EP3988713B1 - Procédé de traitement d'une bande de matière fibreuse et système de traitement pour le traitement d'une bande de matière fibreuse - Google Patents

Procédé de traitement d'une bande de matière fibreuse et système de traitement pour le traitement d'une bande de matière fibreuse Download PDF

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Publication number
EP3988713B1
EP3988713B1 EP21196576.9A EP21196576A EP3988713B1 EP 3988713 B1 EP3988713 B1 EP 3988713B1 EP 21196576 A EP21196576 A EP 21196576A EP 3988713 B1 EP3988713 B1 EP 3988713B1
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EP
European Patent Office
Prior art keywords
air
fiber web
sizing
drying system
advantageously
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EP21196576.9A
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German (de)
English (en)
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EP3988713A1 (fr
Inventor
Vesa Ahvenniemi
Jari Ilomäki
Antti RÄISÄNEN
Henri Vaittinen
Tommi Vanhala
Heikki Vatanen
Mika Viljanmaa
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Valmet Technologies Oy
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Valmet Technologies Oy
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
    • D21H23/56—Rolls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C1/00—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
    • B05C1/04—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
    • B05C1/08—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
    • B05C1/0826—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line the work being a web or sheets
    • B05C1/083—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line the work being a web or sheets being passed between the coating roller and one or more backing rollers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C9/00—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
    • B05C9/06—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying two different liquids or other fluent materials, or the same liquid or other fluent material twice, to the same side of the work
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C9/00—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
    • B05C9/08—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation
    • B05C9/14—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation the auxiliary operation involving heating or cooling
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/22—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/28—Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/34—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/84—Paper comprising more than one coating on both sides of the substrate
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/46—Pouring or allowing the fluid to flow in a continuous stream on to the surface, the entire stream being carried away by the paper
    • D21H23/48—Curtain coaters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04—Physical treatment, e.g. heating, irradiating
    • D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper

Definitions

  • present invention relates to treating of fiber webs in a fiber web production line. More especially the present invention relates to a method according to preamble part of the independent method claim and to a treatment system according to preamble part of the independent treatment system claim.
  • fiber webs are meant for example a paper and board webs.
  • Fiber webs such as paper and board webs are available in a wide variety of types and can be divided according to basis weight in two grades: papers with a single ply and a basis weight of 25-300 g/m 2 and boards manufactured in multi-ply technology and having a basis weight of 150-600 m/m 2 . It should be noted that the borderline between paper and board is flexible since board grades with lightest basis weights are lighter than the heaviest paper grades. Generally speaking, paper is used for printing and board for packaging.
  • Mechanical-pulp based, i.e. wood-containing printing papers include newsprint, uncoated magazine and coated magazine paper.
  • DIP deinked pulp
  • TMP mechanical pulp
  • DIP based newsprint may contain up to 20 % filler.
  • the filler content of a virgin-fiber based newsprint furnish is about 8 %.
  • CSWO newsprint can be regarded as follows: basis weight 40-48.8 g/m 2 , PPS s10 roughness (SCAN-P 76-95) 4.0-4.5 ⁇ m, Bendtsen roughness (SCAN-P21:67) 150 ml/min, density 600-750 kg/m 3 , brightness (ISO 2470:1999) 58-59 %, and opacity (ISO 2470:1998) 92-95%.
  • Uncoated magazine paper (SC-supercalendered) grades usually contain 50 % - 75 % mechanical pulp, 5 % - 25 % chemical pulp, and 10 % - 35 % filler.
  • the paper may also contain DIP.
  • Typical values for calendered SC paper containing e.g.
  • SC-C, SC-B, and SC-A/A+ include basis weight 40-60 g/m 2 , ash content (SCAN-P 5:63) 0-35%, Hunter gloss (ISO/DIS 8254/1) ⁇ 20-50%, PPS s10 roughness (SCAN-P 76:95) 1.0-2.5 ⁇ m, density 700-1250 kg/m 3 , brightness (ISO 2470:1999) 62-75%, and opacity (ISO 2470:1998) 90-95%.
  • Coated mechanical papers include for example MFC (machine finished coated), LWC (lightweight coated), MWC (medium weight coated), and HWC (heavy weight coated) grades.
  • Coated mechanical papers usually contain 45 % -75 % mechanical or recycled fiber and 25 % - 55 % chemical pulp.
  • Semi chemical pulps are typical in LWC paper grades made in the Far East.
  • the filler content is about 5 % -10 %.
  • the grammage is typically in the range 40-80 g/m2.
  • LWC paper can be regarded as follows: basis weight 40-70 g/m 2 , Hunter gloss 50-65%, PPS S10 roughness 1.0-1.5 ⁇ m (offset) and 0.6-1.0 ⁇ m (roto), density 1100-1250 kg/m 3 , brightness 70-75%, and opacity 89-94%.
