EP4040974A1 - Enrobage à fromage - Google Patents
Enrobage à fromageInfo
- Publication number
- EP4040974A1 EP4040974A1 EP20785758.2A EP20785758A EP4040974A1 EP 4040974 A1 EP4040974 A1 EP 4040974A1 EP 20785758 A EP20785758 A EP 20785758A EP 4040974 A1 EP4040974 A1 EP 4040974A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cheese
- package
- coating
- transmission rate
- edible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000013351 cheese Nutrition 0.000 title claims abstract description 120
- 238000000576 coating method Methods 0.000 title claims description 62
- 239000011248 coating agent Substances 0.000 title claims description 53
- 230000005070 ripening Effects 0.000 claims abstract description 32
- 238000000034 method Methods 0.000 claims abstract description 31
- 235000010443 alginic acid Nutrition 0.000 claims abstract description 21
- 229920000615 alginic acid Polymers 0.000 claims abstract description 21
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229940072056 alginate Drugs 0.000 claims abstract description 16
- 230000008569 process Effects 0.000 claims abstract description 15
- 230000005540 biological transmission Effects 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 18
- 229910052760 oxygen Inorganic materials 0.000 claims description 18
- 239000001301 oxygen Substances 0.000 claims description 18
- 239000003086 colorant Substances 0.000 claims description 13
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 6
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 6
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- 235000006770 Malva sylvestris Nutrition 0.000 description 32
- 229920001169 thermoplastic Polymers 0.000 description 29
- 240000002129 Malva sylvestris Species 0.000 description 28
- 239000010410 layer Substances 0.000 description 23
- 238000004806 packaging method and process Methods 0.000 description 23
- 239000004416 thermosoftening plastic Substances 0.000 description 20
- 229920000570 polyether Polymers 0.000 description 17
- 239000004721 Polyphenylene oxide Substances 0.000 description 15
- 239000004952 Polyamide Substances 0.000 description 13
- 229920002647 polyamide Polymers 0.000 description 13
- 239000000203 mixture Substances 0.000 description 11
- 238000011109 contamination Methods 0.000 description 10
- 230000000813 microbial effect Effects 0.000 description 10
- 229920000728 polyester Polymers 0.000 description 10
- -1 polyethylene terephthalate Polymers 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 229920002614 Polyether block amide Polymers 0.000 description 7
- 239000011247 coating layer Substances 0.000 description 7
- 229920001282 polysaccharide Polymers 0.000 description 7
- 229920002988 biodegradable polymer Polymers 0.000 description 6
- 239000004621 biodegradable polymer Substances 0.000 description 6
- 229920005862 polyol Polymers 0.000 description 6
- 238000009937 brining Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000796 flavoring agent Substances 0.000 description 5
- 235000019634 flavors Nutrition 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000013508 migration Methods 0.000 description 5
- 230000005012 migration Effects 0.000 description 5
- 239000005022 packaging material Substances 0.000 description 5
- 150000003077 polyols Chemical class 0.000 description 5
- 239000005017 polysaccharide Substances 0.000 description 5
- 150000004804 polysaccharides Chemical class 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 244000038561 Modiola caroliniana Species 0.000 description 4
- 125000002252 acyl group Chemical group 0.000 description 4
- 239000000783 alginic acid Substances 0.000 description 4
- 229960001126 alginic acid Drugs 0.000 description 4
- 150000004781 alginic acids Chemical class 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 244000017106 Bixa orellana Species 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000001670 anatto Substances 0.000 description 3
- 235000012665 annatto Nutrition 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000008199 coating composition Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- NCXMLFZGDNKEPB-FFPOYIOWSA-N natamycin Chemical compound O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C[C@@H](C)OC(=O)/C=C/[C@H]2O[C@@H]2C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 NCXMLFZGDNKEPB-FFPOYIOWSA-N 0.000 description 3
- 235000010298 natamycin Nutrition 0.000 description 3
- 239000004311 natamycin Substances 0.000 description 3
- 229960003255 natamycin Drugs 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 235000018102 proteins Nutrition 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- 239000004953 Aliphatic polyamide Substances 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 229920002148 Gellan gum Polymers 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- NVNLLIYOARQCIX-MSHCCFNRSA-N Nisin Chemical compound N1C(=O)[C@@H](CC(C)C)NC(=O)C(=C)NC(=O)[C@@H]([C@H](C)CC)NC(=O)[C@@H](NC(=O)C(=C/C)/NC(=O)[C@H](N)[C@H](C)CC)CSC[C@@H]1C(=O)N[C@@H]1C(=O)N2CCC[C@@H]2C(=O)NCC(=O)N[C@@H](C(=O)N[C@H](CCCCN)C(=O)N[C@@H]2C(NCC(=O)N[C@H](C)C(=O)N[C@H](CC(C)C)C(=O)N[C@H](CCSC)C(=O)NCC(=O)N[C@H](CS[C@@H]2C)C(=O)N[C@H](CC(N)=O)C(=O)N[C@H](CCSC)C(=O)N[C@H](CCCCN)C(=O)N[C@@H]2C(N[C@H](C)C(=O)N[C@@H]3C(=O)N[C@@H](C(N[C@H](CC=4NC=NC=4)C(=O)N[C@H](CS[C@@H]3C)C(=O)N[C@H](CO)C(=O)N[C@H]([C@H](C)CC)C(=O)N[C@H](CC=3NC=NC=3)C(=O)N[C@H](C(C)C)C(=O)NC(=C)C(=O)N[C@H](CCCCN)C(O)=O)=O)CS[C@@H]2C)=O)=O)CS[C@@H]1C NVNLLIYOARQCIX-MSHCCFNRSA-N 0.000 description 2
