EP3815553B1 - Filter device for cigarettes and/or pipes - Google Patents

Filter device for cigarettes and/or pipes Download PDF

Info

Publication number
EP3815553B1
EP3815553B1 EP19206886.4A EP19206886A EP3815553B1 EP 3815553 B1 EP3815553 B1 EP 3815553B1 EP 19206886 A EP19206886 A EP 19206886A EP 3815553 B1 EP3815553 B1 EP 3815553B1
Authority
EP
European Patent Office
Prior art keywords
salt
filter device
filter
layer
capsule
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP19206886.4A
Other languages
German (de)
French (fr)
Other versions
EP3815553A1 (en
Inventor
Nikolai N. Korpan
Volodymyr G. Palant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KORPAN, NIKOLAI N.
PALANT, VOLODYMYR G.
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to EP19206886.4A priority Critical patent/EP3815553B1/en
Publication of EP3815553A1 publication Critical patent/EP3815553A1/en
Application granted granted Critical
Publication of EP3815553B1 publication Critical patent/EP3815553B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/16Use of materials for tobacco smoke filters of inorganic materials
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/061Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking

Definitions

  • the invention relates to a filter device for a cigarette and/or pipe for filtering harmful substances when smoking, the filter device comprising at least one filter layer with a carrier medium.
  • the invention also relates to a cigarette with at least one filter device according to the invention.
  • the invention relates to a whistle with at least one filter device according to the invention.
  • Smoking is the main cause for the development of many deadly diseases. Such consequences of smoking not only lead to a deterioration in general well-being and the ability to work, but also damage all organs and systems in the human organism.
  • Cigarette smoke contains more than half of the total amount of all chemical components contained in the cigarette itself, while the total amount of heavy metals in the smoke of both classic and light cigarettes is the same.
  • DE68916902 T2 describes a filter device for a cigarette or pipe for filtering harmful substances when smoking, the filter device comprising at least one filter layer with a carrier medium.
  • the carrier medium is coated with inorganic salt material, where the salt consists of a strong mineral acid such as HCl or HBr and selected metals from main groups 1 and 2 of the periodic table or transition metals, including calcium, potassium, zinc, lithium and magnesium, e.g. ZnCl2, LiBr , KBr, CaBr2, MnCl2, MgCl2.
  • JP2001000165A refers to a cigarette or pipe with a filter that reduces unwanted components such as tar and heavy metals found in tobacco smoke.
  • a granular basic calcium phosphate can be inserted between two filter layers.
  • WO2007028476 A2 discloses a cigarette filter having at least two additives selected from activated carbon, polymer resin, metal oxides and metal hydrates, primarily those of aluminum, silicon, titanium and magnesium.
  • DE2906510 A1 teaches a filter material for gaseous or liquid media, containing activated carbon and at least one of the metals Ca, Mg, Ba, Al, Cu and transition metals.
  • CN102090716A teaches the absorption of heavy metals in cigarette smoke by carboxymethyl chitosan.
  • US3943940A describes a cigarette filter comprising a capsule which can be broken by pressing with fingers and which is filled with an aqueous solution containing potassium permanganate and chlorine. Before the Smoking breaks the capsule, the potassium permanganate solution permeates the filter, and then when smoked, oxidizes the nicotine in the smoke.
  • US3390686A discloses a cigarette filter containing capsules which rupture upon gentle squeezing during smoking and may contain water, flavorings and metal salts, preferably iron salt, for absorbing unwanted constituents of cigarette smoke.
  • filter devices at least one with a Salt layer coated filter layer compared to conventional filter devices have a significantly improved filter effect.
  • an increased sorption capacity of the filter device for the elements lead, strontium, calcium and vanadium could be demonstrated.
  • the filter device comprises two or more filter layers.
  • the filter layers can be glued together in order to prevent the individual filter layers from shifting relative to one another.
  • the at least one filter layer can be in the form of a single-layer pressed tablet, preferably with a thickness of 0.1 to 100 ⁇ m.
  • Textile materials made of linen or cotton, gauze and/or non-woven fabric can be used, for example, as carrier materials which form the filter layers coated with salt.
  • the inorganic salt which forms the salt layer contains a sodium salt.
  • a saline solution for example, is expediently used for the coating.
  • the salt layer according to the invention can therefore also consist of only a single inorganic salt, preferably a sodium salt, particularly preferably common salt.
  • the salt layer can comprise at least one further salt which is selected from the group consisting of: potassium salt, calcium salt, magnesium salt, manganese salt.
  • additional salts or salt mixtures can also be used within the scope of the invention.
  • sea salt can also be used to coat the salt layers on the support media.
  • the salt flower of Sea salt for example, consists on average of more than 97% sodium chloride, 0.5% calcium sulfate, 0.3% magnesium chloride, 0.2% magnesium sulfate ("Epsom salt”) and about 0.1% potassium chloride, the rest is remaining water.
  • the salt layer has a layer thickness of 0.5 to 10 ⁇ m, preferably 1 to 5 ⁇ m.
  • the filter device comprises at least one brine capsule, the at least one brine capsule containing an aqueous salt solution which is surrounded by a capsule shell, the at least one brine capsule being arranged on the at least one filter layer.
  • the filter effect of the filter device can be further improved by moistening the salt layers on the at least one filter layer.
  • One or more brine capsules which are integrated in the filter device and which can be opened by simply squeezing to then release the brine contained therein, are a particularly convenient variant for moistening the filter device according to the invention before or during smoking.
  • brine means an aqueous solution of salts containing at least 14 g of dissolved substances per 1 kg of water.
  • brine is mainly used today for appropriately concentrated sodium chloride solutions.
  • the saline solution is a saline solution with a salt concentration of 0.9 to 35.9%.
  • an isotonic saline solution or a solution of saline (sodium chloride) in injection-suitable water that is isoosmotic to the blood plasma can be used for coating the carrier medium.
  • the capsule shell of the at least one brine capsule can be opened by external force, the capsule shell preferably being made of gelatine or a material containing gelatine.
  • the carrier medium can be formed from gauze, linen and/or non-woven fabric.
  • the object is also achieved by a cigarette with at least one filter device according to the invention.
  • the object is also achieved by a whistle with at least one filter device according to the invention.
  • FIG. 1 1 shows an exemplary cigarette 1 with a filter device 10 for filtering harmful substances when smoking, the filter device 10 in the figure shown comprising three filter layers 100 each having a carrier medium 110 .
  • the filter layers 100 each have a salt layer which is arranged on the carrier medium 110, the salt layer being formed at least from common salt, the salt layer being able to comprise at least one further salt which is selected from the group consisting of: potassium salt, calcium salt, magnesium salt , manganese salt.
  • the salt layers each have a layer thickness of 0.5 to 10 ⁇ m, preferably 1 to 5 ⁇ m.
  • FIG. 2 10 shows a detailed view of the three filter layers 100 of the filter device 10 1 , wherein the individual filter layers 100 are connected by means of an adhesive 150 .
  • FIG. 3 12 shows another exemplary cigarette 2 comprising a brine capsule 200 containing an aqueous saline solution 220 surrounded by a capsule shell 210 , the brine capsule 200 being disposed on a filter layer 100.
  • FIG. A more detailed view of the brine capsule 200 is in 4 to see.
  • the brine capsule 200 contains an aqueous saline solution 220 of 0.1 to 1 ml, the saline solution 220 being a saline solution with a salt concentration of 0.9 to 35.9%.
  • the capsule shell 210 of the brine capsule 200 can be opened by external force, so that the aqueous saline solution contained therein escapes and can get onto or into the filter layer 100 , the capsule shell 210 preferably being made of gelatin or a material containing gelatin.
  • the carrier medium 110 of the filter layer 100 can be formed from gauze, linen and/or non-woven fabric.
  • Cigarette 1.2 filter device 10 filter layer 100 carrier medium 110 adhesive 150 brine capsule 200 capsule shell 210 saline solution 220