  • MFC paper machine finished coated
  • basis weight 48-70 g/m 2 Hunter gloss 25-40%
  • PPS S10 roughness 2.2-2.8 ⁇ m density 900-950 kg/ m 3
  • brightness 70-75% brightness 70-75%
  • opacity 91-95% 91-95%.
  • MWC paper medium weight coated
  • basis weight 70-90 g/ m 2 g/ m 2
  • Hunter gloss 65-70% PPS S10 roughness 0.6-1.0 ⁇ m
  • density 1150-1250 kg/ m 3 a measure of brightness
  • brightness 70-75% a measure of brightness
  • Wood free paper is divided into two segments: uncoated and coated. Conventionally, the furnish of wood free papers consists of bleached chemical pulp, with less than 10 % mechanical pulp.
  • Typical values are for uncoated WFU Copy paper: grammage 70-80 g/m 2 , Bendtsen roughness 150-250 ml/min and bulk > 1.3 cm3/g; for uncoated offset paper: grammage 60-240 g/m 2 , Bendtsen roughness 100-200 ml/min and bulk 1.2- 1.3 cm3/g; and for color copy paper: grammage 100 g/m 2 , Bendtsen roughness ⁇ 50 ml/min and bulk 1.1 cm3/g.
  • WFC coated pulp-based printing papers
  • the amounts of coating vary widely in accordance with requirements and intended application.
  • Containerboard includes both linerboard and corrugating medium. Liners are divided according to their furnish base into Kraft liner, recycled liner and white top liner. Liners are typically 1 - to 3-ply boards with grammage varying in the range 100-300 g/m 2 .
  • Linerboards are generally uncoated, but the production of coated white-top liner is increasing to meet higher demands for printability.
  • the main cartonboard grades are folding boxboard (FBB), white-lined chipboard (WLC), solid bleached board (SBS) and liquid packaging board (LPB). In general, these grades are typically used for different kinds of packaging of consumer goods.
  • Carton board grades vary from one- up to five-ply boards (150-400 g/m 2 ). The top side is usually coated with from one to three layers (20-40 g/m 2 ); the back side has less coating or no coating at all. There is a wide range of different quality data for the same board grade.
  • FBB has the highest bulk thanks to the mechanical or chemi mechanical pulp used in the middle layer of the base board.
  • the middle layer of WLC consists mainly of recycled fiber, whereas SBS is made from chemical pulp, exclusively.
  • FBB's bulk typically is between 1.1-1.9 cm 3 /g whereas WLC is on range 1.1-1.6 cm 3 /g and SBS 0.95-1.3 cm 3 /g.
  • the PPS-s10-smoothess is respectively for FBB between 0.8 - 2.1 ⁇ m, for WLC 1.3- 4.5 ⁇ m and for SBS 0.7 - 2.1 ⁇ m.
  • Release paper is used in label base paper in various end-use applications, such as food packaging and office labels.
  • the most common release paper in Europe is supercalendered glassine paper coated with silicone to provide good release properties.
  • Typical values for supercalendered release papers are basis weight 60 - 95 g/m 2 , caliper 55-79 ⁇ m, IGT 12-15 cm, Cobb Unger for dense side 0.9-1.6 g/m 2 and for open side 1.2-2.5 g/m 2 .
  • Coated label paper is used as face paper for release, but also for coated backing paper and flexible packings.
  • Coated label paper has a grammage of 60-120 g/m 2 and is typically sized or pre-coated with a sizer and single-blade coated on one side.
  • Some typical paper properties for coated and calendered label paper are basis weight 50-100 g/m 2 , Hunter gloss 70-85%, PPS s10 roughness 0.6-1.0 ⁇ m, Bekk smoothness 1500-2000 s and caliper 45-90 ⁇ m.
  • the fiber webs are produced in a fiber web producing process.
  • fiber web producing processes typically comprise an assembly formed by a number of apparatus arranged consecutively in the process line.
  • a typical production and treatment line comprise a head box, a wire section and a press section as well as a subsequent drying section and a reel-up.
  • the production and treatment line can further comprise other devices and/or sections for finishing the fiber web, for example, a pre-calender, a sizer, a final-calender, a coating section.
  • the production and treatment line also typically comprise at least one slitter-winder for forming customer rolls as well as a roll packaging apparatus.
  • sizing is used to alter the properties of a fiber web by adding sizing agents, for example starch.
  • Sizing can be divided to internal sizing and surface sizing.
  • internal sizing the sizing agent is added to pulp in the wet end of the fiber web machine before forming.
  • surface sizing the sizing agent is added onto the surface of the fiber web typically at the dry end of the fiber web machine.
  • Surface sizing is used in production of many fiber web grades, for example of uncoated fine papers and of several board grades.
  • Sizing is used in order to improve paper web properties, in particular water resistance, water absorption properties, strength, internal strength, surface strength and bending stiffness, as well as to improve adherence of coating color to the surface of the fiber web.
  • runnability as well as dusting tendency can be affected favorably.