- 108010053775 Nisin Proteins 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229920003231 aliphatic polyamide Polymers 0.000 description 2
- 229940121375 antifungal agent Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 235000010418 carrageenan Nutrition 0.000 description 2
- 239000000679 carrageenan Substances 0.000 description 2
- 229920001525 carrageenan Polymers 0.000 description 2
- 229940113118 carrageenan Drugs 0.000 description 2
- 235000013365 dairy product Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000008157 edible vegetable oil Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000004309 nisin Substances 0.000 description 2
- 235000010297 nisin Nutrition 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 239000001814 pectin Substances 0.000 description 2
- 235000010987 pectin Nutrition 0.000 description 2
- 229920001277 pectin Polymers 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920001610 polycaprolactone Polymers 0.000 description 2
- 239000004632 polycaprolactone Substances 0.000 description 2
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 2
- WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical group O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 description 1
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 1
- SFHBJXIEBWOOFA-UHFFFAOYSA-N 5-methyl-3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical compound O=C1OC(C)COC(=O)C2=CC=C1C=C2 SFHBJXIEBWOOFA-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920006257 Heat-shrinkable film Polymers 0.000 description 1
- 101000576320 Homo sapiens Max-binding protein MNT Proteins 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000331 Polyhydroxybutyrate Polymers 0.000 description 1
- 229920006121 Polyxylylene adipamide Polymers 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 108010046377 Whey Proteins Proteins 0.000 description 1
- 102000007544 Whey Proteins Human genes 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
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- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229920000704 biodegradable plastic Polymers 0.000 description 1
- 229920000229 biodegradable polyester Polymers 0.000 description 1
- 239000004622 biodegradable polyester Substances 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 235000015115 caffè latte Nutrition 0.000 description 1
- 235000010410 calcium alginate Nutrition 0.000 description 1
- 239000000648 calcium alginate Substances 0.000 description 1
- 229960002681 calcium alginate Drugs 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920006374 copolyamide PA6I/6T Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229920005839 ecoflex® Polymers 0.000 description 1
- 229920005845 ecovio® Polymers 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 150000002194 fatty esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000011617 hard cheese Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229920005684 linear copolymer Polymers 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 238000011169 microbiological contamination Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 150000002921 oxetanes Chemical class 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920006139 poly(hexamethylene adipamide-co-hexamethylene terephthalamide) Polymers 0.000 description 1
- 239000005015 poly(hydroxybutyrate) Substances 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 235000010408 potassium alginate Nutrition 0.000 description 1
- 239000000737 potassium alginate Substances 0.000 description 1
- MZYRDLHIWXQJCQ-YZOKENDUSA-L potassium alginate Chemical compound [K+].[K+].O1[C@@H](C([O-])=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C([O-])=O)O[C@@H](O)[C@@H](O)[C@H]1O MZYRDLHIWXQJCQ-YZOKENDUSA-L 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 238000004826 seaming Methods 0.000 description 1
- 229920006012 semi-aromatic polyamide Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 150000007984 tetrahydrofuranes Chemical class 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 235000021119 whey protein Nutrition 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C19/00—Cheese; Cheese preparations; Making thereof
- A23C19/14—Treating cheese after having reached its definite form, e.g. ripening, smoking
- A23C19/16—Covering the cheese surface, e.g. with paraffin wax
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C19/00—Cheese; Cheese preparations; Making thereof
- A23C19/14—Treating cheese after having reached its definite form, e.g. ripening, smoking
- A23C19/16—Covering the cheese surface, e.g. with paraffin wax
- A23C19/166—Covering the cheese surface, e.g. with paraffin wax with non-edible preformed foils, films or bandages
Definitions
- the invention relates to cheese in a package wherein the cheese is coated with an edible layer.
