EP3586568A1

EP3586568A1 - Levitation melting process

Info

Publication number: EP3586568A1
Application number: EP19721225.1A
Authority: EP
Inventors: Sergejs SPITANS; Henrik Franz; Björn SEHRING; Markus Holz
Original assignee: ALD Vacuum Technologies GmbH
Current assignee: ALD Vacuum Technologies GmbH
Priority date: 2018-04-20
Filing date: 2019-04-18
Publication date: 2020-01-01
Anticipated expiration: 2039-04-18
Also published as: PL3586568T3; RU2736273C1; EP3586568B1; WO2019202111A1; US20210146431A1; KR20200116154A; ES2845253T3; DE102018109592A1; CN111742615A; SI3586568T1; JP6883152B1; CN111742615B; JP2021515374A; TW201944434A; US11370020B2; TWI727304B; KR102226483B1; PT3586568T

Abstract

The invention relates to a method for producing cast bodies in a levitation melting process, wherein a charge of an electrically conductive material is brought, by means of a starting material which has multiple preseparated charges separated by regions with a reduced cross-section, into the reach of at least one alternating electromagnetic field so that the charge is held in a state of levitation. The regions are designed in such a way that the preseparated charges are not detached until during the melting process in an alternating electromagnetic field. The molten metal is then cast into casting molds.

Description

Flash smelting process

This invention relates to a levitation melting process for producing castings with a multiple batch feedstock. The process employs a feedstock having multiple discrete batches separated by areas of reduced cross-section. By supplying the batch with a single ingot, in addition to a more favorable production of the batch materials, a more efficient melting of the batches can be achieved. During the melting process, the melt does not come into contact with the material of a crucible, so that contamination by the crucible material or by reaction of the melt with crucible material is avoided.

The avoidance of such impurities is especially important for metals and alloys with high melting points. Such metals include, for example, titanium, zirconium, vanadium, tantalum, tungsten, hafnium, niobium, rhenium and molybdenum. However, this is also important for other metals and alloys such as nickel, iron and aluminum.

State of the art

Heated melting processes are known from the prior art. For example, DE 422 004 A already discloses a melting process in which the conductive melt is heated by inductive currents and at the same time free-floating is obtained by electrodynamic action. There is also described a casting process in which the molten material is conveyed by a magnet into a mold (electrodynamic pressure casting). The process can be carried out in vacuo.

US 2,686,864 A also describes a method in which a conductive melt z. B. is placed in a vacuum under the influence of one or more coils without the use of a crucible in a floating state. In one embodiment, two coaxial coils are used to stabilize the material in suspension. After the melt, the material is dropped or poured into a mold. With the process described there, a 60 g aluminum portion was suspended.

The removal of the molten metal is carried out by reducing the field strength, so that the melt escapes down through the tapered coil. If the field strength is reduced very rapidly, the metal drops out of the device in a molten state. It has already been recognized that the "weak spot" of such coil arrangements lies in the middle of the coils, so that the amount of material that can be so melted is limited. Also, US 4,578,552 A discloses a device and a method for levitation melting.

The same coil is used both for heating and for holding the melt, in which the frequency of the applied alternating current for regulating the heating power is varied while the current intensity is kept constant.

The particular advantages of levitation melting are that contamination of the melt by a crucible material or other materials that are in contact with the melt in other processes is avoided. The floating melt is only in contact with the surrounding atmosphere, which may be, for. B. can act to vacuum or inert gas. The fact that a chemical reaction with a crucible material is not to be feared, the melt can be heated to very high temperatures. In addition, especially in comparison with the melt in the cold crucible, the rejects of contaminated material are reduced. Nevertheless, the floating melting has not prevailed in practice. The reason for this is that in the levitation melting process, only a relatively small amount of molten material can be held in suspension (see DE 696 17 103 T2, page 2, paragraph 1).