  • a machine including at least one curtain applicator device for coating a material web.
  • the path of the material web following the curtain applicator device comprises first a turning arrangement, which directs the material web downwards, to a drying section where the material web passes through at least one non-contact drying device.
  • WO patent application publication 2004099495A1 is disclosed a method for control of curl of paper in the treatment of surface-sized paper in a finishing section of a paper machine, in which method a paper web is first dried in a forward dryer section of the paper machine in several successive downward open drying groups that apply single-wire draw, after which the paper web is finished in the finishing section, in which finishing section the web is surface-sized in a surface-sizing unit and the surface-sized paper web is dried mainly by means of contact-free drying, at least partly by airborne web-dryers.
  • EP patent application publication 3617403A1 is disclosed a method of treating a fiber web, in which method the fiber web is sized in a sizer, in which the sizing agent is applied onto the fiber web by two hard sizing rolls in a sizing nip, wherein the fiber web is sized with high solids content sizing agent by indirect curtain sizing in a curtain sizer and in the sizing nip at substantially uniform pressure distribution and uniform speed in cross-direction of the fiber web, and after the sizing the fiber web is heat-treated in a heat-treatment zone of a heat-treatment device.
  • An object of the invention is to create a method of treating a fiber web and a treatment system for treatment of a fiber web, in which disadvantages in treating a fiber web with high solids sizing agent are eliminated or at least minimized.
  • a particular object of the invention is to create a method and a system to treat the fiber web to improve the surface strength and/or to create non-porous, advantageously porous controlled, closed surface of the fiber web, which provides good basis for coating, especially for barrier coating, of the fiber web.
  • a particular object is to create a method and a system to treat the fiber web to improve the strength and/or stiffness of the fiber web.
  • a particular object is to create a method and a system to treat the fiber web such, that dusting of the fiber web is eliminated or at least minimized.
  • a particular object is to create a method and a system to treat the fiber web to improve printing properties of the fiber web.
  • the treatment system for treatment of a fiber web according to the invention is mainly characterized by the features of the characterizing part of the independent treatment system claim.
  • the fiber web is sized in a sizer by indirect curtain sizing in a curtain sizer, in which the sizing agent is applied onto at least one side of the fiber web by two sizing rolls with metallic or ceramic surface or with polymeric surface, which polymeric surface has surface hardness 60 - 100 shoreD, advantageously 80 - 95 shoreD, in a sizing nip, in which the fiber web is sized with high solids content sizing agent having solids content of 10 - 60 %, preferably 20 - 40 %, and viscosity of 50 cP- 2000 cP, preferably 100 cP - 1500 cP, and the sizing agent is applied onto the at least one side of the fiber web by the two sizing rolls in the sizing nip, wherein after the sizing the fiber web is directly guided to contactless and supported drying in an air-borne drying system (20) and the run of the fiber web from the sizing nip to beginning
  • the drying is continuous until the moisture content of the fiber web is desired for the next treatment and the fiber web runs without open draws and contacts to rolls.
  • the sizing roll is used a ceramic or metallic roll or advantageously, a roll with a polymeric roll cover (rubber, polyurethane or composite) having surface hardness 60 - 100 shoreD, advantageously 80 - 95 shoreD.
  • the hard sizing nip enhances the strength increase.
  • the fiber web is configured to have a substantially U-formed contactless run in the air-borne drying system or a substantially reversed U-formed contactless run in the air-borne drying system.
  • the fiber web is supported by air blows of the air-borne drying system and by the shape of the U-formed/the reversed U-formed contactless run such, that bending of the fiber web around an imaginary axis in the machine direction is eliminated.
  • maximum blowing air temperature in the air-borne drying system is about 500°C and minimum blowing air temperature is 50°C, advantageously 140-400°C.
  • blowing air velocity in the air-borne drying system is at least 20 m/s, advantageously 40 - 60 m/s.
  • the air-borne drying system comprises at least two, advantageously three air compartments forming chambers of the air-borne drying system and that advantageously temperature and/or velocity of blowing air from each air compartment is adjustable, advantageously such, that both sides of the fiber web can be treated individually.
  • temperature and/or velocity of blowing air of each air compartment is adjustable such, that by increasing the velocity and lowering the temperature, the temperature of the fiber web is lowered at the same drying efficiency.
  • temperature and/or velocity of blowing air of each air compartment is adjustable such, that by decreasing the velocity and increasing the temperature, the temperature of the fiber web is increased. Thus, the temperature of the fiber web is controlled.
  • running direction of the fiber web in the sizer is substantially, vertically upwards and running direction of the fiber web from the air-borne drying system is substantially vertically downwards or substantially inclined in relation to vertical direction substantially inclined downwards.
  • running direction of the fiber web in the sizer is substantially, vertically downwards and running direction of the fiber web from the air-borne drying system is substantially vertically upwards or substantially inclined in relation to vertical direction substantially inclined upwards.
