EP3553794A1 - Method for applying a lining for ferrous and non-ferrous metal wires and cables and their alloys - Google Patents
Method for applying a lining for ferrous and non-ferrous metal wires and cables and their alloys Download PDFInfo
- Publication number
- EP3553794A1 EP3553794A1 EP19168246.7A EP19168246A EP3553794A1 EP 3553794 A1 EP3553794 A1 EP 3553794A1 EP 19168246 A EP19168246 A EP 19168246A EP 3553794 A1 EP3553794 A1 EP 3553794A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- compound
- coating
- wire
- curing
- application
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 58
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 20
- 239000002184 metal Substances 0.000 title claims abstract description 20
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 239000000956 alloy Substances 0.000 title claims abstract description 6
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 64
- 239000011248 coating agent Substances 0.000 claims abstract description 58
- 150000001875 compounds Chemical class 0.000 claims abstract description 52
- 238000004132 cross linking Methods 0.000 claims abstract description 29
- 239000007787 solid Substances 0.000 claims abstract description 18
- 230000005855 radiation Effects 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 9
- 229920000642 polymer Polymers 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 6
- 239000000178 monomer Substances 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims abstract description 6
- 230000008569 process Effects 0.000 claims description 28
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 238000005096 rolling process Methods 0.000 claims description 13
- 238000005516 engineering process Methods 0.000 claims description 12
- 239000000314 lubricant Substances 0.000 claims description 9
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 150000003573 thiols Chemical class 0.000 claims description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052582 BN Inorganic materials 0.000 claims description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- BQMQLJQPTQPEOV-UHFFFAOYSA-N OP(=O)OC=C Chemical class OP(=O)OC=C BQMQLJQPTQPEOV-UHFFFAOYSA-N 0.000 claims description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical class B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims description 2
- 229910000085 borane Inorganic materials 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 238000005034 decoration Methods 0.000 claims description 2
- RSCACTKJFSTWPV-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 RSCACTKJFSTWPV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 239000001023 inorganic pigment Substances 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 239000002105 nanoparticle Substances 0.000 claims description 2
- 239000012860 organic pigment Substances 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- -1 polytetrafluoroethylene Polymers 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims description 2
- 150000004756 silanes Chemical class 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- SYDJVRWZOWPNNO-UHFFFAOYSA-N sucrose-benzoate Natural products OCC1OC(OC2(COC(=O)c3ccccc3)OC(CO)C(O)C2O)C(O)C(O)C1O SYDJVRWZOWPNNO-UHFFFAOYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 229920006305 unsaturated polyester Polymers 0.000 claims description 2
- 150000003673 urethanes Chemical class 0.000 claims description 2
- 229920001567 vinyl ester resin Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 230000001050 lubricating effect Effects 0.000 abstract description 9
- 230000001681 protective effect Effects 0.000 abstract description 5
- 238000001723 curing Methods 0.000 description 9
- 238000010297 mechanical methods and process Methods 0.000 description 7
- 230000005226 mechanical processes and functions Effects 0.000 description 7
- 230000007613 environmental effect Effects 0.000 description 5
- 238000005461 lubrication Methods 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 230000036541 health Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- 239000012855 volatile organic compound Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000001029 thermal curing Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000006223 plastic coating Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B19/00—Apparatus or processes specially adapted for manufacturing insulators or insulating bodies
- H01B19/04—Treating the surfaces, e.g. applying coatings
Definitions
- the present invention relates to a method for forming a solid polymeric coating on the surface of metal wires with a section of any shape and size and cables formed by stranded wires.
- Said method includes a first step of application of the liquid or solid state compound and a second step of curing such compound through the application of an amount of ultraviolet radiation, sufficient to trigger the cross-linking polymerisation which causes the solidification of the compound and the consequent formation of a coating with features of flexibility, elongation, hardness and adhesion, such as to ensure high protective capacity and/or with lubricant features.
- Coatings are used to decorate wires and cables and to protect them from deterioration factors, deriving from oxidation, from chemical and environmental agents, such as corrosion in marine environments, as well as by other aging factors, prolonging the useful life of the wires and cables themselves.
- Wires and cables coatings may also have other purposes.
- An example is that of the drawing and/or rolling of metal (ferrous or non-ferrous) and their alloys wire rod and/or wire, having sections of any shape or size. This process, known since a long time, consists in reducing the section of the wire rod and/or wire by deformation, without removing any material.
- the rod and/or the wire is passed inside of arrays of material of appropriate hardness, commonly called dies, the section of which negatively reproduces the shape and the size of the cross section of the wire rod and/or wire to be obtained.
- One or more steps can be provided through the dies and through one or more machines. These steps create friction on the wire rod or on the wire, with consequent heating of these and with possible consequent breakages. For this reason, the surface of the wire rod and/or the wire must be lubricated, so as to reduce the friction and therefore the heating and the breakage.
- lubricants are generally used, such as stearates, which are solid at room temperature (dry lubrication), or oils that are liquids (bath lubrication). The dry lubricant is applied on the wire rod and/or on the wire, while bath lubrication involves dipping the die into the lubricant.
- the wire rod and/or the wire are deformed by rollers which exert a mechanical pressure on the wire rod and/or wire.
- a second method called rolling
- the wire rod and/or the wire are deformed by rollers which exert a mechanical pressure on the wire rod and/or wire.
