EP4038682A1 - Brennstoffzellenvorrichtung - Google Patents

Brennstoffzellenvorrichtung

Info

Publication number
EP4038682A1
EP4038682A1 EP20785470.4A EP20785470A EP4038682A1 EP 4038682 A1 EP4038682 A1 EP 4038682A1 EP 20785470 A EP20785470 A EP 20785470A EP 4038682 A1 EP4038682 A1 EP 4038682A1
Authority
EP
European Patent Office
Prior art keywords
fuel cell
cell device
exhaust gas
fuel
processor unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20785470.4A
Other languages
German (de)
English (en)
French (fr)
Inventor
Peter Horstmann
Bertram Schweitzer
Tobias ZIMMER
Jochen Winkler
Martin Hoeller
Sebastian Obermeyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
Original Assignee
Robert Bosch GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Robert Bosch GmbH filed Critical Robert Bosch GmbH
Publication of EP4038682A1 publication Critical patent/EP4038682A1/de
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/2484Details of groupings of fuel cells characterised by external manifolds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/2483Details of groupings of fuel cells characterised by internal manifolds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201Reactant storage and supply, e.g. means for feeding, pipes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293Fuel cells with solid oxide electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the present invention relates to a fuel cell device, comprising at least one fuel cell stack and at least one processor unit.
  • Fuel cell devices are already known which have a fuel cell stack and a processor unit.
  • the present invention with the features of the main claim has the advantage that a distributor plate for media routing is arranged between the at least one fuel cell stack and the at least one processor unit. This enables an improved and more compact design of the fuel cell device.
  • a “processor unit” is to be understood as meaning, in particular, a unit or component of the fuel cell device that is not a fuel cell and / or a fuel cell stack.
  • the processor unit is a unit for, preferably chemical and / or thermal, preparation and / or post-processing of at least one medium to be converted and / or converted in the at least one fuel cell stack, such as a fuel gas, air and / or a Exhaust gas.
  • the processor unit is preferably a reformer, an afterburner and / or a heat exchanger.
  • the distribution plate fluidically connects the at least one processor unit with the at least one fuel cell stack.
  • a compact fluidic connection can be created between the at least one processor unit and the fuel cell stack, with the number of parts being reduced at the same time.
  • the distribution plate has media guides that are spatially separated from one another between two sub-plates for at least one medium to be converted and / or converted in the at least one fuel cell stack, whereby particularly good media routing can be implemented.
  • the distributor plate is designed in one piece, preferably as a cast part, as a result of which the production costs can be reduced.
  • FIG. 1 shows a schematic circuit diagram of an exemplary embodiment of a fuel cell device
  • FIG. 2 shows a perspective illustration of the exemplary embodiment of the fuel cell device from FIG. 1,
  • FIG. 3 shows a further perspective illustration of the exemplary embodiment of the fuel cell device from the preceding figures
  • FIG. 4 shows an enlarged illustration of a lower region of the exemplary embodiment of the fuel cell device from the preceding figures
  • FIG. 5 shows a cross section of the lower region of the embodiment of FIG
  • FIG. 6 shows a plan view of a distributor plate of the exemplary embodiments of the fuel cell device from the preceding figures.
  • the fuel cell device 10 comprises two fuel cell stacks 12, which have a multiplicity of fuel cells, in the present case solid oxide fuel cells (SOFC), as well as a multiplicity of processor units 14.
  • SOFC solid oxide fuel cells
  • a “processor unit” 14 is to be understood in particular as a unit or component of the fuel cell device 10 that is not a fuel cell and / or a fuel cell stack 12.
  • the processor units 14 are units for chemical and / or thermal preparation and / or post-processing of at least one medium to be converted and / or converted in the fuel cell stack 12, such as a fuel gas, air and / or an exhaust gas .
  • One of the processor units 14 is a heat exchanger 18 arranged in an air supply 16 for heating one of the fuel cell stacks 12 supplied air L.
  • the air L is supplied to a cathode chamber 20 of the fuel cell stacks 12, for example in normal operation, while reformed fuel RB, in the present hydrogen, is fed to a cathode chamber 22.
  • the reformed fuel is converted electrochemically with the generation of electricity and heat.
  • the reformed fuel RB is generated by supplying fuel B, in the present case natural gas, to the fuel cell device 10 via a fuel feed 24, which fuel B is reformed in a further processor unit 14, in the present case a reformer 26. Furthermore, the fuel cell stacks 12 are connected on the exhaust gas side to a further processor unit 14, in the present case to an afterburner 28. Exhaust gas from fuel cell stacks 12 is fed to afterburner 28, in the present case cathode exhaust gas KA via a cathode exhaust gas duct 30 and anode exhaust gas AA via an anode exhaust gas duct 32.
  • the cathode exhaust gas contains predominantly unused air L, while anode exhaust gas AA contains unreacted fuel B, among other things.
  • the anode exhaust gas AA, or the unreacted fuel B contained therein is burned with admixture of the cathode exhaust gas KA, or the air L contained therein, whereby additional heat can be generated.
  • the hot exhaust gas A produced during the combustion in the afterburner 28 is discharged from the afterburner 28 via an exhaust gas duct 34 via a further processor unit 14, in the present case via a heat exchanger 36.
  • the heat exchanger 36 is in turn fluidically connected to the reformer 26, so that heat is transferred from the hot exhaust gas A to the fuel B supplied to the reformer 26.
