EP3568639A2 - Four, méthode de commande du four et capteurs - Google Patents
Four, méthode de commande du four et capteursInfo
- Publication number
- EP3568639A2 EP3568639A2 EP17822731.0A EP17822731A EP3568639A2 EP 3568639 A2 EP3568639 A2 EP 3568639A2 EP 17822731 A EP17822731 A EP 17822731A EP 3568639 A2 EP3568639 A2 EP 3568639A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- oven
- air
- temperature
- humidity
- sensor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- 238000010438 heat treatment Methods 0.000 claims description 79
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C7/00—Stoves or ranges heated by electric energy
- F24C7/08—Arrangement or mounting of control or safety devices
- F24C7/087—Arrangement or mounting of control or safety devices of electric circuits regulating heat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C3/00—Stoves or ranges for gaseous fuels
- F24C3/12—Arrangement or mounting of control or safety devices
- F24C3/126—Arrangement or mounting of control or safety devices on ranges
- F24C3/128—Arrangement or mounting of control or safety devices on ranges in baking ovens
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C15/00—Details
- F24C15/32—Arrangements of ducts for hot gases, e.g. in or around baking ovens
- F24C15/322—Arrangements of ducts for hot gases, e.g. in or around baking ovens with forced circulation
- F24C15/327—Arrangements of ducts for hot gases, e.g. in or around baking ovens with forced circulation with air moisturising
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21B—BAKERS' OVENS; MACHINES OR EQUIPMENT FOR BAKING
- A21B3/00—Parts or accessories of ovens
- A21B3/04—Air-treatment devices for ovens, e.g. regulating humidity
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C15/00—Details
- F24C15/003—Details moisturising of air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C7/00—Stoves or ranges heated by electric energy
- F24C7/08—Arrangement or mounting of control or safety devices
- F24C7/082—Arrangement or mounting of control or safety devices on ranges, e.g. control panels, illumination
- F24C7/085—Arrangement or mounting of control or safety devices on ranges, e.g. control panels, illumination on baking ovens
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/0044—Furnaces, ovens, kilns
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
- G01J5/08—Optical arrangements
- G01J5/0846—Optical arrangements having multiple detectors for performing different types of detection, e.g. using radiometry and reflectometry channels
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
- G01J5/08—Optical arrangements
- G01J5/0853—Optical arrangements having infrared absorbers other than the usual absorber layers deposited on infrared detectors like bolometers, wherein the heat propagation between the absorber and the detecting element occurs within a solid
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K17/00—Measuring quantity of heat
- G01K17/06—Measuring quantity of heat conveyed by flowing media, e.g. in heating systems e.g. the quantity of heat in a transporting medium, delivered to or consumed in an expenditure device
- G01K17/08—Measuring quantity of heat conveyed by flowing media, e.g. in heating systems e.g. the quantity of heat in a transporting medium, delivered to or consumed in an expenditure device based upon measurement of temperature difference or of a temperature
- G01K17/20—Measuring quantity of heat conveyed by flowing media, e.g. in heating systems e.g. the quantity of heat in a transporting medium, delivered to or consumed in an expenditure device based upon measurement of temperature difference or of a temperature across a radiating surface, combined with ascertainment of the heat transmission coefficient
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K7/00—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements
- G01K7/42—Circuits effecting compensation of thermal inertia; Circuits for predicting the stationary value of a temperature
- G01K7/427—Temperature calculation based on spatial modeling, e.g. spatial inter- or extrapolation
Definitions
- the invention relates to the field of ovens, typically but not exclusively domestic ovens for cooking food. Some aspects of the invention concern heat flux and humidity sensors useful in ovens as well as other applications. Background to the invention Conventional ovens have limited controllability and reproducibility. In the case of ovens for food, they may apply heat to food incorrectly or provide results which are not reproducible. Cooking effects may vary substantially with altitude, humidity or other parameters. Except for expensive commercial ovens, they generally lack the ability to provide sophisticated time variation in cooking parameters. The present invention aims to provide an oven for heat treating an article which provides a controllable, reproducible time varying heat treatment process.
- an oven comprising an oven chamber for receiving an article (e.g. food) to be heat treated (e.g. cooked), at least one (typically electric) heating element, a humidity regulator, an air flow regulator (e.g.
- a fan such as a variable speed fan
- a plurality of sensors comprising at least one temperature sensor (and typically at least one humidity analyser)
- the controller configured (typically programmed) to receive measurements from the plurality of sensors and to control at least the at least one heating element, the air flow regulator (and typically the humidity regulator), responsive to the measurements, to thereby regulate the heat treatment (e.g. cooking) of an article received within the oven chamber (in use).
- the controller thereby regulates convective, radiative (and optionally also conductive) heat fluxes to the article during a heat treatment (e.g. cooking) cycle.
- the controller thereby regulates the rate of mass transfer of water to and/or from the article during the heat treatment (e.g. cooking) process.
- the heat treatment e.g. cooking
- convective, radiative (and optionally conductive) heat fluxes, and the rate of mass transfer of water to and/or from the article are independently regulated by the controller.
- the invention provides improved and reproducible control of the heat treatment cycle. In the case of an oven for cooking food, the resulting food quality is thereby better controlled.
- Embodiments of the invention, described below, enable an oven having a high level of control and reproducibility to be manufactured economically.
- the convective, radiative (and optionally also conductive) heat fluxes to the article, and typically also the rate of mass transfer of water to and/or from the article during the heat treatment (e.g. cooking) process may be varied with time during a heat treatment (e.g. cooking) cycle, in accordance with a predetermined program.
- the plurality of sensors comprises at least one sensor of the hemispherically-averaged radiative temperature above the exposed upper surfaces of the article (e.g. food).
- the controller controls at least one said heating element (and in some embodiments also the humidity regulator and/or the air flow regulator) responsive to the at least one sensor of radiative temperature to thereby regulate the (hemispherically-averaged) radiative heat flux incident on the upper food surfaces in the oven chamber.