- only dry lubrication occurs, similarly to what has already been seen for the first method.
- Another purpose is to limit corrosion and deterioration of the wire rod and/or wire, protecting them from air and moisture with a barrier effect.
- the polymeric compounds used nowadays for these purposes are self-supporting plastic coatings, made by applying to the surface powders and/or polymerising materials, which are subsequently solidified by means of a thermal process.
- the execution of this thermal curing process requires the use of bulky and expensive systems.
- the object of the present invention is to provide a coating of metal wires, cables or wire rods, both for decorative purposes and for protective purposes, as well as lubricant for drawing, rolling or similar processes and, at the same time, clearing the VOC emission, whilst also avoiding the formation of industrial waste, to be achieved with less bulky equipment and systems, characterised by a low initial economical investment and low costs in terms of energy resources.
- the wires and cables are presented in the form of a coil, both inbound and outbound from the process: not excluding different possibilities, such as the application of the coating on the wires and cables of rectilinear shape.
- the industrial applications of the invention relate to the coating of wires and cables used in multiple fields of industrial production, in order both to ensure high standards of protection of the wires and cables from deterioration factors, such as oxidation and the corrosive action of chemical and environmental agents, and to obtain decorating colouring of the surface, and to superficially apply a lubricant for the subsequent processing (extrusion, rolling, etc.).
- the process comprises two sequential operational steps, passing the wire or cable inside two or more serial operating units, one or more for each step, or within one or more operating units, within each of which the two steps are carried out in sequence.
- the first step consists in the physical application of a compound on the outer surface.
- This application is obtained by passing the wire or the cable in the operating units where the operation took place in a manner known per se.
- the wire or cable runs inside of machines and production lines, adapted to perform the two steps, without the constraints of direction, if not those determined by the layout of the machines and of the production lines themselves.
- the compound is formed from monomers and/or oligomers and/or polymers and/or other additives and photoinitiators, it is present in liquid or solid form (powders and solid particles of various size and shape) and is applied to the wire or to the cable with different techniques, known per se.
- one or more may preferably be chosen among (the compounds in brackets are just some examples of compounds belonging to the general categories): oligomers (acrylated urethanes, acrylated polyesters, aliphatic and aromatic epoxy acrylates, unsaturated polyesters, amino functionalised acrylated oligomers, silicone acrylates) monomers (low molecular weight acrylates, vinyl ethers, vinyl esters, propenyl esters, acrylic acid, vinyl phosphonates, vinyl sulfonic acid, fumaric acid, itaconic acid, thiols), photoinitiators, synergists (amines, boranes, thiols, silanes), organic and inorganic pigments, fillers and additives (silica nanoparticles, alumina, sucrose benzoate, boron nitride, polyolefin waxes, metal soaps, zinc stearate, aluminium stearate, polytetrafluor
- All these compounds have a high capacity of polymerisation and cross-linking when irradiated with light of appropriate wavelengths and, under such conditions, do not release volatile substances harmful to health and to the environment.
- polymers that are obtained have a high capacity of corrosion protection and lubrication.
- the compound is present in the liquid state, it is applied by directly contacting the wire or cable with the compound in the liquid state and calibrated through one or more dies, to obtain a uniform thickness on the surface using the following industrial technologies: passage through one or more dies, vacuum applicators, spray systems, mats, roller applicators, pressure dies, all easily available, having a reasonable encumbrance and often already present at the company premises.
- the compound is in the solid state, it is applied by directly contacting the wire or cable with the compound in the solid state in the form of powders and solid particles of various shapes and sizes and calibrated through one or more dies, to obtain a uniform thickness on the surface using industrial technologies known such as, but not limited to: passage through one or more dies, application of electrostatic charge to the wire or cable, passage through one or more pressure dies, fluidised beds, all easily available, having a reasonable encumbrance and often already present in the company.
- the second step consists in the cross-linking polymerisation of the compound applied with the previously disclosed modes.
- the cross-linking polymerisation transforms the compound applied in a solid polymer, the composition of which allows to ensure high standards of protection of the wires and cables from deterioration factors derived from oxidation, from chemical and environmental factors, for example corrosion in marine environments, as well as from other aging factors, thereby extending their useful life. Different compounds are applied for specific protection requirements. Alternatively, such polymers can have high lubricating capacity, allowing the coated material to undergo the main machining operations without overheating or breakages.
- This coating is transparent or coloured.
- the decorative aspect results from the possibility to use the compounds of various colours.
- the cross-linking polymerisation is obtained by irradiating the wire or the cable or the wire rod, coated during the first step, with ultraviolet radiation generated by one or more radiating elements, possibly with the aid of reflectors that allow to optimise the irradiation and that use industrial technologies, such as arc technology, microwave technology, LED technologies.
- said ultraviolet light has a wavelength ranging between 150 and 400 nm, most preferably between 250 and 400 nm. Within these ranges, the polymerisation is very fast.
- the cross-linking polymerisation can be facilitated by limiting the presence of oxygen through the use of inert gases in the environment where the radiation takes place and the consequent cross-linking polymerisation reaction, since oxygen is an inhibitor of such a reaction.
- Ultraviolet radiation can have different wavelengths even within a single cross-linking polymerisation process. This is linked to the type of photoinitiators chosen and ultimately to the features to be obtained for the coating.
