EP3884092A1 - Procédé et dispositif pour le filage à l'état fondu de filaments - Google Patents

Procédé et dispositif pour le filage à l'état fondu de filaments

Info

Publication number
EP3884092A1
EP3884092A1 EP19805958.6A EP19805958A EP3884092A1 EP 3884092 A1 EP3884092 A1 EP 3884092A1 EP 19805958 A EP19805958 A EP 19805958A EP 3884092 A1 EP3884092 A1 EP 3884092A1
Authority
EP
European Patent Office
Prior art keywords
melt
pet
recycling
degassing
recycled
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP19805958.6A
Other languages
German (de)
English (en)
Inventor
Klaus Schäfer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BB Engineering GmbH
BTI Holding SE
Original Assignee
BB Engineering GmbH
BTI Holding SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102018009171.7A external-priority patent/DE102018009171A1/de
Priority claimed from DE102019004051.1A external-priority patent/DE102019004051A1/de
Application filed by BB Engineering GmbH, BTI Holding SE filed Critical BB Engineering GmbH
Publication of EP3884092A1 publication Critical patent/EP3884092A1/fr
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/0005—Direct recuperation and re-use of scrap material during moulding operation, i.e. feed-back of used material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
    • B29B7/748—Plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/80—Component parts, details or accessories; Auxiliary operations
    • B29B7/84—Venting or degassing ; Removing liquids, e.g. by evaporating components
    • B29B7/845—Venting, degassing or removing evaporated components in devices with rotary stirrers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/80—Component parts, details or accessories; Auxiliary operations
    • B29B7/86—Component parts, details or accessories; Auxiliary operations for working at sub- or superatmospheric pressure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00—Treatment of filament-forming or like material
    • D01D1/06—Feeding liquid to the spinning head
    • D01D1/065—Addition and mixing of substances to the spinning solution or to the melt; Homogenising
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F13/00—Recovery of starting material, waste material or solvents during the manufacture of artificial filaments or the like
    • D01F13/04—Recovery of starting material, waste material or solvents during the manufacture of artificial filaments or the like of synthetic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/0026—Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04—Disintegrating plastics, e.g. by milling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0213—Specific separating techniques
    • B29B2017/0217—Mechanical separating techniques; devices therefor
    • B29B2017/0224—Screens, sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/365—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using pumps, e.g. piston pumps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50—Details of extruders
    • B29C48/69—Filters or screens for the moulding material
    • B29C48/694—Cylindrical or conical filters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50—Details of extruders
    • B29C48/76—Venting, drying means; Degassing means
    • B29C48/762—Vapour stripping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50—Details of extruders
    • B29C48/76—Venting, drying means; Degassing means
    • B29C48/763—Vent constructions, e.g. venting means avoiding melt escape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/003—PET, i.e. poylethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/26—Scrap or recycled material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/52—Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Definitions

