EP3829845A1 - Matériaux composites recyclés et procédés associés - Google Patents
Matériaux composites recyclés et procédés associésInfo
- Publication number
- EP3829845A1 EP3829845A1 EP19843254.4A EP19843254A EP3829845A1 EP 3829845 A1 EP3829845 A1 EP 3829845A1 EP 19843254 A EP19843254 A EP 19843254A EP 3829845 A1 EP3829845 A1 EP 3829845A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- recycled
- composite material
- composite
- wind turbine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 86
- 238000000034 method Methods 0.000 title description 8
- 239000000203 mixture Substances 0.000 claims abstract description 78
- 239000004566 building material Substances 0.000 claims abstract description 27
- 239000002245 particle Substances 0.000 claims description 35
- 239000000835 fiber Substances 0.000 claims description 25
- 229920000642 polymer Polymers 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 229920001903 high density polyethylene Polymers 0.000 claims description 13
- 239000004700 high-density polyethylene Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000002952 polymeric resin Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 229920003002 synthetic resin Polymers 0.000 claims description 10
- 238000001125 extrusion Methods 0.000 claims description 8
- -1 polyethylene terephthalate Polymers 0.000 claims description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- 239000011208 reinforced composite material Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 239000011152 fibreglass Substances 0.000 description 21
- 239000000463 material Substances 0.000 description 12
- 239000008188 pellet Substances 0.000 description 6
- 239000002699 waste material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 241000264877 Hippospongia communis Species 0.000 description 1
- 241000256602 Isoptera Species 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 240000007182 Ochroma pyramidale Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000011246 composite particle Substances 0.000 description 1
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- 150000001875 compounds Chemical class 0.000 description 1
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- 230000000593 degrading effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
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- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/02—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type
- B29B7/06—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices
- B29B7/10—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary
- B29B7/12—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary with single shaft
- B29B7/14—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary with single shaft with screw or helix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/0026—Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/04—Disintegrating plastics, e.g. by milling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/04—Disintegrating plastics, e.g. by milling
- B29B17/0404—Disintegrating plastics, e.g. by milling to powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/04—Disintegrating plastics, e.g. by milling
- B29B17/0412—Disintegrating plastics, e.g. by milling to large particles, e.g. beads, granules, flakes, slices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/90—Fillers or reinforcements, e.g. fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
- B29B2017/0213—Specific separating techniques
- B29B2017/0268—Separation of metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
- B29B9/065—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion under-water, e.g. underwater pelletizers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
- B29K2023/0608—PE, i.e. polyethylene characterised by its density
- B29K2023/065—HDPE, i.e. high density polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/003—PET, i.e. poylethylene terephthalate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/08—Blades for rotors, stators, fans, turbines or the like, e.g. screw propellers
- B29L2031/082—Blades, e.g. for helicopters
- B29L2031/085—Wind turbine blades
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/30—Wind power
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Definitions
- compositions and new products comprising polymers and recycled composite materials, such as fiberglass and other glass fiber- and carbon- fiber reinforced materials, and methods of making the compositions.
- Wind energy and more specifically the use of wind turbines to generate electricity, is an exploding market.
- the prospect of recycling wind turbine blades may be attractive and consistent with the notion of wind energy as a "green” power source, it has not previously been technically or economically feasible.
- experts have regarded wind turbine blades as "unrecyclable” and a problematic source of waste. See Liu et ah, "Wind Turbine Blade Waste in 2050," Waste Management, Vol. 62, pp. 229-240 (April 2017). With the growing importance of wind power in worldwide energy production, this problem will only get worse.
- Wind turbine blades and other materials comprising fiberglass and other fiber- reinforced materials have long been difficult to recycle into new and useful products. Despite the ongoing recycling efforts, in many cases, large-scale items such as composite windmill turbine blades are simply buried in landfills or burned.
- the disclosure provides a composition comprising recycled composite material and one or more polymers.
- the recycled composite material is fiberglass-reinforced composite material, for example, crushed recycled or decommissioned wind turbine blades.
- the recycled composite material comprises recycled wind turbine blade fibers or powder.
- the recycled wind turbine blade fibers have a length of about 0.25 mm to about 12 mm.
- the wind turbine blade powder comprises particles with a maximum dimension of about 0.4 mm to about 3 mm.
- the one or more polymers is high density polyethylene (HDPE), polyethylene terephthalate (PET), or a combination thereof.
- HDPE high density polyethylene
- PET polyethylene terephthalate
- the composition is made by extrusion of a mixture of one or more polymers and recycled composite material particles.
- the composition comprises recycled composite material in the amount of about 5% to about 90% of the composition by weight. In certain embodiments, the composition comprises one or more polymers in the amount of about 5% and about 60% of the composition by weight. In some embodiments, the composition comprises about 50 % of HDPE and about 50 % of recycled composite material powder by weight.
