EP3612650B1 - Hochfestes stahlblech mit hervorragender duktilität und dehnungselastizität, verfahren zur herstellung des besagten stahls und verwendung davon - Google Patents

Hochfestes stahlblech mit hervorragender duktilität und dehnungselastizität, verfahren zur herstellung des besagten stahls und verwendung davon Download PDF

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EP3612650B1
EP3612650B1 EP18717386.9A EP18717386A EP3612650B1 EP 3612650 B1 EP3612650 B1 EP 3612650B1 EP 18717386 A EP18717386 A EP 18717386A EP 3612650 B1 EP3612650 B1 EP 3612650B1
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strip
temperature
steel
hot
rolled
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EP3612650A1 (de
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Shangping Chen
Richard MOSTERT
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Tata Steel Nederland Technology BV
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Definitions

  • This invention relates to a high strength steel sheet as hot rolled and cold rolled products useful for frame components for vehicles and automobiles such as frames for trucks.
  • (advanced) high strength steel sheets are increasingly used in car components to reduce weight and fuel consumption.
  • a series of (advanced) high strength steels such as HSLA, Dual phase (DP), Ferritic-bainitic (FB) including stretch-flangeable (SF), Complex phase (CP), Transformation-induced plasticity (TRIP), Hot-formed, Twinning-induced plasticity (TWIP) has been developed to meet the growing requirements.
  • AHSS sheet steels cannot be applied easily to a wide variety of car components because their formability is relatively poor. As steels became increasingly stronger, they simultaneously became increasingly difficult to form into automotive parts. Actually, the real application of AHSS steels (DP, CP and TRIP) to car components is still limited by their formability. Therefore, improving formability and manufacturability become an important issue for AHSS application.
  • AHSS grades have additional relevant failure mechanisms compared to mild steels. This is mainly caused by local failure which is observed more commonly in AHSS due to multi-phase structure and phase changes during deformation. These local failures do not necessarily correlate with elongation and/or n-value. Therefore, steels having higher (uniform and total) elongations do not always have a good formability.
  • microstructures improving ductility are different from those improving formability.
  • the position in the diagram of the elongation-strength is not sufficient to select the proper materials for all parts. In most cases, another relationship between formability and strength is needed for material selection. It is essential to study the behaviour of AHSS under all relevant forming conditions.
  • Each forming mode has a specific governing mechanical parameter such as r-value (the ratio between plastic strain in-plane and the plastic strain through-the-thickness of a tensile test sample), ⁇ (hole expansion ratio) value, and bending angle.
  • r-value the ratio between plastic strain in-plane and the plastic strain through-the-thickness of a tensile test sample
  • ⁇ hole expansion ratio
  • EP 2559783 A1 discloses a high strength hot-rolled steel sheet having a tensile strength of not less than 780 MPa, exhibiting excellent stretch flangeability and excellent fatigue resistance and having a composition close to the one of the present invention.
  • a high strength steel strip having a cementite-free microstructure comprising:
  • the unique and balanced combination of chemical elements ensures that the microstructure of the steel comprises bainitic and ferritic components, and ideally consists only of bainitic and ferritic components. Preferably the entire microstructure consists of bainitic components only. Even though it is sometimes hard to distinguish between ferritic and bainitic components, it is easy to distinguish between ferritic and bainitic components on the one hand, and structures like martensite, retained austenite, cementite, pearlite, etc. on the other hand.
  • Crucial in the invention is the absence of cementite (Fe 3 C) in the microstructure.
  • titanium (Ti) and vanadium (V) cementite formation is prevented and TiC and VC are formed instead.
  • These latter carbides are much smaller ( ⁇ 5-30 nm) and more finely dispersed than the cementite ( ⁇ 200 nm) that would normally have been present.
  • the cementite would also be plate shaped and located between the ferrite laths in the bainite structure, whereas the VC and TiC are usually spherical or needle like and located inside the ferrite lath.
  • This microstructure offers an improved combination of strength and fracture toughness.
  • the microstructure derives its high strength from the ultra-fine grain size, less than 1 ⁇ m, which can additionally be strengthened by the small carbide precipitates.
  • the formation of Fe 3 C or martensitic/austenitic microconstituents is suppressed by using microalloying such as titanium and vanadium.