  • the invention relates to a method for melt spinning filaments made of a polyester and to a device for melt spinning filaments made of a polyester according to the preamble of claim 11.
  • the polymer melt In the production of synthetic threads from a polymer melt, it is customary for the polymer melt to be extruded into the finest filaments by means of a spinneret through a large number of capillary-shaped nozzle openings. After cooling, the filaments are brought together to form a thread or fiber strand and, depending on the end product, are subjected to several treatment steps. The strength and elongation of the filaments play an important role here. Therefore, the polymer melt, in particular in its melt viscosity, must have constant and always constant properties. In the case of a polyester in particular, irregularities in the flow of the melt or in the production of the melt should be avoided.
  • the molecular structure of polyester is determined by long molecular chains, which disintegrate relatively quickly under thermal stress.
  • the polymer melt required for melt spinning polyester threads is therefore generated by a polycondensation plant.
  • Such polycondensation plants usually produce more than 100 tons of melt per day, so that a plurality of spinning devices are used in parallel to produce threads. Due to the large number of spinning devices, relatively large amounts of fiber waste occur, which have to be collected and transported by truck.
  • the invention frees itself from the reservation that melted fiber wastes have an insufficient melt viscosity due to chain degradation of the molecular chains in the polyester, which the spinning of filaments in particular does not guarantee the uniformity for producing physical properties on the filaments. It is known, for example, that in the event of chain breakdown, the binding sites are blocked by water retention in the polyester. Thanks to intensive processing of the fiber waste, it has now surprisingly been possible to generate a PET recycled melt from the fiber waste, which enables an admixture into a PET melt. The melt flow generated from the PET melt and the PET recycled melt by dynamic mixing enables the filaments to be spun continuously and evenly.
  • the device according to the invention has a recycling device for melting and processing fiber waste into a PET recycling melt, which interacts with the melt generating device in order to generate the melt flow from the PET melt and the PET recycling melt for extruding filaments.
  • the process variant is preferred, in which the processing in the PET recycled melt produces a melt viscosity of at least> 95% of the melt viscosity of the PET melt. This also allows the usual physical properties to be achieved on the filament.
  • the melt viscosity of the melt flow can then be increased even further by combining the PET recycled melt and the PET melt in a mixing ratio such that the melt flow has a melt viscosity of at least> 97% of the melt viscosity of the PET melt. Approximately the melt values of the polyester generated by a polycondensation plant can thus be achieved.
  • the device according to the invention has, according to a further development, a dynamic mixing device which enables a uniform and intensive mixing of the PET melt with the PET recycled melt.
  • a dynamic mixing device which enables a uniform and intensive mixing of the PET melt with the PET recycled melt.
  • the process variant in which the PET recycled melt is filtered and degassed under a vacuum atmosphere is particularly advantageous.
  • By filtering in a vacuum atmosphere large-area contact zones between the melt and a vacuum atmosphere can be realized, so that the volatile constituents can dissolve in a relatively short residence time.
  • the binding sites in the short chains of the molecules can be activated in order to intensify the chain structure.
  • the recycling device has a heated degassing device with at least one filter element and a vacuum chamber, the PET recycling melt being able to be passed through the filter element into a vacuum atmosphere of the vacuum chamber.
  • the process variant is provided in which the PET recycled melt is preferably at a temperature in the range from 270 ° C. to 330 ° C. in a range from 285 ° C. to 295 ° C. is filtered and degassed.
  • the chain structure of the molecular structure of the polyester is thus further improved.
  • a vacuum atmosphere of 0.5 mbar to max. 50 mbar is preferably set between 1 mbar and 10 mbar.
  • large contact surfaces can be created on the melt surface.
  • the device according to the invention has a vacuum pump which is connected to the vacuum chamber of the degassing device.
  • the degassing of the PET recycled melt can also be improved by feeding the PET recycled melt to a residence reactor after the filtration and degassing for homogenization and for continuing the degassing.
  • the quality of the PET recycled melt for the extrusion of filaments can thus be further improved.
  • the recycle device can be supplemented by a dwell reactor which is connected to a melt outlet of the degassing device and which has a vacuum connection for a vacuum pump.
  • Dynamic mixing is provided so that the melt flow from the PET recycled melt and the PET melt also have a particular homogeneity.
  • the dynamic mixer is connected to the melt generator and connected to the recycling device by a metering pump. In this way, any mixing ratio for generating the melt flow between the PET melt and the PET recycled melt can be set.
  • the recycling device has a melt extruder which is connected by a transport system to a waste collecting container which is assigned to the spinning devices.
  • the waste collection container contains a plurality of collection points, each of which is assigned to the spinning device. It is essential here that the fiber waste occurring in the spinning or process interruption in the spinning devices is fed directly to the recycling device.
  • at least one filter device and one melt pump are arranged downstream of the melt extruder. This enables a rough pre-filtration to be achieved.
  • the fiber waste is shredded before melting and agglomerated in the heated state.
  • the fiber waste is heated briefly below half the melting temperature so that a large proportion of water evaporates.