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Description

Die Erfindung betrifft eine Filtervorrichtung für eine Zigarette und/oder Pfeife zur Filterung von gesundheitsschädlichen Stoffen beim Rauchen, wobei die Filtervorrichtung zumindest eine Filterschicht mit einem Trägermedium umfasst.The invention relates to a filter device for a cigarette and/or pipe for filtering harmful substances when smoking, the filter device comprising at least one filter layer with a carrier medium.

Weiters betrifft die Erfindung eine Zigarette mit zumindest einer erfindungsgemäßen Filtervorrichtung.The invention also relates to a cigarette with at least one filter device according to the invention.

Weiters betrifft die Erfindung eine Pfeife mit zumindest einer erfindungsgemäßen Filtervorrichtung.Furthermore, the invention relates to a whistle with at least one filter device according to the invention.

Rauchen ist die Hauptursache für die Entwicklung vieler letaler Krankheiten. Derartige Folgen des Rauchens führen nicht nur zu einer Verschlechterung des Allgemeinbefindens und der Arbeitsfähigkeit, sondern fügen allen Organen und Systemen im menschlichen Organismus Schaden zu.Smoking is the main cause for the development of many deadly diseases. Such consequences of smoking not only lead to a deterioration in general well-being and the ability to work, but also damage all organs and systems in the human organism.

