EP3620431A1 - Dual h2 und co-produktion mit co turndown - Google Patents

Dual h2 und co-produktion mit co turndown Download PDF

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Publication number
EP3620431A1
EP3620431A1 EP18192935.7A EP18192935A EP3620431A1 EP 3620431 A1 EP3620431 A1 EP 3620431A1 EP 18192935 A EP18192935 A EP 18192935A EP 3620431 A1 EP3620431 A1 EP 3620431A1
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EP
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Prior art keywords
shift reactor
unit
outlet
swing adsorption
feed
Prior art date
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EP18192935.7A
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English (en)
French (fr)
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EP3620431B1 (de
Inventor
Eugene S. Genkin
Kelly Ann Forester
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Air Products and Chemicals Inc
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Air Products and Chemicals Inc
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Priority to ES18192935T priority Critical patent/ES2831352T3/es
Priority to EP18192935.7A priority patent/EP3620431B1/de
Publication of EP3620431A1 publication Critical patent/EP3620431A1/de
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/046—Purification by cryogenic separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/145—At least two purification steps in parallel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
EP18192935.7A 2018-09-06 2018-09-06 Dual h2 und co-produktion mit co turndown Active EP3620431B1 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES18192935T ES2831352T3 (es) 2018-09-06 2018-09-06 Doble producción de H2 y CO con regulación de CO
EP18192935.7A EP3620431B1 (de) 2018-09-06 2018-09-06 Dual h2 und co-produktion mit co turndown

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP18192935.7A EP3620431B1 (de) 2018-09-06 2018-09-06 Dual h2 und co-produktion mit co turndown

Publications (2)

Publication Number Publication Date
EP3620431A1 true EP3620431A1 (de) 2020-03-11
EP3620431B1 EP3620431B1 (de) 2020-08-19

Family

ID=63524143

Family Applications (1)

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EP18192935.7A Active EP3620431B1 (de) 2018-09-06 2018-09-06 Dual h2 und co-produktion mit co turndown

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EP (1) EP3620431B1 (de)
ES (1) ES2831352T3 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220016462A (ko) * 2019-05-30 2022-02-09 레르 리키드 쏘시에떼 아노님 뿌르 레뜌드 에렉스뿔라따시옹 데 프로세데 조르즈 클로드 일산화탄소, 수소 및 적어도 하나의 산 가스를 각각 함유하는 두 가스상 스트림들의 분리를 위한 방법 및 장치

Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4217759A (en) 1979-03-28 1980-08-19 Union Carbide Corporation Cryogenic process for separating synthesis gas
US4488890A (en) 1982-12-23 1984-12-18 Linde Aktiengesellschaft Low temperature separation of gaseous mixture for methanol synthesis
US4525187A (en) 1984-07-12 1985-06-25 Air Products And Chemicals, Inc. Dual dephlegmator process to separate and purify syngas mixtures
EP0157480A2 (de) 1984-03-02 1985-10-09 Imperial Chemical Industries Plc Verfahren zur Herstellung von Ammoniaksynthesegas
US4566886A (en) 1983-04-12 1986-01-28 Linde Aktiengesellschaft Process and apparatus for obtaining pure CO
US5351491A (en) 1992-03-31 1994-10-04 Linde Aktiengesellschaft Process for obtaining high-purity hydrogen and high-purity carbon monoxide
US5609040A (en) 1994-04-11 1997-03-11 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process and plant for producing carbon monoxide
EP0816290A1 (de) * 1996-06-24 1998-01-07 Bayer Ag Verfahren zur Gewinnung von Kohlenmonoxid und Wasserstoff
US5832747A (en) 1997-08-12 1998-11-10 Air Products And Chemicals, Inc. Cryogenic adjustment of hydrogen and carbon monoxide content of syngas
US6161397A (en) 1998-08-12 2000-12-19 Air Products And Chemicals, Inc. Integrated cryogenic and non-cryogenic gas mixture separation
EP1146009A1 (de) * 2000-04-13 2001-10-17 Air Products And Chemicals, Inc. Kroproduktion von Kohlenmonoxidreichem Syngas und hochreinem Wasserstoff
US20070269690A1 (en) * 2006-05-22 2007-11-22 Doshi Kishore J Control system, process and apparatus for hydrogen production from reforming
EP2414282A1 (de) 2009-04-01 2012-02-08 Air Products and Chemicals, Inc. Kryogene trennung von synthesegas
WO2012078299A1 (en) 2010-12-09 2012-06-14 Praxair Technology, Inc. Steam methane reforming process
EP2565154A2 (de) * 2011-08-30 2013-03-06 Air Products and Chemicals, Inc. Verfahren und Vorrichtung zur Herstellung von Wasserstoff und Kohlenmonoxid
US8828107B2 (en) 2006-01-31 2014-09-09 Linde Process Plants, Inc. Process and apparatus for synthesis gas heat exchange system
US20140373713A1 (en) 2014-09-11 2014-12-25 Air Products And Chemicals, Inc. Pressure Swing Adsorption Process
EP2823872A2 (de) 2014-09-11 2015-01-14 Air Products And Chemicals, Inc. Druckwechsel-Adsorptionsverfahren
US8956587B1 (en) 2013-10-23 2015-02-17 Air Products And Chemicals, Inc. Hydrogen production process with high export steam
US9586819B2 (en) 2015-05-15 2017-03-07 Air Products And Chemicals, Inc. Process for producing hydrogen

