of amino-functionalized silicones include bis-hydroxy/methoxyamodimethicone, biscetearylamodimethicone, amodimethicone, bis(C13-15 alkoxy)PG amodimethicone, aminopropylphenyl trimethicone, aminopropyl dimethicone, Bisamino PEG/PPG-41/3 Aminoethyl PG Contains propyl dimethicone, caprylyl methicone, and mixtures thereof. In some instances, a particularly useful amino-functionalized silicone is a bis-hydroxy/methoxyamodimethicone where in the above structure, X is isobutyl, one of the R is OH, and the other is _OCH3 ; This also includes "bishydroxy/methoxy amodimethicone" and "3-[(2-aminoethyl)amino]-2-methylpropyl Me, diMe, [(hydroxydimethylsilyl)oxy]- and [(methoxydimethylsilyl) ) oxy] terminus. Bis-hydroxy/methoxyamodimethicone is commercially available under the trade name DOWSIL AP-8087 FLUID from The Dow Chemical Company. Non-limiting examples of amodimethicone products containing amino silicones having structure (D) are sold by Wacker under the names BELSIL ADM 652, BELSIL ADM 4000E, or BELSIL ADM LOG 1. A product containing amino silicone having structure (E) is sold by Wacker under the name FLUID WR 1300. Additionally or alternatively, the weight average molecular weight (Mw) of the silicone preferably ranges from 2,000 to 200,000, even more preferably from 5,000 to 100,000, especially from 10,000 to 50,000.

The silicone(s) in the cosmetic compositions of the present disclosure may include at least one silicone and at least one surfactant, such as a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, an anionic surfactant, or an anionic surfactant. It is contained in the form of a silicone emulsion containing a surfactant. The silicone emulsion may be a nanoemulsion, a microemulsion or a macroemulsion. Suitable examples of non-ionic surfactants are polyethylene glycol ethers of alkoxylated aliphatic alcohols or mixtures of C8-C30 aliphatic alcohols, C11-15 pares-7, laureth-9, laureth-12, deces -7, Deceth-10, Trideceth-6, Trideceth-10, Trideceth-12, or mixtures thereof. Suitable examples of amphoteric surfactants are cocamidopropyl betaine, coco-betaine or mixtures thereof. Suitable examples of cationic surfactants are quaternary ammonium compounds such as behentrimonium chloride, cetrimonium chloride, behentrimonium methosulfate or mixtures thereof. Suitable examples of anionic surfactants are sulphate-based compounds, such as those containing up to 5% by weight of surfactants, such as sodium (or ammonium) lauryl sulfate, sodium (or ammonium) laureth sulfate or Further includes mixtures thereof.

Cationic polymer(s)
The cosmetic composition may optionally include one or more cationic polymers. The amount of cationic polymer in the cosmetic composition typically ranges from about 0.1 to about 10% by weight of the total weight of the cosmetic composition. In some instances, the cationic polymer is about 0.1% to about 10%, about 0.1% to about 8%, about 0.1% to about 6% by weight, based on the total weight of the cosmetic composition. , about 0.1 to about 4% by weight, about 0.1 to about 3% by weight; about 0.2 to about 10% by weight, about 0.2 to about 8% by weight, about 0.2 to about 6% by weight , about 0.2 to about 4% by weight, about 0.2 to about 3% by weight; about 1 to about 10% by weight, about 1 to about 8% by weight, about 1 to about 6% by weight, about 1 to about 4% by weight % by weight, about 1 to about 3%; about 1.5 to about 10%, about 1.5 to about 8%, about 1.5 to about 6%, about 1.5 to about 4% by weight. , about 1.5 to about 3% by weight; about 2 to about 10% by weight, about 2 to about 8% by weight, about 2 to about 6% by weight, about 2 to about 4% by weight, about 2 to about 3% by weight the amount, inclusive of ranges and subranges therebetween.

The cationic polymer can contain a mixture of monomer units derived from amine- and/or quaternary ammonium-substituted monomers and/or compatible spacer monomers. Suitable cationic polymers are, for example, copolymers of 1-vinyl-2-pyrrolidine and 1-vinyl-3-methyl-imidazolium salts (for example chloride salts) (referred to as polyquaternium-16), such as LUVIQUAT. those commercially available from BASF under the trade names (e.g. LUVIQUAT FC 370); copolymers of 1-vinyl-2-pyrrolidine and dimethylaminoethyl methacrylate (referred to as polyquaternium-11), e.g. under the trade names GAFQUAT (e.g. GAFQUAT 755N) from Gar Corporation (Wayne, N.J., USA); Contains polymers containing quaternary ammonium groups (referred to as polyquaternium-6 and polyquaternium-7).

Other cationic polymers that may be used include polysaccharide polymers such as cationic cellulose derivatives and cationic starch derivatives. Cationic cellulose is available from Amerchol Corp. in the Polymer JR™ and LR™ polymer series as a salt of hydroxyethylcellulose reacted with trimethylammonium-substituted epoxide. (Edison, N.J., USA) (referred to as Polyquaternium-10). Another type of cationic cellulose includes polymeric quaternary ammonium salts of hydroxyethylcellulose reacted with lauryldimethylammonium-substituted epoxides (designated polyquaternium-24). These materials are sold by Amerchol Corp. under the trade name Polymer LM-200. (Edison, N.J., USA). Additionally or alternatively, the cationic conditioning polymer may include or be selected from cationic guar gum derivatives, such as guar hydroxypropyltrimonium chloride.

The cosmetic composition may include or be selected from polyquaternium. For example, a cosmetic composition may include polyquaternium-1 (ethanol, 2,2',2"-nitrilotris-, 1,4-dichloro-2-butene and N,N,N',N'-tetramethyl-2- butene-1,4-diamine), polyquaternium-2, poly[bis(2-chloroethyl)ether-alt-1,3-bis[3-(dimethylamino)propyl]urea]polyquaternium-4 (hydroxyethylcellulose and Copolymer of dimethyldiallylammonium chloride; diallyldimethylammonium chloride-hydroxyethylcellulose copolymer), Polyquaternium-5 (copolymer of acrylamide and quaternized dimethylammonium ethyl methacrylate), Polyquaternium-6 (poly(diallyldimethylammonium chloride)), Polyquaternium-7 (copolymer of acrylamide and diallyldimethylammonium chloride), polyquaternium-8 (copolymer of methyldimethylaminoethyl methacrylic acid and stearyldimethylaminoethyl ester of methacrylic acid quaternized with dimethyl sulfate), polyquaternium-9 (copolymer of methacrylic acid methyldimethylaminoethyl ester and stearyldimethylaminoethyl methacrylic acid ester), N,N-(dimethylamino)ethyl ester quaternized homopolymer with bromomethane), Polyquaternium-10 (quaternized hydroxyethylcellulose), Polyquaternium-11 (copolymer of vinylpyrrolidone and quaternized dimethylaminoethyl methacrylate), Polyquaternium-12 (copolymer of ethyl methacrylate/abiethyl methacrylate/diethylaminoethyl methacrylate quaternized with dimethyl sulfate), Polyquaternium-13 (copolymer of ethyl methacrylate/oleyl methacrylate/diethylaminoethyl methacrylate quaternized with dimethyl sulfate) polyquaternium-14 (trimethylaminoethyl methacrylate homopolymer), polyquaternium-15 (acrylamide-dimethylaminoethyl methacrylate methyl chloride copolymer), polyquaternium-16 (copolymer of vinylpyrrolidone and quaternized vinyl imidazole), polyquaternium-17 (Adipic acid, dimethylaminopropylamine, dichloroethyl ether copolymer), Polyquaternium-18 (Azelaic acid, dimethylaminopropylamine, dichloroethyl ether copolymer), Polyquaternium-19 (copolymer of polyvinyl alcohol and 2,3-epoxypropylamine) , Polyquaternium-20 (copolymer of polyvinyl octadecyl ether and 2,3-epoxypropylamine), Polyquaternium-22 (copolymer of acrylic acid and diallyldimethylammonium chloride), Polyquaternium-24 (hydroxyethylcellulose reacted with lauryldimethylammonium-substituted epoxide) polyquaternium-27 (block copolymer of polyquaternium-2 and polyquaternium-17), polyquaternium-28 (copolymer of vinylpyrrolidone and methacrylamide propyltrimethylammonium), polyquaternium-29 (modified with propylene oxide) , chitosan quaternized with epichlorohydrin), polyquaternium-30 (ethanaminium, N-(carboxymethyl)-N,N,N-dimethylaniline-2-[(2-methyl-1-oxo-2) -propen-1-yl)oxy]-, inner salt, polymer with methyl 2-methyl-2-propenoate), polyquaternium-31 (quaternized with diethyl sulfate and bonded to blocks of polyacrylonitrile, N,N -dimethylaminopropyl-N-acrylamidine), Polyquaternium-32 (poly(acrylamide 2-methacryloxyethyltrimethylammonium chloride)), Polyquaternium-33, (copolymer of trimethylaminoethyl acrylate and acrylamide) Polyquaternium-34 (1,3 - copolymer of dibromopropane and N,N-diethyl-N',N'-dimethyl-1,3-propanediamine), polyquaternium-35, (copolymer of methacryloyloxyethyltrimethylammonium and methacryloyloxyethyldimethylacetylammonium) sulfate) Polyquaternium-36 (copolymer of N,N-dimethylaminoethyl methacrylate and butyl methacrylate quaternized with dimethyl sulfate) Polyquaternium-37 (poly(2-methacryloxyethyltrimethylammonium chloride)), Polyquaternium-39 ( Polyquaternium-42 (poly[oxyethylene (dimethylimino) ethylene (dimethylimino) ethylene dichloride]), Polyquaternium-43 (acrylamide, acrylamide propyltrimonium chloride, 2- amidopropylacrylamide sulfonate, dimethylaminopropylamine copolymer), Polyquaternium-44 (3-methyl-1-vinylimidazolium methylsulfate-N-vinylpyrrolidone copolymer), Polyquaternium-45 ((N-methyl-N-ethoxy Polyquaternium-46 (terpolymer of vinylcaprolactam, vinylpyrrolidone and quaternized vinylimidazole), Polyquaternium-47 (acrylic acid) , a terpolymer of methacrylamide propyltrimethylammonium chloride and methyl acrylate), and/or polyquaternium-67.