Der Zigarettenrauch, der vom Menschen beim Rauchen eingeatmet wird enthält Schwefel, Chlor, Kalium, Calcium, Brom und praktisch das gesamte Spektrum von Schwermetallen wie Blei, Cadmium, Chrom, Mangan, Eisen, Kupfer, Strontium, Zink und Nickel.Cigarette smoke inhaled by humans when they smoke contains sulphur, chlorine, potassium, calcium, bromine and virtually the entire spectrum of heavy metals such as lead, cadmium, chromium, manganese, iron, copper, strontium, zinc and nickel.

Im Zigarettenrauch sind mehr als die Hälfte der Gesamtmenge aller chemischen Komponenten enthalten, welche in der Zigarette selbst enthalten sind, wobei die Gesamtmenge an Schwermetallen im Rauch sowohl klassischer als auch leichter Zigaretten die gleiche ist.Cigarette smoke contains more than half of the total amount of all chemical components contained in the cigarette itself, while the total amount of heavy metals in the smoke of both classic and light cigarettes is the same.

DE68916902 T2 beschreibt eine Filtervorrichtung für eine Zigarette oder Pfeife zur Filterung von gesundheitsschädlichen Stoffen beim Rauchen, wobei die Filtervorrichtung zumindest eine Filterschicht mit einem Trägermedium umfasst. Das Trägermedium ist mit anorganischem Salzmaterial beschichtet, wobei das Salz aus einer starken Mineralsäure wie HCl oder HBr und ausgewählten Metallen der 1. und 2. Hauptgruppe des Periodensystems oder Übergangsmetallen besteht, einschließlich Kalzium, Kalium, Zink, Lithium und Magnesium, beispielsweise ZnCl2, LiBr, KBr, CaBr2, MnCl2, MgCl2. DE68916902 T2 describes a filter device for a cigarette or pipe for filtering harmful substances when smoking, the filter device comprising at least one filter layer with a carrier medium. The carrier medium is coated with inorganic salt material, where the salt consists of a strong mineral acid such as HCl or HBr and selected metals from main groups 1 and 2 of the periodic table or transition metals, including calcium, potassium, zinc, lithium and magnesium, e.g. ZnCl2, LiBr , KBr, CaBr2, MnCl2, MgCl2.

JP2001000165 A bezieht sich auf eine Zigarette oder Pfeife mit einem Filter, der unerwünschte Bestandteile wie Teer und Schwermetalle, die im Tabakrauch enthalten sind, reduziert. Ein körniges basisches Kalziumphosphat kann zwischen zwei Filterschichten eingefügt werden. JP2001000165A refers to a cigarette or pipe with a filter that reduces unwanted components such as tar and heavy metals found in tobacco smoke. A granular basic calcium phosphate can be inserted between two filter layers.

WO2007028476 A2 offenbart einen Zigarettenfilter, der mindestens zwei Zusatzstoffe aufweist, ausgewählt aus Aktivkohle, Polymerharz, Metalloxiden und Metallhydraten, vor allem solche von Aluminium, Silizium, Titan und Magnesium. WO2007028476 A2 discloses a cigarette filter having at least two additives selected from activated carbon, polymer resin, metal oxides and metal hydrates, primarily those of aluminum, silicon, titanium and magnesium.

DE2906510 A1 lehrt ein Filtermaterial für gasförmige oder flüssige Medien, enthaltend Aktivkohle und mindestens eines der Metalle Ca, Mg, Ba, Al, Cu und Übergangsmetalle. DE2906510 A1 teaches a filter material for gaseous or liquid media, containing activated carbon and at least one of the metals Ca, Mg, Ba, Al, Cu and transition metals.

CN102090716 A lehrt die Absorption von Schwermetallen in Zigarettenrauch mittels Carboxymethyl Chitosan. CN102090716A teaches the absorption of heavy metals in cigarette smoke by carboxymethyl chitosan.

US3943940 A beschreibt einen Zigarettenfilter, der eine Kapsel umfaßt, die beim Drücken mit den Fingern zerbrochen werden kann, und welche mit einer wäßrigen Lösung enthaltend Kaliumpermanganat und Chlor gefüllt ist. Vor dem Rauchen wird die Kapsel zerbrochen, die Kaliumpermanganatlösung durchdringt den Filter und oxidiert dann beim Rauchen das Nikotin im Rauch. US3943940A describes a cigarette filter comprising a capsule which can be broken by pressing with fingers and which is filled with an aqueous solution containing potassium permanganate and chlorine. Before the Smoking breaks the capsule, the potassium permanganate solution permeates the filter, and then when smoked, oxidizes the nicotine in the smoke.