- the process of application and curing of the compound for forming the coating occurs in an environment where inert gases are present in high percentage, so as to obtain optimum results.
- the metal wire or cable enters a tunnel, wherein the ultraviolet radiation irradiate the compound surface by 360°.
- the components of the polymer compound react with the free radicals from the photoinitiators, triggering the cross-linking polymerisation.
- fig. 1 which is a schematic view of a preferable embodiment, relating to the application of the coating on a metal wire immediately downstream of the drawing process
- the uncoated wire or wire rod (1) in form of a coil passes through any type and kind of drawing machine (2), is drawn (3), is passed inside the operating unit where the compound (4) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (5) occurs, then the coated wire is rewound into coils (6), according to a known mechanical process.
- FIG. 2 it is a schematic view of a preferred embodiment, regarding the application of a coating on a metal wire in the form of coil wire, already previously drawn.
- the coil of uncoated metal wire (7) is passed inside the operating unit where the compound (8) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (9) occurs, then the coated wire is rewound in coils (10), according to a known mechanical process.
- Fig. 3 is a schematic view of a preferred embodiment, regarding the application of a coating on a metal wire in the form of wire coils, already previously drawn.
- the coil of uncoated wire (11) is passed in vertical direction inside the operating unit where the compound (12) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (13) occurs, then the coated wire is rewound in coils (14), according to a known mechanical process.
- FIG. 4 it is a schematic view of a preferable embodiment, concerning the application of the coating on a wire or a cable, wherein the wire or cable in the form of coil (15) is made to pass inside the operating unit where the compound (16) is applied and immediately enters the operating unit where the cross-linking polymerisation, induced by ultraviolet radiation (17), occurs. Then the coated wires or cables (18) undergo the process of final mechanical forming cable (19) which is rewound in coils (20), according to a mechanical process known.
- fig. 5 is a schematic view of a preferable embodiment, relating to the application of the coating downstream of the wire forming process, wherein a wire in form of a coil (21) is mechanically formed (22) and is passed inside the operating unit where the compound (23) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (24) occurs, then the coated wire is rewound into coils (25) according to a known mechanical process.
- Fig. 6 is a schematic view of a preferred embodiment, regarding the application of the coating on a metal cable in coil.
- the coil of uncoated metal cable (26) is passed inside the operating unit where the compound (27) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (28) occurs, then the coated cable is rewound in coils (29) according to a known mechanical process.
- FIG. 7 there is a schematic view of a preferred embodiment, regarding the application of a coating on a metal cable in the form of coil.
- the coil of uncoated metal cable (30) is passed in vertical direction inside the operating unit where the compound (31) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (32) occurs, then the coated cable is rewound in coils (33), according to a known mechanical process.
- a schematic view of a preferred embodiment is seen, relating to the application of a lubricating coating.
- the application of the layer of lubricant occurs immediately upstream of the process of drawing and/or rolling, by passing the wire 1 in the operating unit where the coating 2 is applied. Immediately thereafter, it enters the operating unit 5, where a source of UV starts the cross-linking polymerisation.
- the wire 1 then passes through a die 4 and is drawn or rolled (5).
- the wire is then wound in coils (6) .
- the industrial process of application and curing of the compound to form the coating is performed in line with the process of drawing of the wire. However, it is also possible to operate in such a way that the industrial process of application and curing of the compound for forming the coating is not performed in line with the drawing process of the wire.
- the wire rod or wire 7 is passed through the unit 8 where the coating is applied and then, immediately afterwards, into the unit 9, where a source of UV starts the cross-linking polymerisation.
- the wire 7 then passes through an extruder 10, exits in 34 to form the coils 35.
- the industrial process of application and curing of the compound is performed several times, in order to achieve a coating formed by multiple overlapped layers.
- the uncoated wire rod and/or wire 11 is passed in a vertical direction inside the unit 12 where the lubricating coating is applied and then enters the operating unit 13, where a UV source activates the polymerisation, then the wire is wrapped in coils 14 and is thus stored.
- the drawing and/or rolling can be carried out in a second moment, picking up the wire rod and/or the wire from a warehouse 36 and proceeding, in the unit 37, to the drawing and/or rolling.
- the wire is then wound in coils 38.
- the wire rod and/or wire 39 is made to pass in a vertical direction, inside a production unit 40, where the lubricating coating is applied. Subsequently, it enters the operating unit 41, where cross-linking polymerisation occurs, induced by UV rays, then the wire is wound in coils 42 and stored.
- the drawing and/or rolling can be performed at a later time, by taking wire rod and/or wire from the warehouse 43, proceeding to drawing or rolling at 44 and winding the wire in coils at 45.
- the process of application and curing of the compound to form the coating may also be applied to wires and cables, already previously coated.
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Cephalosporin Compounds (AREA)
Abstract
Description
- The present invention relates to a method for forming a solid polymeric coating on the surface of metal wires with a section of any shape and size and cables formed by stranded wires. Said method includes a first step of application of the liquid or solid state compound and a second step of curing such compound through the application of an amount of ultraviolet radiation, sufficient to trigger the cross-linking polymerisation which causes the solidification of the compound and the consequent formation of a coating with features of flexibility, elongation, hardness and adhesion, such as to ensure high protective capacity and/or with lubricant features.