In some instances, the cosmetic compositions of the present disclosure include cationic cellulose derivatives, quaternized hydroxyethyl cellulose (e.g., polyquaternium-10), cationic starch derivatives, cationic guar gum derivatives, acrylamide and dimethyldiallylammonium chloride. (eg, polyquaternium-7), polyquaternium, and mixtures thereof. For example, the cationic polymer(s) may include polyquaterniums such as polyquaternium-4, polyquaternium-5, polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-22, polyquaternium-37, polyquaternium-39, polyquaternium-47. , polyquaternium-53, polyquaternium-67 and mixtures thereof. Combinations of two or more polyquaterniums may be useful.

In one example, the one or more cationic polymers are polyquaternium 4, polyquaternium 6, polyquaternium 7, polyquaternium 10, polyquaternium 11, polyquaternium 16, polyquaternium Quaternium 22, Polyquaternium 28, Polyquaternium 32, Polyquaternium-46, Polyquaternium-51, Polyquaternium-52, Polyquaternium-53, Polyquaternium- 54, Polyquaternium-55, Polyquaternium-56, Polyquaternium-57, Polyquaternium-58, Polyquaternium-59, Polyquaternium-60, Polyquaternium-63 , polyquaternium-64, polyquaternium-65, polyquaternium-66, polyquaternium-67, polyquaternium-70, polyquaternium-73, polyquaternium-74, Polyquaternium-75, Polyquaternium-76, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Poly Quaternium-82, Polyquaternium-84, Polyquaternium-85, Polyquaternium-86, Polyquaternium-87, Polyquaternium-90, Polyquaternium-91, Polyquaternium selected from ternium-92, polyquaternium-94, guar hydroxypropyltrimonium chloride and mixtures thereof.

Nonionic surfactant(s)
The cosmetic composition may optionally include one or more nonionic surfactants. The amount of nonionic surfactant, when present, usually ranges from about 0.05 to about 6% by weight of the total weight of the cosmetic composition. For example, the total weight of the plurality of nonionic surfactants may be about 0.05 to about 6%, 0.05 to about 5%, 0.05 to about 4% by weight based on the total weight of the cosmetic composition. 0.05 to about 3% by weight; 0.1 to about 6% by weight, 0.1 to about 5% by weight, 0.1 to about 4% by weight, 0.1 to about 3% by weight; 0.5 ~about 6% by weight, 0.5 to about 5% by weight, 0.5 to about 4% by weight, 0.5 to about 3% by weight; 0.8 to about 6% by weight, 0.8 to about 5% by weight , 0.8 to about 4%, 0.8 to about 3%; 1 to about 6%, 1 to about 5%, 1 to about 4%, or 1 to about 3% by weight. and includes ranges and subranges therebetween.

Examples of nonionic surfactants that may be suitably incorporated into cosmetic compositions include, in some cases, ethoxylated, propoxylated or glycerolated, for example at least one fatty acid containing from 8 to 18 carbon atoms. The number of ethylene oxide or propylene oxide groups can range from 2 to 50, and the number of glycerol groups can range from 1 to 30. A range of is possible. Maltose derivatives may also be mentioned. Also, but not limited to, copolymers of ethylene oxide and/or propylene oxide; condensates of ethylene oxide and/or propylene oxide with aliphatic alcohols; polyethoxylated fatty acid amides containing, for example, 2 to 30 mol of ethylene oxide; for example, 1.5 to 4. polyglycerolated fatty acid amides containing 1.5 to 5 glycerol groups; ethoxylated fatty acid esters of sorbitan containing 2 to 30 moles of ethylene oxide; ethoxylated oils of vegetable origin; fatty acid esters of sucrose; fatty acid esters of polyethylene glycol; Mention may be made of (C ₆ -C ₂₄ )-alkylglucamine derivatives, amine oxides such as (C ₁₀ -C ₁₄ )alkylamine oxide or N-(C ₁₀ -C ₁₄ )acylaminopropylmorpholine oxide; and mixtures thereof. You can.

As glyceryl esters of fatty acids, mention may be made of glyceryl stearate (mono-, di- and/or tristearate) (INCI name: glyceryl stearate) or glyceryl ricinoleate and mixtures thereof. As glyceryl esters of C ₈ -C ₂₄ alkoxylated fatty acids, mention may be made, for example, of polyethoxylated glyceryl stearates (mono-di- and/or tri-glyceryl stearate), such as PEG-20 glyceryl stearate.

Additionally or alternatively, nonionic surfactants may include or be selected from alkanolamides, polyglucosides, sorbitan derivatives (not including hydration of sorbitan to induce sorbitol), and polyol esters. good.

alkanolamide(s)
Non-limiting examples of alkanolamides include fatty acid alkanolamides. The fatty acid alkanolamide may be a fatty acid monoalkanolamide or a fatty acid dialkanolamide or a fatty acid isoalkanolamide and may have a C _2-8 hydroxyalkyl group (one C _2-8 chain may be substituted with the above -OH group). Non-limiting examples include fatty acid diethanolamide (DEA) or fatty acid monoethanolamide (MEA), fatty acid monoisopropanolamide (MIPA), fatty acid diisopropanolamide (DIPA) and fatty acid glucamide (acylglucamide).

Suitable fatty acid alkanolamides may include those formed by reacting alkanolamines and C ₆ to C ₃₆ fatty acids. Examples include oleic acid diethanolamide, myristic acid monoethanolamide, soybean fatty acid diethanolamide, stearic acid ethanolamide, oleic acid monoisopropanolamide, linoleic acid diethanolamide, stearic acid monoethanolamide (stearamide MEA), and behenic acid monoethanolamide. amide, isostearic acid monoisopropanolamide (isostearamide MIPA), erucic acid diethanolamide, ricinoleic acid monoethanolamide, coconut fatty acid monoisopropanolamide (cocoamide MIPA), coconut acid monoethanolamide (cocamide MEA), palm kernel fatty acid diethanolamide Coco fatty acid diethanolamide, lauric acid diethanolamide, polyoxyethylene coconut fatty acid monoethanolamide, coconut fatty acid monoethanolamide, lauric acid monoethanolamide, lauric acid monoisopropanolamide (lauric acid amide MIPA), myristic acid monoisopropanolamide (myristic acid amide MIPA), coconut fatty acid diisopropanolamide (cocamide DIPA), and mixtures thereof.

In some instances, fatty acid alkanolamides preferably include cocamide MIPA, cocamide DEA, cocamide MEA, cocamide DIPA, and mixtures thereof. In particular, the fatty acid alkanolamide may be cocamide MIPA, which is commercially available under the trade name EMPILAN from Innospec Active Chemicals.