  • the treatment system for treatment of a fiber web comprises a sizer, which is a curtain sizer with at least one curtain application device for indirect application of sizing agent and comprises two sizing rolls with metallic or ceramic surface or with polymeric surface, which polymeric surface has surface hardness 60 - 100 shoreD, advantageously 80 - 95 shoreD, and forming a sizing nip, which curtain sizer with the indirect application of sizing agent is configured to apply the sizing agent in high solids content of 10 - 60 %, preferably 20 - 40 % and in viscosity of 50 cP- 2000 cP, preferably 100 cP - 1500 cP, wherein that the treatment system further comprises an immediately after the sizer located air-borne drying system such, that the run of the fiber from the sizing nip to beginning of the drying in the air-borne drying system is not more than 2 m, advantageously not more than 0,5 m, and / or takes not more time than 0,5 s.
  • the sizing roll is used a ceramic or metallic roll or advantageously, a roll with a polymeric roll cover (rubber, polyurethane or composite) having surface hardness 60 - 100 shoreD, advantageously 80 - 95 shoreD.
  • the hard sizing nip enhances the strength increase.
  • one of the sizing rolls is a deflection compensated roll.
  • the air-borne drying system is configured to have a substantially U-formed contactless run for the fiber web or a substantially reversed U-formed contactless run in the air-borne drying system for the fiber web.
  • the air-borne drying system comprises at least two, advantageously three air compartments forming chambers of the air-borne drying system and that advantageously temperature and/or velocity of blowing air from each air compartment is adjustable such, that the both sides of the web can be individually controlled.
  • drying of the fiber web can be optimized such, that sorption of water and sizing agent into the base of the fiber web is optimized, advantageously minimized.
  • the drying by the air-borne drying system is contactless. Thus, cleaning and other maintenance work is needed very seldom.
  • maximum blowing air temperature in the air-borne drying system is about 500°C and minimum blowing air temperature is 50°C, advantageously 140-400°C.
  • the run of the fiber web is dynamically air pressure supported such, that moisture and/or temperature differences of the fiber web do not cause curl in the cross direction of the fiber web.
  • blowing air velocity in the air-borne drying system is at least 20 m/s, advantageously 40 - 60 m/s.
  • running direction of the fiber web in the sizer is substantially, vertically upwards and running direction of the fiber web from the air-borne drying system is substantially vertically downwards or substantially inclined in relation to vertical direction substantially inclined downwards.
  • running direction of the fiber web in the sizer is substantially, vertically downwards and running direction of the fiber web from the air-borne drying system is substantially vertically upwards or substantially inclined in relation to vertical direction substantially inclined upwards.
  • the fiber web is sized in the curtain sizer and the sizing agent is applied to the fiber web indirectly, i.e. first applying the sizing agent onto a surface of a roll forming a sizing nip, i.e. onto a surface of a sizing roll, and then applying the sizing agent to the fiber web by the sizing roll.
  • the curtain sizer comprises a slot or a slide nozzle.
  • the sizing agent is starch based sizing agent (uncooked starch or modified starch), carboxy methyl cellulose (CMC) based sizing agent, a substance providing a barrier layer comprising PVA (polyvinyl acetate), PVOH (polyvinyl alcohol), PEF (polyethylene furanoate), PLA (polylactic acid), PET (polyethylene terephthalate), PVdC (polyvinylidene chloride), alginates, chitosan, zein protein or nano-(NFC) or micro-fibrillated cellulose (MFC), or other synthetic or bio-based polymer latexes.
  • PVA polyvinyl acetate
  • PVOH polyvinyl alcohol
  • PEF polyethylene furanoate
  • PLA polylactic acid
  • PET polyethylene terephthalate
  • PVdC polyvinylidene chloride
  • alginates chitosan
  • the fiber web is sized with sizing agent comprising fiber suspension.
  • the fiber web is sized with sizing agent comprising natural fibers and/or synthetic fibers.
  • the sizing agent comprises for example pulp and/or cotton and/or nylon and/or polyester and/or aramid fibers.
  • the fiber web is sized with sizing agent comprising fiber suspension with 0,5 % or less fiber consistency.
  • the fibers can be nanoscale fibers and/or microscale fibers, advantageously, length of a fiber in the sizing agent is 0,1 ⁇ m - 10 mm and width of a fiber in the sizing agent is 0.01 - 30 ⁇ m.
  • the fiber web is treated by first adding the high solids sizing agent in the sizer to the fiber web and by thereafter substantially immediately drying the sizing agent by the air-borne drying system and thus increasing the Young's modulus of at least surface parts of the fiber web.
  • the strength of the fiber web especially the surface strength of the fiber web, is improved as the Young's modulus of at least the surface parts of the fiber web with the sizing agent increases due to increased and/or enhanced bonding of fibers.
  • the strength of the fiber web after the drying is improved 10 - 70%.