The batches of starting material are introduced into the induction coil area in the form of individual ingots for all levitation melting processes. This usually takes place by means of a gripper, which picks up the ingots at a feed position, moves them into the induction coil area and then releases them after switching on the magnetic field. This often causes problems with the stability of the ingots in the magnetic field and a splashing during melting. The production of these relatively small ingots is comparatively complicated and expensive.

Another disadvantage with regard to the maximum achievable efficiency in the utilization of the induced eddy currents for heating the ingots is due to the principle. The Lorentz force of the coil field must compensate for the weight of the charge in order to keep it in suspension. It pushes the batch upwards out of the coil field. As a result, the charge does not sink as deeply into the magnetic field as would be necessary for optimum utilization of the magnetic field for heating the charge. It floats above this optimal level.

Finally, the time required for the supply of individual ingots is a limiting factor in the achievable cycle times.

The disadvantages of the processes known from the prior art can be summarized as follows. Vollschweerbmelzverfahren can be carried out only with small amounts of material, so that an industrial application has not yet been done. Further designed pouring into molds is difficult. The levitation principle limits the magnetic field that can be used to heat the charge or its efficiency in generating eddy currents. Problems with the stability of the ingots in the magnetic field and splashing during melting can occur. The production of the ingots is comparatively complicated and expensive.

task

It is thus an object of the present invention to provide a method which allows economical use of levitation melting. In particular, the process should allow a high throughput through improved melting efficiency and allow the use of low cost ingots for the batches.

Description of the invention

The object is achieved by the method according to the invention. Furthermore, the object also solves the use of a starting material according to the invention in a levitation melting process. According to the invention, a method for producing cast bodies from an electrically conductive material, comprising the following steps:

- Introducing the lowest batch of a starting material for several batches in the influence of at least one alternating electromagnetic field (melting range), wherein the starting material of an electrically conductive material has a plurality of pre-separated, separated by areas of reduced cross-section batches and the areas are designed so that a separation of the pre-separated batches takes place only when melting in an electromagnetic alternating field,

- melting the batch,

- Lifting the remaining unmelted starting material from that in one

Suspended molten batch,

- overheating the suspended batch,

Positioning a mold in a filling area below the suspended batch,

Casting the entire batch into the mold,

Removal of the solidified cast body from the mold. The volume of the molten charge is preferably sufficient to fill the casting mold with sufficient dimensions for the production of a cast body ("filling volume"). After filling the mold, it is allowed to cool or cooled with coolant so that the material solidifies in the mold. Thereafter, the casting can be removed from the mold. Casting may consist in dropping the charge, in particular by switching off the alternating electromagnetic field; or the casting may be slowed down by an alternating electromagnetic field, e.g. B. by the use of a coil.

A "conductive material" is understood according to the invention to mean a material which has a suitable conductivity in order to heat the material inductively and to hold it in suspension.

A "floating state" is understood according to the invention to mean a state of complete floating, so that the treated batch does not have any contact with a crucible or platform or the like.

For the purposes of this application, a "cylindrical" ingot means an ingot in the form of the mathematical definition of a general cylinder, in particular a general straight cylinder, the definition explicitly including the special forms of the prism, in particular the straight prism, and of the cuboid. Preferably, it is a straight circular cylinder or a straight prism with six- to twenty-four-sided base surfaces.

The "lowest" charge means, according to the invention, the charge of a starting material according to the invention which is arranged at the end of the starting material which is distal to the end with which the starting material is held and moved.

The supply of batches via a feedstock that combines multiple batches instead of individual batches offers several advantages. By arranging the batches in the manner of a substantially rod-shaped structure, they can first be introduced deeper into the magnetic field of the coils. In contrast to a single batch, the starting material does not need to float, but is mechanically held in position. The remaining starting material can push the lowermost batch to be melted into the magnetic field. This increases the efficiency of the melting of the charge. Only when the batch begins to melt, the molten parts go into suspension. The holding power of the remaining starting material also ensures that the charge is stable in the magnetic field. is lisiert. When the batch has melted, the remaining starting material is pulled upwards and the free-flowing melt is overheated.