  • the heat of the hot exhaust gas A can be used for reforming the fuel B supplied in the reformer 26.
  • a further processor unit 14 Downstream of the heat exchanger 36 there is a further processor unit 14, in the present case the heat exchanger 18, in the exhaust gas duct 34, so that the remaining heat of the hot exhaust gas A can be transferred to the air L supplied in the air supply 16.
  • the remaining heat of the hot exhaust gas can be used to preheat the air L supplied in the air duct 16.
  • the fuel cell device 10 has a return line 38, by means of which anode exhaust gas AA can be partially branched off from the anode exhaust gas line 30 and fed to the fuel supply 22.
  • the return line 34 forms an anode recirculation circuit 40 with the fuel supply 22, by means of which anode exhaust gas AA can be returned to the anode of the fuel cell 12, so that any unconverted fuel B in the anode exhaust gas AA can subsequently be converted, whereby the efficiency of the fuel cell device 10 continues can be increased.
  • the supply of air L in the air supply 16, the supply of fuel B in the fuel supply 24 and the Recirculation rate of the anode exhaust gas AA in the anode recirculation circuit 40 can be regulated and / or coordinated with one another.
  • the fuel cell device has a heating element 44 for, in the present case additional, heating of the air L supplied to the fuel cell stacks 12 in a bypass line 46, as a result of which the operating efficiency of the fuel cell device 10 is increased.
  • FIGS. 2-4 show perspective representations of an exemplary embodiment of a fuel cell device 10, and FIG. 5 shows a cross section of a lower region of the fuel cell device 10.
  • the illustrations show a specific implementation of the fuel cell device 10 according to the circuit diagram from FIG. 1.
  • the processor units 14 are a reformer 26, an afterburner 28 and two heat exchangers 18, 36. From FIGS. 2-5 it can be seen that the processor units 14 are arranged, in the present case on their edges, in such a way that media guide spaces that are separate from one another are formed on or between the processor units 14.
  • the air supply 16 and the exhaust gas duct 34 are designed at least essentially as media ducting spaces 48. As a result, no pipework is required between the processor units 14, which on the one hand simplifies assembly and on the other hand reduces the number of parts.
  • the fuel cell device is now characterized in that a distributor plate 50 for media routing is arranged between the fuel cell stacks 12 and the processor units 14. As a result, a compact design of the fuel cell device 10 can be realized. In addition, the connection or assembly of the fuel cell stacks 12 to the processor units 14 is simplified.
  • the fuel cell stacks 12 and the processor units 14 are arranged spatially separated from one another, as a result of which the accessibility to individual components, for example during maintenance, is improved.
  • the fuel cells 12 are arranged in an upper region 52, while the Processor units are arranged in a lower region 54.
  • the fuel cell device is shown essentially open. In fact, the fuel cell stacks 12 are placed in a first housing (not shown) and the processor units 14 are placed in a second housing 58.
  • the second housing 58 together with the processor units 14, forms the media guides or media guide spaces 48 for the media to be converted and / or converted in the fuel cell stacks, such as fuel B, reformed fuel RB, air L, cathode exhaust gas KA, anode exhaust gas AA and / or the exhaust gas A.
  • the distribution plate 50 now fluidically connects the processor units 14 to the fuel cell stacks 12, which results in a particularly elegant and compact fluidic connection.
  • the distributor plate has between two sub-plates arranged at a distance from one another, media guides 60, which are embodied separately from one another, for the media to be relocated and / or relocated in the fuel cell stack 12.
  • media guides 60 which are embodied separately from one another, for the media to be relocated and / or relocated in the fuel cell stack 12.
  • Fig. 6 a plan view of the distributor plate 50 is shown accordingly.
  • the distributor plate 50 has openings 62 and associated media guides 64 for the air L supplied to the fuel cell stacks 12,
  • the openings shown in dashed lines are made in a first (lower) sub-plate 78, while the openings shown in solid lines are made in a second (upper) sub-plate 80 (cf. FIGS. 4 and 5).
  • the media guides 60 are formed between the openings made in the first (lower) partial plate 78 and the associated openings made in the second (upper) partial plate 80.
  • the media guides 60 are laterally bordered and sealed by walls 82.
  • the walls 82 in turn separate the first (lower) sub-plate 78 and the second (upper) sub-plate from one another, which in turn creates space for any further supply and / or discharge lines despite the compactness. which can also be connected and / or introduced from the outside, for example.
  • the connections of the fuel cell stacks 12 and the connections of the second partial housing 84, which has the processor units 14, can also be adapted to one another by means of the distributor plate 50 or through the media guides 60 introduced in the distributor plate.
  • different types of fuel cell stacks 12 can be used as required by adapting the media guides 60.
  • the distributor plate 50 is designed in one piece, preferably as a cast part, as a result of which the production costs are reduced.
  • the distributor plate 50 it would also be possible for the distributor plate 50 to be welded from sheet metal parts and / or to be produced by 3D printing.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
EP20785470.4A 2019-10-02 2020-09-28 Brennstoffzellenvorrichtung Pending EP4038682A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102019215230.9A DE102019215230A1 (de) 2019-10-02 2019-10-02 Brennstoffzellenvorrichtung
PCT/EP2020/077047 WO2021063859A1 (de) 2019-10-02 2020-09-28 Brennstoffzellenvorrichtung