  • the recycling device has a comminution device and an agglomerator, which are arranged upstream of the melting extruder and which prepare the fiber waste supplied for melting.
  • Fig. F schematically shows a first embodiment of the inventive device for melt spinning filaments
  • Fig. 2 schematically shows another embodiment of the device according to the invention for melt spinning filaments
  • FIG. 3 schematically shows a cross-sectional view of an exemplary embodiment of a degassing device of the exemplary embodiment from FIG. F
  • a first embodiment of the Vorrich device according to the invention for melt spinning filaments is shown schematically.
  • the exemplary embodiment has a spinning device 2, which has a large number of spinning positions for producing synthetic threads.
  • the first three spinning positions 3.1, 3.2 and 3.3 are only shown as examples.
  • a large number of filaments are extruded into each of the spinning positions and are bundled together to form several threads.
  • the threads are drawn off as a family of threads after extrusion and wound up into bobbins at the end.
  • the design of the spinning device 2 is known and exemplary and is therefore not explained in detail here.
  • the filaments of several spinning positions can also be brought together to form fiber strands, which are processed, for example, into staple fibers.
  • the spinning positions 3.1, 3.2 and 3.3 are connected to a main melt line 14, through which a melt flow is fed to the spinning positions 3.1 to 3.3 for extruding the filaments.
  • the main melt line 14 is connected to a mixing device 12.
  • the mixing device 12 is designed as a dynamic mixer and has a mixer drive 12.1 which drives the mixing elements 12.2 arranged within the mixing device 12.
  • the mixing device 12 is connected via a melt line 13.1 to a melt generator device 1.
  • the melt generator device 1 could be formed, for example, by a polycondensation plant. Alternatively, however, there is also the possibility that the melt generator device 1 is formed by an extruder at relatively few spinning positions.
  • the mixing device 12 is connected to a recycle device 4 via a second melt line 13.2.
  • the recycle device 4 serves to melt and process fiber waste which occurs in the spinning positions of the spinning device 2 during a process start or a process failure.
  • the spinning device 2 is assigned a waste collection container 5 in this embodiment.
  • the waste collection container 5 is used to hold all waste Waste that occurs in the spinning positions 3.1, 3.2 and 3.3, for example when piecing or during a process interruption or when changing the bobbin.
  • the fiber waste can be automated or manually guided into the waste container 5.
  • the waste collection container 5 may also contain facilities for shredding the fiber waste.
  • the waste collection container 5 is connected to a melt extruder 7 of the recycling device 4 via a transport system 6.
  • a conveying line is shown as the transport system 6, through which the fiber waste is conveyed pneumatically to the melt extruder 7.
  • the recycling device 4 has in addition to the melt extruder 7, a Filtervor direction 8, a melt pump 9, a degassing device 10 and a Do sierpumpe 11.
  • the melt extruder 7 can have one or more shafts and is connected to the filter device 8 on an outlet side.
  • the filter device 8 is followed by the melt pump 9, which is driven by a pump drive 9.1.
  • the melt pump 9 is connected to the degassing device 10.
  • the degassing device 10 has a melt outlet 10.7, which is assigned to a metering pump 11.
  • the metering pump 11 is driven by a pump drive 11.1 at a predetermined speed.
  • the metering pump 11 is connected to the melt line 13.2, so that the partial flow generated by the metering pump 11 is fed to a PET recycling melt of the mixing device 12.
  • the degassing device 10 has a housing 10.1, which is cylindrical in this case.
  • a vacuum chamber 10.2 is formed within the housing 10.1.
  • Within the vacuum chamber 10.2 there are several filter elements 10.4 arranged in the form of hollow cylindrical filter cartridges.
  • the filter elements 10.4 have a pressure chamber 10.5 inside, which is connected to a melt inlet 10.6 on the housing 10.1.
  • the filter elements 10.4 are closed at the free cantilever end and have a permeable filter wall.
  • a sump 10.8 is formed in the vacuum chamber below the free ends of the filter elements 10.4.
  • the sump 10.8 is connected to a melt outlet 10.7 in the housing 10.1.
  • the melt outlet 10.7 is arranged centrally on the bottom of the housing 10.1, the sump 10.8 extending in a funnel shape above the melt outlet 10.7.
  • the vacuum chamber 10.2 is connected via a vacuum connection 10.3 to a collector 10.10 and a vacuum pump 10.11.
  • a heating device 10.9 is arranged on the circumference of the housing 10.1.
  • the heating device 10.9 preferably has electrical heating means, which are not shown here.
  • FIGS. 1 and 3 To explain the function of the recycling device 4, reference is now made to FIGS. 1 and 3.
  • the comminuted fiber waste is fed to the melting extruder 7, which could alternatively also be designed with a vacuum unit.
  • the melting zeextruder 7 melts the fiber waste into a PET recycled melt, which is fed to the filter device 8 via an extruder outlet 7.1.
  • the PET recycled melt is pre-filtered with a relatively large filter fineness under pressure in order to remove foreign particles and unmelted polyester materials from the PET recycled melt.
  • the filtration of the PET recycled melt takes place in an overpressure atmosphere which is generated by the extruder 7.
  • the pre-filtered PET recycling melt is from the Melt pump 9 is added and supplied to the degassing device 10 under a predefined operating pressure.
  • the PET recycled melt reaches the pressure chamber 10.5 of the degassing device 10 via the melt inlet 10.6 and penetrates the filter elements 10.4.
  • the PET recycled melt enters the vacuum chamber 10.2 of the degassing device 10.
  • Inside the vacuum chamber 10.2, a vacuum atmosphere is generated via the vacuum pump 10.11.
  • the vacuum atmosphere is set to a value in the range from 0.5 mbar to max. 50 mbar.
  • a vacuum in the vacuum chamber 10.2 of 1 mbar to 10 mbar is preferably set.
  • the degassing device 10 is heated by the heating device 10.9 to a temperature which is preferably in the range from 270 ° C. to 330 ° C. in the range from 285 ° C. to 295 ° C.