  • microalloying precipitation strengthening is an effective way to increase strength without sacrificing toughness, when microstructural refinement is used simultaneously.
  • higher amount of micro alloying with V and Ti is necessary to avoid (coarse) Fe3C.
  • C is an element that forms cementite-free bainite, thus contributing to an increase in strength.
  • the low carbon content of between 0.005 and 0.08 wt.% in the steel ensures that the cooling rate dependence of the microstructure is low.
  • At these low carbon contents in a preferable embodiment of less than 0.05 wt.%, preferably less than 0.045 wt.%, more preferably less than 0.04%, even more preferably less than 0.035 wt.% carbon partitioning does not occur during the austenite to ferrite transformation.
  • a suitable minimum carbon content is 0.01 wt.% to obtain the bainitic structure and ensure the high strength of a UTS of 760 MPa or more.
  • bainitic microstructures By optimizing the other alloying elements, it is possible to obtain a uniform bainitic microstructure that will form across a very large range of cooling rates in a very similar manner. In the absence of carbide formers, some cementite will form.
  • the bainitic microstructures can be made cementite free by further alloying with Ti and/or V. Also, the low carbon concentrations may bring about good low temperature impact toughness balanced with adequate weldability.
  • Ti combines with N, S and C to form nitrides, carbosulphides and carbides depending on the specific chemical composition of the steel.
  • the Ti content exceeds 0.20% it is difficult to dissolve coarse Ti carbides during reheating of the slab prior to hot rolling.
  • V is added to replace some amount of Ti and V will combined with rest of carbon to form VC.
  • the titanium content is at least 0.03%.
  • TiC and VC will completely prevent the formation of cementite.
  • Ti also plays the role of fixing N. Any free nitrogen is detrimental to the hardenability improving effect of B, and therefore the nitrogen scavenging effect of the titanium is desired.
  • the vanadium content is at most 0.30%.
  • a suitable minimum value for C/(Ti_sol+V) is 0.15.
  • the Ti_sol > 0, preferably > 0.01 wt.%, more preferably > 0.02 wt.%.
  • cementite-free is intended to mean that the aim is that no cementite (Fe 3 C) whatsoever is present in the microstructure.
  • a composition satisfying the equation presented above should ensure that this is the case.
  • due to local compositional fluctuations in the steel strip it may inadvertently and unintentionally occur that a minute amount of cementite is discernible in the microstructure that does not affect the properties and performance of the steel strip as a whole.
  • Manganese (Mn) is an essential element for promoting low carbon bainitic microstructures and in improving the balance between strength and low temperature toughness.
  • the Mn content is at least 1.30 and at most 2.30 wt.%.
  • Mn stabilizes austenite and delays the bainite transformation at a given temperature and ensures a good hardenability. The austenite field is extended to lower temperatures, which offers a wide temperature gap for proper controlled rolling. Furthermore, Mn promotes the formation of fine acicular ferrite and lower-bainite. Disadvantages of very high Mn contents are, deterioration of HAZ toughness, increased centreline segregation of the continuous cast steel slabs, and poor surface quality after hot rolling due to increased interior oxidation.
  • the Mn content is preferably at least 1.5, and preferably at most 2.0 wt.%. More preferably Mn is at least 1.65 and at most 1.95 wt.%.
  • B Boron
  • B is a potent hardenability enhancer in low C, low alloy steels. A small amount of B is added to low carbon steels to ensure that bainitic microstructures can be produced at lower cooling rates without formation of proeutectoid ferrite.
  • the B content is at least 2 and at most 35 ppm. B is the most effective alloying element in increasing the yield strength. The B content should preferably be at most 25 ppm so as not to impair low temperature toughness.
  • N Nitrogen
  • the N content is at least 5 and at most 65 ppm.
  • a suitable and practical minimum N content is 10 ppm.
  • the titanium content is at least 0.03 and at most 0.20 wt.% Ti, and preferably at least 0.06 and at preferably at most 0.18, more preferably at most 0.16 wt.%.
  • the steels are preferably additionally alloyed with one or both of copper (Cu) or chromium (Cr) to a maximum of 1.50 wt.% Cu and 0.75 wt.% Cr.
  • a suitable maximum is 1.25 wt.% Cu.
  • Cu can promote low carbon bainitic structures, and provide solid solution hardening.