  • schematical form of the strength variation in thickness direction of the fiber web corresponds to the form of an I-beam cross section form. Accordingly, also the bending stiffness of the fiber web is improved.
  • linear load in the sizing nip is 5 - 450 kN/m, more preferably the linear load in the sizing nip is 5 - 200 kN/m.
  • the fiber web the high solids content of the sizing agent and the high viscosity of the sizing agent combined with the hard sizing nip of the sizer provide that the sizing agent remains on the surface/surfaces of the fiber web after the sizing in the sizer.
  • the drying in the air-borne drying system configured to dry the sizing agent such, that the sizing agent substantially remains on the surface of the fiber web i.e. only minimally protrudes inside the fiber web provides strength to the surfaces: improved Youngs modulus and steep force-strain curve, which provides improved flexural strength of the fiber web.
  • the drying by the air-borne drying system with hot air blows is configured to provide circumstances, in which the moisture towards the surfaces and the high blow velocity of the hot air blows the moisture mass-transfer with lower partial steam pressure and removes moisture and thus decreases the partial steam pressure the air, which both factors increase diffusion outwards from the moist sizing agent on the surface of the fiber web and thus diffusion and capillary effect towards inside of the fiber web are reduced significantly.
  • sizing agent transfer towards inside the fiber web is decreased.
  • the continued drying and immediately after sizing beginning drying configured by the air-borne drying system significantly prevent moisture sorption by capillary effect.
  • one of the sizing rolls is a deflection compensated roll by which the pressure distribution and speed of the sizing nip can be adjusted in cross-direction of the fiber web and thus substantially uniform speed and uniform pressure distribution in the sizing nip in cross-direction of the fiber web is achieved.
  • the sizing nip is formed between two sizing rolls, one of which is a deflection compensated roll and due to the effect provided by the deflection compensated roll the sizing nip is substantially straight, by which the runnability of the fiber web is improved.
  • the hard sizing nip is formed between the two sizing rolls with metallic or ceramic surface or with polymeric surface, which polymeric surface has surface hardness 60 - 100 shoreD, advantageously 80 - 95 shoreD.
  • the sizing roll is used a ceramic or metallic roll or advantageously, a roll with a hard-polymeric roll cover (rubber, polyurethane or composite) having surface hardness 60 - 100 shoreD, advantageously 80 - 95 shoreD.
  • the hard sizing nip enhances the strength increase.
  • the system in accordance with the invention are to be by configurating an existing fiber web production line, for example by adding the treatment system to a fiber production line without a sizing section at a location after the drying section, as the sizing section with the air-borne drying system or by amending an existing sizing section to be in accordance with the treatment system comprising the hard nip sizer and the air-borne drying system in accordance with the invention.
  • either one or both sides of the fiber web are treated.
  • the method and the system according to an advantageous aspect of the invention are also well applicable in sizing with two-component sizing agent as in this type of curtain sizing there is no return circulation of sizing substance.
  • the two-component sizing agent may harden in the return circulation and thus cause problems in the return circulation.
  • the method and the system according to an advantageous aspect of the invention also sizing agents with platy particle shaped substance suspensions, for example kaolin, can be used as in curtain sizing no metering rods are needed for applicating the sizing substance.
  • sizing agents with platy particle shaped substance suspensions for example kaolin
  • grooves of the metering rods would block if platy particle shaped substance suspensions would be used.
  • the sizing agent can also comprise two-component sizing agent, for example lignin with acidic activator, and/or polymers, for example polyethene and/or polypropylene, and/or mineral fillers and/or particles, for example kaolin in platy particle shape.
  • sizing agents comprising cross-linking substances can be used.
  • the strength, especially the surface strength, of the fiber web is significantly improved.
  • the fiber web is supported and without long free runs, which provides for good runnablility of the fiber web in the treatment section
  • the fiber web with high solids content sizing agent advantageously with fiber suspension, has a stiff structure as the sizing agent tends to remain more in the surface parts of the fiber web and the surface pores close and thus need of calendering is decreased.
  • the air-borne drying provides for contactless drying and support of the surface sized fiber web and thus, adherence problems are avoided.
  • the fiber web sized with sizing agent comprising according to the advantageous feature of the invention fiber suspension improves the adherence of coating color to the surface of the fiber web.
  • sizing in the hard sizing nip between the two sizing rolls with metallic or ceramic surface or with polymeric surface, which polymeric surface has surface hardness 60 - 100 shoreD, advantageously 80 - 95 shoreD does not roughen the surface smoothness of the fiber web as is typical when the sizing nip has a soft sizing roll but instead the surface smoothness increases.
  • the present invention also provides a compact layout of the treatment system.
  • the treatment system comprises a sizer 10 and an air-borne drying system 20 for treating a fiber web W.
  • the sizer 10 is a curtain sizer and comprises two rotating, hard sizing rolls 11A, 11B with metallic or ceramic surface or with polymeric surface, which polymeric surface has surface hardness 60 - 100 shoreD, advantageously 80 - 95 shoreD, between of which a hard sizing nip N is formed.