  • the water components contained in the PET recycled melt are dissolved. Due to the vacuum atmosphere, the dissolving gases and vapors are drawn out of the PET recycled melt and discharged from the vacuum chamber 10.2 via the vacuum connection 10.3 and separated into the collecting container 10.10. Through the escape and removal of the water components, reactive binding sites are formed on the molecular chains, which enables the molecules to build up a chain and thus leads to an increased melt viscosity. After a short dwell time, a melt viscosity was generated in the PET recycled melt that is above 95% in relation to the melt viscosity of a PET melt. In particular, a relatively high vacuum and high temperatures favor the chain structure of the PET recycling melt.
  • the PET recycled melt prepared by degassing and filtration collects in the sump 10.8 at the bottom of the housing 10.1 and leaves the degassing device 10 via the melt outlet 10.7. From the melt outlet 10.7, the processed PET recycled melt reaches a metering pump 11. The metered pump 11 is driven at a predetermined pump speed by the pump drive 11.1 such that a predetermined flow rate of the PET recycled melt is generated and fed to the mixing device 12.
  • a PET melt supplied via the melt line 13.1 is dynamically mixed with the PET recycled melt.
  • the mixing device 12 generates a melt flow therefrom, which is fed to the spinning device 2 via the main melt line 14 on the outlet side.
  • a predetermined mixing ratio between the PET melt, which is produced, for example, by a polycondensation plant, and the PET recycled melt can also further improve the melt viscosity of the melt flow that is fed to the spinning device 2. So there is the possibility that the melt viscosity of the melt flow is in the range above 97% of the melt viscosity of the PET melt. This enables very stable and uniform spinning processes for the production of high quality threads.
  • a secondary extruder 17 is arranged in the exemplary embodiment according to FIG. 1 of the mixing device 12, through which an additive is fed.
  • the additive is mixed thoroughly with the PET melt and the PET recycled melt.
  • the melt flow then generated is fed via the main melt line 14 to the spinning device.
  • the device according to the invention and the method according to the invention thus have the great advantage that the fiber waste arising in the process is immediately returned to the melting circuit. There is no external disposal of the fiber waste.
  • FIG. 2 a further exemplary embodiment of the device according to the invention is shown schematically in FIG. 2.
  • the embodiment of FIG. 2 is essentially identical to the embodiment of FIG. 1, so that only the differences are explained at this point and otherwise reference is made to the aforementioned description.
  • the degassing device 4 is coupled to a residence reactor 16.
  • the degassing device 10 is connected to the induction reactor 16 on an outlet side in a bottom region 10.12.
  • the filtered and degassed PET recycling melt of the degassing device 10 is now fed directly to an inlet area of the residence reactor 16.
  • the indwelling reactor 16 has a vacuum connection 16.2 on an outlet side.
  • the vacuum connection 16.2 is connected to a separate vacuum pump (not shown here in more detail) or alternatively to the vacuum pump 10.11 of the degassing device 10.
  • a driven screw shaft 16.1 is arranged inside the indwelling reactor 16 and feeds the PET recycled melt to a reactor outlet 16.3.
  • a discharge extruder 18 is directly coupled to the reactor outlet 16.3 in order to discharge the filtered and degassed PET recycling melt.
  • the discharge extruder 18 is followed by a discharge pump 19 and an end filter device 15.
  • the end filter device 15 is arranged in the melt line 13.2 and thus the mixing device 12 is arranged upstream.
  • the degassing and ho mogenization of the PET recycled melt is intensified by the additional dwell actuator 16. In this way, other gases and vapors that can be safely removed from the plastic melt can be removed via the vacuum connection 16.2.
  • the PET recycled melts produced in this way have an intrinsic viscosity with an IV value> 0.8.
  • 4 shows a further exemplary embodiment of a recycling device 4, such as would be used, for example, in the exemplary embodiments of the device according to the invention according to FIG. 1 or FIG. 2.
  • a supplied fiber waste is first comminuted in a pre-comminution device 20 and then agglomerated in an agglomerator 21 in the heated state.
  • a large proportion of water can be removed from the fiber waste by evaporation even before melting.
  • the upstream water extraction enables a further improvement in the processing of the PET recycled melt.
  • the agglomerates can then be fed directly to the melt extruder 7.
  • the melt extruder 7 has a vacuum connection 7.1, which is connected to a vacuum pump 10.11.
  • a vacuum pump 10.11 In this way, pre-degassing and thus further water removal can be achieved when the fiber waste is melted.
  • the melted fiber waste is conveyed into the degassing device 10 by means of a melt pump 9 after a pre-filtration by the filter device 8.
  • the degassing device 10 is designed according to the exemplary embodiment according to FIG. 3, so that after filtering and degassing the PET recycled melt can be removed by a metering pump 11 and a further filter device 22.
  • the embodiment of the recycling device shown in FIG. 4 is therefore particularly suitable for, on the one hand, volatile impurities such as, for example, spin oils or preparation liquids, and solid impurities such as e.g. To remove dust and degradation products from the fiber waste and, on the other hand, to maintain an intensive chain structure to increase the melt viscosity.
  • volatile impurities such as, for example, spin oils or preparation liquids
  • solid impurities such as e.g.
  • the inventive method and the inventive device for melt spinning filaments made of polyester is suitable for all known melt spinning processes in which fiber waste occurs.
  • the integration of the recycling facility means that separate recycling of the fiber waste is no longer necessary.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Sustainable Development (AREA)
  • Environmental & Geological Engineering (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

