EP3541548A1 - Dispositif de coulée continue pour brames minces - Google Patents

Dispositif de coulée continue pour brames minces

Info

Publication number
EP3541548A1
EP3541548A1 EP17817121.1A EP17817121A EP3541548A1 EP 3541548 A1 EP3541548 A1 EP 3541548A1 EP 17817121 A EP17817121 A EP 17817121A EP 3541548 A1 EP3541548 A1 EP 3541548A1
Authority
EP
European Patent Office
Prior art keywords
walls
hereinbefore
casting
crystallizer
slab
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP17817121.1A
Other languages
German (de)
English (en)
Other versions
EP3541548B1 (fr
Inventor
Alfredo Poloni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Danieli and C Officine Meccaniche SpA
Original Assignee
Danieli and C Officine Meccaniche SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Danieli and C Officine Meccaniche SpA filed Critical Danieli and C Officine Meccaniche SpA
Publication of EP3541548A1 publication Critical patent/EP3541548A1/fr
Application granted granted Critical
Publication of EP3541548B1 publication Critical patent/EP3541548B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/0406—Moulds with special profile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/0408—Moulds for casting thin slabs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/041—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds for vertical casting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/05—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds into moulds having adjustable walls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/051—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds into moulds having oscillating walls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/053—Means for oscillating the moulds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/12—Accessories for subsequent treating or working cast stock in situ
    • B22D11/1206—Accessories for subsequent treating or working cast stock in situ for plastic shaping of strands