- the invention further relates to a process for ripening cheese, and to the use of alginate and a package for ripening a cheese.
- Ripening is an essential aspect in the production of cheese. During ripening cheeses are susceptible to microbiological contamination, a problem that is addressed in various ways.
- Cheeses may be coated using water-borne dispersions or emulsions of synthetic copolymers, for example comprising esters of monoglycerides of hydrogenated fatty esters as described in EP 141299.
- Well-known products comprise poly(vinyl acetate-co-di-n-butyl maleate), poly(vinyl acetate-co-ethylene) and the like.
- Coatings often are difficult to remove from a cheese and may therefore consist of multiple layers to facilitate removal, for example in WO 2008/110550 describing a two-layer coating comprising an inner coating that is a fat and an outer coating that is a polyvinyl acetate-based plastic foil.
- the ripening process may be carried out by packaging cheese in a seal-tight film following the brining step.
- This approach described in EP 1287744, is referred to as foil ripening and the films that are used normally do not allow water and/or oxygen to pass.
- Foil ripening is less labor intensive compared to coating but has only limited development of flavor in the cheese.
- This drawback can be overcome by using packaging materials that have specific water vapor transmission rates (WVTR) and/or oxygen transmission rates (OTR) as described in WO 2009/47332, describing e.g. a single or two or more thermoplastic layers, in particular a thermoplastic, monolithic film.
- WVTR water vapor transmission rates
- OTR oxygen transmission rates
- Another drawback of foil ripening is that it does not allow for efficient introduction of coloring agents onto cheeses, which often is a key feature for discriminating between various cheeses.
- a drawback of synthetic coatings is that they are non-edible and thus human intake must be avoided. This has been overcome by introduction of edible coating materials, for example based on alginate as described in EP 615691 . Unfortunately, in practice these edible coatings are not very successful since the edibility of the coating also attracts microbial contamination. Nevertheless, there remains a need for edible coating of cheeses. For example, because the coating can mechanically protect the cheese surface, or because the coating can be used to bring characterizing markings and colors to the cheese for the retailer and consumer to discriminate one type of cheese from the other.
- Coating and packaging of cheeses may be combined.
- preservation of cheese using an edible food gel and a package is described in US 4,911 ,935.
- this technology is developed with a different objective, namely to bring about growth of external flora on the coating layer of the cheese, by bringing surface ferments on the coating layer.
- the objective of US 4,911 ,935 is reached by providing a package with very high oxygen permeability.
- the object of the present invention is to provide a cheese with an edible coating that may be ripened and/or preserved without being susceptible to microbial contamination.
- alginate refers to alginic acid and derivatives of alginic acid.
- Derivatives of alginic acid include salts which include metal salts. Examples are calcium alginate, magnesium alginate, potassium alginate, sodium alginate and the like.
- Alginic acid (also called algin) is a linear copolymer with homopolymeric blocks of (1-4)-linked b-D- mannuronate and its C-5 epimer a-L-guluronate, respectively, covalently linked together in different sequences or blocks.
- bag refers to a packaging container having an open top, side edges, and a bottom edge.
- the term “bag” also encompasses lay-flat bags, pouches, casings (seamless casings and back-seamed casings, including lap-sealed casings, fin-sealed casings, and butt-sealed back-seamed casings having back-seaming tape thereon).