［式中、Ｒ_４は、４～２０炭素原子のアルキル鎖であり（Ｒ_４は、例えばラウリン酸、ココヤシ酸、パルミチン酸、ミリスチン酸、ベヘン酸、ババスーヤシ脂肪酸、イソステアリン酸、ステアリン酸、コーン脂肪酸、大豆脂肪酸、シアバター脂肪酸、カプリル酸、カプリン酸及びそれらの混合物から選択されてもよい）；Ｒ_５は、－ＣＨ_２ＯＨ、－ＣＨ_２ＣＨ_２ＯＨ、－ＣＨ_２ＣＨ_２ＣＨ_２ＯＨ、－ＣＨ_２（ＣＨＯＨ）_４ＣＨ_２ＯＨ、－ベンジル及びそれらの混合物から選択され；Ｒ_６は、－Ｈ、－ＣＨ_３、－ＣＨ_２ＯＨ、－ＣＨ_２ＣＨ_３、－ＣＨ_２ＣＨ_２ＯＨ、－ＣＨ_２ＣＨ_２ＣＨ_２ＯＨ、－－ＣＨ_２（ＣＨＯＨ）_４ＣＨ_２ＯＨ、－ベンジル及びそれらの混合物から選択される］
のものを含む。 Fatty acid alkanolamide has the following structure:

[wherein R ₄ is an alkyl chain of 4 to 20 carbon atoms (R ₄ is, for example, lauric acid, coconut acid, palmitic acid, myristic acid, behenic acid, babasou coconut fatty acid, isostearic acid, stearic acid, corn fatty acid , soybean fatty acids, shea butter fatty acids, caprylic acid, capric acid and mixtures thereof); R ₅ is -CH ₂ OH, -CH ₂ CH ₂ OH, -CH ₂ CH ₂ CH ₂ OH, selected from _-CH2 (CHOH) _4CH2OH , _-benzyl and mixtures _thereof ; _R6 is _-H , _-CH3 , _-CH2OH , _-CH2CH3 , _-CH2CH2OH , _{-CH2CH2CH2OH , -CH2} (CHOH) _4CH2OH , _-benzyl and mixtures thereof _]
including those of

In some instances, one or more of the fatty acid alkanolamides include one or more acylglucamides, such as acylglucamides having a carbon chain length of 8-20. Non-limiting examples include lauroyl/myristoyl methyl glucamide, capryloyl/capryl methyl glucamide, lauroyl methyl glucamide, myristoyl methyl glucamide, capryloyl methyl glucamide, capryloyl methyl glucamide, cocoyl methyl glucamide, capryloyl/capryloyl methyl glucamide, Includes loyl methyl glucamide, cocoyl methyl glucamide, lauryl methyl glucamide and oleoyl methyl glucamide oleate, stearoyl methyl glucamide stearate, sunflower oil fatty acid methyl glucamide, and copheryl methyl glucamide succinate.

Alkyl polyglucoside(s)
In some embodiments, the one or more alkyl polyglucosides include those selected from lauryl glucoside, octyl glucoside, decyl glucoside, coconut glucoside, caprylyl/caprylic glucoside, sodium lauryl glucose carboxylate, and mixtures thereof. . In some cases, the alkyl polyglucoside includes or is selected from lauryl glucoside. Additionally or alternatively, the alkyl polyglucoside may be selected from glycerin (C ₆ -C ₂₄ ) alkyl polyglycosides, including for example polyethoxylated fatty acid mono- or diesters of glycerin (C ₆ -C ₂₄ ) alkyl polyglycosides. In some instances, additional alkyl polyglucosides that may be suitably incorporated into cosmetic compositions have the following formula:
R ¹ -O-(R ² O) _n -Z(x)
[wherein R ¹ is an alkyl group having 8-18 carbon atoms,
R ² is an ethylene or propylene group,
Z is a saccharide group having 5 to 6 carbon atoms,
n is an integer from 0 to 10,
x is an integer from 1 to 5]
Contains alkyl polyglucosides with the structure.

In some instances, useful alkyl polyglucosides may include lauryl glucoside, octyl glucoside, decyl glucoside, coconut glucoside, caprylyl/caprylic glucoside, and sodium lauryl glucose carboxylate. Typically, the at least one alkyl polyglucoside compound is selected from the group consisting of lauryl glucoside, decyl glucoside and coconut glucoside. In some instances, decyl glucoside is particularly preferred.

Sorbitan derivative(s)
Suitable sorbitan derivatives that may be incorporated into multiple nonionic surfactants include polysorbate-20 (POE(20) sorbitan monolaurate), polysorbate-21 (POE(4) sorbitan monolaurate), polysorbate-20 (POE(20) sorbitan monolaurate), polysorbate-21 (POE(4) sorbitan monolaurate), 40 (POE(20) Sorbitan Monopalmitate), Polysorbate-60 (POE(20) Sorbitan Monostearate), Polysorbate-61 (POE(4) Sorbitan Monostearate), Polysorbate-65 (POE(20) Sorbitan Tristearate) stearate), polysorbate 80 (POE (20) sorbitan monooleate), polysorbate-81 (POE (4) sorbitan monooleate), polysorbate 85 (POE (20) sorbitan trioleate), sorbitan isostearate, sorbitan monolaurate , sorbitan monooleate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate and sorbitan tristearate, and mixtures thereof.

Additional and/or alternative sorbitan derivatives may be formed by esterification with sorbitol of at least one fatty acid containing at least one saturated or unsaturated linear alkyl chain, each having from 16 to 22 carbon atoms. Contains sorbitan esters, including esters of ₁₆ to _C22 fatty acids and sorbitan. These esters can be chosen in particular from the stearates, behenates, arachidates, palmitates or oleates of sorbitan and mixtures thereof. Examples of optional sorbitan esters are sorbitan monostearate (INCI name: sorbitan stearate) sold by Croda under the name Span 60, tristearate sold by Croda under the name Span 65V. Sorbitan, sold by Croda under the name Span 40 Sorbitan monooleate (INCI name: Sorbitan palmitate), sold by Croda under the name Span 80 V or Span 85 Contains sorbitan trioleate, sold by the company dUniqema under V. A preferred sorbitan ester is sorbitan tristearate.

Polyol ester(s)
Non-limiting examples of polyol esters include those selected from alkoxylated polyol esters. For example, the alkoxylated polyol ester may be selected from PEGylated derivatives of propylene glycol oleate, propylene glycol caprylate/caprate, propylene glycol cocoate, propylene glycol stearate, and mixtures thereof. In certain embodiments, the alkoxylated polyol esters include PEG-55 propylene glycol oleate, PEG-6 propylene glycol caprylate/caprate, PEG-8 propylene glycol cocoate, PEG-25 propylene glycol stearate, and PEG-120 propylene. selected from glycol stearate, and mixtures thereof. In some instances, the polyol ester is or includes PEG-55 propylene glycol oleate. Additionally and/or alternatively, the polyol ester may be selected from ethoxylated fatty acid esters of sorbitan containing 2 to 30 mol of ethylene oxide.

In some cases, polyol esters are esters of polyols with fatty acids having, for example, saturated or unsaturated chains containing from 8 to 24 carbon atoms, preferably from 12 to 22 carbon atoms, and preferably from 10 to 200 carbon atoms. , more preferably having a number of alkylene oxides from 10 to 100, such as C ₈ -C ₂₄ , preferably C ₁₂ , preferably having a number of alkylene oxides from 10 to 200, more preferably from 10 to 100. - Glyceryl esters of C ₂₂ fatty acids or acids and their alkoxylated derivatives; C ₈ -C ₂₄ , preferably C ₁₂ -C ₂₂ fatty acids or Polyethylene glycol esters of acids and their alkoxylated derivatives; sorbitol esters of C ₈ -C ₂₄ , preferably C ₁₂ -C ₂₂ fatty acids or acids, preferably with a number of alkylene oxides from 10 to 200, more preferably from 10 to 100. and alkoxylated derivatives thereof; preferably C ₈ -C ₂₄ , preferably C ₁₂ -C ₂₂ fatty acids or acid sugars (sucrose, glucose, alkyl esters of glycose) and their alkoxylated derivatives; ethers of sugars and C ₈ -C ₂₄ , preferably C ₁₂ -C ₂₂ aliphatic alcohols; and mixtures thereof.

Examples of ethoxylated fatty acid esters that may be mentioned are adducts of ethylene oxide with esters of lauric acid, palmitic acid, stearic acid or behenic acid, and mixtures thereof, especially those containing from 9 to 100 oxyethylene groups. , such as PEG-9 to laurate to PEG-50 (INCI name: PEG-9 to PEG-50 laurate); PEG-9 to palmitate to PEG-50 (INCI name: PEG-9 to palmitate) PEG-9 to PEG-50 stearate (INCI name: PEG-9 stearate to PEG-50 stearate); PEG-9 to PEG-50 palmitostearate; PEG-9 behenate to PEG-50 (INCI name: PEG-9 to PEG-50 behenate); polyethylene glycol monostearate 100EO (INCI name: PEG-100 stearate); and mixtures thereof.

Sources of unsaturated polyol esters of glycerin include synthetic oils, natural oils (eg, vegetable oils, algae oils, bacterially derived oils, and animal fats), combinations thereof, and the like. Non-limiting examples of vegetable oils include abyssinia oil, tonsil oil, apricot oil, apricot kernel oil, argan oil, avocado oil, babassu oil, baobab oil, black cumin oil, black currant oil, borage oil, camelina oil, carinata oil, canola oil, castor oil. oil, cherry kernel oil, coconut oil, corn oil, cottonseed oil, echium oil, evening primrose oil, flaxseed oil, grapefruit oil, grapefruit oil, hazelnut oil, hempseed oil, jatropha oil, jojoba oil, kukui nut oil, flaxseed oil, macadamia nut oil, meadowfoam oil, moringa oil, neem oil, olive oil, palm oil, palm kernel oil, peach kernel oil, peanut oil, pecan oil, gooseberry oil, perilla oil, pistachio oil, pomegranate oil , pongamia oil, pumpkin oil, raspberry oil, red palm olein, rice bran oil, rosehip oil, safflower oil, sea buckthorn fruit oil, sesame oil, shea olein, sunflower oil, soybean oil, tonko bean oil, tung oil , walnut oil, malt oil, high oleoyl soybean oil, high oleoyl sunflower oil, high oleoyl safflower oil, high erucic rapeseed oil, combinations thereof, and the like. Non-limiting examples of animal fats include lard, tallow, chicken fat, yellow grease, fish oil, emu oil, combinations thereof, and the like. Non-limiting examples of synthetic oils include tall oil, which is a byproduct of wood pulp production. In some embodiments, natural oils are refined, bleached, and/or deodorized.