- the disclosure provides composite building material comprising the compositions of the disclosure, such as panel or boards.
- the building material comprises recycled composite material, polymer resin, water, and a release agent.
- the building material is prepared from the composition of Claim 1 comprising about 89 wt% of recycled composite material, about 6 wt% of polymer resin, about 4 wt% of water, and about 1 wt% of a release agent.
- the building material is a panel with a thickness of about 0.5 cm to about 4 cm.
- FIGETRE 1 depicts a decommissioned wind turbine blade being moved to a recycling facility.
- FIGETRE 2 is a schematic of wind turbine blade recycling: metal parts are removed and recycled, and the remaining composite body comprising fiberglass composite is processed into recycled composite particles and fibers. In this manner, up to 99% of the blade can be recycled.
- FIGETRE 3 is a photograph of pelleted exemplary composition comprising HDPE and powdered recycled wind turbine material.
- FIGETRE 4 is a graph comparing structural properties (modulus of rupture (MOR) and the modulus of elasticity (MOE)) of an exemplary composite panel and OSB/structural and particle/MDF structural panels.
- the exemplary panel comprises about 89 wt% of a recycled composite material (e.g., fibers), about 6 wt% of polymer resin, about 4 wt% of water, and about 1 wt% of a release agent.
- FIGETRE 5 is a graph comparing moisture influence properties (water absorption and thickness swell) of an exemplary composite panel and OSB/structural and particle/MDF structural panels.
- the exemplary panel comprises about 89 wt% of a recycled composite material (e.g., fibers), about 6 wt% of polymer resin, about 4 wt% of water, and about 1 wt% of a release agent.
- compositions comprising one or more polymers and a recycled composite material, such as particles formed from a reclaimed (or recycled) composite material.
- a recycled composite material such as particles formed from a reclaimed (or recycled) composite material.
- the compositions of the present disclosure possess certain advantageous properties such as superior moisture resistance and fire resistance compared to the individual components combined to form the compositions.
- the compositions comprise recycled composite material which comprises fiberglass fibers or carbon fibers.
- the composite material is a fiberglass fiber-reinforced material or carbon-fiber-reinforced material.
- Any suitable composite material can be included in the compositions disclosed herein. Any pre-existing composite products or raw materials that are waste, surplus, or damaged beyond usefulness can be included in the compositions disclosed herein.
- sources of such materials include cured or uncured scrap and rovings from fiberglass and fiber-reinforced plastic manufacturers and product manufacturers, boat hulls and other marine equipment, composite turbine blades, including windmill blades, and aircraft parts.
- the input materials are fiber- reinforced materials formed from polyester and styrene resin.
- Non-limiting examples of fiber materials include fiberglass, graphite, carbon, nylon, and KEVLARTM and other synthetic fibers.
- recycled composite material particles and “recycled composite material fibers” refer to particles and fibers, respectively, prepared from a variety of such composite materials which comprises fiberglass fibers or carbon fibers.
- the recycled composite material particles are particles formed from recycled composite turbine blades, including wind turbine blades.
- Wind turbine blades are typically made of composite fiberglass materials such as fiber- reinforced epoxy or unsaturated polyester.
- the blades are typically composed of about 70% to about 75% fiberglass by weight and must meet very strict mechanical requirements such as high rigidity and resistance to torsion and fatigue.
- a standard 35- to 40-meter blade for a 1.5-MW turbine can weigh 6 to 7 tons.
- Epoxy is generally preferred because it offers stronger mechanical performance for blades longer than 26 m (85 ft).
- the recycled composite material used to prepare recycled composite material particles can comprise other components, such as wood or polymeric resins.
- wind turbine blades can comprise, in addition to fiberglass and resin composite, balsa wood and foam.
- the recycled composite material particles or fibers comprise up to about 85% fiberglass by weight.
- the recycled composite material particles comprise between about 40% and about 90% fiberglass, between about 50% and about 90% fiberglass, between about 50% and about 75% fiberglass, between about 60% and about 90% fiberglass, or between about 70% and about 90% fiberglass.
- the recycled composite material used to form the compositions disclosed herein can be broken down into particles by any suitable method, including, as non limiting examples, shredding, crushing, chopping, cutting, ripping, tearing, pounding, grinding or otherwise degrading a composite material to form small pieces of composite material.
- the small pieces of composite material may then be ground to form smaller particles of composite material.
- the particles of recycled composite material are produced according to the methods as disclosed in U.S. Pat. No. 9,028,731, which is hereby incorporated by reference as if fully set forth.
- the particles are separated into size fractions, e.g., by passing through one or more screens or filters.
- the particles comprise fibers formed from recycled wind turbine blades which are retained by a 40 mesh screen.