- the incident radiative temperature may be regulated to a target incident radiative temperature. A numerical value of the incident radiative temperature may be calculated.
- Some or all of the heating elements are typically electric.
- the at least one heating element may comprise or be another heating element, such as a gas heater.
- the at least one said heating element may comprise one or more radiative heating elements, typically on the roof of the oven chamber.
- the current to such electric heating elements may be pulsed under the control of the controller, and the controller may vary the duty cycle, peak current or peak temperature to thereby control radiative heat transfer in the oven chamber.
- the temperature of the radiating heating elements may also be controlled, to adjust the peak intensity wavelength band of the emitted radiation.
- the plurality of sensors comprises convective heat transfer sensing means (such as one or more sensors, the outputs of which are together indicative of the convective heat transfer coefficient of air within the oven chamber) configured to measure convective heat transfer within the oven.
- the controller controls at least one said heating element and the humidity regulator (and optionally also the air flow regulator) responsive to the measured convective heat transfer to thereby regulate convective heat transfer to (or from) the article.
- Convective heat transfer to the article depends on the convective heat transfer coefficient of air within the oven chamber (which depends on the humidity and pressure of the air), the difference between the (measured) temperature of the air impinging on the article and the temperature of the surface of the article, and also the speed of impingement of air on the article (which is regulated by the air flow regulator).
- the controller may therefore regulate the convective heat transfer coefficient of air within the oven chamber.
- the controller may regulate the convective heat transfer coefficient of air within the oven chamber to a target convective heat transfer coefficient.
- the controller may calculate a numerical value of the convective heat transfer coefficient.
- the controller processes at least the humidity measured by the humidity analyser and controls at least the humidity regulator (and optionally also the air flow regulator and one or more electrical heating elements) to regulate the humidity of air in the oven chamber, for example to a target humidity.
- the controller may calculate a numerical value of the humidity of the air.
- the convective heat transfer coefficient of air within the oven and/or the rate of convective heat transfer to the article within the oven chamber is controlled independently of the humidity of air within the oven chamber.
- humidity is a factor which affects convective heat transfer, it is possible to vary other parameters, such as the speed of impingement of air on the article and thereby to independently vary these parameters.
- Humidity also affects radiative heat transfer (absorption of IR by asymmetric stretch and other absorption bands associated with triatomic molecules such as H 2 0, C0 2 ). Independently controlling humidity and convective heat transfer allows mass transfer and convective heating to be independently varied, under the control of the controller, which is especially useful when heat treating articles which are moisture sensitive, notably food.
- the controller may control one or more heating elements (in conductive thermal communication with an article in the oven compartment in use) to regulate the amount of heat conducted to the article, for example to a target conductive heat flux or to a target temperature of a support (e.g. a shelf) which receives the article in use.
- the oven comprises a shelf, the shelf comprising at least one said (typically electric) heating element controlled by the controller and at least one said temperature sensor.
- the said at least one (typically electric) heating element and at least one temperature sensor are preferably integrated within the shelf.
- the controller may control at least one said (e.g. electric) heating element of the shelf responsive to the temperature measured by the at least one temperature sensor of the shelf to thereby regulate the heat transmitted to food located on the shelf by conduction, in use (typically through a container in which the food is located).
- the controller may process temperature measurements of the at least one temperature sensor of the shelf and the time history of heat generation by the at least one heating element of the shelf to calculate heat transmitted to food located on the shelf by conduction.
- the shelf is typically fixed.
- the shelf may form the base of the oven chamber.
- the controller may comprise at least one processor and memory storing at least one heat treatment (e.g. cooking) program.
- the controller reads a stored heat treatment program which is indicative of target values of one or more operating parameters during a heating cycle. Values indicated by the program may in some embodiments be modified by user instructions (e.g. as to duration) received through a user interface and/or other parameters (such as altitude).
- the operating parameters determine how the controller independently controls convective, radiative (and optionally conductive) heat fluxes, and the rate of mass transfer of water to and/or from the article, and how this varies with time.
- the operating parameters typically comprise one or more of the said target incident radiative temperature, the said target convective heat transfer coefficient, the said humidity, and the said target conductive heat flux or temperature.
- the controller may store current target values of one or more said operating parameters in dependence on the heat treatment program.
- different programs may be associated with different food types, or different dish types (for example, different ways of cooking the same or different foodstuffs).
- the mass of food should be optionally entered by user - which may be used by the controller to optimise settings (most importantly the total cooking time).
- a recipe may include multiple stages, such as the sequential defrosting of a frozen bread dough, proofing of the same, baking of the same and finally cooling, all under optimal controlled conditions.
- the function of the controller may be implemented using a single processor (e.g.
- the controller may comprise a plurality of separate control circuits or units which receive a subset of sensor measurements and regulate a subset of the components which are controlled by the controller, for example, there may be a circuit which receives humidity measurements from the humidity analyser and controls the humidity regulator responsive thereto. There may be a circuit which receives measurements of the temperature in the fixed shelf and regulates the electrical heating element in the fixed shelf responsive thereto.
- the oven chamber has an oven enclosure which forms the base, roof and walls of the oven chamber (and typically also an oven door) the oven further comprises an air circulation conduit extending between one or more inlets located in the oven enclosure and one or more outlets (typically nozzles) located in the oven enclosure and spaced apart from the one or more inlets, and the air flow regulator regulates the speed of flow of air through the air circulation conduit from the one or more inlets to the one or more outlets.
- the air flow regulator may be a variable air impeller.
- the air flow regulator may be a variable speed fan.
- the air flow regulator may be a variable damper connecting the suction and discharge sides of a fan (which may therefore be constant speed).
- air circulates out of the oven chamber, through the inlets, through the air circulation conduit, driven by the air flow regulator, and back into the over chamber through the outlets, thereby circulating.