Definitions

  • the present invention concerns a continuous casting device, in particular to cast slabs with an extremely limited thickness, for example comprised between 5 and 40 mm.
  • the first category of casting machines comprises a vertically oscillating crystallizer consisting of plates made of material with a high coefficient of heat conductivity, cooled by cooling devices, such as pipes made in the thickness of the plates, to remove heat from the molten metal that is made to pass through the crystallizer.
  • cooling devices such as pipes made in the thickness of the plates
  • the product exits from the crystallizer When the product exits from the crystallizer, it has an external solidified skin, and a liquid or semi-liquid core inside.
  • Rolling stands are disposed downstream of the casting line, to reduce the thickness of the cast slab.
  • This first category also has disadvantages connected to the conformation of the crystallizer.
  • the crystallizer walls for this purpose, have a taper such as to follow the heat shrinkage of the metal that gradually solidifies and such as to prevent re- melting or sticking.
  • these types of crystallizers provide to insert a discharger into the central upper part of the crystallizer to introduce molten metal between the walls.
  • the other type of casting machines is represented by the so-called "Twin roll strip caster” technology, in which the machines comprise two counter-rotating rolls cooled internally, and the casting channel formed by them is closed laterally by refractory plates. With this type of machine, it is possible to obtain a high slab casting speed, even more than 60 m/min, and to obtain very thin products, formed by the union of two skins generated by the contact with the two cooled rolls and the liquid steel.
  • the cooled rolls allow to generate a skin of the metal that is cast which, as it exits from the roll, is just a few millimeters thick.
  • the cast slab can have a maximum thickness of 3-4mm overall.
  • Another purpose of the present invention is to obtain a continuous casting device able to produce a high quality cast product.
  • Another purpose of the present invention is to obtain a continuous casting device for slabs which allows to increase the casting speed with respect to traditional plate-type crystallizers for slabs.
  • Another purpose of the present invention is to obtain a continuous casting device able to cast slabs which are thicker than those that can be cast with twin roll crystallizers.
  • the Applicant has devised, tested and embodied the present invention to overcome the shortcomings of the state of the art and to obtain these and other purposes and advantages.
  • a device for casting metal slabs that, in conformity with claim 1, comprises a crystallizer provided with two first walls facing each other with respect to a casting plane, and two second walls facing each other, with a smaller surface extension than the surface extension of the first walls, and associated with the first walls to define a concavity for containing liquid metal.
  • the two first walls are defined by plates having a convex shape with a convexity facing toward the inside of the concavity.
  • the device comprises at least a pair of presser rolls disposed parallel to the casting plane and positioned at the exit end of the crystallizer.
  • At least one of the first walls is associated with at least one actuator configured to move at least one of the first walls along a curved path lying on a plane orthogonal to the casting plane.
  • at least one actuator configured to move at least one of the first walls along a curved path lying on a plane orthogonal to the casting plane.
  • the present invention also concerns a wall for a crystallizer for casting slabs, in which the wall is provided with an entrance edge through which, during use, the liquid metal is introduced, and with an exit edge through which, during use, the slab exits at least partly solidified.
  • the wall according to the invention, is defined by a plate with a convex shape, with a convexity that extends from the entrance edge to the exit edge.
  • - fig. 1 shows a lateral section of the casting device of the invention
  • - fig. 2 is a three-dimensional view of the crystallizer belonging to the casting device of fig. 1 ;
  • - fig. 3 is another three-dimensional view of the crystallizer of fig. 2,
  • - fig. 4 shows a lateral section of the crystallizer of fig. 2;
  • FIG. 5 is a plan view of the sealing rolls of the casting device of the invention.
  • - fig. 6 is a schematic representation of the oscillatory motion of the crystallizer of the casting device of fig. 1.
  • a casting device for thin slabs comprises, in a preferential but non-exclusive configuration, a mold 1 or casting apparatus provided with a crystallizer 2 configured to solidify the liquid metal that is introduced into it.
  • the crystallizer 2 comprises two first walls 5, 6 with a conformation with plates that are located facing each other, and two second walls 7, 8 which also have a conformation with plates facing each other and associated with the first walls 5, 6 to define together a concavity 17 containing liquid metal that is cast.
  • the first walls 5, 6 substantially define the flat surfaces of the slab while the second walls 7, 8 substantially define the thickness of the slab.
  • the first walls 5, 6 have a width substantially corresponding to the width of the slab 18, much larger than the width of the second walls 7, 8.
  • the first walls 5, 6 have a width equal to or greater than 3 times the width of the second walls 7, 8.
  • the first walls 5, 6 are disposed facing each other and with respect to a casting plane Z interposed between the first walls 5, 6.
  • the casting plane Z vertical during use, identifies the plane according to which the slab 18 is cast; and the first walls 5, 6 are disposed on one side and on the other of the casting plane Z.
  • the first walls 5, 6 are each provided with an entrance edge 23 through which the liquid metal is introduced, and an exit edge, or lower surfaces 9, 10, in correspondence with which the slab 18 comes out of the crystallizer 2.
  • the entrance edge 23 is opposite the exit edge 9, 10.