- the particles comprise fibers having a length of about 0.25 mm to about 12 mm. In certain embodiments, the particles have a length of about 0.5 mm to about 12 mm, about 1 mm to about 12 mm, or about 2 mm to about 12 mm.
- the composite material particles are fine particles with a maximum dimension of about 0.4 mm to about 3 mm. In certain embodiments, the particles have a maximum dimension of about 0.1 mm to about 5 mm, about 0.2 mm to about 3 mm, about 1 mm to about 5 mm, or about 1 mm to about 3 mm. In other embodiments, the particles comprise both fibers and fine particles as described above.
- the particles of recycled composite material are combined with one or more polymers to form the compositions disclosed herein.
- the polymers of the compositions disclosed herein are polyester polymers or ethylenic backbone polymers.
- Exemplary polymers include high density polyethylene (HDPE) and polyethylene terephthalate (PET).
- the polymer is HDPE.
- a composition of the disclosure comprises one or more polymers and particles of recycled composite material.
- the particles of recycled composite material form no more than about 50% by weight of the composition.
- the particles form about 90%, about 80%, about 70%, about 60%, about 55%, about 50%, about 45%, about 40%, about 30%, about 25%, about 20%, about 15%, about 10%, or about 5% by weight of the composition.
- the polymer comprises about 60%, about 55%, about 50%, about 45%, about 40%, about 30%, about 25%, about 20%, about 15%, about 10%, or about 5% of the weight of the composition.
- the composition comprises about 50% of polymer such as HDPE and about 50% of particles of recycled composite material, such as recycled wind turbine blades, by weight. In some embodiments, the compositions comprise up to 90% of recycled composite material particles. In certain embodiments, the compositions comprise about 70% to about 90% of recycled composite material such as particles and/or fibers described above.
- the compositions disclosed herein are formed by extrusion. Any suitable extrusion method can be used to form the compositions of the disclosure.
- the compositions are extruded into pellets.
- a Milacron extruder is used in order to produce the pellets of the compositions disclosed herein.
- the pellets of the compositions disclosed herein are produced using ECON pelletizing machines.
- compounding extrusion is used to produce the compositions disclosed herein.
- Compounding extrusion is a process that mixes one or more polymers with additives, such as powdered recycled composite materials, to give plastic compounds, i.e., compositions of the invention.
- the feeds in compounding extrusion can be in the form of pellets, powder, and/or liquids, and the product is usually in pellet form, to be used in other plastic-forming processes such as extrusion and injection molding.
- the composition can be in the form of pellets, as shown in FIGETRE 3. Any suitable extruder can be used to produce the compositions disclosed herein.
- compositions disclosed herein include additional components.
- additional components include binders, fillers, resins, catalysts, reinforcements, and strengthening agents.
- Additional non-limiting examples of components include aggregate solid particulates, aggregate rock, gravel, sand, wood, textiles, pipes, rods, bars, fibers, metals, honeycombs, spacers, fillers, resin, recycled resin, plastic resin, catalysts, recycled polymers, paper fibers, binders, cement, magnesium oxide, water, cement, limestone, granite, chemical additives, and combinations thereof.
- an additional component is mixed into the polymer-particle mixture.
- a component is disposed or placed into the form, mold, cast or the like prior to the addition of the mixture.
- the component is disposed or placed into the form, mold, cast or the like after the addition of the mixture.
- compositions disclosed herein can be used to produce new composite products that, unlike the starting recycled composite materials used to make the compositions, can be recycled over again and easily turned into other products.
- the disclosure provides composite products comprising compositions of the disclosure, for example, composite building materials such as siding panels or decking boards.
- composite products comprising compositions of the disclosure include flooring, siding, partitions, countertops, facade materials, case goods, containers, and pallets.
- the composite products comprising compositions of the disclosure (e.g., composite building materials) comprise recycled wind turbine blade fibers or particles such as those described above.
- the fibers have a length of about 0.25 mm to about 12 mm.
- the composite products of the disclosure comprise recycled wind turbine blade particles and particles prepared from another type of recycled composite material, such as RV panels.
- the composite building materials comprise recycled composite material (e.g., fibers, fine particles, and/or powder), polymer resin, water, and a release agent.
- the building material is prepared from a composition comprising about 80 wt% to about 90 wt% of a recycled composite material (e.g., fibers), about 5 wt% to about 10 wt% of polymer resin, about 3 wt% to about 5 wt% of water, and about 0 wt% to about 1.5 wt% of a release agent.
- the building material is prepared from a composition comprising about 89 wt% of a recycled composite material (e.g., fibers), about 6% of polymer resin, about 4 wt% of water, and about 1 wt% of a release agent. Colorants and other components can be included in the compositions used to make the building materials of the disclosure. In certain embodiments, the building materials can be painted.
- Any suitable release agent can be used in the preparation of the building material of the disclosure.