US3390686 A offenart einen Zigarettenfilter enthaltend Kapseln, die beim leichten Drücken während des Rauchens aufbrechen, und Wasser, Aromastoffe und Metallsalze enthalten können, vorzugsweise Eisensalz zur Absorption ungewünschter Bestandteile des Zigarettenrauchs. US3390686A discloses a cigarette filter containing capsules which rupture upon gentle squeezing during smoking and may contain water, flavorings and metal salts, preferably iron salt, for absorbing unwanted constituents of cigarette smoke.

Es ist eine Aufgabe der Erfindung, eine Filtervorrichtung für Zigaretten und/oder Pfeifen bereitzustellen, welche verbesserte Filtereigenschaften aufweist.It is an object of the invention to provide a filter device for cigarettes and/or pipes which has improved filter properties.

Diese Aufgabe wird durch die Merkmale der Ansprüche 1 und 5 gelöst.This object is solved by the features of claims 1 and 5.

In bisher noch nicht veröffentlichten Voruntersuchungen konnte von den Erfindern überraschenderweise festgestellt werden, dass Filtervorrichtungen zumindest einer mit einer Salzschicht beschichtete Filterschichte im Vergleich zu herkömmlichen Filtervorrichtungen eine deutlich verbesserte Filterwirkung aufweisen. Mit Hilfe der Röntgen-Fluoreszenz-Analyse konnte eine erhöhte Sorptionsfähigkeit der Filtervorrichtung bei den Elementen Blei, Strontium, Calcium und Vanadium nachgewiesen werden.In previously unpublished preliminary studies, the inventors surprisingly found that filter devices at least one with a Salt layer coated filter layer compared to conventional filter devices have a significantly improved filter effect. With the help of X-ray fluorescence analysis, an increased sorption capacity of the filter device for the elements lead, strontium, calcium and vanadium could be demonstrated.

Es kann vorgesehen sein, dass die Filtervorrichtung zwei oder mehrere Filterschichten umfasst.It can be provided that the filter device comprises two or more filter layers.

Es kann vorgesehen sein, dass die zwei oder mehreren Filterschichten zumindest abschnittsweise miteinander verbunden sind. Beispielsweise können die Filterschichten miteinander verklebt sein, um solcherart ein gegenseitiges Verschieben der einzelnen Filterschichten zu vermeiden.Provision can be made for the two or more filter layers to be connected to one another at least in sections. For example, the filter layers can be glued together in order to prevent the individual filter layers from shifting relative to one another.

Es kann vorgesehen sein, dass die zumindest eine Filterschicht in Form einer einschichtig gepressten Tablette ausgebildet ist, vorzugsweise mit einer Dicke von 0,1 bis 100 µm.Provision can be made for the at least one filter layer to be in the form of a single-layer pressed tablet, preferably with a thickness of 0.1 to 100 μm.

Besonders zweckmäßig kann es sein, wenn bei einer erfindungsgemäßen Filtervorrichtung zwei oder mehrere Filterschichten aus unterschiedlichen Trägermedien hergestellt sind.It can be particularly expedient if, in a filter device according to the invention, two or more filter layers are produced from different carrier media.

Als Trägermaterialien, die die mit Salz beschichteten Filterschichten bilden, können beispielsweise Textilmaterialien aus Leinen oder Baumwolle, Mull, und/oder Vliesstoff eingesetzt werden.Textile materials made of linen or cotton, gauze and/or non-woven fabric can be used, for example, as carrier materials which form the filter layers coated with salt.

Besonders vorteilhaft kann es sein, wenn das anorganische Salz, welches die Salzschicht bildet, ein Natriumsalz enthält. Zweckmäßig wird zur Beschichtung beispielsweise eine Kochsalzlösung verwendet. Die Salzschicht gemäß der Erfindung kann somit auch nur aus einem einzigen anorganischen Salz, vorzugsweise einem Natriumsalz, besonders bevorzugt aus Kochsalz, bestehen.It can be particularly advantageous if the inorganic salt which forms the salt layer contains a sodium salt. A saline solution, for example, is expediently used for the coating. The salt layer according to the invention can therefore also consist of only a single inorganic salt, preferably a sodium salt, particularly preferably common salt.