Most preferably, the charge is introduced so far into the alternating electromagnetic field that the induced eddy current is maximum. In this way, the batch can be optimally heated, which leads to an acceleration of the entire casting process.

In a most preferred embodiment of the method according to the invention, the starting material for a plurality of batches consists of a cylindrical rod having along its longitudinal axis regions which have a reduced cross-section, the individual regions having the unreduced cross-section corresponding in each case to the quantity of material in a batch. In principle, the effect according to the invention of stabilization and improved utilization of the generated magnetic field is achieved in any desired form of the batches. However, rods in the form of a circular cylinder or a prism with an approximately circular base surface can be produced in a particularly simple and cost-effective manner, for example in continuous casting. It then only have to be introduced by turning, sawing or cutting the batches separating areas in the raw rod.

With no design form of the starting material according to the invention, it is necessary that the batches are the same size. As a rule, although large batches are required for a series production of similar parts. However, it is also conceivable to use molds with several cavities which require different filling quantities. Customized starting materials with different batches are therefore encompassed by the present invention.

The areas of reduced cross-section, which separate the individual batches, on the one hand ensure lower heat conduction and, on the other hand, a restriction of the induced eddy currents on the charge to be melted in the magnetic field.

Preferably, therefore, in the case of the starting material for a plurality of batches, the cross section between the batches is reduced so much and / or the regions of reduced cross section are so long that there is such extensive confinement of the eddy current induced in an alternating electromagnetic field in a batch adjacent batch is not melted down with. When designing the areas connecting the batches, this must be taken into account accordingly in order to achieve an optimum ratio of space-saving arrangement and the risk of melting off the adjacent batch. Likewise, the heat conduction of the areas with the reduced cross-section is correspondingly preferably so low in the starting material for a plurality of batches that the adjacent batch is not melted when a batch is melted.

For the method according to the invention, it is highly preferred if, in the case of the starting material for a plurality of batches, the regions with the reduced cross section are dimensioned at least such that they have a mechanical load capacity which is sufficient for the weight of the respective starting material to be supported. Since the starting materials are used in a suspended arrangement, it is advantageous if the areas connecting the charges, which have the lowest mechanical strength due to the reduced cross-section, are able to support the entire area below them. This can be avoided that a feed mechanism must be used, which ensures stabilization of the starting material. If the minimum possible cross sections are used, they decrease from top to bottom. It is not necessary to make all cross-sections the same, therefore, to be based on the connection of the top charge.

In a preferred embodiment, the electrically conductive material used according to the invention has at least one refractory metal from the following group: titanium, zirconium, vanadium, tantalum, tungsten, hafnium, niobium, rhenium, molybdenum. Alternatively, a less high-melting metal such as nickel, iron or aluminum can be used. As a conductive material, a mixture or alloy with one or more of the aforementioned metals can be used. Preferably, the metal has a content of at least 50% by weight, in particular at least 60% by weight or at least 70% by weight, of the conductive material. It has been found that these metals benefit particularly from the advantages of the present invention. In a particularly preferred embodiment, the conductive material is titanium or a titanium alloy, in particular TiAl or TiAIV. These metals or alloys can be processed particularly advantageously, since they have a pronounced dependence of the viscosity on the temperature and moreover are particularly reactive, in particular with regard to the materials of the casting mold. Since the method according to the invention combines contactless melting in suspension with extremely rapid filling of the casting mold, a particular advantage can be realized precisely for such metals. With the method according to the invention castings can be produced which have a particularly thin or even no oxide layer from the reaction of the melt with the material of the casting mold. And especially in the case of refractory metals, the achieved improved utilization of the induced eddy current and the associated faster heating in the cycle times are noticeable. An advantageous embodiment of the method uses the electrically conductive material in powder form. If the batches are to be designed, for example, in spherical form, then a lot of material would have to be removed when turning from a solid metal rod. An assembly of individual balls, which are screwed together with rods, would cause considerable additional work during production and assembly. If one deviates from powder, however, one can produce the form more easily. Most preferably, this is done by compression with a binder and / or sintering. Conceivable binders are, for example, paraffins, waxes or polymers, which in each case allow a low working temperature.