- the one or more inlets are in a lower region of the oven enclosure (e.g. in the lower half or lowest quarter of the oven chamber).
- some or all of the outlets are located in an upper region of the oven enclosure (e.g. in the upper half, or upper quarter, or roof of the oven chamber).
- At least one said (e.g. electric) heating element may be configured to heat air in the air circulation conduit (typically between the one or more inlets and the air flow regulator so that the air flow regulator mixes heated air).
- upper and lower, and related terms refer to the orientation in which the oven chamber is configured to be oriented during operation. This is typically defined by one or more ground contacting legs, one or more oven retaining formations adapted for locating the oven in a specific orientation, one or more shelves for receiving food on an upper surface thereof, and/or indicia (such as writing) defining an orientation of the oven.
- the orientation is typically also defined by the inlets and outlets of the air circulation channel and the air flow regulator which are arranged to impel air downwards through the oven chamber during use.
- a portion of the air circulation conduit is in gaseous communication with atmospheric air (for example through the air inlet vent and/or air outlet vent discussed below).
- the combined resistance to air flow of the one or more inlets and the combined resistance to air flow of the one or more outlets are substantially the same (for example to within 25% or within 10%).
- the air pressure in the oven chamber will remain similar to atmospheric pressure during operation (as the pressure difference between the one or more air inlets and the air flow regulator will be similar to the pressure difference between the air flow regulator and the one or more air outlets).
- the combined resistance to air flow of the one or more inlets and the combined resistance to air flow of the one or more outlets amounts to greater than 85%, or greater than 90%, of the resistance to air flow through the air circulation conduit. This improves the evenness of air flow through the outlets into the oven chamber and/or increases the speed of air impinging on the article.
- the invention also extends, in a second aspect to an oven comprising an oven housing, an oven chamber within the oven housing and a door opening into the oven chamber, an air circulation conduit extending between a plurality of inlets into the oven chamber and a plurality of outlets into the oven chamber, a part of the air circulation conduit intermediate the plurality of inlets and the plurality of outlets being in gaseous communication with atmospheric air, and an air impeller (which is typically an air flow regulator) (such as a fan) within the air circulation conduit, wherein (due to the number and shape of the inlets and outlets) the combined resistance to air flow of the one or more inlets and the combined resistance to air flow of the one or more outlets are substantially the same (for example to within 25% or within 10%).
- an air impeller which is typically an air flow regulator
- the combined resistance to air flow of the one or more inlets and the combined resistance to air flow of the one or more outlets are substantially the same (for example to within 25% or within 10%).
- the humidity regulator is configured to vary the humidity of air received into the air circulation conduit through the one or more inlets.
- the humidity regulator may be located in the air circulation conduit.
- the humidity regulator comprises a humidifier to controllably increase the humidity of the air in the air circulation conduit, for example, a water tank and a steam generator (comprising an electrical heating element) controllable to generate steam and thereby increase humidity.
- the humidity regulator may comprise a controllable vent (such as the air output vent described below) to allow humid air to controllably escape into the surrounding atmosphere.
- the air circulation conduit may comprise an air input vent (typically located between the one or more inlets and the air flow regulator) and/or an air output vent (typically located between the air flow regulator and the one or more outlets).
- the air input vent and/or air output vent may be regulated to control the flow of atmospheric air into the oven and the flow of humid air out of the oven to the surrounding atmosphere.
- the air input vent and/or air output vent may comprise dampers to vary the flow of air into or out of the air circulation conduit.
- the air input vent and air output vent may comprise dampers with a common actuator, for example they may comprise rotary dampers mounted on a common shaft driven by a rotary actuator under the control of the controller.
- the combined resistance to air flow of the one or more inlets and the combined resistance to air flow of the one or more outlets amounts to greater than 85%, or greater than 90%, of the resistance to air flow through the air circulation conduit.
- the oven comprises an air channel extending from within the oven (typically from within the air circulation conduit, typically between the air flow regulator and the outlets) and the exterior of the oven and a temperature regulator which in use regulates the temperature of air within a region of the air channel to above 100°C (to thereby prevent condensation on the walls of the air channel in said region), wherein the humidity analyser comprises a water partial pressure sensor located within the temperature regulated region of the air channel. Accordingly, the humidity of air within the oven adjacent the air channel (and therefore typically within the air circulation conduit) can be measured accurately.
- the invention extends in a third aspect to an oven comprising an oven housing, an oven chamber within the oven housing (and typically a door opening into the oven chamber), an air channel extending from within the oven and the exterior of the oven, through the oven housing, and a temperature regulator which in use regulates the temperature of air within a region of the air channel to above 100°C (to thereby prevent condensation on the walls of the air channel in said region), and a water partial pressure sensor located within the temperature regulated region of the air channel.
- the oven comprises an air circulation conduit having a plurality of inlets and a plurality of outlets and an air impeller (typically an air flow regulator) within the air circulation conduit and the air channel extends from the air circulation conduit to the exterior of the oven.
- the oven of the third aspect typically comprises a humidity regulator (typically a humidifier) as set out above.
- the humidity analyser may determine humidity in another way.
- the humidity analyser may comprise a circuit or program code executed on a processor (e.g. the processor of the controller) which infers the humidity of air from the power consumption and rotational speed of the air flow regulator (e.g. fan), and the temperature of air passing through the air flow regulator (measured with a temperature sensor).
- the invention extends in a fourth aspect to a method of determining the humidity of air circulating through an air circulation conduit, impelled by an electric fan, the method comprising monitoring the power consumption of the fan (and typically also the speed of the fan, or of the air in the air circulation conduit), the temperature of the air (and typically also the altitude or current atmospheric pressure) and thereby determining the humidity of the air in the air circulation conduit.