Es kann vorgesehen sein, dass die Salzschicht zumindest ein weiteres Salz umfasst, das ausgewählt ist aus der Gruppe bestehend aus: Kaliumsalz, Calciumsalz, Magnesiumsalz, Mangansalz. Im Rahmen der Erfindung können neben Kochsalz auch noch andere Salze oder Salzmischungen eingesetzt werden. Beispielsweise kann auch Meersalz zum Beschichten der Salzschichten auf den Trägermedien verwendet werden. Die Salzblume von Meersalz besteht beispielhaft im Mittel aus über 97 % Natriumchlorid, 0,5 % Calciumsulfat, 0,3 % Magnesiumchlorid, 0,2 % Magnesiumsulfat ("Bittersalz") und etwa 0,1 % Kaliumchlorid, der Rest ist verbliebenes Wasser.Provision can be made for the salt layer to comprise at least one further salt which is selected from the group consisting of: potassium salt, calcium salt, magnesium salt, manganese salt. In addition to table salt, other salts or salt mixtures can also be used within the scope of the invention. For example, sea salt can also be used to coat the salt layers on the support media. The salt flower of Sea salt, for example, consists on average of more than 97% sodium chloride, 0.5% calcium sulfate, 0.3% magnesium chloride, 0.2% magnesium sulfate ("Epsom salt") and about 0.1% potassium chloride, the rest is remaining water.

Es kann vorgesehen sein, dass die Salzschicht eine Schichtdicke von 0,5 bis 10 µm, vorzugsweise 1 bis 5 µm, aufweist.It can be provided that the salt layer has a layer thickness of 0.5 to 10 μm, preferably 1 to 5 μm.

Die Aufgabe wird ebenso gemäß Anspruch 5 dadurch gelöst, dass die Filtervorrichtung zumindest eine Salzsolekapsel umfasst, wobei die zumindest eine Salzsolekapsel eine wässrige Salzlösung enthält, die von einer Kapselhülle umgeben ist, wobei die zumindest eine Salzsolekapsel an der zumindest einen Filterschicht angeordnet ist.The object is also achieved according to claim 5 in that the filter device comprises at least one brine capsule, the at least one brine capsule containing an aqueous salt solution which is surrounded by a capsule shell, the at least one brine capsule being arranged on the at least one filter layer.

In den Voruntersuchungen der Erfinder hat sich überraschend gezeigt, dass durch Befeuchten der Salzschichten auf der zumindest eine Filterschicht die Filterwirkung der Filtervorrichtung weiter verbessert werden kann. Eine oder mehrere Salzsolekapseln, die in der Filtervorrichtung integriert sind und die durch einfaches Zusammendrücken geöffnet werden können, um sodann die darin befindliche Salzsole freizusetzen, sind eine besondere komfortable Variante, um die erfindungsgemäße Filtervorrichtung vor oder während des Rauchens befeuchten zu können.The preliminary investigations of the inventors surprisingly showed that the filter effect of the filter device can be further improved by moistening the salt layers on the at least one filter layer. One or more brine capsules, which are integrated in the filter device and which can be opened by simply squeezing to then release the brine contained therein, are a particularly convenient variant for moistening the filter device according to the invention before or during smoking.

Unter dem Begriff "Salzsole" versteht man eine wässrige Lösung von Salzen, die mindestens 14 g gelöster Stoffe pro 1 kg Wasser enthält. Die Bezeichnung Salzsole wird heute hauptsächlich für entsprechend konzentrierte Natriumchlorid-Lösungen verwendet.The term "brine" means an aqueous solution of salts containing at least 14 g of dissolved substances per 1 kg of water. The term brine is mainly used today for appropriately concentrated sodium chloride solutions.

Es kann vorgesehen sein, dass die Salzlösung eine Kochsalzlösung mit einer Salzkonzentration von 0,9 bis 35,9% ist.It can be provided that the saline solution is a saline solution with a salt concentration of 0.9 to 35.9%.

Beispielsweise können eine isotonische Kochsalzlösung, oder eine zum Blutplasma isoosmotische Lösung aus Kochsalz (Natriumchlorid) in injektionsgeeignetem Wasser zur Beschichtung des Trägermediums verwendet werden.For example, an isotonic saline solution or a solution of saline (sodium chloride) in injection-suitable water that is isoosmotic to the blood plasma can be used for coating the carrier medium.

Es kann vorgesehen sein, dass die zumindest eine Salzsolekapsel von 0,1 bis 1 ml einer wässrigen Salzlösung enthält.Provision can be made for the at least one brine capsule to contain from 0.1 to 1 ml of an aqueous saline solution.

Es kann vorgesehen sein, dass die Kapselhülle der zumindest einen Salzsolekapsel durch äußere Krafteinwirkung öffenbar ist, wobei die Kapselhülle vorzugsweise aus Gelatine oder einem Gelatine-enthaltenden Material hergestellt ist.It can be provided that the capsule shell of the at least one brine capsule can be opened by external force, the capsule shell preferably being made of gelatine or a material containing gelatine.