The polyol ester may optionally be a natural polyol ester selected from vegetable oils, animal fats, algae oils and mixtures thereof; the synthetic polyol esters may be ethylene glycol, propylene glycol, glycerol, polyglycerol, polyethylene A material selected from the group consisting of glycol, polypropylene glycol, poly(tetramethylene) ether glycol, pentaerythritol, dipentaerythritol, tripentaerythritol, trimethylolpropane, neopentyl glycol, in one embodiment sugar, sucrose and mixtures thereof. It originates from

Additional non-limiting examples of non-ionic surfactants that may be optionally used in the cosmetic compositions may be selected from and/or alkanolamides; polyoxyalkylenated non-ionic polyglycerolated nonionic surfactants; ethoxylated fatty acid esters; ethoxylated, propoxylated or glycerolated esters of alcohols, alpha diols, alkylphenols and fatty acids; copolymers of ethylene oxide and/or propylene oxide; Condensates of ethylene oxide and/or propylene oxide with aliphatic alcohols; polyethoxylated fatty acid amides; ethoxylated oils of vegetable origin; fatty acid esters of sucrose; fatty acid esters of polyethylene glycol; N-(C ₆ -C ₂₄ )alkyl _{and mixtures thereof .}

pH adjuster(s)
The cosmetic composition may include one or more pH adjusting agents to raise or lower the overall pH of the cosmetic composition. For example, one or more acids may be included to lower the pH of the cosmetic composition. Examples of acids suitable for lowering the pH of cosmetic compositions include, but are not limited to, citric acid, acetic acid, and the like. The cosmetic composition may include one or more bases such as sodium hydroxide, potassium hydroxide, etc. to increase the pH of the cosmetic composition. Additional or alternative acids and bases suitable for adjusting the pH of cosmetic compositions will be readily apparent to those skilled in the art.

The amount of pH adjusting agent in the cosmetic composition may be based on the desired pH of the final cosmetic composition and/or product. For example, the cosmetic composition may have a pH of about 3 to about 7, preferably about 3.5 to about 6.5, preferably about 3.5 to about 6, or preferably about 3.5 to about 5. The amount of the pH adjuster may be such that the pH value is 5.

The amount of pH adjusting agent in the cosmetic composition may be based on the desired pH of the final cosmetic composition and/or product. For example, the total amount of pH adjusting agent may range from about 0.05 to about 20% by weight based on the total weight of the cosmetic composition. In some instances, the total amount of pH adjusting agent is from about 0.05 to about 15%, from about 0.1 to about 10%, or from about 0.12 to about 5% by weight, based on the total weight of the cosmetic composition. %, including ranges and subranges therebetween.

Monoalcohol(s)
The cosmetic composition may optionally include monoalcohol(s), such as those having 1 to 10 carbons, preferably 2 to 6 carbons. The amount of monoalcohol present in the cosmetic composition may range from about 0.1 to about 10% by weight, based on the total weight of the cosmetic composition. For example, the amount of monoalcohol present in the cosmetic composition may range from about 0.1% to about 10%, from about 0.1% to about 8%, from about 0.1% to about 6% by weight, about 0.1 to about 4% by weight, about 0.1 to about 3% by weight; about 0.2 to about 10% by weight, about 0.2 to about 8% by weight, about 0.2 to about 6% by weight, about 0.2 to about 4% by weight, about 0.2 to about 3% by weight; about 1 to about 10% by weight, about 1 to about 8% by weight, about 1 to about 6% by weight, about 1 to about 4% by weight, about 1 to about 3% by weight; about 1.5 to about 10% by weight, about 1.5 to about 8% by weight, about 1.5 to about 6% by weight, about 1.5 to about 4% by weight, about 1.5 to about 3% by weight; about 2 to about 10% by weight, about 2 to about 8% by weight, about 2 to about 6% by weight, about 2 to about 4% by weight, about 2 to about 3% by weight, including ranges and subranges therebetween.

The one or more monoalcohols of the cosmetic composition include ethanol, propanol, butanol, pentanol, hexanol, isopropyl alcohol, cyclohexanol, isobutyl alcohol, 2-methyl-2-butanol (2-methylbutan-2-ol) and It may also be selected from mixtures thereof. In some instances, the monoalcohol includes or is selected from ethanol, propanol, butanol, pentanol, isomers thereof, or combinations thereof. In a further example, the one or more monoalcohol(s) comprises or consists of ethanol.

ester(s)
The cosmetic composition may optionally include an ester, such as an ester oil selected from one or more diesters, one or more triglycerides, and mixtures thereof. The amount of diester present in the cosmetic composition can be, for example, from about 0.05 to about 4.5%, from about 0.1 to about 4%, from about 0.1 to about 3.5% by weight, about 0.1 to about 3%, about 0.5 to about 3%, about 0.5 to about 2.5%; about 0.5 to about 2%, or about 0 It may range from .5% to about 1.5% by weight, including all ranges and subranges therebetween. In certain embodiments, the amount of diester present in the cosmetic composition is about 0.05, 0.1, 0.15, 0.2, 0.25, 0.3 based on the total weight of the cosmetic composition. , 0.35, 0.4, 0.45, 0.5, 0.75, 1, 1.25, 1.5, 1.75, 2, 2.25, 2.5, 2.75, 3 Weight%.

Non-limiting examples of liquid esters include fatty acid esters from C ₆ -C ₃₂ fatty acids and/or C ₆ -C ₃₂ fatty alcohols, which are liquid at 25° C. and 1 atmosphere. These esters are liquids of saturated or unsaturated, linear or branched C ₁ -C ₂₆ aliphatic mono- or polyacids and saturated or unsaturated, linear or branched C ₁ -C ₂₅ aliphatic mono- or polyalcohols. It may also be an ester, the total number of carbon atoms in the ester being equal to or greater than 10. In some cases, as esters of monoalcohols, at least one of the alcohols or acids from which the esters of the invention result are branched. Among the monoesters of monobasic acids and monoalcohols, mention may be made of alkyl myristates such as ethyl palmitate, isopropyl myristate or ethyl myristate, isocetyl stearate and 2-ethylhexyl isononanoate, isononan These are isononyl acid, isodecyl neopentanoate and isostearyl neopentanoate.

In some cases, it is particularly useful to include cetyl esters in hair conditioning compositions. Cetyl esters are mixtures of the following esters of saturated fatty acids and fatty alcohols: cetyl palmitate, cetyl stearate, myristyl myristate, myristyl stearate, cetyl myristate and stearyl stearate.

Esters of C ₄ -C ₂₂ dicarboxylic or tricarboxylic acids and C ₁ -C ₂₂ alcohols, and monocarboxylic, dicarboxylic or tricarboxylic acids and C ₄ -C ₂₆ dihydroxy, trihydroxy, tetrahydroxy or pentahydroxy non-sugar alcohols Esters of may also be used. Mention may be made in particular of diethyl sebacate; diisopropyl sebacate; diisopropyl adipate; di-n-propyl adipate; triisopropyl citrate; glyceryl trilactate; glyceryl trioctanoate; neopentyl glycol diheptanoate; and diisononane acid diethylene glycol.

Non-limiting liquid esters (ester oils) or liquid fatty acid esters that may be mentioned are, for example, sunflower oil, corn oil, soybean oil, bone marrow oil, grapeseed oil, sesame oil, hazelnut oil, apricot oil, macadamia oil, Arara oil. oil, castor oil, avocado oil, olive oil, rapeseed oil, coconut oil, wheat malt oil, sweet almond oil, apricot oil, safflower oil, candlenut oil, coconut oil, camelina oil, tamanu oil, babassu oil and prakasi oil, Contains jojoba oil and shea butter oil.

The esters of the present disclosure may also further include solid fatty acid esters and/or fatty acid esters, including solid esters obtained from C ₉ -C ₂₆ fatty acids and C ₉ -C ₂₅ fatty alcohols. Among these esters, mention may be made of octyldodecyl behenate and isocetyl behenate, cetyl lactate, stearyl octoate, octyl octoate, cetyl octoate, decyl oleate, myristyl stearate, octyl palmitate. , octyl pelargonate, octyl stearate, cetyl myristate, myristyl myristate or stearyl myristate, and hexyl stearate.

In embodiments, the one or more esters of the cosmetic compositions of the present disclosure are one or more diesters, particularly diisostearyl malate, neopentyl glycol dioctoate, dibutyl sebacate, di- _C12 malate. _-13 alkyl, dicetearyl dimer dilinoleate, dicetyl adipate, diisocetyl adipate, diisononyl adipate, diisostearyl dimer dilinoleate, diisostearyl fumarate salt, and mixtures thereof.