- Coatings are used to decorate wires and cables and to protect them from deterioration factors, deriving from oxidation, from chemical and environmental agents, such as corrosion in marine environments, as well as by other aging factors, prolonging the useful life of the wires and cables themselves.
- Wires and cables coatings may also have other purposes. An example is that of the drawing and/or rolling of metal (ferrous or non-ferrous) and their alloys wire rod and/or wire, having sections of any shape or size. This process, known since a long time, consists in reducing the section of the wire rod and/or wire by deformation, without removing any material.
- According to a first method, the rod and/or the wire is passed inside of arrays of material of appropriate hardness, commonly called dies, the section of which negatively reproduces the shape and the size of the cross section of the wire rod and/or wire to be obtained. One or more steps can be provided through the dies and through one or more machines. These steps create friction on the wire rod or on the wire, with consequent heating of these and with possible consequent breakages. For this reason, the surface of the wire rod and/or the wire must be lubricated, so as to reduce the friction and therefore the heating and the breakage. For this purpose, lubricants are generally used, such as stearates, which are solid at room temperature (dry lubrication), or oils that are liquids (bath lubrication). The dry lubricant is applied on the wire rod and/or on the wire, while bath lubrication involves dipping the die into the lubricant.
- According to a second method, called rolling, the wire rod and/or the wire are deformed by rollers which exert a mechanical pressure on the wire rod and/or wire. In this case, only dry lubrication occurs, similarly to what has already been seen for the first method.
- These techniques involve significant harmful emissions, especially of dust, in the environment, with risks for the safety and health of the operators.
- Another purpose is to limit corrosion and deterioration of the wire rod and/or wire, protecting them from air and moisture with a barrier effect.
- The polymeric compounds used nowadays for these purposes are self-supporting plastic coatings, made by applying to the surface powders and/or polymerising materials, which are subsequently solidified by means of a thermal process. The execution of this thermal curing process requires the use of bulky and expensive systems.
- Other coatings for wires and cables used nowadays, other than polymeric ones, use solvent-based protective paintings, also cured and transformed into a solid coating by means of a thermal process. The execution of this thermal curing process also requires the use of bulky and expensive plants and is related to significant atmospheric emissions of volatile organic compounds (VOCs) originating environmental impacts and significant risks for the health of the workers, associated to inhalation of these vapours.
- Other coatings for wires and cables used nowadays, different than polymeric ones, use metals, such as zinc, nickel, copper, aluminium and their alloys, transformed into coatings through processes of dipping in fused baths or fluidised beds, or by electrochemical action. The execution of these processes requires the use of bulky and expensive systems and the industrial processes implemented in these systems generate significant environmental problems, linked to the use of heavy metals and their transformation into processing residues (acids, sludges, other special residues), hazardous to health and of problematic disposal.
- The object of the present invention is to provide a coating of metal wires, cables or wire rods, both for decorative purposes and for protective purposes, as well as lubricant for drawing, rolling or similar processes and, at the same time, clearing the VOC emission, whilst also avoiding the formation of industrial waste, to be achieved with less bulky equipment and systems, characterised by a low initial economical investment and low costs in terms of energy resources.
- In addition, the times of application and solidification of the compound must be strictly limited and allow a production speed higher than that of the described systems. This can be achieved with a method for the formation of a solid polymeric coating on a surface of wires of ferrous and non-ferrous metal and of their alloys with homogeneous section of any shape and size and cables formed by stranded wires, characterised in that it includes the steps of:
- application: coating the surface of wires and cables with a compound in liquid state or in the form of powders and solid particles of various size and shape, constituted by monomers and/or oligomers and/or polymers, as well as additives and photoinitiators;
- curing: exposing the previously applied compound to an amount of ultraviolet radiation, with one or more wavelengths, which is sufficient to react the photoinitiators and to trigger the cross-linking polymerisation which causes the curing of the compound and therefore forms the polymeric coating. According to a first aspect, said coating is a layer of decoration and/or protection, while, according to a second aspect, said coating is a lubricant for drawing or rolling.
- Further features of the method of the invention claimed are apparent from the following description, which contains the references to some preferred industrial embodiments thereof, given by way of example and explained by referring to the drawings contained in the attached document, without having the purpose of limiting in any way the scope of protection of the present invention. As already specified above, other embodiments can be realised with modifications of detail, within the spirit and scope of the claims.
- In particular, the wires and cables are presented in the form of a coil, both inbound and outbound from the process: not excluding different possibilities, such as the application of the coating on the wires and cables of rectilinear shape.
- In addition, the operating units are presented graphically in a separated manner. It is reiterated that the method of which the invention is claimed is realised through an industrial process in two sequential steps, by passing the wire or cable inside of two or more serial operating units, one or more for each step, or within one or more operating units within each of which the two steps are carried out in sequence. This graphical representation therefore has the only purpose to represent the process in a simple way, to help understanding the description.
