EP4108738A1 - Procédé de conversion de déchets de matières plastiques en hydrocarbures - Google Patents
Procédé de conversion de déchets de matières plastiques en hydrocarbures Download PDFInfo
- Publication number
- EP4108738A1 EP4108738A1 EP21180964.5A EP21180964A EP4108738A1 EP 4108738 A1 EP4108738 A1 EP 4108738A1 EP 21180964 A EP21180964 A EP 21180964A EP 4108738 A1 EP4108738 A1 EP 4108738A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- stream
- process according
- waste plastics
- furnace
- supplied
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004033 plastic Substances 0.000 title claims abstract description 62
- 229920003023 plastic Polymers 0.000 title claims abstract description 62
- 239000002699 waste material Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 47
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 17
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 14
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 14
- 239000000571 coke Substances 0.000 claims abstract description 32
- 238000005194 fractionation Methods 0.000 claims abstract description 26
- 239000003054 catalyst Substances 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 8
- 239000003921 oil Substances 0.000 claims description 22
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical group [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 12
- 239000000155 melt Substances 0.000 claims description 11
- AZSFNUJOCKMOGB-UHFFFAOYSA-N cyclotriphosphoric acid Chemical compound OP1(=O)OP(O)(=O)OP(O)(=O)O1 AZSFNUJOCKMOGB-UHFFFAOYSA-N 0.000 claims description 8
- 239000001175 calcium sulphate Substances 0.000 claims description 6
- 235000011132 calcium sulphate Nutrition 0.000 claims description 6
- 239000010779 crude oil Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 3
- 238000004821 distillation Methods 0.000 claims description 3
- 238000005292 vacuum distillation Methods 0.000 claims description 3
- 239000002910 solid waste Substances 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000001506 calcium phosphate Substances 0.000 description 3
- 229910000389 calcium phosphate Inorganic materials 0.000 description 3
- 235000011010 calcium phosphates Nutrition 0.000 description 3
- 230000004992 fission Effects 0.000 description 3
- 235000011007 phosphoric acid Nutrition 0.000 description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 3
- 206010011906 Death Diseases 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000010812 mixed waste Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000013502 plastic waste Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
- C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP21180964.5A EP4108738A1 (fr) | 2021-06-22 | 2021-06-22 | Procédé de conversion de déchets de matières plastiques en hydrocarbures |
| PCT/EP2022/066611 WO2022268664A1 (fr) | 2021-06-22 | 2022-06-17 | Procédé de conversion de déchets plastiques en hydrocarbures |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP21180964.5A EP4108738A1 (fr) | 2021-06-22 | 2021-06-22 | Procédé de conversion de déchets de matières plastiques en hydrocarbures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4108738A1 true EP4108738A1 (fr) | 2022-12-28 |
Family
ID=76553647
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP21180964.5A Withdrawn EP4108738A1 (fr) | 2021-06-22 | 2021-06-22 | Procédé de conversion de déchets de matières plastiques en hydrocarbures |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP4108738A1 (fr) |
| WO (1) | WO2022268664A1 (fr) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101230284A (zh) * | 2007-01-25 | 2008-07-30 | 华东理工大学 | 废弃塑料的延迟焦化处理方法及其处理装置 |
| CN106554796A (zh) * | 2015-09-25 | 2017-04-05 | 中国石油天然气股份有限公司 | 一种提高液体产品收率的催化焦化方法 |
| US10968396B1 (en) * | 2020-01-29 | 2021-04-06 | Saudi Arabian Oil Company | Method and process for producing needle coke from aromatic polymer material and aromatic bottoms of an aromatic recovery complex |
-
2021
- 2021-06-22 EP EP21180964.5A patent/EP4108738A1/fr not_active Withdrawn
-
2022
- 2022-06-17 WO PCT/EP2022/066611 patent/WO2022268664A1/fr unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101230284A (zh) * | 2007-01-25 | 2008-07-30 | 华东理工大学 | 废弃塑料的延迟焦化处理方法及其处理装置 |
| CN106554796A (zh) * | 2015-09-25 | 2017-04-05 | 中国石油天然气股份有限公司 | 一种提高液体产品收率的催化焦化方法 |
| US10968396B1 (en) * | 2020-01-29 | 2021-04-06 | Saudi Arabian Oil Company | Method and process for producing needle coke from aromatic polymer material and aromatic bottoms of an aromatic recovery complex |
Non-Patent Citations (3)
| Title |
|---|
| "Ullmann's Encyclopedia of Industrial Chemistry", 23 September 2014, WILEY-VCH, Weinheim, ISBN: 978-3-527-30673-2, article HEINRICH PREDEL: "Petroleum Coke", pages: 1 - 21, XP055559241, DOI: 10.1002/14356007.a19_235.pub3 * |
| VESPER D E ET AL: "ROHSTOFFLICHE VERWERTUNG - EIEN UBERSICHT", KUNSTSTOFFE, CARL HANSER VERLAG, MUNCHEN, DE, vol. 83, no. 11, 1 November 1993 (1993-11-01), pages 905 - 909, XP000399974, ISSN: 0023-5563 * |
| WANJEK H ET AL: "ROHSTOFFRECYCLING - DIE VERFAHRENSTECHNIK. RECYCLING OF RAW MATERIALS - THE PROCESS TECHNOLOGY", KUNSTSTOFFE, CARL HANSER VERLAG, MUNCHEN, DE, vol. 84, no. 2, 1 February 1994 (1994-02-01), pages 109 - 112, XP000433552, ISSN: 0023-5563 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2022268664A1 (fr) | 2022-12-29 |
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| STAA | Information on the status of an ep patent application or granted ep patent |
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| 18D | Application deemed to be withdrawn |
Effective date: 20230629 |