  • linear load in the sizing nip is 5 - 450 kN/m, more preferably the linear load in the sizing nip is 5 - 200 kN/m.
  • One of the sizing rolls 11A;11B is advantageously a deflection compensated roll and thus a straight sizing nip N is formed.
  • the sizing rolls is used ceramic or metallic rolls or advantageously with a polymeric roll cover (rubber, polyurethane or composite) having surface hardness 60 - 100 shoreD, advantageously 80 - 95 shoreD.
  • the fiber web W is sized by indirect curtain sizing i.e.
  • sizing agent TA, TB is first applied by a curtain sizing device 12A, 12B on the surface of the sizing roll 11A, 11B and guided on the surfaces of the rotating sizing rolls 11A, 11B to the sizing nip N, in which the sizing agent TA, TB is applied on both sides of the fiber web W.
  • the sizing agent TA, TB is thus via the surfaces of the sizing rolls 11A, 1B guided onto the surfaces of the fiber web W such that in the sizing nip N the sizing agent TA, TB is pressed to the fiber web surfaces.
  • the sizing agent TA; TB may also be applied only on one of the sides of the fiber web W, in which case the sizer may comprise only one curtain sizing device 12A; 12B for applying the sizing agent TA; TB on the corresponding rotating, sizing roll 11A; 11B.
  • the fiber web W is directly guided to drying in the air-borne drying system 20.
  • the run of the fiber web W from the sizing nip N to beginning of the drying in the air-borne drying system 20 is not more than 2 m, advantageously not more than 0,5 m, and / or takes not more than 0,5 s.
  • the air-borne drying system 20 is shown as a schematical cross-sectional.
  • the air-borne drying system 20 extends substantially over the width of the fiber web W.
  • the fiber web W is dried by contactless drying by hot air blows, which blows also support the run of the fiber web W such, that the fiber web W runs contactless through the air-borne drying system 20 supported by the hot, drying air blows.
  • the air-borne drying system 20 comprises at least two, advantageously three in, the example five air compartments 13A, 13B, 14A, 14B, 15 forming chambers of the air-borne drying system 20.
  • Each air compartment 13A, 13B, 14A, 14B, 15 is advantageously adjustable such, that the both sides of the web can be individually controlled, which provides possibility of planning and controlling the optimum drying strategy and also for the possibility of controlling curl of the fiber web.
  • the drying is controlled one-sidedly such, that more effective drying is configured to be provided on one side of the fiber web W compared to the other side of the fiber web W.
  • five drying temperature zones for drying the fiber web W can be provided.
  • the fiber web W has a substantially U-formed contactless run in the air-borne drying system 20 ( figs 2 and 3 ) or a substantially reversed U-formed contactless run in the air-borne drying system 20 ( figs. 1 and 4 ).
  • Two of the air compartments 13A, 13B are rectangular, box-type air chambers and located outside the substantially straight branches of the U-form of the reversed U-form.
  • Two of the air compartments 14A, 14B are rectangular ( figs. 1-2 ), or at least partially oblique angled box-type air chambers and located inside the substantially straight branched of the U-form or of the reversed U-form and located next to each other with two longitudinal "back" sides towards each other i.e. the sides without nozzles are located towards each other and the sides with nozzles towards the passing fiber web W.
  • the fifth air compartment 15 is a turning air compartment, as a substantially curved outer, advantageously semi-circular outer surface and located inside the curved part of the U-form or of the reversed U-form with the straight surface towards the surfaces of other two air compartments 14A, 14B inside the U-form or the reversed U-form.
  • the branches of the U-form or of the reversed U-form are substantially parallel and in the examples of figure 3-4 the branches of the U-form or of the reversed U-form are substantially inclined and recede from each other from the curved part of the U-form or of the reversed U-form.
  • Radius of the curved air compartment 15 is advantageously 800 - 1200 mm.
  • the height of the box-type air compartments 13A, 13B, 14A, 14B in the running direction S, SE of the fiber web W is advantageously 800 - 1200 mm and have advantageously minimum width of 5 - 6 m in perpendicular direction in respect of the running direction S, SE of the fiber web W.
  • the configuration of air-borne drying system 20 is thus such, that the fiber web W has first a longitudinal, straight run thereafter a semi-circular run and next another longitudinal, straight run.
  • the air-borne drying system 20 comprises thus the straight portions and the curved, turning portion.
  • each air compartment 13A, 13B, 14A, 14B, 15 is configured to blow hot drying air blows for drying the passing fiber web W.
  • the air-borne drying system 20 is a double-pass dryer system configured to the U-shaped air dryer system.
  • the drying air of the air-borne drying system 20 can also superheated steam or other gas than air, for ex. nitrogen.
  • the maximum blowing air temperature is advantageously about 500°C and the minimum blowing air temperature is 50°C, advantageously 140-400°C.