-
Figure 1 : cross-linking polymerisation of a wire coating in line with the drawing operation. -
Figure 2 : cross-linking polymerisation of a wire coating not in line with the drawing operation. -
Figure 3 : cross-linking polymerisation of a wire coating not in line with the drawing operation with application of the coating in the vertical direction. -
Figure 4 : cross-linking polymerisation of a coating of a wire or of a cable in line and upstream of mechanical forming process of the cable. -
Figure 5 : cross-linking polymerisation of a coating of a cable in line and downstream of the mechanical forming process of the cable. -
Figure 6 : cross-linking polymerisation of a coating of a cable not in line with the mechanical forming process. -
Figure 7 : cross-linking polymerisation of a coating in vertical direction, not in line with the mechanical forming process. -
Figure 8 : represents the polymerisation on a wire rod or on a wire of a single layer lubricating coating in line, on a machine for drawing and/or rolling. -
Figure 9 : represents the polymerisation on a wire rod or wire in line on a machine for drawing and/or rolling of a multiple coating. -
Figure 10 : represents the polymerisation of a lubricating coating in vertical. -
Figure 11 : represents the polymerisation of a lubricating coating in horizontal. - The method for which the invention is claimed is achieved through an innovative industrial process, which has never been applied to metal wires or cables, nor to wire rods.
- The industrial applications of the invention relate to the coating of wires and cables used in multiple fields of industrial production, in order both to ensure high standards of protection of the wires and cables from deterioration factors, such as oxidation and the corrosive action of chemical and environmental agents, and to obtain decorating colouring of the surface, and to superficially apply a lubricant for the subsequent processing (extrusion, rolling, etc.).
- The process comprises two sequential operational steps, passing the wire or cable inside two or more serial operating units, one or more for each step, or within one or more operating units, within each of which the two steps are carried out in sequence.
- The first step consists in the physical application of a compound on the outer surface. This application is obtained by passing the wire or the cable in the operating units where the operation took place in a manner known per se. Preferably, the wire or cable runs inside of machines and production lines, adapted to perform the two steps, without the constraints of direction, if not those determined by the layout of the machines and of the production lines themselves.
- The compound is formed from monomers and/or oligomers and/or polymers and/or other additives and photoinitiators, it is present in liquid or solid form (powders and solid particles of various size and shape) and is applied to the wire or to the cable with different techniques, known per se.
- As the compound to be applied in the first step, one or more may preferably be chosen among (the compounds in brackets are just some examples of compounds belonging to the general categories): oligomers (acrylated urethanes, acrylated polyesters, aliphatic and aromatic epoxy acrylates, unsaturated polyesters, amino functionalised acrylated oligomers, silicone acrylates) monomers (low molecular weight acrylates, vinyl ethers, vinyl esters, propenyl esters, acrylic acid, vinyl phosphonates, vinyl sulfonic acid, fumaric acid, itaconic acid, thiols), photoinitiators, synergists (amines, boranes, thiols, silanes), organic and inorganic pigments, fillers and additives (silica nanoparticles, alumina, sucrose benzoate, boron nitride, polyolefin waxes, metal soaps, zinc stearate, aluminium stearate, polytetrafluoroethylene, graphite, borax pentahydrate, molybdenum, calcium stearate, sodium stearate), antioxidants and stabilisers. All these compounds have a high capacity of polymerisation and cross-linking when irradiated with light of appropriate wavelengths and, under such conditions, do not release volatile substances harmful to health and to the environment. In addition, polymers that are obtained have a high capacity of corrosion protection and lubrication.
- If the compound is present in the liquid state, it is applied by directly contacting the wire or cable with the compound in the liquid state and calibrated through one or more dies, to obtain a uniform thickness on the surface using the following industrial technologies: passage through one or more dies, vacuum applicators, spray systems, mats, roller applicators, pressure dies, all easily available, having a reasonable encumbrance and often already present at the company premises.
- If the compound is in the solid state, it is applied by directly contacting the wire or cable with the compound in the solid state in the form of powders and solid particles of various shapes and sizes and calibrated through one or more dies, to obtain a uniform thickness on the surface using industrial technologies known such as, but not limited to: passage through one or more dies, application of electrostatic charge to the wire or cable, passage through one or more pressure dies, fluidised beds, all easily available, having a reasonable encumbrance and often already present in the company.
- The second step consists in the cross-linking polymerisation of the compound applied with the previously disclosed modes. The cross-linking polymerisation transforms the compound applied in a solid polymer, the composition of which allows to ensure high standards of protection of the wires and cables from deterioration factors derived from oxidation, from chemical and environmental factors, for example corrosion in marine environments, as well as from other aging factors, thereby extending their useful life. Different compounds are applied for specific protection requirements. Alternatively, such polymers can have high lubricating capacity, allowing the coated material to undergo the main machining operations without overheating or breakages.
- This coating is transparent or coloured. The decorative aspect results from the possibility to use the compounds of various colours.
- The cross-linking polymerisation is obtained by irradiating the wire or the cable or the wire rod, coated during the first step, with ultraviolet radiation generated by one or more radiating elements, possibly with the aid of reflectors that allow to optimise the irradiation and that use industrial technologies, such as arc technology, microwave technology, LED technologies. Preferably, said ultraviolet light has a wavelength ranging between 150 and 400 nm, most preferably between 250 and 400 nm. Within these ranges, the polymerisation is very fast.
- The cross-linking polymerisation can be facilitated by limiting the presence of oxygen through the use of inert gases in the environment where the radiation takes place and the consequent cross-linking polymerisation reaction, since oxygen is an inhibitor of such a reaction.
- Ultraviolet radiation, even within the ranges previously defined, can have different wavelengths even within a single cross-linking polymerisation process. This is linked to the type of photoinitiators chosen and ultimately to the features to be obtained for the coating.