- the invention extends to an oven having an air circulation conduit and a controller configured (e.g. programmed) to determine the humidity of air circulating through the air circulation conduit by the said method.
- the speed of air flow through the nozzles is regulated by the air flow regulator. This in turn determines the speed of air impingement on the article.
- this speed is in the range 0.2 - 10 ms "1 .
- the upper end of this range is much higher than is typical in a domestic oven.
- the speed of air impingement is greater than 1 ms " , greater than 2 ms "1 or greater than 4 ms " .
- the vertical position of the article in the oven chamber is less important than would otherwise be the case. Accordingly, it may be that the oven chamber does not comprise any intermediate shelves (and in some embodiments any demountable shelf retaining formations) between the base of the oven chamber and the top of the oven chamber.
- the base of the oven chamber is formed by the above described shelf.
- the plurality of sensors may comprise at least one sensor of (hemispherically-averaged) radiative temperature above the exposed surfaces of the article (e.g. food), and the plurality of sensors may comprise convective heat transfer sensing means. It may be that the least one sensor of (hemispherically-averaged) radiative temperature and the convective heat transfer sensing means are integrated.
- the plurality of sensors may comprise a heat sensor for independently determining (hemispherically-averaged) radiative temperature (above the exposed surfaces of the article, e.g.
- the convective heat transfer coefficient of air within the chamber comprising a plurality of temperature sensors, the outputs from which are processable (and in use are analysed by the controller) to independently derive the (hemispherically-averaged) radiative temperature within the oven and the convective heat transfer coefficient of air within the oven, or parameters related to these properties.
- the heat sensor may comprise a sensor body comprising insulation, a heat sink, a sensing surface having first and second surface mounted elements thereon, the first surface mounted element having a relatively lower emissivity surface and thermally coupled to the heat sink through a first thermal conduction path extending through the insulation, the second surface mounted element having a relatively higher emissivity surface and thermally coupled to the heat sink through a second thermal conduction path extending through the insulation, a temperature sensor configured to measure the temperature of the heat sink, a temperature sensor configured to measure the temperature of the first surface mounted element, a temperature sensor configured to measure the temperature of the second surface mounted element, at least two temperature sensors configured to measure the temperature at spaced apart locations along the first thermal conduction path and at least two temperature sensors configured to measure the temperature at spaced apart locations along the second thermal conduction path.
- the invention extends in a fifth aspect to a heat sensor for independently determining (hemispherically-averaged) radiative temperature and the convective heat transfer coefficient of gas on a sensing surface of the heat sensor, the sensor comprising a sensor body comprising insulation, a heat sink, a sensing surface having first and second surface mounted elements thereon, the first surface mounted element having a relatively lower emissivity exterior and thermally coupled to the heat sink through a first thermal conduction path extending through the insulation, the second surface mounted element having a relatively higher emissivity exterior and thermally coupled to the heat sink through a second thermal conduction path extending through the insulation, a temperature sensor configured to measure the temperature of the heat sink, a temperature sensor configured to measure the temperature of the first surface mounted element, a temperature sensor configured to measure the temperature of the second surface mounted element, at least two temperature sensors configured to measure the temperature at spaced apart locations along the first thermal conduction path and at least two temperature sensors configured to
- the sensing surface further comprises a gas temperature sensor.
- the gas temperature sensor typically has a cross-section area of less than 10% (or less than 1 %) of the cross-sectional area of the first and second surface mounted elements and so is much less sensitive to convective heat transfer. It is small so it has a rapid response to change, and it has a low emissivity surface (e.g. may be gold plated) so that it is unaffected by incident radiation.
- the first and second surface mounted elements have the same size and shape but different emissivities. It may be that the emissivity of the first and second surface mounted elements differs by at least 0.25, at least 0.5, at least 0.75 or at least 0.9.
- the emissivity of the first surfaced mounted element is typically less than 0.1 .
- the emissivity of the second surface mounted element is typically greater than 0.9. They may be formed from the same material (typically a metal) but with different coatings, for example, the first surface mounted element may have a matt black coating and the second surface mounted element may have a metal (e.g. gold) coating.
- the first and second surface mounted elements may be generally planar. They typically protrude into the oven chamber. They may be oriented in the same direction. They may be adjacent and parallel. They may be adjacent and parallel to the roof and base of the oven chamber.
- the first and second surface mounted elements thereby have a similar sensitivity to convective heat transfer but different emissivities and therefor dissimilar sensitivity to radiative heat transfer.
- the temperatures measured by the temperature sensors are measured repetitively to thereby determine at least one rate of change of temperature.
- the temperatures measured by the said temperature sensors can be processed to independently determine the (hemispherically-averaged) radiative temperature at the sensing surface and the conductive heat transfer parameter. Furthermore, these properties can be determined independently of the temperature of the heat sensor itself.
- the first and second surface mounted elements may be hollow (to thereby reduce their heat capacity and increase their rate of temperature response to changes in radiative temperature and/or convective heat transfer).
- the controller may be configured (e.g.
- the controller may take into account (actual or average local) atmospheric pressure.
- the oven may comprise a pressure sensor.
- the controller may comprise stored data concerning the altitude or average atmospheric pressure at the location of the oven and the controller may be configured to take that stored data into account during operation.
- the controller may be configured to receive the altitude or average atmospheric pressure data, for example through a user interface.
- the oven chamber is typically enclosed.
- the oven chamber is adapted for receiving a product (typically food) to be cooked.
- the cooking chamber typically comprises a door.
- the interior of the cooking chamber is typically defined by the oven enclosure and the interior of the door.
- the oven may be a domestic oven, for example, it may have an oven chamber with a capacity of less than 150 litres. It may have a width of less than 80 cm. It may have a depth of less than 1 m. It may have a height of less than 1 m.