  • the lower surfaces or exit edges 9, 10 of the first walls 5, 6 are disposed parallel to each other and determine the exit thickness of the slab 18 from the mold.
  • the sizing of the exit thickness of the slab exiting from the crystallizer 2 is regulated by the action of moving at least one of the first walls 5, 6 of the crystallizer nearer to or away from the other, actuated for example by means of an actuator unit 19.
  • the actuator unit 19 is connected to at least one of the first two walls 5, 6 to move, in a direction incident to the casting plane Z, a first wall 6 nearer to the other.
  • the first walls 5, 6 have a convex shape with the convexity facing toward the inside of the concavity 17.
  • the surfaces of the first walls 5, 6 facing toward the concavity 17, have said convex shape.
  • this convexity extends along a transverse plane of the first walls 5, 6 intersecting the entrance edge 23 and the exit edge 9, 10 thereof.
  • the first walls 5, 6 disposed on the opposite sides of the casting plane Z are curved with the convexity facing toward the inside of the concavity 17 so that the latter has a section that tapers from the upper zone towards the bottom, where the exit of the product is disposed.
  • the first walls 5, 6 have a convexity that extends for their whole height, determined in a direction parallel to the casting plane Z, that is, from the entrance edge 23 to the exit edge 9, 10.
  • the convexity of the first walls 5, 6 is defined by an arc of a circle.
  • the arc of a circle can have a radius of curvature R comprised between 2 and 10 meters.
  • the first walls 5, 6 have a tangent plane that develops in a direction parallel to the casting plane Z and in which the tangent planes of the edges of the exit edges 9, 10 are parallel to each other.
  • the first walls 5, 6 also have portions of wall, for example positioned in correspondence with the entrance edge 23 and exit edge 9, 10, having a flat conformation.
  • the exit edges 9, 10 are distanced from each other by a first distance El, while the entrance edges 23 of the first walls 5, 6 are distanced from each other by a second distance E2, bigger than the first distance El.
  • the first walls 5, 6 are made of at least a heat conducting material, that is, a material with high heat conductivity, typically copper or copper alloys.
  • the first walls 5, 6 can be cooled by devices, that is, cooling elements or systems.
  • devices that is, cooling elements or systems.
  • distribution channels of a cooling fluid are associated with the first walls 5, 6.
  • the channels can be integrated into the thickness of the walls 5, 6 or outside the walls, or defined by interspaces in which the cooling fluid flows, provided on the surface of the first walls 5, 6 that is external during use.
  • the cooling devices allow the solidification of the liquid metal that comes into contact with the first walls 5, 6, and the formation of two independent skins, one on each first wall 5, 6.
  • the casting speed of the slab 18 can be controlled so that, in correspondence with the exit edge 9, 10 of the first walls 5, 6, the solidified skins generated by contact with each first wall 5, 6 are not yet joined together.
  • first walls 5, 6 have a bigger surface extension than the second walls 7, 8.
  • the second walls 7, 8, on the contrary, have a substantially flat conformation and are associated with the first walls 5, 6 in correspondence with the lateral edges of the latter.
  • the second side walls 7, 8, therefore, close the concavity 17 on the sides.
  • the second walls 7, 8 are made of refractory material and allow to maintain a high temperature of the liquid metal, preventing the steel from solidifying on contact with them.
  • the concavity 17 defined by the first walls 5, 6 and the second walls 7, 8 therefore has a cross section, from the entrance edge 23 to the exit edges 9, 10, which reduces toward the latter.
  • This conformation allows to have, in the upper part of the crystallizer 2, a width such that it is possible to insert a discharger 22 to pour the molten metal, for example from a tundish, and at the same time to allow to reduce the turbulence, while in the lower part the distance between the first walls 5, 6 defines the exit width of the slab 18, delimited by the second walls 7, 8, on the narrow sides.
  • the slab casting device 100 comprises a sealing unit 3 disposed directly and immediately under the crystallizer 2 in order to close the slab 18, and in particular the edges 21.
  • the sealing unit 3 can comprise two presser rolls 11, 12 disposed parallel to the casting plane Z and positioned at the exit end defined by the exit edges 9, 10 of the crystallizer 2.
  • the presser rolls 1 1, 12 can be preferably idle, that is, free to rotate around the respective axes of rotation.
  • the presser rolls 11, 12 can be associated with cooling members provided to cool the presser rolls 11, 12 internally.
  • the presser rolls 11, 12 extend for a length at least equal to or greater than the width of the first walls 5, 6.
  • the exit edges 9, 10 are distanced from each other by said first distance El, and the presser rolls 11, 12 define between them a passage gap 26 with a width G equal to or less than the first distance El .
  • This condition allows to exert on the solidified skins exiting from the crystallizer 2, a pressure action such as to define the slab 18.
  • the presser rolls 11, 12 have end portions 24 between which a central portion 25 is interposed, having a smaller diameter than that of the end portions 24.
  • the central portion 25 has a first diameter Dl while the end portions 24 have a second diameter D2 greater than the first diameter Dl.
  • the distance between the respective surfaces of the two presser rolls 11, 12 is therefore minimal at the ends and greater in the central segment, so as to laterally join the two skins formed upstream by the contact along the first walls 5, 6 and then to form an edge 21 closed on each side of the slab 18, at the same time allowing a still liquid or semi-liquid core to remain inside the forming slab.
  • the crystallizer 2 is subjected to an alternate motion with a vector component parallel to the casting direction.
  • At least the first walls 5, 6 are associated with at least one actuator 15 configured to move at least the first walls 5, 6 along respective curved paths 20 lying on a plane orthogonal to the casting plane Z and intersecting the entrance edge 23 and exit edge 9, 10.