Patent Citations (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4217759A (en) 1979-03-28 1980-08-19 Union Carbide Corporation Cryogenic process for separating synthesis gas
US4488890A (en) 1982-12-23 1984-12-18 Linde Aktiengesellschaft Low temperature separation of gaseous mixture for methanol synthesis
US4566886A (en) 1983-04-12 1986-01-28 Linde Aktiengesellschaft Process and apparatus for obtaining pure CO
EP0157480A2 (de) 1984-03-02 1985-10-09 Imperial Chemical Industries Plc Verfahren zur Herstellung von Ammoniaksynthesegas
US4525187A (en) 1984-07-12 1985-06-25 Air Products And Chemicals, Inc. Dual dephlegmator process to separate and purify syngas mixtures
US5351491A (en) 1992-03-31 1994-10-04 Linde Aktiengesellschaft Process for obtaining high-purity hydrogen and high-purity carbon monoxide
US5609040A (en) 1994-04-11 1997-03-11 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process and plant for producing carbon monoxide
EP0816290A1 (de) * 1996-06-24 1998-01-07 Bayer Ag Verfahren zur Gewinnung von Kohlenmonoxid und Wasserstoff
US5832747A (en) 1997-08-12 1998-11-10 Air Products And Chemicals, Inc. Cryogenic adjustment of hydrogen and carbon monoxide content of syngas
US6161397A (en) 1998-08-12 2000-12-19 Air Products And Chemicals, Inc. Integrated cryogenic and non-cryogenic gas mixture separation
EP1146009A1 (de) * 2000-04-13 2001-10-17 Air Products And Chemicals, Inc. Kroproduktion von Kohlenmonoxidreichem Syngas und hochreinem Wasserstoff
US8828107B2 (en) 2006-01-31 2014-09-09 Linde Process Plants, Inc. Process and apparatus for synthesis gas heat exchange system
US20070269690A1 (en) * 2006-05-22 2007-11-22 Doshi Kishore J Control system, process and apparatus for hydrogen production from reforming
EP2414282A1 (de) 2009-04-01 2012-02-08 Air Products and Chemicals, Inc. Kryogene trennung von synthesegas
WO2012078299A1 (en) 2010-12-09 2012-06-14 Praxair Technology, Inc. Steam methane reforming process
EP2565154A2 (de) * 2011-08-30 2013-03-06 Air Products and Chemicals, Inc. Verfahren und Vorrichtung zur Herstellung von Wasserstoff und Kohlenmonoxid
US8956587B1 (en) 2013-10-23 2015-02-17 Air Products And Chemicals, Inc. Hydrogen production process with high export steam
US20140373713A1 (en) 2014-09-11 2014-12-25 Air Products And Chemicals, Inc. Pressure Swing Adsorption Process
EP2823872A2 (de) 2014-09-11 2015-01-14 Air Products And Chemicals, Inc. Druckwechsel-Adsorptionsverfahren
US9381460B2 (en) 2014-09-11 2016-07-05 Air Products And Chemicals, Inc. Pressure swing adsorption process
US9586819B2 (en) 2015-05-15 2017-03-07 Air Products And Chemicals, Inc. Process for producing hydrogen

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SMITH R J ET AL.: "Int. J. of Chem. Reactor Engg.", vol. 8, 2010, THE BERKELEY ELECTRONIC PRESS, article "A Review of the Water Gas Shift Reaction Kinetics"

Also Published As

Publication number Publication date
EP3620431B1 (de) 2020-08-19
ES2831352T3 (es) 2021-06-08

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