Chelating agent(s)
The cosmetic composition may optionally include a chelating agent. The amount of chelating agent present in the cosmetic composition can be, for example, from about 0.01 to about 20%, from about 0.01 to about 15%, from about 0.01 to about 10% by weight, based on the total weight of the cosmetic composition. % by weight, about 0.01 to about 8%, about 0.01 to about 6%, about 0.01 to about 5%, about 0.01 to about 4%, about 0.01 to about 3 wt%, about 0.01 to about 2 wt%, about 0.01 to about 1 wt%; about 0.1 to about 20 wt%, about 0.1 to about 15 wt%, about 0.1 to about 10 % by weight, about 0.1 to about 8%, about 0.1 to about 6%, about 0.1 to about 5%, about 0.1 to about 4%, about 0.1 to about 3 wt%, about 0.1 to about 2 wt%, about 0.1 to about 1 wt%; about 0.25 to about 20 wt%, about 0.25 to about 15 wt%, about 0.25 to about 10 % by weight, about 0.25 to about 8%, about 0.25 to about 6%, about 0.25 to about 5%, about 0.25 to about 4%, about 0.25 to about 3 wt%, about 0.25 to about 2 wt%, about 0.25 to about 1 wt%; about 0.5 to about 20 wt%, about 0.5 to about 15 wt%, about 0.5 to about 10 % by weight, about 0.5 to about 8 %, about 0.5 to about 6 %, about 0.5 to about 5 %, about 0.5 to about 4 %, about 0.5 to about 3 wt%, about 0.5 to about 2 wt%, about 0.5 to about 1 wt%; about 0.75 to about 20 wt%, about 0.75 to about 15 wt%, about 0.75 to about 10 % by weight, about 0.75 to about 8%, about 0.75 to about 6%, about 0.75 to about 5%, about 0.75 to about 4%, about 0.75 to about 3 wt%, about 0.75 to about 2 wt%; about 1 to about 20 wt%, about 1 to about 15 wt%, about 1 to about 10 wt%, about 1 to about 8 wt%, about 1 to about 6 wt% %, about 1 to about 5%, about 1 to about 4%, about 1 to about 3%, or about 1 to about 2% by weight, including ranges and subranges therebetween.

Non-limiting examples of chemical chelating agents include aminotrimethylphosphonic acid, β-alanine diacetic acid, cyclodextrin, cyclohexanediaminetetraacetic acid, diethylenetriaminepentamethylenephosphonic acid, diethanolamine N-acetic acid, ethylenediaminetetraacetic acid (EDTA or _YH4 ) and their sodium (YH ₃ Na, Y ₂ H ₂ Na ₂ , YHNa ₃ and YNa ₄ ), potassium (YH ₃ K, Y ₂ H ₃ K ₃ and YK ₄ ), calcium disodium and diammonium salts, and their Salts with triethanolamine (TEA-EDTA), etidronic acid, galactanic acid, hydroxyethylethylenediaminetetraacetic acid (HEDTA) and its trisodium salt, gluconic acid, glucuronic acid, nitrilotriacetic acid (NTA) and Its trisodium salt, pentetate, phytic acid, ribbon acid, diammonium citrate, disodium azacycloheptanediphosphonate, disodium pyrophosphate, hydroxypropylcyclodextrin, methylcyclodextrin, pentapotassium triphosphate, aminotriphosphate Pentasodium methylenephosphonate, pentasodium ethylenediaminetetramethylenephosphonate, pentasodium pentetate, pentasodium triphosphate, potassium citrate, potassium EDTMP, sodium EDTMP, chitosan sodium methylenephosphonate, sodium hexametaphosphate, sodium metaphosphate, polyphosphorus potassium acid, sodium polyphosphate, sodium trimetaphosphate, sodium dihydroxyethylglycinate, potassium gluconate, sodium gluconate, sodium gluceptate, sodium glycereth-1 polyphosphate, tetrapotassium pyrophosphate and triethanolamine polyphosphate (TEA), Tetrasodium pyrophosphate, trisodium phosphate, potassium triphosphonomethylamine oxide, sodium metasilicate, sodium phytate, sodium polydimethylglycinophenol sulfonate, tetrahydroxyethylethylenediamine, tetrahydroxypropylethylenediamine, tetrapotassium etidronate, etidrone tetrasodium acid, tetrasodium iminodisuccinate, trisodium ethylenediamine disuccinate, ethanolamine N,N-diacetic acid, disodium acetate, dimercaprol, deferoxame, Zylox, and/or iron chelating agents, all of which are as disclosed and claimed in WO 94/61338, which is incorporated herein for the purpose of. Examples of biological chelators include metallothionein, transferrin, calmodulin and chitosan sodium methylene phosphonate.

In at least one instance, the chelating agent is trisodium ethylenediamine disuccinate.

Preservative(s)
Preservatives are usually present in cosmetic compositions, from about 0.01 to about 20% by weight, from about 0.01 to about 18%, from about 0.01 to about 16% by weight, based on the total weight of the cosmetic composition. about 0.01 to about 14% by weight, about 0.01 to about 12% by weight, about 0.01 to about 10% by weight, about 0.01 to about 8% by weight, about 0.01 to about 7% by weight, about 0.01 to about 6% by weight, about 0.01 to about 5% by weight; about 0.1 to about 20% by weight, about 0.1 to about 18% by weight, about 0.1 to about 16% by weight; about 0.1 to about 14% by weight, about 0.1 to about 12% by weight, about 0.1 to about 10% by weight, about 0.1 to about 8% by weight, about 0.1 to about 7% by weight, about 0.1 to about 6% by weight, about 0.1 to about 5% by weight; about 1 to about 20% by weight, about 1 to about 18% by weight, about 1 to about 16% by weight, about 1 to about 14% by weight %, about 1 to about 12%, about 1 to about 10%, about 1 to about 8%, about 1 to about 7%, about 1 to about 6%, about 1 to about 5%; about 4 to about 20% by weight, about 4 to about 18% by weight, about 4 to about 16% by weight, about 4 to about 14% by weight, about 4 to about 12% by weight, about 4 to about 10% by weight, about 4 It may be included in an amount from about 8% by weight or from about 4% to about 7% by weight, including all ranges and subranges therebetween. Non-limiting examples of preservatives include sodium benzoate, potassium sorbate, phenoxyethanol, salicylic acid, tocopherol, chlorphenesin, BHT, disodium EDTA, pentaerythrityl tetra(di-t-butylhydroxyhydrocinnamate), and including mixtures thereof.

Kits Aspects of the present disclosure are directed to kits containing the cosmetic compositions contemplated herein. In embodiments, the cosmetic composition of the present disclosure is a hair cosmetic or hair treatment composition. For example, a kit may include at least one cosmetic composition according to the present disclosure, such as a hair cosmetic and/or hair treatment composition, and one or more additional compositions, such as a shampoo, conditioner, etc. The various compositions are included separately in the kit. In some instances, the kit includes one or more cosmetic compositions, such as hair cosmetic and/or hair treatment compositions, shampoos, conditioners, masks, and/or other hair treatment products according to the present disclosure; They are all included separately.

The cosmetic compositions of the kit may be packaged in a variety of different containers, such as, for example, ready-to-use containers. Non-limiting examples of useful packaging include tubes, jars, lids, unit-dose packages, and bottles, including squeezable tubes, bottles, and sprayable containers. The packaging may be configured so that it can be attached to a wall, such as a bathroom wall, including a shower or bathtub wall. For example, the package may be a container configured to be attached to a wall such that when pressure is applied to the container, the composition contained therein is forced out of one or more openings in the container. good. In some cases, the package is a tube, such as a tube with two compartments or a dual tube, each forming a separate compartment. Each compartment may contain a different composition. For example, one tube or compartment may contain a cosmetic composition according to the present disclosure, and the other tube may contain a cosmetic composition, such as a shampoo, conditioner, all-in-one shampoo/conditioner (i.e., conditioning shampoo; also referred to as a "co-cleaning solution"). compositions used with masks or other cosmetic products.

Method(s) of manufacturing cosmetic compositions
Aspects of the disclosure relate to methods of making cosmetic compositions. The method of manufacturing a cosmetic composition typically comprises (I)
(a) about 0.1 to about 25% by weight citric acid; and (b) about 0.2 to about 40% by weight of one or more urea compounds selected from dimethylurea, hydroxylethylurea, or combinations thereof. Producing a deep eutectic solvent system comprising: a deep eutectic solvent system in which the weight ratio of (a) citric acid to (b) urea compound is 1 or less;
(II) adding the deep eutectic solvent system of (I) to the base composition to produce a cosmetic composition.

The method further includes forming a deep eutectic solvent (DES) system of (I) by mixing citric acid and urea compound(s), e.g., in a ratio discussed herein. Good too. In some cases, DES systems may be formed at room temperature, for example, if the citric acid and urea compounds mix as liquids at room temperature. In other cases, the method also includes heating the mixture/combination of citric acid and urea compounds to a temperature of about 70°C to about 90°C. Heating the mixture/combination of citric acid and urea compounds is usually beneficial when the citric acid and urea compounds do not mix as liquids at room temperature. The mixture/combination of citric acid and urea compounds may be heated to a temperature such that the citric acid and urea compounds mix as a liquid. For example, the mixture/combination of citric acid and urea compounds may be from about 75°C to about 90°C, from about 80°C to about 90°C, from about 85°C to about 90°C, from about 70°C to about 85°C, from about 75°C to about 85°C. °C, about 80 °C to about 85 °C, about 70 °C to about 80 °C, about 75 °C to about 80 °C, or about 70 °C to about 75 °C, or any range or subrange thereof. Good too.