- Casing configurations are known to the skilled person and are, for example, disclosed in US 6,764,729.
- bag configurations including L-seal bags, back-seamed bags, and U-seal bags (also referred to as pouches), are known from i.e. US 6,790,468.
- biodegradable refers to films, polymers or products that have the ability to break down, safely and relatively quickly, by biological means, into the raw materials of nature and disappear into the environment. These products can be solids biodegrading into the soil (which we also refer to as compostable), or liquids biodegrading into water. Biodegradable plastic is intended to break up when exposed to microorganisms.
- film is inclusive of plastic web, regardless of whether it is film or sheet or tubing.
- package is inclusive of packages made from containers or tubes, by placing a product in the article and sealing the article so that the product is substantially surrounded by the heat-shrinkable film from which the packaging container is made.
- taciness refers to the extent to which coating remains firm and visually unchanged and adhered to the cheese after storage in a package.
- the invention provides cheese in a package wherein said cheese is coated with an edible layer and said package has a water vapor transmission rate of at least 10 g/m 2 .24 h measured at 10°C and 85% relative humidity according to ASTM E96B cup test.
- Packaging the coated cheese results in achieving the object of the invention, namely to provide a cheese with an edible coating that may be ripened and/or preserved without being susceptible to microbial contamination.
- ripening conditions close to those of foil-free cheeses are obtained while at the same time it was found that neither the coating material sticks to the packaging material, nor did any coloring agents migrate from coating to packaging.
- coloring agents notably anatto
- the edible layer comprises natural ingredients based on polysaccharides, proteins and lipids, that may be extracted from plants, foods and animal tissues. These ingredients offer alternative packaging options that minimize environmental pollution at a relatively low cost. Proteins and polysaccharides have good film-forming abilities, although their barrier and mechanical properties are often limited, a problem that is solved in the instant invention. Examples of suitable polysaccharides, proteins and lipids that may be used in the context of the present invention are, but are not limited to, alginate, carrageenan, casein, gelatin, gellan (high acyl and low acyl), pectin, whey protein isolate, xanthan gum, and the like. These compounds may also be applied in mixtures in order to profit from individual beneficial properties. Use of alginate as ingredient for an edible coating has the additional advantage that application is simple by immersion in a liquid alginate solution which forms a coating upon contact with ions like calcium. The latter are (or can be made) available in regular cheese brining baths.
- the coating layer comprises additional components.
- coloring agents may be added. Coloring agents are used to visually differentiate one brand or type of cheese from the other but can also function to alter the influence of light on the cheese.
- the edible coatings of the instant invention are highly suitable for adding coloring agents as coloring results in a homogeneous color.
- EP 513922 describes an edible oil in water emulsion based on fats and emulsifiers wherein microbial protection is realized by the addition of an antifungal agent such as natamycin. These edible oil in water emulsions are however not suited for application of color to the surface of a cheese because coloration is non- homogeneous and more often than not results in smears that are not acceptable for retailers or consumers.
- An additional advantage of the coatings of the present invention is that coloring components do not migrate from the coating.
- hydroxylated cellulose derivates such as hydroxypropyl cellulose
- Suitable additional components can also comprise antifungal and/or antimicrobial compounds.
- Suitable examples or non-synthetic products examples of which are natamycin and/or nisin. Such compounds may be contained in the coating or applied on the coating of the present invention.
- suitable configurations of a package may be a film (which can be used to wrap around cheese), a bag or a pouch (in which the cheese can be placed).
- the package of the invention may be heat sealable.
- the package is biodegradable, for example as described in WO 2018/185235, and may consist of at least 30%, 40%, 50%, 60%, 70%, 80%, 90%, 95%, 99% or 100% by weight of biodegradable polymers.
- Biodegradable polymers may be polysaccharides, (co)polyesters and their blends. Examples of suitable polysaccharides are starches, preferably potato starches and their derivatives. Examples of suitable biodegradable polyesters are polycaprolactone, polyhydroxy butyrate, polylactic acid esters or co-polyesters of 1 ,4-butanediol, adipic acid and terephthalic acid such as described in WO 96/15173. Further suitable biodegradable polymers are polyester amides, as for example described in WO 96/21692.
- the package includes a film comprising at least two layers referred to as A and B.