In an advantageous embodiment of the invention, the conductive material is overheated during melting to a temperature which is at least 10 ° C, at least 20 ° C or at least 30 ° C above the melting point of the material. The overheating prevents the material from immediately solidifying on contact with the mold, whose temperature is below the melting temperature. It is achieved that the charge can spread in the mold before the viscosity of the material becomes too high. It is an advantage of levitation smelting that no crucible in contact with the melt needs to be used. Thus, the high loss of material of the cold crucible method is avoided as well as a contamination of the melt by crucible components. Another advantage is that the melt can be heated relatively high, since operation in a vacuum or under protective gas is possible and no contact with reactive materials takes place. However, most materials can not be overheated arbitrarily, otherwise a violent reaction with the mold is to be feared. Therefore, the overheating is preferably limited to at most 300 ° C, especially at most 200 ° C, and more preferably at most 100 ° C above the melting point of the conductive material.

In an advantageous embodiment of the method, in order to concentrate the magnetic field and stabilize the charge, at least one ferromagnetic element is arranged horizontally around the region in which the charge is melted. The ferromagnetic element may be arranged annularly around the melting region, whereby "annular" not only circular elements, but also square, in particular four- or polygonal ring elements are understood. The element may have a plurality of rod sections which protrude in particular hori zontally in the direction of the melting region. The ferromagnetic element consists of a ferromagnetic material, preferably with an amplitude permeability m ₃ > 10, more preferably m ₃ > 50 and particularly preferably m ₃ > 100. The amplitude permeability relates in particular to the permeability in a temperature range between 25 ° C and 100 ° C and at a magnetic flux density between 0 and 400 mT. The amplitude permeability is in particular at least one hundredth, in particular at least 10 dogs. or 25ths of the amplitude permeability of soft magnetic ferrite (eg 3C92). The person skilled in suitable materials are known.

According to the invention is also the use of an electrically conductive material as the starting material for a Schweießmelzverfahren in which the starting material has a plurality of pre-separated, separated by areas of reduced cross-section batches, wherein a separation of the pre-separated batches until melting in an electromagnetic Alternating field.

Brief description of the figures

FIG. 1 is a side view of three embodiments of a starting material according to the invention.

Fig. 2 is a side view showing the structure of a fusion region with ferromagnetic element, coils and the lower portion of a multiple charge source material.

Fiqurenbeschreibunq

The figures show preferred embodiments. They are for illustration only.

FIG. 1 shows a side view of three embodiments of an inventive starting material of electrically conductive material. All three are vertical circular cylindrical shapes. At the upper end, an area is arranged, which is suitable for mounting in a feeder. Depending on the method of attachment, this area can be made smooth as shown in the figure or provided with holes or a three-dimensional surface structure, in particular a peripheral circumferential widening, which makes it possible to detect with a hook or gripper.

The left starting material has six, the middle five and the right eight batches (1). In the left starting material, the individual batches (1) are separated by notches in triangular form. These indentations can be produced, for example, without material loss via a punch. In the intermediate starting material, the individual charges (1) are spaced by wider areas of reduced cross-section. Such an embodiment can be produced in a simple and cost-effective manner by twisting off a cylindrical rod. In contrast, the right-hand starting material has narrow circumferential cuts for the division of the individual batches (1). In principle, the structure is thus as in the middle starting material, the distances are only reduced and the cross-section of the reduced cross-sectional areas is further reduced. By the further reduced Cross-section, a better restriction of the induced eddy currents and lower heat conduction can be achieved to compensate for the shorter distance.