  • the first walls 5, 6 can also be connected to guide means and/or articulated mechanisms configured to define the movement along the curved paths 20 of the first walls 5, 6.
  • the movement is alternated along the curved paths 20 and, as well as promoting the advance of the slab 18 towards the exit from the crystallizer 2, also prevents the latter from sticking, that is, welding to the first walls 5, 6 causing the so-called sticking phenomenon.
  • the sealing unit 3, that is, the presser rolls 1 1, 12, are connected to the first walls 5, 6 and oscillate with them, that is, they are mobile together with the first walls 5, 6 by the at least one actuator 15.
  • the presser rolls 11, 12 and the first walls 5, 6 are installed on at least one common support structure 26, and the at least one actuator 15 is connected to the at least one support structure 26 to move together with each other the first walls 5, 6 and the presser rolls 11, 12 along the curved paths 20.
  • the movement that is, the curved paths 20, shown schematically in fig. 6, are obtained by moving the first walls 5 and 6, together with the relative and integral presser rolls 11, 12 of the sealing unit 3, by means of the actuator 15, along two arcs of a circle.
  • the arcs of a circle can have their respective virtual centers disposed in symmetrical positions with respect to the casting plane Z.
  • the virtual centers can substantially correspond to the centers of the radiuses of curvature of the first walls 5, 6. This solution allows to limit the mechanical stresses and perturbations to which the metal product is subjected as it forms in the crystallizer 2.
  • the oscillatory movement along the two arcs of a circle allows the gradual descent of the skins along the crystallizer 2 toward the zone where they are joined to form the slab 18.
  • the oscillation of the first walls 5, 6 is such as to maintain the exit edges 9, 10 always distanced by the same first distance El. This allows to guarantee that the slab 18 exits always with the same thickness.
  • the sealing unit 3 is followed by a drawing unit 4 provided to facilitate the discharge of the slab 18 from the crystallizer 2.
  • the sealing unit 3 and the drawing unit 4 are disposed in succession along the casting direction.
  • the drawing unit 4 is integral with the mold 1, that is, it is installed in a fixed position with respect to the first walls 5, 6 and the presser rolls 1 1, 12.
  • the drawing unit 4 can comprise motorized rolls 13, 14 located downstream of the presser rolls 11, 12 and having their own axes parallel to each other and parallel to the axes of the presser rolls 1 1, 12.
  • the motorized rolls 13, 14 can have a constant diameter along their axis.
  • the motorized rolls 13, 14 can be moved reciprocally nearer to or away from each other, to adapt to the thickness of the cast product, that is, the slab 18.
  • the discharger 22 shown schematically to comprise the functioning of the casting device 100, during casting operations, pours the cast metal from a container, for example from the tundish, into the crystallizer 2.
  • the molten metal goes into contact with the first walls 5, 6 and the second walls 7, 8.
  • the first walls 5, 6, as described above, can have different heat conductivity properties, in fact the molten metal gives up heat to form a solid thickness along the first walls 5, 6, while it remains in its liquid state in the interface with the second walls 7, 8 which do not transmit heat or do it only to a negligible degree.
  • the oscillation can take place according to an arc of a circle indicated by the arrows 20, determined by the casting radius along which the first two opposite walls 5, 6 slide.
  • the slab 18, seen from a cross section view has three layers forming its thickness: the external layers are the two solidified skins whereas the central layer consists of the liquid or semi-liquid core.
  • the sides of the product are closed by contact with the second walls 7, 8, before exit from the crystallizer 2, then by the presser rolls 11, 12.
  • the next step consists of the passage of the slab 18 into the sealing unit 3 which, as described above, follows the oscillation of the crystallizer 2 and has the two presser rolls 11, 12, having a larger diameter D2 at the ends than the diameter Dl in the central zone.
  • the skins are joined in the lateral zones, forming the closed edges 21 and preventing the liquid core from escaping when the slab ceases to be in contact with the second walls 7, 8.
  • the subsequent passage in the drawing unit 4 is essential for an optimal casting speed and extraction of the product, which at the same time can be calibrated in tolerance by a compression of the thickness of the slab, for example it can be taken to parity with the thickness of the sides sealed by the sealing unit 3.
  • the drawing group 4 by suitably choosing the distance between the presser rolls 1 1, 12, can also perform a simple extraction of the material without reducing its thickness.
  • the casting device 100 described here allows to produce very thin and high quality slabs, with a reduction in complexity and plant costs.
  • the high casting speed for example 6-7 m/min, and the particular constitution of the crystallizer 2, with long walls of regular and curved geometry, without concavities, forming a cross-section similar to a V on the curved sides, and with the short lateral walls made of refractory material, allows to obtain extremely homogeneous cast products, with a considerable reduction in defects and without the problem of the skin re-melting in the crystallizer, resulting in a high quality of the finished product.
  • the geometry of the concavity 17, similar to a funnel, also allows to adjust the height of the meniscus of the molten metal, which makes it possible to obtain thicker or thinner skins in relation to the time of contact with the first walls 5, 6 which is defined when controlling the casting device. This makes it possible to cast different thicknesses or special metals with different structural and chemical characteristics that require different casting speeds.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)