- the package may be a film comprising three layers that may be A/B/A.
- layer(s) A may be from biodegradable polymers such as Ecoflex, polycaprolactone, Ecovio (BASF), MaterBi (Novamont), and layer B comprises starch.
- the biodegradable polymer of layer(s) A may be a heat sealable biodegradable polymer.
- the package comprises, for example as described in WO 2009/047332, a thermoplastic layer, in particular a thermoplastic, monolithic film.
- the package comprises a single thermoplastic layer.
- the package comprises two or more thermoplastic layers of different or the same composition.
- the surface of the layer(s) can be printed, for example for branding purposes, as known in the art.
- the package comprises at least two thermoplastic layers
- printing can be positioned between two thermoplastic layers.
- Multilayer films can be obtained by methods known in the art such as co-extrusion or lamination. In the case of printing the outer layer in reverse, the multilayer structure is usually obtained by a laminating process.
- thermoplastic layer can be a blend of several thermoplastic polymers.
- the thermoplastic polymer used for the thermoplastic film(s) is preferably a polyamide, a polyester, a polyether, the copolymers thereof or a mixture of at least two of these thermoplastic polymers.
- Preferred copolymers are block copolymers. More preferably, the thermoplastic polymer used for the thermoplastic film is polyamide, polyether ester, polyether amide or mixtures thereof.
- suitable polyamides are aliphatic polyamides, that may eventually be branched polyamides, such as PA6, PA46, PA66, PA6/66, PA11 , PA12, semi aromatic polyamides as MXD6, PA6I/6T, PA66/6T, fully aromatic polyamides and copolymers and blends of the listed polyamides.
- Compositions comprising polyamide may have a high amide content, such as for example PA6 in contrast to for example PA11 or PA12, since these polyamides as such have higher water vapor transmission rates than PA11 or PA12.
- polyesters examples include polyethylene terephthalate, polybutylene terephthalate, polypropylene terephthalate, polyethylene naphtanoate, polybutylene naphtanoate.
- a polyether ester respectively a polyether amide block copolymer is understood to be a copolymer containing soft blocks of a polyether and hard polyester respectively polyamide blocks.
- the polyether blocks are preferably those derived from base- or acid-catalyzed ring-opening polymerization of cyclic ethers such as epoxides, oxetanes, oxolanes, and the like. Mixtures of different types of polyethers can be used.
- Preferred polyethers are polyether polyols.
- polyether polyols include, but are not limited to, polyoxypropylene polyols, polyoxyethylene polyols, ethylene oxide-propylene oxide copolymers, polytetramethylene ether glycols, oxetane polyols, and copolymers of tetrahydrofuran and epoxides.
- Preferred aliphatic polyether are a poly(alkylene oxide) derived from an alkylene oxide of 2-6 C-atoms, preferably 2-4 C-atoms, or combinations thereof.
- polyesters examples include polyethylene oxide), poly(tetramethylene oxide), polypropylene oxide) and ethylene oxide-terminated polypropylene oxide).
- Suitable polyester respectively polyamide blocks in the polyether ester respectively polyether amide block copolymers are those defined above for the polyester respectively the polyamide.
- the hard polyester block is preferably built up from ethylene terephthalate or propylene terephthalate repeating units, and in particular from butylene terephthalate units.
- Preferred polyester blocks are PBT blocks.
- Preferred polyamide blocks are aliphatic polyamide blocks, preferably PA6, PA66 or PA12.
- the polyether ester and the polyether amide preferably has a polyether content of at least 30 wt.%.
- the amount of polyether ester and/or polyether amide in the thermoplastic film is preferably such that the ether content is at least 1 wt.%, more preferably at least 2 wt.% and even more preferably at least 4 wt.% (relative to the total amount of thermoplastic polymers in the thermoplastic film).
- the amount of polyether ester and/or polyether amide in the thermoplastic film is preferably such that the ether content is at most 70 wt.% (relative to the total amount of thermoplastic polymers in the thermoplastic film).