  • the strength of the steel is increased by precipitation hardening of nano-sized Cu precipitates. Through a thermo-mechanical precipitation control process (TPCP) it is possible to obtain Cu precipitation during coil cooling after hot rolling, and therefore no extra heat treatment is necessary. Cr increases the strength mainly due to transformation strengthening.
  • TPCP thermo-mechanical precipitation control process
  • Nickel (Ni) improves toughness as well as hardenability. Nickel imparts good toughness to the steel material at a high level of strength. In addition to increasing the strength and toughness of the steel, Ni counters the hot shortness caused by any Cu alloying. Ni is preferably present only as an impurity, mainly from a cost perspective. Ni can be added up to 0.5 wt% to prevent hot shortness when the Cu content exceeds 0.5%. In an embodiment no nickel is added to the steel.
  • Silicon (Si) is added to improve the strength though solution hardening and transformation hardening. However, with excess of Si, the HAZ toughness, weldability and coatability are impaired.
  • the silicon is maximised at 0.6 wt.%, preferably maximised at 0.5%.
  • Aluminium is utilized as a deoxidizing element and is an element effective for improving the steel cleanliness. It is necessary to set the total Al content in the steel at 0.005 wt.% or more to obtain such an effect.
  • the Al content is maximised at 0.1 wt.% and preferably at 0.05 wt.% because the higher the content the higher the likelihood of cause surface defects and the higher the costs of the alloy.
  • Molybdenum (Mo) has been found to promote low carbon bainitic structure at small concentrations of about 0.1 wt%, but at higher concentration it can deteriorate toughness of high strength cementite free bainitic steels. Mo is not an economically preferred alloying element and it is not recommended to use as an alloying element in these steels.
  • Sulphur (S) is present in steel as an impurity.
  • Primary MnS particles will be formed in Mn containing steels during casting. These coarse MnS particles are very detrimental because they are elongated in the rolling direction.
  • Ti is added, Ti 4 S 2 C 2 and/or MnS are formed during casting depending on the concentrations of Ti, C and S.
  • Ti 4 S 2 C 2 will be present as primary coarse particles and needs to be avoided as much as possible.
  • the S content should be at most 0.012, preferably at most 0.01 wt.% and most preferably below 0.005 wt.%.
  • Phosphorus (P) is present in steel as impurity.
  • P content exceeds 0.03%, segregation in the grain boundaries becomes marked, resulting in degradation in toughness and weldability.
  • the P content is decreased as much as possible.
  • the P content should be at most 0.012, preferably at most 0.01 wt.% and most preferably below 0.005 wt.%.
  • the steel according to the invention may be a hot-rolled steel and used as such, or a subsequently cold-rolled and annealed steel.
  • the hot-rolled or cold-rolled steel may be provided with a metallic coating.
  • the coating may be provided by means of hot-dipping, and preferably the metallic coating is a zinc or aluminium based coating.
  • the optional coating of the steel is performed by conventional means and includes, but is not limited to, hot dip coating, electrocoating, PVD or CVD.
  • the steel according to the invention does not contain niobium (Nb) as alloying element.
  • Nb niobium
  • Table 1 indicate a presence as impurity only, and no niobium is added to the steel.
  • the invention is also embodied in a process for producing a high strength steel strip having a cementite-free microstructure, a yield strength of at least 570 MPa, a tensile strength of at least 760 MPa, a total elongation (A50) of at least 10.3 % and a hole expansion ratio ( ⁇ ) value of at least 70%, said process comprising:
  • a steel melt is conventionally cast in the form of a thick slab, a thin slab or a strip. After casting it is brought to hot-rolling temperatures by (re-)heating and/or homogenising and hot-rolled. The last hot-rolling pass is performed on the steel while still fully austenitic, i.e. the finish rolling temperature is above Ar3. After finish rolling the steel is cooled on the run-out table of the hot strip mill at an average cooling rate of between 15 and 100 °C/s to a coiling temperature of at most 500 °C followed by cooling of the coil by natural cooling down to ambient temperature.
  • the slab reheating temperature for the steel has to be sufficiently high to dissolve coarse Ti and V carbides precipitated in the slab during casting.
  • a suitable maximum SRT is 1300 °C.