- In a preferred embodiment, the process of application and curing of the compound for forming the coating occurs in an environment where inert gases are present in high percentage, so as to obtain optimum results.
- In a preferred embodiment, the metal wire or cable enters a tunnel, wherein the ultraviolet radiation irradiate the compound surface by 360°. In a very short time (from 0.1s to 10s) the components of the polymer compound react with the free radicals from the photoinitiators, triggering the cross-linking polymerisation.
- Examining the drawings in detail, it is noted that in
fig. 1 , which is a schematic view of a preferable embodiment, relating to the application of the coating on a metal wire immediately downstream of the drawing process, the uncoated wire or wire rod (1) in form of a coil passes through any type and kind of drawing machine (2), is drawn (3), is passed inside the operating unit where the compound (4) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (5) occurs, then the coated wire is rewound into coils (6), according to a known mechanical process. - Regarding
fig. 2 , it is a schematic view of a preferred embodiment, regarding the application of a coating on a metal wire in the form of coil wire, already previously drawn. The coil of uncoated metal wire (7) is passed inside the operating unit where the compound (8) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (9) occurs, then the coated wire is rewound in coils (10), according to a known mechanical process. -
Fig. 3 is a schematic view of a preferred embodiment, regarding the application of a coating on a metal wire in the form of wire coils, already previously drawn. The coil of uncoated wire (11) is passed in vertical direction inside the operating unit where the compound (12) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (13) occurs, then the coated wire is rewound in coils (14), according to a known mechanical process. - Turning now to
fig. 4 , it is a schematic view of a preferable embodiment, concerning the application of the coating on a wire or a cable, wherein the wire or cable in the form of coil (15) is made to pass inside the operating unit where the compound (16) is applied and immediately enters the operating unit where the cross-linking polymerisation, induced by ultraviolet radiation (17), occurs. Then the coated wires or cables (18) undergo the process of final mechanical forming cable (19) which is rewound in coils (20), according to a mechanical process known. - In turn,
fig. 5 is a schematic view of a preferable embodiment, relating to the application of the coating downstream of the wire forming process, wherein a wire in form of a coil (21) is mechanically formed (22) and is passed inside the operating unit where the compound (23) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (24) occurs, then the coated wire is rewound into coils (25) according to a known mechanical process. -
Fig. 6 is a schematic view of a preferred embodiment, regarding the application of the coating on a metal cable in coil. The coil of uncoated metal cable (26) is passed inside the operating unit where the compound (27) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (28) occurs, then the coated cable is rewound in coils (29) according to a known mechanical process. - In
fig. 7 , there is a schematic view of a preferred embodiment, regarding the application of a coating on a metal cable in the form of coil. The coil of uncoated metal cable (30) is passed in vertical direction inside the operating unit where the compound (31) is applied and immediately enters the operating unit where the cross-linking polymerisation induced by ultraviolet radiation (32) occurs, then the coated cable is rewound in coils (33), according to a known mechanical process. - In
fig. 8 a schematic view of a preferred embodiment is seen, relating to the application of a lubricating coating. The application of the layer of lubricant occurs immediately upstream of the process of drawing and/or rolling, by passing the wire 1 in the operating unit where the coating 2 is applied. Immediately thereafter, it enters theoperating unit 5, where a source of UV starts the cross-linking polymerisation. The wire 1 then passes through adie 4 and is drawn or rolled (5). The wire is then wound in coils (6) . In practice, the industrial process of application and curing of the compound to form the coating is performed in line with the process of drawing of the wire. However, it is also possible to operate in such a way that the industrial process of application and curing of the compound for forming the coating is not performed in line with the drawing process of the wire. - In
fig. 9 it can be seen that, for each die upstream of which it is decided to apply the lubricating coating, the wire rod orwire 7 is passed through theunit 8 where the coating is applied and then, immediately afterwards, into theunit 9, where a source of UV starts the cross-linking polymerisation. Thewire 7 then passes through anextruder 10, exits in 34 to form thecoils 35. In practice, the industrial process of application and curing of the compound is performed several times, in order to achieve a coating formed by multiple overlapped layers. - In
fig. 10 , the uncoated wire rod and/orwire 11 is passed in a vertical direction inside theunit 12 where the lubricating coating is applied and then enters the operatingunit 13, where a UV source activates the polymerisation, then the wire is wrapped incoils 14 and is thus stored. - The drawing and/or rolling can be carried out in a second moment, picking up the wire rod and/or the wire from a
warehouse 36 and proceeding, in theunit 37, to the drawing and/or rolling. The wire is then wound incoils 38. - Finally, in
fig. 11 , the wire rod and/orwire 39 is made to pass in a vertical direction, inside aproduction unit 40, where the lubricating coating is applied. Subsequently, it enters the operatingunit 41, where cross-linking polymerisation occurs, induced by UV rays, then the wire is wound incoils 42 and stored. - The drawing and/or rolling can be performed at a later time, by taking wire rod and/or wire from the
warehouse 43, proceeding to drawing or rolling at 44 and winding the wire in coils at 45. - It can be expected that the industrial process of application and curing of the compound to form the coating is applied to a cable formed by a bundle of cables.
- Finally, the process of application and curing of the compound to form the coating may also be applied to wires and cables, already previously coated.