- a sixth aspect of the invention there is provided a method of operating an oven, the oven comprising an oven chamber for receiving an article (e.g. food) to be heat treated (e.g. cooked), at least one (typically electric) heating element, a humidity regulator, an air flow regulator (e.g. a fan, such as a variable speed fan), a plurality of sensors, and typically a controller, the plurality of sensors comprising at least one temperature sensor (and typically at least one humidity analyser), the method comprising making measurements using the plurality of sensors, and controlling at least the at least one heating element and the air flow regulator (and typically the humidity regulator), responsive to the measurements, and thereby regulating the heat treatment (e.g.
- convective, radiative (and optionally also conductive) heat fluxes to the article are thereby regulated during a heat treatment (e.g. cooking) cycle.
- the rate of mass transfer of water to and/or from the article during the heat treatment (e.g. cooking) process is thereby regulated.
- convective, radiative (and optionally conductive) heat fluxes, and the rate of mass transfer of water to and/or from the article are thereby independently regulated.
- the convective, radiative (and optionally also conductive) heat fluxes to the article, and typically also the rate of mass transfer of water to and/or from the article during the heat treatment e.g.
- the cooking process may be varied with time during a heat treatment (e.g. cooking) cycle, typically in accordance with a predetermined program.
- the plurality of sensors comprises at least one sensor of the hemispherically-averaged radiative temperature above the exposed upper surfaces of the article (e.g. food) and the output of at least one said heating element (and in some embodiments also the humidity regulator and/or the air flow regulator) is controlled responsive to the at least one sensor of radiative temperature to thereby regulate the (hemispherically-averaged) radiative heat flux incident on the upper food surfaces in the oven chamber.
- the incident radiative temperature may be regulated to a target incident radiative temperature.
- the temperature of the radiating heating elements may also be controlled, to adjust the peak intensity wavelength band of the emitted radiation.
- the plurality of sensors comprises convective heat transfer sensing means (such as one or more sensors, the outputs of which are together indicative of the convective heat transfer coefficient of air within the oven chamber) configured to measure convective heat transfer within the oven and the controller controls at least one said heating element and the humidity regulator (and optionally also the air flow regulator) responsive to the measured convective heat transfer to thereby regulate convective heat transfer to (or from) the article.
- the method may comprise regulating the convective heat transfer coefficient of air within the oven chamber, for example to a target convective heat transfer coefficient.
- the method may comprise calculating a numerical value of the convective heat transfer coefficient.
- the humidity regulator (and optionally also the air flow regulator and one or more electrical heating elements) is regulated to regulate the humidity of air in the oven chamber, for example to a target humidity, typically taking into account the humidity measured by the humidity analyser. A numerical value of the humidity of the air may be calculated.
- the convective heat transfer coefficient of air within the oven and/or the rate of convective heat transfer to the article within the oven chamber is controlled independently of the humidity of air within the oven chamber.
- the power output of one or more heating elements in conductive thermal communication with an article in the oven compartment in use) may be controlled to regulate the amount of heat conducted to the article, for example to a target conductive heat flux or to a target temperature of a support (e.g.
- the method may be carried out by at least one processor in electronic communication with a memory storing at least one heat treatment (e.g. cooking) program.
- the method may comprise circulating air, using an air flow regulator, through an air circulation conduit extending between one or more inlets located in the oven enclosure and one or more outlets (typically nozzles) located in the oven enclosure and spaced apart from the one or more inlets.
- the method may comprise regulating the humidity of air received into the air circulation conduit through the one or more inlets.
- the humidity may be regulated by regulating a humidifier (e.g. a steam generator) and/or an air output vent which is selectively openable to vent humid air.
- a humidifier e.g. a steam generator
- the method may comprise passing air from within the air circulation conduit through a channel having a region at a temperature of at least 100°C and measuring the partial pressure of water in the air in that region.
- the invention extends to a computer readable storage medium storing computer program code which, when executed on the controller of an oven, causes the oven to carry out the method of the sixth aspect of the invention. Further optional features of the sixth aspect of the invention correspond to optional features set out in respect of the first five aspects of the invention and, indeed, optional features mentioned above in respect of any aspect of the invention apply to each aspect of the invention.
- Figure 1 is a schematic cross-section through an oven
- Figure 2 is a schematic diagram of the controller of the oven
- Figure 3 is a side elevation section through a humidity analyser
- Figure 4 is a plan view of a combined convective heat and radiant heat flux sensor
- Figure 5 is an example of the variation of cooking parameters (y-axis) with time (x- axis) throughout a cooking cycle, specified by a cooking programme.
- Figure 1 illustrates a domestic oven (1 ) for cooking food.
- the oven comprises an outer oven wall (2) including a thermally insulating material, an oven chamber (4) having an oven enclosure (6) and a door (8), which together define the oven chamber, where food is cooked in use.
- a controller (100) is located within the oven outer wall but outside of the oven enclosure.
- a fixed shelf (10) which supports food (12), retained within a container (14) (such as a metal tray) during use.
- the fixed shelf comprises a shelf heating element (16) and a shelf temperature sensor (18).
- An air circulation conduit (20) extends around the periphery of the oven chamber between a plurality of inlet apertures (22), located near the base of the oven chamber, and a plurality of nozzles (24), located in the roof of the oven chamber, and retains a variable speed fan (32) which is controlled in use to cause air to re-circulate through the air circulation conduit and oven chamber as shown by the arrows in Figure 1 .
- the number and cross-section area of the inlet apertures, and the number and shape of the nozzles are selected to provide a similar level of resistance to air flow and the total resistance of the inlet apertures and nozzles makes up at least 90% of the resistance to air flow of the air circulation path through the air circulation conduit.
- a humidity regulator shown generally as (28) comprises a water tank (30) and a controllable electrical heating element (32), which is controllable by the controller to generate steam as required, and thereby controllably humidify air in the air circulation conduit.