  • the blowing velocity of the hot air blows is at least 20 m/s, advantageously 40 - 60 m/s.
  • Various types of nozzles can be used in connection with the air compartments, advantageously the nozzles are overpressure-nozzles.
  • the fiber web running in direction S in the sizer 10 and is sized with high solids content sizing agent comprising advantageously fiber suspension, preferably 10-60 % solids content, more preferably 20 - 40 % solids content.
  • Viscosity of the sizing agent is 50 cP - 2000 cP, preferably 100 cP - 1500 cP and surface tension of the sizing agent is advantageously 50 mN/m.
  • the running direction S of the fiber web W in the sizer 10 is substantially, vertically upwards. In the examples of figures 2 and 3 the running direction S of the fiber web W in the sizer 10 is substantially, vertically downwards.
  • the running direction SE of the fiber web W from the air-borne drying system 20 is substantially vertical.
  • the running direction SE of the fiber web W from the air-borne drying system 20 is substantially vertically downwards and in the example of the figure 2 the running direction SE of the fiber web W from the air-borne drying system 20 is substantially vertically upwards.
  • the running direction SE of the fiber web W from the air-borne drying system 20 is substantially inclined in relation to vertical direction.
  • the running direction SE of the fiber web W from the air-borne drying system 20 is substantially inclined upwards and in the example of the figure 4 the running direction SE of the fiber web W from the air-borne drying system 20 is substantially vertically inclined downwards.

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Claims (15)

  1. Procédé de traitement d'une bande de matière fibreuse, dans lequel procédé la bande de matière fibreuse est encollée dans une encolleuse (10) par encollage indirect à rideau dans une encolleuse à rideau (10) dans laquelle l'agent d'encollage (TA, TB) est appliqué sur au moins une face de la bande de matière fibreuse par deux rouleaux d'encollage (11A, 11B) dotés d'une surface métallique ou céramique ou d'une surface polymérique, laquelle surface polymérique a une dureté de surface de 60 à 100 Shore D, avantageusement 80 à 95 Shore D, dans un interstice d'encollage (N) dans lequel la bande de matière fibreuse (W) est encollée avec de l'agent d'encollage à forte teneur en solides (TA, TB) ayant une teneur en solides de 10 à 60 %, de préférence de 20 à 40 %, et une viscosité de 50 cP à 2000 cP, de préférence 100 cP à 1500 cP, et l'agent d'encollage (TA ; TB) est appliqué sur l'au moins une face de la bande de matière fibreuse (W) par les deux rouleaux d'encollage (11A, 11B) dans l'interstice d'encollage (N), caractérisé en ce que, après l'encollage, la bande de matière fibreuse (W) est guidée directement vers un séchage sans contact et assisté dans un système de séchage aéroporté (20) et que le passage de la bande de matière fibreuse (W) de l'interstice d'encollage (N) au début du séchage dans le système de séchage aéroporté (20) ne se produit pas sur plus de 2 m, avantageusement plus de 0,5 m, et/ou ne prend pas plus de temps que 0,5 s.
  2. Procédé selon la revendication 1, caractérisé en ce que, dans le procédé, la bande de matière fibreuse (W) est configurée de manière à pouvoir un passage sans contact sensiblement en forme de U dans le système de séchage aéroporté (20) (figures 2 et 3) ou un passage en forme de U sensiblement inversé sans contact dans le système de séchage aéroporté (20) (figures 1 et 4).
  3. Procédé selon la revendication 1 ou 2, caractérisé en ce que, dans le procédé, la température maximale d'air de soufflage dans le système de séchage aéroporté (20) est d'environ 500 °C et la température minimale d'air de soufflage et de 50 °C, avantageusement 140 à 400 °C.
  4. Procédé selon l'une quelconque des revendications 1 à 3, caractérisé en ce que, dans le procédé, la vitesse de l'air de soufflage dans le système de séchage aéroporté (20) est d'au moins 20 m/s, avantageusement 40 à 60 m/s.
  5. Procédé selon l'une quelconque des revendications 1 à 4, caractérisé en ce que le système de séchage aéroporté (20) comprend au moins deux, avantageusement trois, compartiments à air (13A, 13B, 14A, 14B, 15) formant des chambres du système de séchage aéroporté (20) et que la température et/ou la vitesse de l'air de soufflage de chaque compartiment à air (13A, 13B, 14A, 14B, 15) est avantageusement réglable.
  6. Procédé selon l'une quelconque des revendications 1 à 5, caractérisé en ce que le sens de circulation (S) de la bande de matière fibreuse (W) dans l'encolleuse (10) est dirigé sensiblement verticalement vers le haut et le sens de circulation (SE) de la bande de matière fibreuse (W) depuis le système de séchage aéroporté (20) est dirigé sensiblement verticalement vers le bas ou sensiblement incliné par rapport au sens vertical sensiblement incliné vers le bas.