  • the hot rolling finishing temperature has to be in the austenite range, and is preferably between 850 °C to 950 °C. This range of 850 °C to 950 °C is applied to produce a fine austenite grain size in the strip after the last rolling pass, and to keep Ti and V in solid solution.
  • the strips are cooled by accelerated cooling at rates in the range of 15 to 100 °C/s to a coiling temperature of at most 500°C. After coiling the coil is allowed to cool to ambient temperature without further accelerated cooling.
  • ambient temperature has the same meaning as room temperature.
  • the average cooling rate after hot rolling of 15 to 100 °C/s is needed to avoid the formation of pearlite and to avoid the formation of ferrite and coarse Ti and V carbides.
  • the hot-rolled sheet After cooling, the hot-rolled sheet is coiled at a coiling temperature up to 500°C.
  • the coiled strip cools slowly, which allows for the bainitic phase transformation to occur.
  • the bainite phase formed in the steels according to the invention during coiling in this coiling temperature range is cementite-free, which is preferable for the steel sheet to exhibit excellent stretch flangeability.
  • the precipitation of fine TiC and/or VC carbides may occur within this coiling temperature range, enabling additional hardening to be obtained.
  • cementite might be formed as pearlite or degenerated pearlite and the resulting stretch flangeability is markedly lower than in the process according to the invention.
  • the coiling temperature is at least 420 °C, because for lower values of the coiling temperature there is a risk of the formation of too much martensite and retained austenite and the formability of the resulting steel will be reduced as a consequence thereof. This risk is more prominent for higher carbon contents.
  • the coiling temperature should be in the range of 420 to 500 °C , as the microstructure and properties, especially stretch flangeability are rather sensitive to the process routes.
  • the CCT diagram for the VS72 alloy shown in Figure 1 indicates that depending on the cooling rate different microstructures develop.
  • the cooling rate after hot rolling has to be in the range of 15 to 100 °C/s and the coiling temperature has to be below 500 °C.
  • No minimum coiling temperature is specified, because the risk of forming martensite or the presence of retained austenite is very low.
  • the coiling temperature is preferably not below 420 °C.
  • the inventors found that the mechanical properties were relatively insensitive to cooling rate and the cooling temperature. As the CCT diagram for VS74 alloy ( Figure 2 ) and the microstructures ( Figure 3 ) already suggest, the final structure is relatively insensitive to the cooling trajectory. This is particularly the case for the steel grades containing Cu and/or Cr.
  • the cooling rate range may be obtained by means of a water or air/water mixture spray, depending on the thickness of the sheet, at the exit of the finishing mill.
  • the coiling temperature is preferably at least 440 °C and/or at most 480 °C.
  • the cooling rate after rolling and prior to coiling is at least 25 °C/s.
  • the hot-rolled strip is subsequently cold rolled, a cold rolling reduction is applied to obtain the required thickness.
  • the total cold-rolling reduction of the hot-rolled strip is preferably between 50 and 90 %.
  • the cold-rolled full-hard strip is reheated to a solution temperature above Ac3, preferably in the temperature range of 850-1000 °C, and held at the solution temperature for 2 to 8 minutes, and then cooled with a cooling rate in the range of 15 to 50 °C/s to a holding temperature between 440 and 480 °C, and held for up to 30 min, and preferably for 0.5 to 30 min, to allow the bainitic transformation to take place and avoid the risk for formation of martensite in amounts that adversely affect the formability.
  • the sheet should be cooled with a cooling rate of 0.5 to 100 °C/s to room temperature.
  • the cooling rate should preferably be between 10 and 100 °C/s.
  • a higher reheating temperature is preferable to allow more TiC dissolve in to austenite.
  • the invention is also embodied in a car or truck component, such as an automotive chassis component, a component of the body in white, a component of the frame or the subframe, said component having been produced from the steel sheet according to the invention.
  • a car or truck component such as an automotive chassis component, a component of the body in white, a component of the frame or the subframe, said component having been produced from the steel sheet according to the invention.
  • Steels having compositions shown in Table 1 were cast into 30 kg ingots of 200 mm x 110 mm x 110 mm in dimensions.
  • Steel VS71 is a comparable example because the C/(T_sol+V) ratio is out of the invented composition range.
  • the ingots were reheated to 1250 °C and soaked for 1 hour and then rough hot rolled to 35 mm thickness.
  • the shrinkage and segregation zone from both ends were cut off.