- a humidity regulator shown generally as (28) comprises a water tank (30) and a controllable electrical heating element (32), which is controllable by the controller to generate steam as required, and thereby controllably humidify air in the air circulation conduit.
- Between the nozzles and the roof of the oven chamber are located strips of radiant electrical heating elements (34) under the control of the controller.
- the radiant electrical heating elements have maximum operating temperatures in the range of 800°C - 2000°C, which can be helpful in some types of cooking, for example to simulate the direct exposure to burning wood found in some pizza ovens.
- a control circuit enables the controller to vary both the maximum temperature of the radiant heating elements and the duty cycle of the electrical heating elements, and so the controller can regulate both the spectrum of radiant heat incident on the food from the radiant electrical heating elements, and also the average power delivered by the electrical heating elements.
- the oven chamber includes a heat sensor (300) which extends through the enclosure wall and which is configured to measure both the convective heat transfer coefficient of air adjacent the oven chamber wall and the (hemispherically-averaged) incident radiative temperature above the exposed upper surfaces of the article (e.g. food).
- the heat sensor is described further below with reference to Figure 4.
- the air circulation conduit also includes an inlet (38) for receiving ambient air and an outlet (40) for venting humid air to the surrounding atmosphere (36), and an inlet damper (42) and an outlet damper (44) which regulate air flow through the inlet and the outlet. Typically, these are controlled in common.
- the dampers (42 and 44) are controlled using a common shaft (46) driven by a rotary actuator (48) under the control of the controller.
- the relative orientation of the dampers is selected to achieve a preferred pressure distribution within the air circulation conduit.
- the relative orientation of the dampers is fine tuned for each individual oven during manufacture to thereby adapt for manufacturing tolerances.
- the air circulation conduit comprises an aperture (202) communicating with a conduit (204) through which a small proportion of re-circulating air (50) may pass out of the oven, to the atmosphere (36), through a humidity sensing arrangement (200), which is described further below with reference to Figure 3. Because the humidity sensing arrangement is located in the air circulation conduit downstream of the fan, there is a slight positive air pressure which drives air out to the atmosphere, and the dimensions of the aperture and conduit are selected to have a suitable resistance to air flow such that only a small proportion of re-circulating air is lost through the humidity sensing arrangement.
- the controller (100) comprises a control module (102) comprising a microprocessor (104) and memory (106) which stores a control program (108) and various cooking programs (1 1 OA, 1 10B, 1 10C etc.).
- the control module has a plurality of inputs for receiving signals from the various sensors, including temperature signals (120) from each of the various temperature sensors (18, 309, 31 1 , 312, 307, 314, 316, 317, 305 and typically others), a humidity signal (122) from the humidity sensor (207) and typically other signals such as a fan power level or air speed signal or fan speed signal (124) from a tachometer in the air circulation conduit.
- the signals are digitised using an ADC (if they are not already in digital format).
- the controller may also receive user interface command signals (128) such as a door open signal, inputs (130) from manual user interface controls buttons, knobs etc., and remote user interface instructions (132) received from other devices through a wired or wireless electronic interface (e.g. via internet protocol). These may include maximum temperature or duration settings etc., or the mass of the food.
- the controller also stores relevant user settings (134), including preferred programs and settings and also including the altitude (136) or a parameter related to the altitude (e.g.
- the controller stores calculated parameters in the memory during use, such as calculated values of incident radiative temperature (138) in the oven chamber, the convective heat transfer coefficient (140), the humidity of air in the oven (142), air pressure in the air circulation conduits (144) and so forth.
- the controller also stores target values of key operating parameters during use, for example target values of incident radiative temperature (146), heat transfer coefficient (148), humidity (150) etc.
- the controller has a number of outputs including a fan control output (152), fan damper actuator control output (154), humidifier control output (156), radiant heater maximum temperature (or maximum current) control output (158), radiant heater duty cycle control output (160) (e.g. a digital or analogue values communicate to a radiant heater control circuit, or a digital signal which switches a FET or other switch, to switch current to the radiant heater on and off), shelf temperature (162) or shelf electrical heater control output (164), a heater control output (166) for the electrical heater (16) in the shelf (10), a heater control output (168) for the electrical heater in the humidity analyser etc.
- a fan control output 152
- fan damper actuator control output 154
- humidifier control output 156
- radiant heater maximum temperature (or maximum current) control output 158
- radiant heater duty cycle control output 160
- a digital or analogue values communicate to a radiant heater control circuit, or a digital signal which switches a FET or other switch, to switch current to the radiant heater on and off
- the function of the controller is carried out by a module having a microprocessor executing a program
- the controller may comprise multiple distributed modules which address individual parts of the function of the controller.
- the regulation of temperature in the shelf, or in the humidity analyser may be implemented by a simple electronic feedback circuit in the shelf or humidity analyser respectively.
- the derivation of radiant temperature and convective heat transfer coefficient by the heat sensor may be carried out by a circuit or microprocessor within the heat sensor etc.
- the humidity analyser (200) measures the humidity of air within the air circulation channel (20) (and thereby introduced into the oven chamber).
- the air circulation channel has an aperture (202) and a channel (204) extending through the humidity analyser.
- the humidity analyser has a body (205) outside of the oven outer wall (2) comprising thermal insulation (206). Due to the positive pressure of air in the air circulation channel (arising from the action of the fan), air passes into channel (204) and out of an external aperture (21 1 ) to the outside air (36). Within the body there is a block of metal (209) or another thermally conductive material, and a heater element (210) and temperature sensor (208) are used to regulate the temperature of block of metal to about 105°C. At this temperature, the interior of the channel, where it passes through the block of metal, is kept clear of condensation but the maximum temperature of the temperature and humidity sensing elements is not exceeded.
- a combined humidity and temperature sensor (207) (for example, a capacitive sensor, such as a HIH8000 Series solid state digital humidity/temperature sensor available from Honeywell, Inc., Morris Plains, New Jersey) measures the partial pressure of water within the channel.