Es kann vorgesehen sein, dass das Trägermedium aus Mull, Leinen und/oder Vliesstoff gebildet ist.Provision can be made for the carrier medium to be formed from gauze, linen and/or non-woven fabric.

Die Aufgabe wird ebenso gelöst durch eine Zigarette mit zumindest einer erfindungsgemäßen Filtervorrichtung.The object is also achieved by a cigarette with at least one filter device according to the invention.

Die Aufgabe wird ebenso gelöst durch eine Pfeife mit zumindest einer erfindungsgemäßen Filtervorrichtung.The object is also achieved by a whistle with at least one filter device according to the invention.

Nachfolgend wird die Erfindung anhand von beispielhaften Zeichnungen näher erläutert. Hierbei zeigt

  • Fig. 1 eine beispielhafte Zigarette mit einer Filtervorrichtung mit drei Filterschichten;
  • Fig. 2 eine Detailansicht der Filterschichten aus Fig. 1;
  • Fig. 3 eine weitere beispielhafte Zigarette mit einer Filtervorrichtung, welche eine Salzsolekapsel umfasst; und
  • Fig. 4 eine Detailansicht der Salzsolekapsel aus Fig. 3.
The invention is explained in more detail below with reference to exemplary drawings. Here shows
  • 1 an exemplary cigarette having a filter device with three filter layers;
  • 2 a detailed view of the filter layers 1 ;
  • 3 another exemplary cigarette having a filter device comprising a brine capsule; and
  • 4 a detailed view of the brine capsule 3 .

Fig. 1 zeigt eine beispielhafte Zigarette 1 mit einer Filtervorrichtung 10 zur Filterung von gesundheitsschädlichen Stoffen beim Rauchen, wobei die Filtervorrichtung 10 in der gezeigten Figur drei Filterschichten 100 mit jeweils einem Trägermedium 110 umfasst. 1 1 shows an exemplary cigarette 1 with a filter device 10 for filtering harmful substances when smoking, the filter device 10 in the figure shown comprising three filter layers 100 each having a carrier medium 110 .

Die Filterschichten 100 weisen jeweils eine Salzschicht auf, welche auf dem Trägermedium 110 angeordnet ist, wobei die Salzschicht zumindest aus Kochsalz gebildet ist, wobei die Salzschicht zumindest ein weiteres Salz umfassen kann, das ausgewählt ist aus der Gruppe bestehend aus: Kaliumsalz, Calciumsalz, Magnesiumsalz, Mangansalz.The filter layers 100 each have a salt layer which is arranged on the carrier medium 110, the salt layer being formed at least from common salt, the salt layer being able to comprise at least one further salt which is selected from the group consisting of: potassium salt, calcium salt, magnesium salt , manganese salt.

Die Salzschichten weisen dabei jeweils eine Schichtdicke von 0,5 bis 10 µm, vorzugsweise 1 bis 5 µm, auf.The salt layers each have a layer thickness of 0.5 to 10 μm, preferably 1 to 5 μm.

Fig. 2 zeigt hierzu eine Detailansicht der drei Filterschichten 100 der Filtervorrichtung 10 aus Fig. 1 , wobei die einzelnen Filterschichten 100 mittels eines Klebemittels 150 verbunden sind. 2 10 shows a detailed view of the three filter layers 100 of the filter device 10 1 , wherein the individual filter layers 100 are connected by means of an adhesive 150 .

Fig. 3 zeigt eine weitere beispielhafte Zigarette 2, umfassend eine Salzsolekapsel 200, welche eine wässrige Salzlösung 220 enthält, die von einer Kapselhülle 210 umgeben ist, wobei die Salzsolekapsel 200 an einer Filterschicht 100 angeordnet ist. Eine detailliertere Ansicht der Salzsolekapsel 200 ist in Fig. 4 zu sehen. 3 12 shows another exemplary cigarette 2 comprising a brine capsule 200 containing an aqueous saline solution 220 surrounded by a capsule shell 210 , the brine capsule 200 being disposed on a filter layer 100. FIG. A more detailed view of the brine capsule 200 is in 4 to see.

Die Salzsolekapsel 200 enthält dabei eine wässrige Salzlösung 220 von 0,1 bis 1 ml, wobei die Salzlösung 220 eine Kochsalzlösung mit einer Salzkonzentration von 0,9 bis 35,9% ist.The brine capsule 200 contains an aqueous saline solution 220 of 0.1 to 1 ml, the saline solution 220 being a saline solution with a salt concentration of 0.9 to 35.9%.