Claims (15)
- Method for the formation of a solid polymeric coating on a surface of wires of ferrous and non-ferrous metal and of their alloys with homogeneous section of any shape and size and cables formed by stranded wires, characterised in that it comprises the steps of:- application: coating the surface of wires and cables with a compound in liquid state or in the form of powders and solid particles of various size and shape, constituted by monomers and/or oligomers and/or polymers, as well as additives and photoinitiators;- curing: exposing the previously applied compound to an amount of ultraviolet radiation, with one or more wavelengths, sufficient to react the photoinitiators and to trigger the cross-linking polymerisation which causes the curing of the compound and therefore forms the polymeric coating.
- Method according to claim 1, characterised in that the wire and cable run inside of machines and production lines, adapted to carry out the two steps, without the constraints of direction except those determined by the layout of the machines and production lines themselves.
- Method according to claims 1 or 2, characterised in that the industrial process of application and curing of the compound is performed several times, in order to achieve a coating formed by multiple overlapped layers.
- Method according to any one of claims 1 to 3, characterised in that the step of application is carried out by directly contacting the wire or cable with the compound in liquid state and calibrated to obtain a uniform thickness on the surface using the following industrial technologies: passage through one or more dies, vacuum applicators, spray systems, mats, roller applicators or pressure dies.
- Method according to any one of claims 1 to 3, characterised in that the step of application is carried out by directly contacting the wire and cable with the compound in solid state in the form of powders and solid particles of various shapes and sizes and calibrated to obtain a uniform thickness on the surface using industrial technologies such as: passage through one or more dies, application of electrostatic charge to the wire and cable, fluidised beds.
- Method according to any one of the preceding claims, characterised in that, as a compound to be applied in the first step, it can be preferably choosen among one or more of: oligomers (acrylated urethanes, acrylated polyesters, aliphatic and aromatic epoxy acrylates, unsaturated polyesters, amino functionalised acrylated oligomers, silicone acrylates) monomers (low molecular weight acrylates, vinyl ethers, vinyl esters, propenyl esters, acrylic and methacrylic acid, vinyl phosphonates, vinyl sulfonic acid, fumaric acid, itaconic acid, thiols), photoinitiators, synergists (amines, boranes, thiols, silanes), organic and inorganic pigments, fillers and additives (silica nanoparticles, alumina, sucrose benzoate, boron nitride, polyolefin waxes, metal soaps, zinc stearate, aluminium stearate, polytetrafluoroethylene, graphite, borax pentahydrate, molybdenum, calcium stearate, sodium stearate), antioxidants and stabilisers.
- Method according to any one of the preceding claims, characterised in that the step of curing the compound is carried out through ultraviolet radiations, generated by one or more irradiators that use industrial technologies, such as: arc technology, microwave technology, LED technology.
- Method according to any one of the preceding claims, characterised in that the industrial process of application and curing of the compound to form the coating is performed in line with the process of drawing of the wire.
- Method according to any one of claims 1 to 7, characterised in that the industrial process of application and curing of the compound to form the coating is not performed in line with the drawing process of the wire.
- Method according to any one of the preceding claims, characterised in that the industrial process of application and curing of the compound to form the coating is applied to a cable formed by a bundle of cables.
- Method according to any one of the preceding claims, characterised in that the process of application and curing of the compound to form the coating is applied to wires and cables, already previously coated.
- Method according to any one of the preceding claims, characterised in that the process of application and curing of the compound to form the coating takes place in an environment where inert gases are present in high percentage.
- Method according to any one of the preceding claims, characterised in that said coating is a decoration and/or protection layer.
- Method according to any one of claims 1 to 12, characterised in that said coating is a lubricant for drawing or rolling.
- Method as in any one of the preceding claims, characterised in that said ultraviolet light has a wavelength ranging between 150 and 400 nm, most preferably between 250 and 400 nm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ARP200100984A AR118620A1 (en) | 2018-04-10 | 2020-04-08 | HETEROCYCLIC COMPOUNDS |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT201800004338 | 2018-04-10 | ||
IT102018000004462A IT201800004462A1 (en) | 2018-04-13 | 2018-04-13 | METHOD FOR THE APPLICATION AND HARDENING THROUGH ULTRAVIOLET RADIATION (UV) OF A SURFACE COATING OF A LUBRICANT MATERIAL AND / OR LUBRICATION SUPPORT FOR DRAWING AND / OR LAMINATION OF IRON AND NON IRON AND NON-IRON METAL WIRE ALLOYS. |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3553794A1 true EP3553794A1 (en) | 2019-10-16 |
EP3553794B1 EP3553794B1 (en) | 2023-11-22 |
Family
ID=66041374
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19168246.7A Active EP3553794B1 (en) | 2018-04-10 | 2019-04-09 | Method to limit corrosion and deterioration of wires and cables of ferrous metal and their alloys |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP3553794B1 (en) |
AR (1) | AR118620A1 (en) |
ES (1) | ES2971618T3 (en) |
PL (1) | PL3553794T3 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115028986A (en) * | 2022-06-27 | 2022-09-09 | 重庆泰山电缆有限公司 | Cable sheath material and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3813322A (en) * | 1971-12-29 | 1974-05-28 | Bell Telephone Labor Inc | Radiation curable styrenated polyester coating compositions and process of curing them |
WO2010112493A1 (en) * | 2009-03-31 | 2010-10-07 | Dsm Ip Assets B.V. | Radiation curable resin composition for wire coating |