- a capacitive sensor such as a HIH8000 Series solid state digital humidity/temperature sensor available from Honeywell, Inc., Morris Plains, New Jersey
- Figure 4 is a plan view, from above, of heat sensor (300), which independently measures both the convective heat transfer coefficient of circulating air and the hemispherically averaged radiative temperature of incident radiation.
- the heat sensor is located on the oven enclosure with the sensing surfaces facing upwards, generally in the middle of the oven chamber and extends through the thermal insulation (2) of the oven outer wall.
- the heat sensor has a high emissivity sensor spade (313), functioning as the second surface mounted element and a low emissivity sensor spade (308), functioning as the first surface mounted element.
- the sensor spades are planar and hollow, and aligned parallel to the roof and base of the oven (thereby facing the radiant elements in the roof and the air nozzles). They are made of the same material with different coatings - gold in the case of the low emissivity sensor spade, and a matt black coating in the case of the high emissivity sensor spade.
- Each sensor spade includes a temperature sensor (314, 309) respectively and is connected through a thermally conductive (typically metal) rod (315,310) to the heat sink (303).
- Further temperature sensors are located in the heat sink (305), and at spaced apart locations (31 1 , 312) along the thermally conductive rod which connects the low emissivity sensor spade to the heat sink, and at spaced apart locations (316, 317) along the thermally conductive rod which connects the high emissivity sensor spade to the heat sink.
- the sensing surface also comprises an air temperature sensor (307) which is small to ensure rapid response to changes in temperature, and is gold coated (being a low emissivity coating to minimise convective heat transfer).
- the controller can monitor and independently vary the convective, radiative and conductive heat flow to the food, as well as mass transfer of water to and/or from the food.
- the velocity of air impingement is at least 0.2 ms ⁇ ⁇ and typically several times this. Because of the level of control of heat flux to the food, and the regulation of the humidity of the air within the oven compartment, the vertical position of the food within the oven chamber is relatively unimportant.
- the food can be located on a simple shelf forming the base of the oven chamber.
- the convective, radiative and conductive heat flow to the food, as well as mass transfer of water to and/or from the food are determined with reference to a program which specifies how these parameters vary during use.
- the program may specify the variation with time (x-axis) of the convective heat transfer coefficient, /?, (400), radiative heat temperature level (404), conductive heat transfer (406) through the shelf, and humidity (402) which affects mass transfer of water between the air in the oven chamber and the food.
- This allows sophisticated food cooking programs to be implemented automatically.
- a number of user input options, such as a maximum temperature or time may also be provided which modulate the program.
- the controller can determine a target time course of key parameters such as radiative heat temperature level, convective heat transfer coefficient, humidity, radiant heater power or temperature etc. Heating can be adapted depending on the altitude of the device. Altitude affects the density of air in the oven, and hence affects both radiative and convective heat transfer. Altitude is therefore used along with food mass to modulate the aspects of the program, such as duration. Cooking generally takes longer at altitude than sea level.
- the controller repetitively makes measurements from the sensors, processes the stored measurements to calculate operating parameters, compares these operating parameters with target values, and controls the sensor outputs using conventional feedback logic to achieve the target operating parameters as closely as possible.
- Some embodiments of the invention include an automatic self-test protocol to detect fouling of the high or low emissivity sensor spades.
- the fan Before a heat treatment cycle is commenced, the fan is switched to maximum speed, the radiant heating strips in the roof of the oven chamber are switched to maximum power for a short period of time (e.g. 10 seconds) and then off again.
- the subsequent change in temperature of the sensor spades indicated by temperature sensors (209, 214) is then monitored.
- the temperature of the high-emissivity sensor spade should increase substantially and then decay.
- the temperature of the low-emissivity sensor spade should be affected to only a very limited extent by the radiant heat.
- the measured temperature responses with time are compared with patterns of expected temperature responses with time stored in the memory.
- the fan is run at a fixed speed (to reduce cost) and a variable damper is provided, adjacent the fan, connecting the fan suction and discharge. Instead of regulating the speed of the fan, the position of the damper (how open it is) is controlled, to thereby regulate the air flow speed.
- humidity is inferred rather than directly measured, for example from the power consumption or speed of the fan.
- the electrical power of the fan is a function of fan speed (which can be measured), temperature (which is already measured in the system), atmospheric pressure (which has previously been received and stored), and the density of the oven chamber atmosphere (which is a linear function of the ratio of air to water vapour).
- fan power and fan speed, unless that is fixed
- This has the advantage that there is not a humidity sensor to get contaminated (e.g. by condensation of volatile oils from food, silicone compounds vaporised from oven door seals etc.)