Those skilled in the art will appreciate that the method may include producing the base of the cosmetic composition by combining one or more ingredients such as aliphatic compounds, polyols, thickeners, water-soluble solvents, silicone oils, etc. One will understand how to combine the aforementioned components and/or compounds such that the base of the composition is stable and/or homogeneous. In some cases, the base of the cosmetic composition can be heated, mixed and/or subjected to shearing forces, such as from an emulsifier.

Method(s) of treating hair
Aspects of the present disclosure also relate to methods of using such cosmetic compositions. Methods of treating hair according to disclosed embodiments typically include:
(I) optionally applying shampoo to the hair;
(II) optionally rinsing the hair to remove at least a portion of the shampoo;
(III)
(a) about 0.1 to about 25% by weight citric acid; and (b) about 0.2 to about 40% by weight of one or more urea compounds selected from dimethylurea, hydroxylethylurea, or combinations thereof. a cosmetic composition comprising: a cosmetic composition in which the molar ratio of (a) citric acid to (b) urea compound is 1 or less;
(IV) optionally rinsing the hair to remove at least a portion of the cosmetic composition.

Methods of treating and/or cleansing hair according to the present disclosure will generally vary, but include applying the cosmetic compositions disclosed herein and allowing the cosmetic compositions to remain on the hair for a sufficient length of time. and rinsing the cosmetic composition from the hair.

In some instances, however, the cosmetic composition may be a no-rinse composition. For example, the cosmetic composition may be allowed to remain on the hair indefinitely, ie, the cosmetic composition may not be removed or rinsed from the hair prior to styling.

The cosmetic composition may be applied to the hair in sequence with other compositions. For example, the cosmetic composition may be applied to the hair before shampooing the hair, after shampooing the hair, before conditioning the hair, and/or after conditioning the hair, etc. However, it is not necessary that the cosmetic compositions be used in any particular order.

Cosmetic compositions are useful for improving hair conditioning, handling, durability, and/or improving hair resistance to heat aging. The cosmetic composition can be applied to wet or damp hair and may be massaged into the hair and spread through the hair, for example using the hands and/or using a comb or brush. This results in smoothing and softening of the hair, reducing frizz, dryness and unwanted volume. Alternatively, the cosmetic composition and exogenous water may be combined, optionally mixed, and then applied to the body. For example, the cosmetic composition may be combined in a container, bowl, package, bottle, etc. and subsequently applied to the body after formation of an opaque emulsion.

In some cases, the cosmetic composition is used during an individual's normal shower/bath routine, for example in combination with a routine additional hair care composition. The cosmetic compositions may be applied individually to the hair or may be combined with one or more additional compositions. For example, the cosmetic composition may be mixed with a shampoo (or conditioner) before application to the hair. In this case, a mixture of shampoo (or conditioner) and cosmetic composition is simultaneously applied to the hair and rinsed from the hair at the same time during the cleansing or conditioning process. Alternatively, the cosmetic composition may be layered onto (or lathered into) hair to which shampoo (or conditioner) has already been applied, or vice versa. In this case, the cosmetic composition may be applied to the hair without rinsing it from the hair, and then the shampoo (or conditioner) is subsequently applied to the hair. Alternatively, the shampoo (or conditioner) may be applied to the hair first without rinsing the shampoo (or conditioner) from the hair, and the cosmetic composition is also applied to the hair.

When used in combination with a shampoo and/or conditioner, the cosmetic composition has a composition of about 1:10 to about 10:1, about 1:5 to about 5:1, about 1:3 to about 3:1, about 1 :2 to about 2:1, about 1:1 to about 4:1, about 1:1 to about 3:1, or about 1:1 to about 2:1 (cosmetic compositions of the present disclosure: shampoo/conditioner) etc.) may be mixed or used with shampoos and/or conditioners.

If the cosmetic composition is not mixed with another composition prior to application to the hair, the cosmetic composition may be used immediately after the hair is treated with another composition (e.g., shampoo and/or conditioner). It may be applied to the hair before or immediately before. For example, the cosmetic composition may be applied to the hair within seconds or 1, 2, 5, 10 or 20 minutes before or after the shampoo and/or conditioner is applied to the hair.

The term "INCI" is an abbreviation for the International Nomenclature of Cosmetic Ingredients, which is used by the International Nomenclature Committee to describe personal care ingredients. in the system of names provided by the Personal Care Products Council of the Personal Care Products Council. be.

As used herein, all ranges provided are meant to include all specified ranges and combinations of subranges between the given ranges. Thus, the range 1 to 5 includes inter alia 1, 2, 3, 4 and 5, as well as subranges such as 2 to 5, 3 to 5, 2 to 3, 2 to 4, 1 to 4, and so on.

All components and elements affirmatively mentioned in this disclosure may be negatively excluded from the claims. In other words, the hair cleansing compositions of the present disclosure can be free or essentially free of all ingredients and elements positively described throughout this disclosure. In some instances, the hair cleansing compositions of the present disclosure are substantially free of non-incidental amounts of ingredient(s) or compound(s) described herein. A non-incidental amount of an ingredient or compound is the amount of that ingredient or compound that is added alone to a hair cleansing composition. For example, a hair cleansing composition may be substantially free of non-incidental amounts of ingredients or compounds, but such ingredient(s) or compound(s) may be a blend of two or more compounds. may be present as part of the raw materials included as

Some of the various categories of components identified may overlap. In such cases, if overlap exists and the hair cleansing composition contains both ingredients (or the composition contains two or more ingredients that overlap), then the overlapping compound contains more than one ingredient. Not expressed. For example, a compound may be characterized as both an emulsifier and a surfactant. If a particular hair composition includes both an emulsifier and a surfactant, a compound that can be characterized as being both an emulsifier and a surfactant serves only as either an emulsifier or a surfactant, but not both.

All publications and patent applications mentioned in this specification are herein incorporated by reference for all purposes as if each individual publication or patent application was specifically and individually indicated to be incorporated by reference. Incorporated herein. In the event of a conflict between this disclosure incorporated herein and a referenced publication or patent application, this disclosure will control.

As used herein, the terms "comprising," "having," and "including" are used in their open, non-limiting sense. The terms "a" and "the" are understood to include the plural as well as the singular. Thus, the term "a mixture thereof" also relates to "mixtures thereof". Throughout this disclosure, the term "mixtures thereof" is used where the letters A-F represent elements, according to the list of elements as shown in the following example: "A, B, C, D, E , F, and mixtures thereof"). The term "mixture thereof" does not require that the mixture include all of A, B, C, D, E and F (but does not include all of A, B, C, D, E and F). ). Rather, it indicates that mixtures of any two or more of A, B, C, D, E and F can be included. In other words, it means "one or more selected from the group consisting of A, B, C, D, E, F, and mixtures of any two or more of A, B, C, D, E, and F. is equivalent to the phrase "elements of".

The expression "one or more" means "at least one" and thus includes individual components as well as mixtures/combinations. Except in the examples or when otherwise indicated, all numbers expressing amounts of components and/or reaction conditions are in all instances expressed as "about" meaning within ±5% of the number indicated. May be modified by the term.

The term "treatment" (and grammatical variations thereof), as used herein, refers to the application of a composition of the present disclosure to the surface of a keratinous substrate, such as hair on a user's head and/or body. Point.

As used herein, the term "substantially free" or "essentially free" means that the particular material added to the composition is less than about 2% by weight, based on the total weight of the composition. It means that. However, the composition may contain less than about 1%, less than about 0.5%, less than about 0.1%, or none at all by weight of the specified materials. All components mentioned herein may be optionally included or excluded in the composition/method/kit. If excluded, the composition/method/kit may be free or essentially free of that component. For example, certain compositions may be free or essentially free of silicone.