  7. Procédé selon l'une quelconque des revendications 1 à 5, caractérisé en ce que le sens de circulation (S) de la bande de matière fibreuse (W) dans l'encolleuse (10) est dirigé sensiblement verticalement vers le bas et le sens de circulation (SE) de la bande de matière fibreuse (W) depuis le système de séchage aéroporté (20) est dirigé sensiblement verticalement vers le haut ou sensiblement incliné par rapport au sens vertical sensiblement incliné vers le haut.
  8. Système de traitement pour le traitement d'une bande de matière fibreuse, lequel système de traitement comprend une encolleuse (10) qui est une encolleuse à rideau (10) dotée d'au moins un dispositif d'application à rideau (12A ; 12B) pour l'application indirecte d'agent d'encollage (TA; TB) et comprend deux rouleaux d'encollage (11A, 11B) dotés d'une surface métallique ou céramique ou d'une surface polymérique, laquelle surface polymérique a une dureté de surface de 60 à 100 Shore D, avantageusement 80 à 95 Shore D, et formant un interstice d'encollage (N), laquelle encolleuse à rideau (10) avec application indirecte d'agent d'encollage (TA, TB) étant configurée pour appliquer l'agent d'encollage à forte teneur en solides (TA, TB) de 10 à 60 %, de préférence de 20 à 40 %, et une viscosité de 50 cP à 2000 cP, de préférence 100 cP à 1500 cP, caractérisé en ce que le système de traitement comprend en outre un système de séchage aéroporté (20) situé juste en aval de l'encolleuse (10) de manière à ce que le passage de la bande de matière fibreuse (W) de l'interstice d'encollage (N) au début du séchage dans le système de séchage aéroporté (20) ne se produise pas sur plus de 2 m, avantageusement plus de 0,5 m, et/ou ne prenne pas plus de temps que 0,5 s.
  9. Système de traitement selon la revendication 8, caractérisé en ce que l'un des rouleaux d'encollage (11A; 11B) est un rouleau compensé par déflection.
  10. Système de traitement selon la revendication 8 ou 9, caractérisé en ce que le système de séchage aéroporté est configuré de manière à avoir un passage sans contact sensiblement en forme de U pour la bande de matière fibreuse (W) (figures 2 et 3) ou un passage sans contact sensiblement en forme de U inversé dans le système de séchage aéroporté (20) pour la bande de matière fibreuse (W) (figures 1 et 4).
  11. Système de traitement selon l'une quelconque des revendications 8 à 10, caractérisé en ce que le système de séchage aéroporté (20) comprend au moins deux, avantageusement trois, compartiments à air (13A, 13B, 14A, 14B, 15) formant des chambres du système de séchage aéroporté (20) et que la température et/ou la vitesse de l'air de soufflage de chaque compartiment à air (13A, 13B, 14A, 14B, 15) est avantageusement réglable.
  12. Système de traitement selon l'une quelconque des revendications 8 à 11, caractérisé en ce que la température maximale d'air de soufflage dans le système de séchage aéroporté (20) est d'environ 500 °C et la température minimale d'air de soufflage est de 50 °C, avantageusement 140 à 400 °C.
  13. Système de traitement selon l'une quelconque des revendications 8 à 12, caractérisé en ce que la vitesse d'air de soufflage dans le système de séchage aéroporté (20) est d'au moins 20 m/s, avantageusement 40 à 60 m/s.
  14. Système de traitement selon l'une quelconque des revendications 8 à 13, caractérisé en ce que le sens de circulation (S) de la bande de matière fibreuse (W) dans l'encolleuse (10) est dirigé sensiblement verticalement vers le haut et le sens de circulation (SE) de la bande de matière fibreuse (W) depuis le système de séchage aéroporté (20) est dirigé sensiblement verticalement vers le bas ou sensiblement incliné par rapport au sens vertical sensiblement incliné vers le bas.
  15. Système de traitement selon l'une quelconque des revendications 8 à 13, caractérisé en ce que le sens de circulation (S) de la bande de matière fibreuse (W) dans l'encolleuse (10) est dirigé sensiblement verticalement vers le bas et le sens de circulation (SE) de la bande de matière fibreuse (W) depuis le système de séchage aéroporté (20) est dirigé sensiblement verticalement vers le haut ou sensiblement incliné par rapport au sens vertical sensiblement incliné vers le haut.
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JAMES M. RENNES: "METERING SIZE PRESS DRYING", TAPPI METERED SIZE PRESS FORUM 2002, 1 May 2002 (2002-05-01) - 4 May 2002 (2002-05-04), pages 79 - 98, XP093198165, ISBN: 1-930657-91-9

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US20220170192A1 (en) * 2019-03-26 2022-06-02 Resolute Fp Canada, Inc. Curled fiber mats and methods of making and using same
US12104298B2 (en) * 2019-03-26 2024-10-01 Resolute Fp Canada, Inc. Curled fiber mats and methods of making and using same

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