US20150368496A1 (en) * | 2014-06-23 | 2015-12-24 | Southwire Company, Llc | Uv-resistant superhydrophobic coating compositions |
-
2019
- 2019-04-09 ES ES19168246T patent/ES2971618T3/en active Active
- 2019-04-09 PL PL19168246.7T patent/PL3553794T3/en unknown
- 2019-04-09 EP EP19168246.7A patent/EP3553794B1/en active Active
-
2020
- 2020-04-08 AR ARP200100984A patent/AR118620A1/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3813322A (en) * | 1971-12-29 | 1974-05-28 | Bell Telephone Labor Inc | Radiation curable styrenated polyester coating compositions and process of curing them |
WO2010112493A1 (en) * | 2009-03-31 | 2010-10-07 | Dsm Ip Assets B.V. | Radiation curable resin composition for wire coating |
US20150368496A1 (en) * | 2014-06-23 | 2015-12-24 | Southwire Company, Llc | Uv-resistant superhydrophobic coating compositions |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115028986A (en) * | 2022-06-27 | 2022-09-09 | 重庆泰山电缆有限公司 | Cable sheath material and preparation method thereof |
CN115028986B (en) * | 2022-06-27 | 2023-06-23 | 重庆泰山电缆有限公司 | Cable sheath material and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
PL3553794T3 (en) | 2024-04-08 |
AR118620A1 (en) | 2021-10-20 |
ES2971618T3 (en) | 2024-06-06 |
EP3553794B1 (en) | 2023-11-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3553794B1 (en) | Method to limit corrosion and deterioration of wires and cables of ferrous metal and their alloys | |
US6195486B1 (en) | Fiber optic cable having a component with an absorptive polymer coating and a method of making the cable | |
WO2015105972A1 (en) | Coated overhead conductor | |
EP1157750A2 (en) | Treatment of plastics containers | |
CN102354584B (en) | Production process for enamelled wire by coating thin paint for many times | |
CA2414686C (en) | Method for powder coating plastic articles and articles made thereby | |
KR20110110090A (en) | Methods and compositions for coating pipe | |
CN104903008B (en) | Powder for non-conductive component and particularly Brake pad is coated(Electrostatic spraying)Method and apparatus | |
WO2020079669A1 (en) | Functionalized product fabricated from a resin comprising a functional component and a polymeric resin, and method of making the same | |
NL8302411A (en) | METHOD FOR COATING BAR-METAL FORM BODIES WITH THERMOPLASTIC PLASTIC | |
CN110729084A (en) | Processing technology of copper wire | |
US2798509A (en) | Metallized-galvanized electrical conduit and method of making same | |
US10020646B2 (en) | Busbar and method of manufacturing the same | |
JPS6019609B2 (en) | Manufacturing method of insulated wire | |
US3667095A (en) | Apparatus for coating surfaces and curing the same at high speeds | |
US20230147245A1 (en) | Method for treating the surface of metal foils with uv-cured protective varnish | |
US6306468B1 (en) | Metal tube coating process | |
US20030161966A1 (en) | System and method of coating a continuous length of material | |
IT201800004462A1 (en) | METHOD FOR THE APPLICATION AND HARDENING THROUGH ULTRAVIOLET RADIATION (UV) OF A SURFACE COATING OF A LUBRICANT MATERIAL AND / OR LUBRICATION SUPPORT FOR DRAWING AND / OR LAMINATION OF IRON AND NON IRON AND NON-IRON METAL WIRE ALLOYS. | |
KR20140003202A (en) | Powder coating method and powder coated film manufactured thereby | |
CN203721385U (en) | Ultraviolet light irradiation crosslinking and automobile wire/cable plastic extrusion production line | |
US11426753B2 (en) | Method and device for applying coating layers to a coating material | |
EP1336069A1 (en) | Plastic pipe with a barrier lager | |
US20050046177A1 (en) | Corrosion resistant barrier consisting of a UV light cured anti-corrosive basecoat and thermoplastic topcoat | |
KR910003211B1 (en) | Method of forming a colored coating film on a cross-linked polyethylene sheet or electric wire |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20200416 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
17Q | First examination report despatched |
Effective date: 20200910 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
RAP3 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: LUBRIMETAL S.P.A. |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20230719 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602019041760 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20231120 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG9D |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: T3 Ref document number: E 43387 Country of ref document: SK Ref country code: NL Ref legal event code: MP Effective date: 20231122 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20240223 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20240322 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20231122 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1634623 Country of ref document: AT Kind code of ref document: T Effective date: 20231122 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20231122 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20231122 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20231122 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20231122 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20240322 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20240223 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20240222 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20231122 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20240322 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: RO Payment date: 20240318 Year of fee payment: 6 Ref country code: CZ Payment date: 20240229 Year of fee payment: 6 Ref country code: SK Payment date: 20240301 Year of fee payment: 6 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20231122 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20231122 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20240222 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20231122 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20231122 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20240227 Year of fee payment: 6 Ref country code: PL Payment date: 20240228 Year of fee payment: 6 Ref country code: IT Payment date: 20240227 Year of fee payment: 6 Ref country code: FR Payment date: 20240227 Year of fee payment: 6 Ref country code: BE Payment date: 20240329 Year of fee payment: 6 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2971618 Country of ref document: ES Kind code of ref document: T3 Effective date: 20240606 |