Embodiments of the Disclosure In certain embodiments, the cosmetic composition comprises:
- from about 0.1 to about 25%, preferably from about 0.5 to about 20%, preferably from about 1 to about 20%, by weight of citric acid;
- Imidazolidinyl urea, diazolidinyl urea, m-dimethylaminophenyl urea, dimethyl urea, hydroxyethyl urea, urea, urea derivatives, imidazolidinyl urea, diazolidinyl urea, m-dimethylaminophenyl urea, dimethyl urea, hydroxyethyl urea, N-(2 -hydroxyethyl)urea; N-(2-hydroxypropyl)urea; N-(3-hydroxypropyl)urea; N-(2,3-dihydroxypropyl)urea; N-(2,3,4,5, 6-pentahydroxyhexyl)urea; N-methyl-N-(1,3,4,5,6-pentahydroxy-2-hexyl)urea; N-methyl-N'-(1-hydroxy-2-methyl- 2-propyl)urea; N-(1-hydroxy-2-methyl-2-propyl)urea; N-(1,3-dihydroxy-2-propyl)urea; N-(tris-hydroxymethylmethyl)urea; N -Ethyl-N'-(2-hydroxyethyl)urea;N,N-bis(2-hydroxyethyl)urea;N,N'-bis(2-hydroxyethyl)urea;N,N-bis(2-hydroxyethyl)urea;N,N'-bis(2-hydroxypropyl)urea;N,N-bis(2-hydroxyethyl)-N'-propylurea;N,N-bis(2-hydroxypropyl)-N'-(2-hydroxyethyl)urea;N-tert-butyl-N'-(2-hydroxyethyl)-N'-(2-hydroxypropyl)urea; N-(1,3-dihydroxy-2-propyl)- N'-(2-hydroxyethyl)urea; N,N-bis(2-hydroxyethyl). -N',N'-dimethylurea;N,N,N',N'-tetrakis(2-hydroxyethyl)urea;N',N'-bis(2-hydroxyethyl)-N',N'-bis (2-hydroxypropyl)-urea, and mixtures thereof, from about 0.2 to about 40% by weight, preferably from about 0.2 to about 35%, more preferably from about 0.5 to about 30% by weight. % of one or more urea compounds;
- about 20% by weight or more, preferably about 20 to about 90% by weight, more preferably about 50 to about 90% by weight of water, wherein the citric acid of (a) and the urea compound of (b) The molar ratio is less than or equal to 1, preferably from about 10:1 to about 0.5:10, more preferably from about 1:1 to about 1:3, and all weight percentages are based on the total weight of the cosmetic composition.

In additional embodiments, the cosmetic composition comprises:
The molar ratio of (a) citric acid to (b) urea compound is 1 or less, preferably about 10:1 to about 0.5:10, more preferably about 1:1 to about 1:3;
- about 0.1 to about 25%, preferably about 0.5 to about 20%, preferably about 1 to about 20% by weight of citric acid;
- from about 0.2 to about 40%, preferably from about 0.2 to about 35%, more preferably from about 0.5 to about 30% by weight selected from dimethylurea, hydroxylethylurea or combinations thereof. one or more urea compounds; and - about 20% or more, preferably about 20 to about 90%, more preferably about 50 to about 90%, by weight water;
- optionally cetrimonium chloride, steartrimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidotrimonium chloride, distearyldi Monium chloride, dicetyldimonium chloride, tricetyldimonium chloride, oleamidepropyldimethylamine, linolamidepropyldimethylamine, stearamidepropyldimethylamine, oleylhydroxyethylimidazoline, stearamidepropyldimethylamine, behenamidopropyldimethylamine, selected from behenamidopropyldiethylamine, behenamideethyldiethylamine, behenamideethyldimethylamine, arachidamidepropyldimethylamine, arachidamidepropyldiethylamine, arachidamideethyldiethylamine, arachidamideethyldimethylamine and mixtures thereof, about 0 .1 to about 10% by weight, preferably about 0.1 to about 8% by weight, more preferably about 0.2 to about 6% by weight of one or more cationic surfactants;
- optionally from about 0.1 to about 25% by weight, preferably about 0.5%, optionally including, for example, fatty alcohols, fatty acid esters, fatty ethers, fatty acids, waxes, oils, derivatives or mixtures thereof; ~18% by weight, more preferably from about 1 to about 16% by weight of one or more aliphatic compounds;
- optionally at least about 20% by weight, preferably about 20 to about 87% by weight polyol, more preferably about 20 to about 80% by weight. In some cases, the polyol is propylene glycol;
- optionally, for example polyacrylate crosspolymers or crosslinked polyacrylate polymers, cationic acrylate copolymers, anionic acrylic or carboxylic acid polymers, polyacrylamide polymers, polysaccharides, rubbers, polyquaternium, vinylpyrrolidone homopolymers/ from about 0.1 to about 20% by weight, preferably from about 0.1 to about 18% by weight, comprising copolymers, C8-24 hydroxyl-substituted fatty acids, C8-24 conjugated fatty acids, sugar fatty acid esters, polyglyceryl esters or mixtures thereof; more preferably from about 0.1 to about 14% by weight thickener;
- optionally from about 0.1 to about 35%, preferably from about 1 to about 25%, more preferably from about 1 to about 20% by weight of an aqueous solvent, such as an alkyl having 1 to 4 carbon atoms; Alcohols, glycol ethers, 2-pyrrolidone, N-methyl-2-pyrrolidone, 1,3-dimethyl-2-imidazolidinone, formamide, acetamide, dimethyl sulfoxide, sorbitol, sorbitan, acetin, diacetin, triacetin, sulfolane and the like mixture of;
- optionally from about 0.01 to about 20%, preferably from about 0.01 to about 14%, more preferably from about 0.01 to about 7% by weight of a preservative, such as sodium benzoate, sorbin; potassium acid, phenoxyethanol, salicylic acid, tocopherol, chlorphenesin, BHT, disodium EDTA, pentaerythrityltetradi-t-butylhydroxyhydrocinnamate, or mixtures thereof;
- optionally from about 0.1 to about 10%, preferably from about 0.1 to about 9%, more preferably from about 0.2 to about 8% by weight of a silicone, such as polydimethylsiloxane (dimethicone) , polydiethylsiloxane, polydimethylsiloxane with terminal hydroxyl groups (dimethiconol), polymethylphenylsiloxane, phenylmethylsiloxane, amino-functional polydimethylsiloxane (amodimethicone), bis-aminopropyl dimethicone, trimethylsilyl amodimethicone dimethicone copolyol, dimethicone such as those selected from copolyol esters, dimethicone copolyol quaternium nitrogen-containing compounds, dimethicone copolyol phosphate esters and mixtures thereof;
- optionally from about 0.01 to about 20%, preferably from about 0.01 to about 15%, more preferably from about 0.1 to about 8% by weight of a chelating agent;
- optionally, from about 0.01 to about 20% by weight of a pH adjuster, preferably in an amount such that the pH of the composition is from about 3 to about 7 m; and - optionally, about 0.001 ~10% by weight fragrance, where all weight percentages are based on the total weight of the cosmetic composition.

In still further embodiments, the method of manufacturing a cosmetic composition comprises:
(I)
(a) about 0.1 to about 25%, preferably about 0.5 to about 20%, preferably about 1 to about 20% by weight of citric acid; and (b) dimethylurea, hydroxylethylurea, or the like. from about 0.2 to about 40%, preferably from about 0.2 to about 35%, more preferably from about 0.5 to about 30%, by weight of one or more urea compounds selected from a combination of It is a deep eutectic solvent system, and the molar ratio of (a) citric acid to (b) urea compound is 1 or less, preferably about 10:1 to about 0.5:10, more preferably about 1:1. producing a deep eutectic solvent system that is about 1:3;
(II) adding the deep eutectic solvent system of (I) to a base composition to produce a cosmetic composition.

Implementation of the present disclosure is provided by the following examples. The following examples serve to clarify aspects of the technology, but are not limiting in nature.

Example 1
Three exemplary cosmetic compositions (Exemplary Compositions AC) were prepared from deep eutectic solvent ("DES") systems. A DES system was prepared by mixing citric acid and dimethylurea at a temperature of about 80°C to about 85°C. Afterwards, the DES system became soluble in distilled water. The formulations of exemplary compositions AC are shown in Table 1.

Example 2
Exemplary compositions B and D were applied to hair swatches and evaluated in comparison to application of conventional sulfate shampoo alone (control). Exemplary Composition D had the same formulation as Exemplary Composition B, except that the DES system was not formed from citric acid and dimethylurea before preparing the cosmetic composition.

Exemplary compositions B and D were applied after washing and rinsing natural brown Caucasian wavy hair swatches (medium curls) using a conventional sulfate-based shampoo. Exemplary compositions B and D in an amount of 0.4 grams each per gram of hair swatch were massaged onto each hair swatch for 1 minute, left on the hair swatch without rinsing for an additional minute, rinsed for 30 seconds, and then Then, blow dry for 2 minutes. These hair swatches were then evaluated to estimate the effectiveness of Exemplary Compositions B and D using a rinse-off procedure. A control was prepared according to the procedure described above, except that no cosmetic composition was applied to the hair swatch after conventional sulfate shampoo.

Additional hair swatches were prepared by applying exemplary compositions B and D to the hair swatches in an amount of 0.15 grams each of the compositions per gram of hair swatch. Specifically, each hair swatch was massaged with Exemplary Compositions B and D for one minute, left on the hair swatch without rinsing for one minute, and then blow dried for two minutes. These hair swatches were evaluated to estimate the effectiveness of Exemplary Compositions B and D using a no-rinse procedure.

The anti-frizziness or degree of frizziness of each hair swatch was evaluated using imaging analysis. After blow-drying the hair swatch, the hair swatch is anti-frizz after 1 hour, 2 hours, 4 hours, 8 hours, 12 hours and 24 hours after placing the hair swatch in a humidity bath at 80% relative humidity and room temperature. The gender was evaluated.

FIG. 1 provides images of hair swatches treated with exemplary compositions B and D and a control using a rinse procedure. FIG. 2 provides images of hair swatches treated with exemplary compositions B and D and a control using a no-rinse procedure. As seen in Figures 1 and 2, exemplary compositions B and D provided significantly better anti-frizz properties relative to the control hair swatches. Additionally, exemplary compositions B and D provided better hair volume control. As shown in Table 2, surprisingly, Exemplary Composition B provides better volume control than Exemplary Composition D and the control.