La présente invention concerne un procédé et un dispositif pour le filage à l'état fondu de filaments à partir d'un polyester. Une pluralité de filaments est donc extrudée par un dispositif de filage à partir d'un courant de matière fondue. Le courant de matière fondue est produit par mélange intensif à partir de PET fondu d'un dispositif produisant de la matière fondue et à partir de PET fondu recyclé d'un dispositif de recyclage.
EP19805958.6A 2018-11-22 2019-11-19 Procédé et dispositif pour le filage à l'état fondu de filaments Pending EP3884092A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102018009171.7A DE102018009171A1 (de) 2018-11-22 2018-11-22 Verfahren und Vorrichtung zum Recyceln von Kunststoffen
DE102019004051.1A DE102019004051A1 (de) 2019-06-07 2019-06-07 Verfahren und Vorrichtung zum Schmelzspinnen von Filamenten
PCT/EP2019/081758 WO2020104434A1 (fr) 2018-11-22 2019-11-19 Procédé et dispositif pour le filage à l'état fondu de filaments

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EP3884092A1 true EP3884092A1 (fr) 2021-09-29

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CN (1) CN113166977B (fr)
WO (1) WO2020104434A1 (fr)

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Publication number Priority date Publication date Assignee Title
DE102020119505A1 (de) * 2020-07-23 2022-01-27 Gottfried Wilhelm Leibniz Universität Hannover, Körperschaft des öffentlichen Rechts Verfahren und Einrichtung zum Trennen unterschiedlicher Kunststoffsorten von einem Materialgemisch
BR102021025568B1 (pt) * 2021-12-17 2023-01-17 Senai/Cetiqt - Serviço Nacional De Aprendizagem Industrial-Centro De Tecnologia Da Indústria Química E Têxtil Processo de reaproveitamento de resíduos têxteis sintéticos para obtenção de fio contínuo
AT525834B1 (de) * 2022-02-11 2024-01-15 Erema Eng Recycling Maschinen & Anlagen Gmbh Vorrichtung zur Bearbeitung von Materialien

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4138374A (en) * 1978-02-03 1979-02-06 E. I. Du Pont De Nemours And Company Process for manufacturing shaped polyester article using scrap materials
FR2439074A1 (fr) * 1978-10-18 1980-05-16 Rhone Poulenc Textile Procede de regeneration de polymere a partir de dechets
DE3206203C2 (de) * 1982-02-20 1983-12-15 Norddeutsche Faserwerke GmbH, 2350 Neumünster Verfahren zur Verwertung von Abfällen schmelzgesponnener Fasern
DD216723A1 (de) * 1983-07-18 1984-12-19 Guben Chemiefaserwerk Verfahren zur wiederverwendung fadenfoermiger, thermisch beanspruchter polyesterabfaelle
DE19811280C2 (de) * 1998-03-12 2002-06-27 Inventa Fischer Gmbh Verfahren und Vorrichtung zur Rückgewinnung von linearem Polyester
DE10063286A1 (de) 2000-12-19 2002-06-20 Zimmer Ag Verfahren zum Spinnen und Aufspulen von PET-Filamenten
CN103911681B (zh) * 2014-04-14 2015-12-02 杭州华尔利化纤有限公司 一种利用回收的pet瓶制造纺织用长丝的方法
CN108251901B (zh) * 2017-12-29 2021-05-11 黎明职业大学 一种掺加废旧非织造布再生料制备纤维的方法

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WO2020104434A1 (fr) 2020-05-28
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