Die Kapselhülle 210 der Salzsolekapsel 200 ist durch äußere Krafteinwirkung öffenbar, sodass die darin enthaltene wässrige Salzlösung austritt und auf bzw. in die Filterschicht 100 gelangen kann, wobei die Kapselhülle 210 vorzugsweise aus Gelatine oder einem Gelatine-enthaltenden Material hergestellt ist.The capsule shell 210 of the brine capsule 200 can be opened by external force, so that the aqueous saline solution contained therein escapes and can get onto or into the filter layer 100 , the capsule shell 210 preferably being made of gelatin or a material containing gelatin.

Bei beiden gezeigten Varianten der Zigaretten 1, 2 kann das Trägermedium 110 der Filterschicht 100 aus Mull, Leinen und/oder Vliesstoff gebildet sein. LISTE DER BEZUGSZEICHEN Zigarette 1,2 Filtervorrichtung 10 Filterschicht 100 Trägermedium 110 Klebemittel 150 Salzsolekapsel 200 Kapselhülle 210 Salzlösung 220 In both variants of the cigarettes 1, 2 shown, the carrier medium 110 of the filter layer 100 can be formed from gauze, linen and/or non-woven fabric. <b>LIST OF REFERENCE MARKS</b> Cigarette 1.2 filter device 10 filter layer 100 carrier medium 110 adhesive 150 brine capsule 200 capsule shell 210 saline solution 220

Claims (11)

  1. Filter device (10) for a cigarette and/or pipe for filtering substances harmful to health during smoking, the filter device (10) comprising at least one filter layer (100) with a carrier medium (110), the at least one filter layer (100) having a salt layer arranged on the carrier medium (110), the salt layer being formed from at least one inorganic salt
    characterized in that
    the inorganic salt forming the salt layer comprises common salt.
  2. Filter device according to claim 1, characterized in that the filter device (10) comprises two or more filter layers (100).
  3. Filter device according to one of claims 1 or 2, characterized in that the salt layer comprises at least one further salt selected from the group consisting of: Potassium salt, Calcium salt, Magnesium salt, Manganese salt.
  4. Filter device according to any one of claims 1 to 3, characterized in that the salt layer has a layer thickness of 0.5 to 10 µm, preferably 1 to 5 µm.
  5. Filter device for a cigarette and/or pipe for filtering substances harmful to health during smoking, wherein the filter device (10) comprises at least one filter layer (100) with a carrier medium (110), characterized in that the filter device comprises at least one salt-sole capsule, wherein the at least one salt capsule (200) contains an aqueous salt solution (220) surrounded by a capsule shell (210), wherein the at least one salt capsule (200) is disposed on the at least one filter layer (100), wherein the salt solution is a common salt solution.
  6. Filter device according to claim 5, characterized in that the salt solution (220) is a saline solution having a salt concentration of 0.9 to 35.9%.
  7. Filter device according to claim 5 or 6, characterized in that the at least one salt capsule (200) contains from 0.1 to 1 ml of an aqueous salt solution (220).
  8. Filter device according to any one of claims 5 to 7, characterized in that the capsule shell (210) of the at least one salt capsule (200) is openable by external force, wherein the capsule shell (210) is preferably made of gelatin or a gelatin-containing material.
  9. Filter device according to any one of claims 1 to 8, characterized in that the carrier medium (110) is formed of gauze, linen and/or nonwoven fabric.
  10. Cigarette having at least one filter device according to any one of claims 1 to 9.
  11. Pipe having at least one filter device according to any one of claims 1 to 9.
EP19206886.4A 2019-11-04 2019-11-04 Filter device for cigarettes and/or pipes Active EP3815553B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP19206886.4A EP3815553B1 (en) 2019-11-04 2019-11-04 Filter device for cigarettes and/or pipes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP19206886.4A EP3815553B1 (en) 2019-11-04 2019-11-04 Filter device for cigarettes and/or pipes

Publications (2)

Publication Number Publication Date
EP3815553A1 EP3815553A1 (en) 2021-05-05
EP3815553B1 true EP3815553B1 (en) 2022-05-11

Family

ID=68426291

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19206886.4A Active EP3815553B1 (en) 2019-11-04 2019-11-04 Filter device for cigarettes and/or pipes

Country Status (1)

Country Link
EP (1) EP3815553B1 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE68916902T2 (en) * 1988-10-17 1995-03-09 Hoechst Celanese Corp Selective delivery and retention of nicotine by-products from cigarette smoke.