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- Spectroscopy & Molecular Physics (AREA)
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Abstract
L'invention concerne un four, approprié pour une utilisation domestique de cuisson d'aliments, comprenant des capteurs de température, d'humidité, de transfert de chaleur par convection et de température rayonnante, et commandant des flux de chaleur convective, rayonnante et conductrice, ainsi que le taux de transfert de masse d'eau vers un article, et/ou depuis ce dernier, tel qu'un aliment, tout au long d'un processus de cuisson. Un canal de circulation d'air comporte des entrées et des buses de sortie, et un régulateur de vitesse d'air variable, les entrées, les sorties et la vitesse d'air étant conçues pour fournir une vitesse d'impact d'air relativement élevée sur un article se trouvant dans le four, permettant à un article de reposer sur la base du four, et de réduire au minimum la perte d'air conditionné par rapport à la chaleur et à l'humidité lors de l'ouverture de la porte de four. Un capteur de température rayonnante et de coefficient de transfert de chaleur par convection comporte des première et seconde fourches de capteur, à revêtements à haute et faible émissivités, connectées à un dissipateur thermique par l'intermédiaire de conducteurs, une pluralité de capteurs de température situés dans les fourches de capteur et espacés le long des conducteurs, et un capteur de température d'air, des lectures de température étant prises périodiquement de façon à déterminer indépendamment la température rayonnante et le coefficient de transfert de chaleur par convection d'air.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB1620108.9A GB201620108D0 (en) | 2016-11-28 | 2016-11-28 | Oven method of controlling oven and sensors |
PCT/GB2017/053569 WO2018096369A2 (fr) | 2016-11-28 | 2017-11-28 | Four, procédé de commande de four et capteurs |
Publications (1)
Publication Number | Publication Date |
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EP3568639A2 true EP3568639A2 (fr) | 2019-11-20 |
Family
ID=58073415
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17822731.0A Withdrawn EP3568639A2 (fr) | 2016-11-28 | 2017-11-28 | Four, méthode de commande du four et capteurs |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP3568639A2 (fr) |
GB (3) | GB201620108D0 (fr) |
WO (1) | WO2018096369A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022235154A1 (fr) | 2021-05-04 | 2022-11-10 | Hukseflux Holding B.V. | Capteur thermique, système de mesure et procédé d'estimation d'une température de l'air et/ou d'un coefficient de transfert de chaleur par convection |
WO2022235153A1 (fr) * | 2021-05-04 | 2022-11-10 | Hukseflux Holding B.V. | Système de mesure de confort thermique |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB201814623D0 (en) * | 2018-09-07 | 2018-10-24 | Cambridge Sensor Innovation Ltd | Oven and method of operating an oven |
CN109163810B (zh) * | 2018-10-15 | 2020-06-09 | 北京环境特性研究所 | 高温转子辐射测温装置及方法 |
GB201915605D0 (en) * | 2019-10-28 | 2019-12-11 | Cambridge Sensor Innovation Ltd | Humidity measurement |
EP4118381A4 (fr) * | 2020-03-13 | 2023-11-22 | Femas Metal San. Ve Tic. A.S. | Four avec unité de régulation de température |
CN111493353A (zh) * | 2020-05-18 | 2020-08-07 | 深圳市创美威节能设备有限公司 | 一种烤烟方法及烤烟装置 |
CN114264127A (zh) * | 2020-09-16 | 2022-04-01 | 科峤工业股份有限公司 | 烤箱的热回收效率的监控方法及其装置 |
BE1029519B1 (de) * | 2021-06-23 | 2023-01-30 | Miele & Cie | Verfahren zum Betreiben eines Gargeräts und Gargerät |
GB2619736A (en) * | 2022-06-14 | 2023-12-20 | Ooni Ltd | Electric pizza oven and method of use |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5062066A (en) * | 1989-08-17 | 1991-10-29 | Nabisco Brands, Inc. | Model referenced control of a food treatment device |
GC0000245A (en) * | 2001-09-07 | 2006-03-29 | Exxonmobil Upstream Res Co | High-pressure separation of a multi-component gas |
DE50206991D1 (de) * | 2002-03-07 | 2006-07-06 | Eloma Gmbh | Verfahren zum Erfassen der Feuchte in einem Gerät zur Behandlung und Zubereitung von Nahrungsmitteln sowie Gerät zur Behandlung und Zubereitung von Nahrungsmitteln |
DE102006058617B3 (de) * | 2006-12-11 | 2008-02-21 | Miele & Cie. Kg | Verfahren zur Bestimmung des zeitlichen Verlaufs der während eines Garvorgangs in einem Garraum eines Backofens von einem Gargut abgegebenen Dampfmenge sowie Vorrichtung zur Durchführung des Verfahrens |
DE102010062504B4 (de) * | 2010-12-07 | 2013-04-25 | BSH Bosch und Siemens Hausgeräte GmbH | Einschubteil für einen Garraum und System aus einem Gargerät und diesem Einschubteil |
DE102010055983A1 (de) * | 2010-12-23 | 2012-06-28 | Rational Aktiengesellschaft | Verfahren zum Steuern eines Garverfahrens in einem Gargerät sowie Gargerät |
US20180184668A1 (en) * | 2014-06-05 | 2018-07-05 | Ingo Stork Genannt Wersborg | Heat treatment monitoring system |
-
2016
- 2016-11-28 GB GBGB1620108.9A patent/GB201620108D0/en not_active Ceased
-
2017
- 2017-11-28 GB GB1821250.6A patent/GB2566401B/en active Active
- 2017-11-28 GB GB201821284A patent/GB2567076B/en active Active
- 2017-11-28 EP EP17822731.0A patent/EP3568639A2/fr not_active Withdrawn
- 2017-11-28 WO PCT/GB2017/053569 patent/WO2018096369A2/fr unknown
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022235154A1 (fr) | 2021-05-04 | 2022-11-10 | Hukseflux Holding B.V. | Capteur thermique, système de mesure et procédé d'estimation d'une température de l'air et/ou d'un coefficient de transfert de chaleur par convection |
WO2022235153A1 (fr) * | 2021-05-04 | 2022-11-10 | Hukseflux Holding B.V. | Système de mesure de confort thermique |
NL2028140B1 (en) | 2021-05-04 | 2022-11-10 | Hukseflux Holding B V | Thermal sensor and measurement system |
NL2028142B1 (en) * | 2021-05-04 | 2022-11-23 | Hukseflux Holding B V | Thermal comfort measuring system |
Also Published As
Publication number | Publication date |
---|---|
WO2018096369A2 (fr) | 2018-05-31 |
GB2567076B (en) | 2019-12-25 |
GB201620108D0 (en) | 2017-01-11 |
GB201821284D0 (en) | 2019-02-13 |
GB2566401B (en) | 2019-09-11 |
GB2567076A (en) | 2019-04-03 |
GB201821250D0 (en) | 2019-02-13 |
GB2566401A (en) | 2019-03-13 |
WO2018096369A3 (fr) | 2018-07-26 |
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