Example 3
Hair swatches treated with Exemplary Compositions A and C were evaluated and compared to hair swatches treated with only a conventional sulfate-based shampoo (control). Hair swatches were washed and rinsed using a conventional sulfate-based shampoo, and then Exemplary Compositions A and C were applied in an amount of 0.15 grams of composition each per gram of hair swatch. The composition was massaged onto each hair swatch for 1 minute, left on the swatch without rinsing for 1 minute, and then blow dried for 2 minutes. A control was prepared according to the procedure described above, except that no cosmetic composition was applied to the hair swatches after a conventional sulfate-based shampoo.

These hair swatches were evaluated to estimate the effectiveness of Exemplary Compositions A and C using a no-rinse procedure. The durability of the hair sample was determined by subjecting the hair sample to cycle fatigue using a cycle testing machine. A cycle tester simulates daily hair care by subjecting a set number of fibers to repeated cyclic tensile deformations until failure. Additionally, hair swatches were evaluated for crosslinking density of the amorphous matrix and associated thermal denaturation temperature using differential scanning calorimetry. Differential scanning calorimetry measures the thermal stability of the main morphological components of hair.

As seen in Figures 3 and 4, the hair swatches treated with Exemplary Composition C exhibited significantly better durability and denaturing temperatures than the control hair swatches. Hair swatches treated with Exemplary Composition A also exhibited improved durability and denaturing temperatures over control hair swatches.

Example 4
Hair swatches treated with Exemplary Compositions A and E and Comparative Compositions 1 and 2 were evaluated in comparison to hair swatches treated with conventional sulfate-based shampoos only (control). Exemplary Composition E had the same formulation as Exemplary Composition A, except that the cosmetic composition was prepared without preparing the DES system from citric acid and dimethylurea. Table 3 provides the formulations for Comparative Compositions 1 and 2.

Massage each hair swatch for 1 minute with each of Exemplary Compositions A and E and Comparative Compositions 1 and 2 in an amount of 0.4 grams per gram of hair swatch, and then massage the hair swatch for an additional minute without rinsing. , rinsed for 30 seconds, then blow dried for 2 minutes. These hair swatches were then evaluated to estimate the effectiveness of Exemplary Compositions A and E and Comparative Compositions 1 and 2 using a rinse-off procedure. A control was prepared according to the procedure described above, except that no cosmetic composition was applied to the hair swatches after a conventional sulfate-based shampoo.

Additional hair swatches were treated with Exemplary Composition A in an amount of 0.15 grams per gram of hair swatch. Each hair swatch was massaged with Exemplary Composition A for 1 minute, left on the hair swatch for 1 minute without rinsing, and then blow dried for 2 minutes. Hair swatches were evaluated to estimate the effectiveness of Exemplary Composition A using a no-rinse procedure.

Then, to estimate the effect of Exemplary Compositions A and E on heat denaturation temperature (corresponding to crosslink density), hair durability, Young's modulus and elongation to break compared to the effect of Comparative Compositions 1 and 2 and the control. The hair was evaluated. As discussed in Example 2, the heat denaturation temperature and durability of hair were determined.

Hair treated with Exemplary Composition A in the rinse-off and no-rinse procedures showed significantly better durability as measured by break cycles, and better modification temperatures. For example, hair treated with Exemplary Composition A showed an approximately 40% increase in durability compared to Comparative Compositions 1 and 2. Similarly, the elongation to break and Young's modulus of hair treated with Exemplary Composition A were better than the elongation to break of hair treated with Comparative Compositions 1 or 2. 5-8 are graphs of breakage cycles, denaturation temperatures, Young's modulus and breakage elongation of hair treated with exemplary compositions A and E compared to Comparative Compositions 1 and 2 and the control.

Claims (20)

(a) about 0.1 to about 25% by weight citric acid;
(b) about 0.2 to about 40% by weight of one or more urea compounds;
(c) about 20% by weight or more of water;
The molar ratio of (a) citric acid and (b) urea compound is 1 or less,
all weight percentages are based on the total weight of the cosmetic composition;
Cosmetic composition. 2. The cosmetic composition of claim 1, comprising an amount of deep eutectic solvent. Cosmetic composition according to claim 1, wherein the amount of deep eutectic solvent is greater than or equal to 1% by weight. 2. A cosmetic composition according to claim 1, wherein the urea compound of (a) is selected from dimethylurea, hydroxyethylurea, urea, and mixtures thereof. 3. The cosmetic composition of claim 2, wherein the deep eutectic solvent comprises (a) citric acid and (b) a urea compound. 2. The cosmetic composition of claim 1, wherein the weight ratio of (a) citric acid to (b) urea compound is from about 1:10 to about 0.5:10. 7. The cosmetic composition of claim 6, wherein the weight ratio of (a) citric acid to (b) urea compound is from about 3:2 to about 1:3. 2. The cosmetic composition of claim 1, wherein the molar ratio of (a) citric acid to (b) urea compound is from about 10:1 to about 0.5:10. 2. The cosmetic composition of claim 1, wherein the molar ratio of (a) citric acid to (b) urea compound is from about 1:1 to about 1:4. (a) from about 2.5 to about 40% by weight of one or more urea compounds;
(b) about 1.5 to about 25% by weight citric acid. (a) about 20 to about 40% by weight of one or more urea compounds;
(b) about 15 to about 25% by weight citric acid. (d) Cetrimonium chloride, steartrimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidotrimonium chloride, distearyldimonium chloride, Dicetyldimonium chloride, tricetyldimonium chloride, oleamidepropyldimethylamine, linolamidepropyldimethylamine, stearamidepropyldimethylamine, oleylhydroxyethylimidazoline, stearamidepropyldimethylamine, behenamidopropyldimethylamine, behenamide from about 0.1 to about 0.1 to 1,000,000 selected from propyldiethylamine, behenamideethyldiethylamine, behenamideethyldimethylamine, arachidamidepropyldimethylamine, arachidamidepropyldiethylamine, arachidamideethyldiethylamine, arachidamideethyldimethylamine, and mixtures thereof. Cosmetic composition according to any one of claims 1 to 9, further comprising about 10% by weight of one or more cationic surfactants. (e) from about 0.1 to about 25% by weight of one or more aliphatic compounds selected from aliphatic alcohols, fatty acid esters, aliphatic ethers, fatty acids, waxes, oils, derivatives thereof, and mixtures thereof; Cosmetic composition according to any one of claims 1 to 9, comprising. (f) about 20% or more by weight selected from ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, pentylene glycol, diethylene glycol, dipropylene glycol, 1,3 propanediol, glycerin, polyethylene glycol, and mixtures thereof; Cosmetic composition according to any one of claims 1 to 9, further comprising a polyol. (a) about 0.1 to about 25% by weight citric acid;
(b) from about 0.2 to about 40% by weight of one or more urea compounds selected from dimethylurea, hydroxylethylurea, or a combination thereof;
(c) about 20% or more water by weight;
(d) optionally from about 0.1 to about 10% by weight of one or more cationic surfactants;
(e) optionally from about 0.1 to about 25% by weight of one or more aliphatic compounds;
(f) optionally about 20% or more polyol;
(g) optionally from about 0.1 to about 20% by weight of a thickening agent;
(h) optionally from about 0.1 to about 35% by weight of a water-soluble solvent;
(i) optionally from about 0.01 to about 20% by weight of a preservative;
(j) optionally from about 0.1 to about 10% by weight silicone;
(k) optionally from about 0.01 to about 20% by weight of a chelating agent;
(l) optionally from about 0.01 to about 20% by weight of a pH adjusting agent;
(m) optionally comprising from about 0.001 to about 10% by weight of fragrance;
The molar ratio of (a) citric acid and (b) urea compound is 1 or less,
all weight percentages are based on the total weight of the cosmetic composition;
Cosmetic composition. A method of manufacturing a cosmetic composition, the method comprising:
(I)
(a) from about 0.1 to about 25% by weight of citric acid; and (b) from about 0.2 to about 40% by weight of one or more selected from dimethylurea, hydroxylethylurea, or combinations thereof. Producing a deep eutectic solvent system containing a urea compound, wherein the molar ratio of (a) citric acid to (b) urea compound is 1 or less;
(II) adding the deep eutectic solvent system of (I) to a base composition to produce a cosmetic composition. mixing (a) the citric acid and (b) the urea compound; and optionally heating (a) the citric acid and (b) the urea compound to a temperature of about 70°C to about 90°C. 17. The method of claim 16, further comprising the step of: A cosmetic composition prepared by the method of claim 16. A method of treating hair, the method comprising:
(I) optionally applying shampoo to the hair;
(II) optionally rinsing the hair to remove at least a portion of the shampoo;
(III) applying the cosmetic composition according to claim 1;
(IV) optionally rinsing the hair to remove at least a portion of the cosmetic composition. - provide frizz control to the hair, and/or - improve manageability of the hair, and/or - condition the hair, and/or - provide alignment to the hair, and/or - protect the hair from damage. protect and/or - give shine;
20. The method according to claim 19.

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