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1299606B (en) * 1963-06-26 1969-07-24 Engel Geb Jatsch Anna Process for the production of very effective, abrasion-resistant catalysts for cleaning engine exhaust gases
US3943940A (en) * 1974-09-13 1976-03-16 Isao Minami Method of removing nicotine in smoking and a smoking filter to be used therefor
FI790530A (en) * 1978-02-21 1979-08-22 Siren M J O FILTER MATERIALS SAMT FOERFARANDE FOER FRAMSTAELLNING AV OCH ANVAENDNING AV DETSAMMA
JP2001000165A (en) * 1999-06-22 2001-01-09 Tokyo Bio Ceramics Kenkyusho:Kk Filter-tipped cigarette and filter for cigarette
BRPI0617062A2 (en) * 2005-09-05 2011-07-12 Rhodia Acetow Gmbh filter or filter element, provided with a basically cylindrical filter body having at least two different additives, filter or filter element, for tobacco smoke fitted with a basically cylindrical filter body, cigarette with such a filter or filter element and method for manufacturing tobacco smoke filters or filter elements
CN102090716A (en) * 2011-03-03 2011-06-15 中国海洋大学 Novel cadmium-removal filter tip

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE68916902T2 (en) * 1988-10-17 1995-03-09 Hoechst Celanese Corp Selective delivery and retention of nicotine by-products from cigarette smoke.

Also Published As

Publication number Publication date
EP3815553A1 (en) 2021-05-05

Similar Documents

Publication Publication Date Title
DE2623065A1 (en) CONTAINER FOR THE REMOVAL OF ORGANOVINYL COMPOUNDS CONTAINED IN BREATHING AIR
EP1785167A2 (en) Adsorbing filter material with a biological and chemical protection function and its use
EP3675659B1 (en) Smoking article and method for cooling a heated particle-loaded gas
DE1131076B (en) Process for the production of artificial sausage casings from animal material which can be easily peeled off from the sausage mass
DE2358759A1 (en) PROCESS FOR PREPARING A THERAPEUTIC COMPOSITION
DE60302204T2 (en) anesthesia reflector
EP3815553B1 (en) Filter device for cigarettes and/or pipes
DE2757576C2 (en) Impregnated activated carbon to remove acidic, catalytically decomposable and chemically bound pollutants from the air
DE3819736C2 (en)
DE102016124196A1 (en) Face mask with embedded nose pad
DE4418126A1 (en) Protective mask and process for its manufacture
CH646185A5 (en) FILTER MATERIAL.
DE1498855A1 (en) Alcohol indicator
DD278501A1 (en) DEVICE FOR ATTACHING AND HUMIDIFYING VENTILATION GASES
DE102017001996A1 (en) Method for operating a vehicle
DE102009001059A1 (en) floor mat
DE1087579B (en) Process for impregnation of activated carbon with heavy metal salts
DE509032C (en) Gas protection filter cartridge
DE10004682B4 (en) Respiratory healing mask
DE3143103C2 (en) Breathing apparatus as a filter device with additional oxygen supply, especially as an escape device
DE102008020608A1 (en) Method and system for preserving anesthetic, heat and moisture
DE2313468A1 (en) GAS FILTERS TO REMOVE OR FILTERING CADMIUM AND CADMIUM COMPOUNDS FROM GASES, IN PARTICULAR TOBACCO SMOKE, AND METHOD FOR MANUFACTURING SUCH FILTER
DE19914309A1 (en) Formation of limited local climatic zones for breathing using e.g. multilayer mask in natural materials, containing active substances and retaining moisture, to set up ideal, therapeutic breathing conditions
DE202022105551U1 (en) Evaporator with active filter
DE2137725C3 (en) Process for separating hydrogen sulfide from gas mixtures

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20211104

RBV Designated contracting states (corrected)

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

RIN1 Information on inventor provided before grant (corrected)

Inventor name: PALANT, VOLODYMYR G.

Inventor name: KORPAN, NIKOLAI N.

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: PALANT, VOLODYMYR G.

Owner name: KORPAN, NIKOLAI N.

RIN1 Information on inventor provided before grant (corrected)

Inventor name: PALANT, VOLODYMYR G.

Inventor name: KORPAN, NIKOLAI N.

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

INTG Intention to grant announced

Effective date: 20220322

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1490633

Country of ref document: AT

Kind code of ref document: T

Effective date: 20220515

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502019004334

Country of ref document: DE

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG9D

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20220511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220912

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220811

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220812

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220811

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220911

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502019004334

Country of ref document: DE

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

26N No opposition filed

Effective date: 20230214

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221130

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221104

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20221104

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20231130

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20231129

Year of fee payment: 5

Ref country code: DE

Payment date: 20231129

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20231129

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20220511

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20191104