- the thermoplastic polymers used in the thermoplastic film consist essentially of polyamide and polyether amide and/or polyether ester. It has surprisingly been found that a package comprising such a thermoplastic film can advantageously be applied for foil-ripening of cheese as such packaging allows to increase the ripening, but not at the expense of the flavor development, the consistency and the mould and/or yeast growth. More preferably, the thermoplastic polymers used in the thermoplastic film consist essentially of 70 to 90 wt.% of polyamide and 10 to 30 wt.% polyether ester (relative to the total amount of thermoplastic polymers in the thermoplastic film). The polyether ester preferably has a polyether content of at least 30 wt.%.
- US 4,911 ,935 discloses a package with very high oxygen permeability. In our hands this feature proved to be detrimental for the production of cheeses where microbiological surface contamination is to be avoided. This applies to various cheeses such as semi-hard cheeses or rind cheeses such as for instance Cascaval, Cheddar, Edam, Emmental, Maasdam, Manchego, Gouda, Gruyere, Pecorino, Raclette, Rigatino, Taleggio, Tilsit, and Tomme Noire, and the like.
- the package has an oxygen transmission rate of at most 500 cm 3 /m 2 .24 h.atm measured at 10°C and 85% relative humidity according to ASTM D3985.
- the oxygen transmission rate is at most 100 cm 3 /m 2 .24 h.atm. More preferably, the oxygen transmission rate is at most 40 cm 3 /m 2 .24 h.atm at 10°C and 85% relative humidity.
- Suitable ranges of oxygen transmission rate at 10°C and 85% relative humidity are from 1 cm 3 /m 2 .24 h.atm to 100 cm 3 /m 2 .24 h.atm, or from 2 cm 3 /m 2 .24 h.atm to 40 cm 3 /m 2 .24 h.atm, or from 3 cm 3 /m 2 .24 h.atm to 35 cm 3 /m 2 .24 h.atm.
- low oxygen transmission rates have the advantage that microbial contamination forms less easily, or not at all, on the surface of the (coated) cheese.
- the package has a water vapor transmission rate of at least 10 g/m 2 .24 h measured at 10°C and 85% relative humidity according to ASTM E96B cup test.
- water vapor transmission through the package allows for the ripening process of the cheese to proceed to a large extend comparable to natural ripening of coated cheeses and results in favorable flavor.
- the water vapor transmission rate may, for example, be from 100 to 1000 g/m 2 .24 h or from 500 to 900 g/m 2 .24 h measured at 10°C and 85% relative humidity according to ASTM E96B cup test.
- Lower water vapor transmission rates for example lower than 2 g/m 2 .24 h as described in Del Nobile M.A. et al. (Carbohydrate Polymers 78 (2009) 151-156) are not suited for acceptable flavor development.
- the above water vapor transmission rate and oxygen transmission rate are combined to provide for ideal methods for ripening or preserving cheese, including the coated cheese of the invention.
- the package has, at 10°C and 85% relative humidity, a water vapor transmission rate of at least 10 g/m 2 .24 h and an oxygen transmission rate of at most 500 cm 3 /m 2 .24 h.atm.
- the package has a water vapor transmission rate of at least 10 g/m 2 .24 h and an oxygen transmission rate of from 2 cm 3 /m 2 .24 h.atm to 40 cm 3 /m 2 .24 h.atm.
- the outer surface of the package may be printed and/or may include other packaging articles such as parchments or paper articles, traditionally used in cheese packaging, which are kept enclosed in the package.
- the package of the present invention provides for optimal conditions for ripening the edible coated cheeses of the invention without the occurrence of microbial contamination that is normally associated with edible coatings. Further, it was found that tackiness of edible coatings in the package of the invention is superior over synthetic coatings such as the commonly used coatings based on vinyl acetate and maleic acid dibutyl ester copolymer, and tackiness remains good after prolonged periods of time.
- no surface ferments are present on the coating edible layer of the cheese.
- Surface ferments for growing external surface flora in prior art documents such as US 4,911 ,935 are chosen from PeniciIHum species and are usually placed on the outer surface of the coating layer.
- the invention provides a process for ripening and/or preserving a cheese comprising the steps of:
- step (ii) introducing the coated cheese obtained in step (i) into a package containing an opening for receiving cheese;
- the cheese is contacted with a bivalent metal salt prior to or during step (i) and/or in between steps (i) and (ii).