  • the cut blocks were reheated at 1200 °C for 30 min and then hot rolled to 3 mm thickness in 5 passes.
  • the finish rolling temperature was about 900 °C.
  • the strips were cooled at 30-60 °C/s to 500 °C in the run-out table and were then transferred to a preheated furnace at 440 °C or 480 °C and held for 1 hour to simulate the coiling process. The materials were then taken out the furnace and cooled in the air to the room temperature. The hot rolled strips were then pickled in HCl at 85 °C to remove the oxide layers. Samples for microstructure observations, tensile tests and hole expansion tests were machined for hot rolled strips.
  • the hot rolled strips were subsequently cold-rolled at a cold rolling reduction of 67%.
  • the cold rolled 1 mm strips were then heat treated at 900 °C for 2 min and then cooled with 3 different conditions, as specified in Table 3.
  • Room temperature tensile tests were performed in a Schenk TREBEL testing machine following NEN10002 standard to determine tensile properties (yield strength YS (MPa), ultimate tensile strength UTS (MPa), total elongation TE (%)). For each condition, three tensile tests were performed and the average values of mechanical properties are reported.
  • Bending test The 3-point "guided bending tests" were conducted on samples with dimensions 40 mm x 30 mm. The length direction of the samples was parallel to the rolling direction of steel sheets. Parallel bending tests where the bending axis is perpendicular to the rolling direction of the sheets were carried out. For this method, a former and two supporting cylinders were used in order to bend the steel sheets. The cylinders and the punch were mounted in a tensile testing machine. The load cell is used to measure the punch force and the displacement of the crosshead gives the punch displacement. The experiments were stopped at different bending angles and the bent surface of the specimen was inspected for identification of failure in order to determine the bending angle.
  • Figure 1 The CCT diagram for VS72 alloy.
  • FIG. 2 The CCT diagram for VS74 alloy.
  • Figure 3 The microstructure of the VS74 alloy (taken from the samples of figure 2 ).

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Claims (14)

  1. Hochfestes Stahlband, das eine zementitfreie Mikrostruktur aufweist, umfassend:
    • 0,005-0,08 Gew.-% C;
    • 1,30-2,30 Gew.-% Mn;
    • 2-35 ppm B;
    • 5-65 ppm N;
    • 0,005-0,1 Gew.-% Al_tot;
    • 0,03 bis 0,20 Gew.-% Ti;
    • 0-1,5 Gew.-% Cu;
    • 0-0,75 Gew.-% Cr;
    • 0-0,05 Gew.-% Mo;
    • 0-0,50 Gew.-% Ni;
    • 0-0,30 Gew.-% V;
    • 0-0,6 Gew.-% Si;
    • 0-0,03 Gew.-% P;
    • 0-0,01 Gew.-% S;
    • C Ti sol + V ≤ 0,25
    Figure imgb0005
     wobei Ti_sol=Ti-((48/14)·N)
    Rest Eisen und unvermeidbare Verunreinigungen, wobei das Stahlband eine Streckgrenze von zumindest 570 MPa, eine Zugfestigkeit von zumindest 760 MPa, eine Gesamtdehnung (A50) von zumindest 10,3 % und einen Wert des Lochausdehnungsverhältnisses (λ) von zumindest 70% aufweist.
  2. Stahl nach Anspruch 1, enthaltend zumindest eines von
    • 0-1,5 Gew.-% Cu;
    • 0-0,75 Gew.-% Cr;