- Application to or inclusion of a release agent in the composition can provide a barrier between the molding surface and substrate, facilitating separation of the cured part, such as a board, from the mold, preventing the substrate from becoming fused to the mold surface.
- release agents include PVA (polyvinyl alcohol), PTFE (polytetrafluoroethylene), and reactive polysiloxanes.
- the building material is in the form of panels with a smooth or textured surface and a typical thickness in the range of about 0.3 cm to about 5 cm, about 0.5 cm to about 3 cm, or about 0.5 cm to about 2.5 cm. Thickness of the panel can be tailored to a particular application by those of skill in the art.
- the panels have a density of about 800 kg/m 3 to about 1100 kg/m 3 . Panels comprising the compositions of the disclosure can be of any suitable for a given application size.
- the panels are produced from a masterboard (e.g., a masterboard having dimensions of about 6 feet by about 36 feet).
- the building material is a decking board or tile.
- the building materials of the disclosure such as composite panels, surprisingly have certain advantageous properties, such as moisture resistance, termite resistance, strength and other mechanical properties.
- FIGURES 4 and 5 demonstrate that an exemplary panel of the disclosure has properties superior to common wood-based building products such as MDF particleboard and OSB structural paneling. As shown in FIGURE 5, an exemplary panel comprising about 89% of recycled composite material fibers has significantly lower water sorption properties while maintaining the mechanical properties (FIGURE 4).
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Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201862714460P | 2018-08-03 | 2018-08-03 | |
PCT/US2019/045166 WO2020028914A1 (fr) | 2018-08-03 | 2019-08-05 | Matériaux composites recyclés et procédés associés |
Publications (2)
Publication Number | Publication Date |
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EP3829845A1 true EP3829845A1 (fr) | 2021-06-09 |
EP3829845A4 EP3829845A4 (fr) | 2022-06-22 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP19843254.4A Withdrawn EP3829845A4 (fr) | 2018-08-03 | 2019-08-05 | Matériaux composites recyclés et procédés associés |
Country Status (3)
Country | Link |
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EP (1) | EP3829845A4 (fr) |
CN (1) | CN113165215A (fr) |
WO (1) | WO2020028914A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7875655B2 (en) | 2006-01-20 | 2011-01-25 | Material Innovations, Llc | Carpet waste composite |
US20170136713A1 (en) | 2015-11-13 | 2017-05-18 | James C. Holmes, IV | Composite materials and related methods for manufacturing composite materials |
US11572646B2 (en) | 2020-11-18 | 2023-02-07 | Material Innovations Llc | Composite building materials and methods of manufacture |
US12053908B2 (en) * | 2021-02-01 | 2024-08-06 | Regen Fiber, Llc | Method and system for recycling wind turbine blades |
DK181029B1 (en) * | 2021-03-30 | 2022-10-07 | Leicon Aps | Floating foundation for wind turbines and method for manufacturing a floating foundation for wind turbines |
SE2200045A1 (en) * | 2021-11-16 | 2023-05-12 | Hiform As | A composition for a sleeper and methods to produce sleepers based on used wind turbine blades |
ES1285027Y (es) * | 2021-12-17 | 2022-04-08 | Tecnorenova Reciclaje S L | Material de construcción |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6495635B1 (en) * | 2000-05-26 | 2002-12-17 | Gerald E. Edson | Waterproof, durable products made from recycled rubber products |
US7022756B2 (en) * | 2003-04-09 | 2006-04-04 | Mill's Pride, Inc. | Method of manufacturing composite board |
US10227470B2 (en) * | 2010-03-15 | 2019-03-12 | Washington State University | Recycled composite materials and related methods |
CA2793478C (fr) * | 2010-03-15 | 2018-08-28 | Global Recycle Solutions, Inc. | Materiaux composites recycles et procedes s'y rapportant |
US9422423B2 (en) * | 2012-12-04 | 2016-08-23 | Rutgers, The State University Of New Jersey | Composite articles compression molded from recycled plastic |
EP2781539A1 (fr) * | 2013-03-19 | 2014-09-24 | Siemens Aktiengesellschaft | Composite en plastique à fibres renforcées, procédé de fabrication associé, matériau de départ composite en plastique servant pour la fabrication du composite en plastique à fibres renforcées et composant d'une turbine éolienne comprenant le composite en plastique à fibres renforcées |
-
2019
- 2019-08-05 CN CN201980065643.5A patent/CN113165215A/zh active Pending
- 2019-08-05 EP EP19843254.4A patent/EP3829845A4/fr not_active Withdrawn
- 2019-08-05 WO PCT/US2019/045166 patent/WO2020028914A1/fr unknown
Also Published As
Publication number | Publication date |
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CN113165215A (zh) | 2021-07-23 |
WO2020028914A1 (fr) | 2020-02-06 |
EP3829845A4 (fr) | 2022-06-22 |
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