- Bivalent metal salts such as calcium (but also magnesium and the like) were found to promote the formation of the certain coating layers, for example in case of alginate, carrageenan, gellan (high acyl and low acyl), and pectin. Calcium is amongst the preferred bivalent metal salts as it is relatively inexpensive and helps to form rigid structures.
- the method only includes cheese ripening, and in another embodiment, the method only includes cheese preserving.
- the method includes cheese ripening followed by preserving.
- Conditions for ripening and/or preservation may differ and typically range from a relative humidity of from 20 to 95% and temperatures of from 1 to 25°C.
- Packaged cheeses may be stored at temperatures of from 10 to 20°C and at relative humidity of from 75 to 95%, for example in a maturation room or cell until, for example, a typical percentage of dry matter, taste, and/or color is reached.
- At least one brining pre-treatment of the cheese is performed before the method of the second aspect of the invention.
- the brining step may be performed as known in the art.
- Preferably a calcium salt is added or present during brining. This has the advantage that no additional crosslinking step is required which facilitates the coating and packaging procedure.
- Del Nobile M.A. et al. (Carbohydrate Polymers 78 (2009) 151-156) describes a process for the production of fior di latte. In this process, the dairy product is dipped into sodium alginate solution and, prior to packaging in a foil with a very low water vapor transmission rate, is immersed in a calcium chloride solution to crosslink the polymeric matrix.
- step (i) the latter step is not required and hence in an embodiment the process of the second aspect is carried out without immersing the coated cheese obtained in step (i) in a calcium chloride solution.
- step (i) the process of the second aspect is carried out without immersing the coated cheese obtained in step (i) in a calcium chloride solution.
- step (i) the process of the second aspect is carried out without immersing the coated cheese obtained in step (i) in a calcium chloride solution.
- at least a part of the ripening is performed while the cheese is present in the package.
- the package may be closed by clipping or sealing, for example by heat sealing.
- the package tightly covers the surface of the cheese so as to avoid air remaining between cheese and package. Remaining air may lead to unwanted mold formation and/or non-homogeneous cheese ripening.
- the package may be vacuumed and, optionally, heat shrunk prior to closing, as commonly known in the art of packaging.
- the package is vacuumed at pressures comprised between 0.5 and 1000 mbar, preferably for hard to semi-hard cheese from 5 to 25 mbar and for sensitive cheese from 600 to 800 mbar.
- Heat-shrinking may be carried out by submersion in hot water baths, preferably at temperatures not higher than 90°C for no more than 5 to 10 sec.
- hot air shrinking may be applied, for instance by hot air heating at 140-160°C for no more than 5 to 10 sec.
- the package is vacuumed and shrunk.
- the packaging container is a pre-made bag whereby the method comprises introducing cheese to be ripened into a bag or pouch and closing the bag, for example by hermetically sealing the opening for receiving the cheese to be ripened.
- the pre-made bag may be produced from flat film and contain at least one seal or alternatively, the bag may be produced from a tubular film resulting in a seamless tubular casing.
- the cheese is packaged according to a form-fill-seal process, as known in the art, with a package or film as described above.
- the time allowed for ripening may be in the range of about 20 days or longer, and in general equal to or less than about 2 years, preferably equal to or less than about 1 year, such as for instance of about 3 months or less, depending on the cheese.
- the ripening may be performed at temperatures such as for instance from 2 to 18°C, or from 4 to 15°C or from 10 to 14°C and at a relative humidity of 75-85%.
- Examples of cheeses to be coated and packaged according to the present invention are hard or semi-hard cheeses or rind cheeses such as for instance a Cascaval, Cheddar, Edam, Emmental, Maasdam, Manchego, Gouda, Gruyere, Pecorino, Raclette, Rigatino, Taleggio, Tilsit, and Tomme Noire.
- the present invention may further comprise adding an antimicrobial compound such as for instance natamycin and/or nisin.
- an antimicrobial compound such as for instance natamycin and/or nisin.
- Such compound may be added to the solution comprising an alginate used in step (i) but may also be applied in between steps (i) and (ii) to the surface of the coated cheese.
- step (i) no surface ferments are applied to the coated cheese.
- no surface ferments from PeniciIHum species are applied to the outer surface of the coating layer.
- the method of the invention results in good consistency, flavor and taste of cheese and prevents undesired fermentations and mold growth. Also, the method of coating and packaging of the present invention results in maintenance of the shape of the cheese.