FIG. 2 shows the section of the lowest three charges (1) of the middle starting material from FIG. 1. The lowest charge (1) is within the influence of electromagnetic alternating fields (melting range) which are generated with the aid of the coils (2). Below the batch (1) is an empty mold, which is held by a holder in the filling area (not shown). To the sphere of influence of the coils (2) a ferromagnetic element (3) is arranged. The batch (1) is melted and levitated in the process of the invention. After melting the batch (1), the remaining starting material is pulled up and the melt overheated. Thereafter, the melt is poured into the mold and finally removed the solidified cast body from the mold.

Bezuaszeichenliste

1 batch

2 coil

3 ferromagnetic element

Claims

claims

1. A process for the production of castings from an electrically conductive material in the Schweekmelzverfahren, comprising the following steps:

- Introducing the bottom batch (1) of a starting material for several batches (1) in the influence of at least one alternating electromagnetic field, wherein the starting material of an electrically conductive material has a plurality of pre-separated, separated by areas of reduced cross section batches (1) and the areas so that a separation of the pre-separated batches (1) takes place only when they are melted in an electromagnetic alternating field,

Melting the charge (1),

- Lifting the remaining unmelted starting material from that in one

Suspended molten charge (1),

- overheating the suspended charge (1),

- Positioning a mold in a filling area below the suspended batch

(1 ),

Casting the entire batch (1) into the mold,

- Removal of the solidified cast body from the mold.

2. The method according to claim 1, characterized in that the charge (1) is inserted so far into the electromagnetic alternating field that the induced eddy current is maximum.

3. The method according to claim 1 or 2, characterized in that the starting material for a plurality of batches (1) consists of a cylindrical rod, which has along its longitudinal axis on areas which have a reduced cross-section, wherein the individual areas with the unreduced cross section in each case correspond to the amount of material of a batch (1).

4. The method according to any one of the preceding claims, characterized in that in the starting material for a plurality of batches (1) the cross section between the batches (1) is so far reduced and / or the areas with reduced cross section are so long that such a far reaching Limitation of the in an electromagnetic alternating field in a batch (1) induced eddy current occurs that the adjacent batch (1) is not melted with.

5. The method according to any one of the preceding claims, characterized in that in the starting material for a plurality of batches (1) the areas with the reduced cross-section are at least dimensioned so that they have a mechanical load capacity, the weight to be supported in each case Starting material is sufficient.

6. The method according to any one of the preceding claims, characterized in that in the starting material for a plurality of batches (1), the heat conduction of the areas with the reduced cross section is so low that when melting a batch (1) the adjacent batch (1) not is melted.

7. The method according to any one of the preceding claims, characterized in that the electrically conductive material contains at least one metal from the following group: titanium, zirconium, vanadium, tantalum, tungsten, hafnium, niobium, rhenium, molybdenum, nickel, iron, aluminum.

8. The method according to claim 7, characterized in that the metal has a content of at least 50 wt .-%, in particular at least 60 wt .-% or at least 70 wt .-%, of the conductive material.

9. The method according to any one of the preceding claims, characterized in that the electrically conductive material is titanium or a titanium alloy, in particular TiAl or TiAIV.

10. The method according to any one of the preceding claims, characterized in that the electrically conductive material is used in powder form.

1 1. A method according to claim 10, characterized in that the starting material for a plurality of batches (1) from the electrically conductive material is produced by pressing with a binder and / or sintering.

12. The method according to any one of the preceding claims, characterized in that the conductive material is overheated during melting to a temperature which is at least 10 ° C, at least 20 ° C or at least 30 ° C above the melting point of the material.

13. Use of an electrically conductive material as a starting material for a floating melting process, characterized in that the starting material has several advantages parried, separated by areas of reduced cross section batches (1), where in a separation of the pre-separated batches (1) only takes place during melting in an electromagnetic alternating field.