  3. Stahl nach einem der vorhergehenden Ansprüche, wobei die Mikrostruktur bainitische und ferritische Körner umfasst.
  4. Stahl nach einem der vorhergehenden Ansprüche, wobei C höchstens 0,045 Gew.-% ist.
  5. Verfahren zum Produzieren eines hochfesten Stahlbandes, das eine zementitfreie Mikrostruktur, eine Streckgrenze von zumindest 570 MPa, eine Zugfestigkeit von zumindest 760 MPa, eine Gesamtdehnung (A50) von zumindest 10,3% und einen Wert des Lochausdehnungsverhältnisses (λ) von zumindest 70 % aufweist, wobei das Verfahren Folgendes umfasst:
    - Gießen einer Schmelze in eine Bramme oder ein Band, die/das die folgende Zusammensetzung aufweist:
    • 0,005-0,08 Gew.-% C;
    • 1,30-2,30 Gew.-% Mn;
    • 2-35 ppm B;
    • 5-65 ppm N;
    • 0,005-0,1 Gew.-% Al_tot;
    • 0,03 bis 0,20 Gew.-% Ti;
    • 0-1,5 Gew.-% Cu;
    • 0-0,75 Gew.-% Cr;
    • 0-0,05 Gew.-% Mo;
    • 0-0,50 Gew.-% Ni;
    • 0-0,30 Gew.-% V;
    • 0-0,6 Gew.-% Si;
    • 0-0,03 Gew.-% P;
    • 0-0,01 Gew.-% S;
    • C Ti sol + V ≤ 0,25
    Figure imgb0006
     wobei Ti_sol=Ti-((48/14) ·N);
    • Rest Eisen und unvermeidbare Verunreinigungen,
    - Wiedererwärmen der Bramme auf eine Brammenwiedererwärmungstemperatur von zumindest 1200 °C;
    - Warmwalzen der Bramme oder des Bandes zu einem warmgewalzten Band, wobei die Warmwalzendtemperatur über Ar3 ist;
    - Abkühlen des warmgewalzten Bandes bei einer durchschnittlichen Abkühlrate von 15 bis 100 °C/s auf dem Auslauftisch innerhalb eines Zeitraums von 2 Sekunden zwischen Fertigwalzen und Beginn des Abkühlens auf eine Haspeltemperatur unter 500 °C und dann Haspelabkühlen durch natürliches Abkühlen auf Umgebungstemperatur.
  6. Verfahren nach Anspruch 5, wobei die Bramme oder das Band zumindest eines von Folgendem enthält:
    • 0-1,5 Gew.-% Cu;
    • 0-0,75 Gew.-% Cr;
  7. Verfahren nach Anspruch 5 oder Anspruch 6, wobei der Kohlenstoffgehalt des Stahls zumindest 0,03 % ist und wobei die Aufwickeltemperatur zumindest 420 °C ist.
  8. Verfahren nach einem der Ansprüche 5 bis 7, wobei C höchstens 0,045 Gew.-% ist.
  9. Verfahren nach einem der Ansprüche 5 bis 8, wobei die Aufwickeltemperatur zumindest 440 °C und/oder höchstens 480 °C ist.
  10. Verfahren nach einem der Ansprüche 5 bis 9, wobei warmgewalztes Band anschließend kaltgewalzt wird, um ein kaltgewalztes Band zu erhalten.
  11. Verfahren nach Anspruch 10, wobei das kaltgewalzte Band geglüht wird, indem das Band wieder auf eine Temperatur über Ar3 erhitzt, gehalten und anschließend auf Umgebungstemperaturen abgekühlt wird.
  12. Verfahren nach Anspruch 10, wobei die gesamte Kaltwalzreduktion zwischen 50 und 90 % ist.
  13. Verfahren nach einem von Anspruch 10 bis 12, wobei das kaltgewalzte Vollhartband wieder auf eine Lösungstemperatur über Ac3 in dem Bereich von 850-1000 °C erwärmt, 2 bis 8 Minuten bei der Lösungstemperatur gehalten, mit einer Abkühlrate in dem Bereich von 15 bis 50 °C/s auf eine Haltetemperatur zwischen 440 und 480 °C abgekühlt, 0 bis 30 Min. bei der Haltetemperatur gehalten, um zu ermöglichen, dass die bainitische Umwandlung stattfindet, und dann auf Raumtemperatur abgekühlt wird.
  14. PKW- oder LKW-Komponente, wie eine Kfz-Fahrgestellkomponente, eine Komponente der Rohkarosserie, eine Komponente des Rahmens oder des Hilfsrahmens, wobei die Komponente aus dem Stahlblech nach einem der Ansprüche 1 bis 4 produziert worden ist.
EP18717386.9A 2017-04-20 2018-04-19 Hochfestes stahlblech mit hervorragender duktilität und dehnungselastizität, verfahren zur herstellung des besagten stahls und verwendung davon Active EP3612650B1 (de)

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US6364968B1 (en) * 2000-06-02 2002-04-02 Kawasaki Steel Corporation High-strength hot-rolled steel sheet having excellent stretch flangeability, and method of producing the same
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