- the method of the present invention results in cheeses that are coated with an edible layer which have undergone ripening closely resembling natural ripening and which do not suffer from microbial contamination in or on the edible coating during the ripening process.
- packaging materials can be removed without unwanted sticking of the coating to the packaging material and added components, such as coloring agents, do not migrate to cheese or packaging material.
- the invention provides use of an edible coating and a package for ripening and/or preserving a cheese.
- the edible coating comprises an alginate.
- the package has an oxygen transmission rates and/or water vapor transmission rate as outlined in the first aspect of the invention.
- the invention provides a ripened cheese comprising an edible coating obtainable according to the method of the second aspect.
- the coating comprises alginate.
- the cheese comprises a coating that is both edible and does not suffer from microbial contamination.
- DelvoCoat 13014 was obtained from DSM in the Netherlands and is a vinyl acetate and maleic acid dibutyl ester copolymer dispersion.
- Example 1
- Alginate coating compositions were prepared according to the below Table. Reference cheeses were coated with DelvoCoat 13014. Table Alginate-comprising coating compositions (amounts are further specified in individual experiments)
- Tackiness refers to the extent to which the coating remains firm and visually unchanged after storage in Pack-Age as a result of which the Pack-Age can be removed from the coated cheese without any or all of the coating sticking to the Pack-Age.
- Gouda-type cheeses of 1 kg were brined, alginate-coated and packaged according to the above procedure. Tackiness and migration of color from coating to package was monitored with the essentially the same results as in Example 1 demonstrating that the combination of the invention outperformed the combination wherein DelvoCoat 13014 was use as coating material in terms of tackiness and color migration.
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
- Packages (AREA)
Abstract
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EP19201845 | 2019-10-08 | ||
PCT/EP2020/078021 WO2021069453A1 (fr) | 2019-10-08 | 2020-10-07 | Enrobage à fromage |
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DE3338492C2 (de) | 1983-10-22 | 1985-10-17 | H.B. Fuller GmbH, 2120 Lüneburg | Verfahren zum Verpacken, Schützen und/oder zur konservierenden Behandlung von Hartkäsen, festen und halbfesten Schnittkäsen in Form von ganzen Käselaiben oder Teilstücken hiervon |
CA1292141C (fr) | 1985-05-10 | 1991-11-19 | Catherine Marie-Yvonne Fillaud | Procede de fabrication d'un produit alimentaire fromager et produit alimentaireainsi obtenu |
DK0513922T3 (da) | 1991-05-17 | 1996-07-08 | Gist Brocades Nv | Overtræk til levnedsmidler og landbrugsprodukter til forebyggelse af væksten af skimmelsvampe |
US6221410B1 (en) | 1992-09-25 | 2001-04-24 | Cryovac, Inc. | Backseamed casing and packaged product incorporating same |
NL9300470A (nl) | 1993-03-16 | 1994-10-17 | Friesland Frico Domo Coop | Kaashuid voor de vochtregulatie en ter bescherming tegen microbiële invloeden. |
DE4440858A1 (de) | 1994-11-15 | 1996-05-23 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
DE19500756A1 (de) | 1995-01-13 | 1996-07-18 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
US6790468B1 (en) | 1997-09-30 | 2004-09-14 | Cryovac, Inc. | Patch bag and process of making same |
NL1018856C2 (nl) | 2001-08-30 | 2003-03-03 | Friesland Brands Bv | Werkwijze voor het bereiden van een half-harde of harde kaas en aldus verkregen kaas. |
WO2008110550A1 (fr) | 2007-03-12 | 2008-09-18 | Dsm Ip Assets B.V. | Enrobages préalables pour aliments |
PL2200447T3 (pl) | 2007-10-12 | 2013-12-31 | Dsm Ip Assets Bv | Sposób dojrzewania sera w folii |
DK2338353T3 (da) * | 2009-12-17 | 2019-09-16 | Csk Food Enrichment Bv | Fremgangsmåde til modning af en ost ved tilstedeværelsen af en ramme |
WO2018185235A1 (fr) | 2017-04-06 | 2018-10-11 | Cryovac, Inc. | Film, emballage et procédé d'affinage et de conservation de fromage |
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