Publications (1)

Publication Number Publication Date
EP4038682A1 true EP4038682A1 (de) 2022-08-10

Family

ID=72709354

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20785470.4A Pending EP4038682A1 (de) 2019-10-02 2020-09-28 Brennstoffzellenvorrichtung

Country Status (6)

Country Link
US (1) US20220384836A1 (ko)
EP (1) EP4038682A1 (ko)
KR (1) KR20220073774A (ko)
CN (1) CN114503319A (ko)
DE (1) DE102019215230A1 (ko)
WO (1) WO2021063859A1 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102021207778A1 (de) 2021-07-21 2023-01-26 Robert Bosch Gesellschaft mit beschränkter Haftung Brennstoffzellenvorrichtung
DE102021214811A1 (de) 2021-12-21 2023-06-22 Robert Bosch Gesellschaft mit beschränkter Haftung Brennstoffzellenvorrichtung
DE102021214807A1 (de) 2021-12-21 2023-06-22 Robert Bosch Gesellschaft mit beschränkter Haftung Brennstoffzellenvorrichtung
DE102021214810A1 (de) 2021-12-21 2023-06-22 Robert Bosch Gesellschaft mit beschränkter Haftung Brennstoffzellenvorrichtung, sowie Verfahren zur Herstellung einer solchen Brennstoffzellenvorrichtung
DE102021214809A1 (de) 2021-12-21 2023-06-22 Robert Bosch Gesellschaft mit beschränkter Haftung Brennstoffzellenvorrichtung
DE102021214865A1 (de) 2021-12-22 2023-06-22 Robert Bosch Gesellschaft mit beschränkter Haftung Brennstoffzellenvorrichtung
DE102022201024A1 (de) 2022-02-01 2023-08-03 Robert Bosch Gesellschaft mit beschränkter Haftung Brennstoffzellenvorrichtung

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5733675A (en) * 1995-08-23 1998-03-31 Westinghouse Electric Corporation Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer
DE19618220A1 (de) * 1996-05-07 1997-11-13 Bosch Gmbh Robert Vorrichtung zur Erzeugung von Wärme und zur elektrochemischen Stromerzeugung
US6627339B2 (en) * 2000-04-19 2003-09-30 Delphi Technologies, Inc. Fuel cell stack integrated with a waste energy recovery system
US6869717B2 (en) * 2001-07-09 2005-03-22 Hydrogenics Corporation Manifold for a fuel cell system
US7279246B2 (en) * 2002-06-24 2007-10-09 Delphi Technologies, Inc. Solid-oxide fuel cell system having an integrated air/fuel manifold
US7771884B2 (en) * 2006-04-19 2010-08-10 Delphi Technololgies, Inc. Solid oxide fuel cell stack having an integral gas distribution manifold
DE102012101023A1 (de) * 2012-02-08 2013-08-08 Elringklinger Ag Brennstoffzellenvorrichtung und Verfahren zum Herstellen einer Brennstoffzellenvorrichtung
US9647291B2 (en) * 2013-08-29 2017-05-09 Delphi Technologies, Inc. Heater and supporting structure thereof
DE102015224088A1 (de) * 2015-12-02 2017-06-08 Bayerische Motoren Werke Aktiengesellschaft Verfahren zur Reparatur eines Brennstoffzellenstapels
DE102016222109A1 (de) * 2016-11-10 2018-05-17 Robert Bosch Gmbh Brennstoffzellensystem
DE102017200995A1 (de) * 2016-12-28 2018-06-28 Robert Bosch Gmbh Brennstoffzellenvorrichtung und Verfahren zu einem Anfahren der Brennstoffzellenvorrichtung
AT521064B1 (de) * 2018-03-19 2020-03-15 Avl List Gmbh Stapelartig aufgebautes Brennstoffzellensystem

Also Published As

Publication number Publication date
CN114503319A (zh) 2022-05-13
US20220384836A1 (en) 2022-12-01
KR20220073774A (ko) 2022-06-03
DE102019215230A1 (de) 2021-04-08
WO2021063859A1 (de) 2021-04-08

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