Abstract

La présente invention concerne un dispositif de coulée de brames minces qui consiste en un cristalliseur à deux parois mobiles courbes (5, 6) composées d'un matériau présentant une bonne conductivité thermique, refroidies et situées en regard du plan de coulée (Z), et deux parois latérales fixes (7, 8), perpendiculaires au premier matériau réfractaire de sorte à former une section transversale ayant une forme d'entonnoir.
EP17817121.1A 2016-11-18 2017-11-17 Dispositif de coulée continue pour brames minces Active EP3541548B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT102016000116859A IT201600116859A1 (it) 2016-11-18 2016-11-18 Dispositivo di colata continua per bramme sottili
PCT/IB2017/057226 WO2018092090A1 (fr) 2016-11-18 2017-11-17 Dispositif de coulée continue pour brames minces

Publications (2)

Publication Number Publication Date
EP3541548A1 true EP3541548A1 (fr) 2019-09-25
EP3541548B1 EP3541548B1 (fr) 2020-09-09

Family

ID=58266115

Family Applications (1)

Application Number Title Priority Date Filing Date
EP17817121.1A Active EP3541548B1 (fr) 2016-11-18 2017-11-17 Dispositif de coulée continue pour brames minces

Country Status (4)

Country Link
EP (1) EP3541548B1 (fr)
CN (1) CN110198795B (fr)
IT (1) IT201600116859A1 (fr)
WO (1) WO2018092090A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113231610B (zh) * 2021-04-30 2022-09-23 中冶赛迪工程技术股份有限公司 弧形振动薄带连铸方法及薄带连铸连轧生产线
CN114226458B (zh) * 2021-11-24 2023-05-16 吕梁学院 一种镁合金镁薄板滚压成型的合金熔炼设备

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT271765B (de) * 1965-11-15 1969-06-10 Continua Internat Continuous C Durchlaufkokille zum Stranggießen von Metallen, insbesondere in Form von Brammen, Platten, Blechen od.dgl.
JPS6021171A (ja) * 1983-07-16 1985-02-02 Nisshin Steel Co Ltd 幅広薄板連続鋳造装置
FR2645463B1 (fr) * 1989-04-06 1991-05-31 Techmetal Promotion Procede et installation de coulee de produits metalliques minces
CN1022739C (zh) * 1992-05-07 1993-11-17 冶金工业部钢铁研究总院 薄板坯连铸楔形结晶器
IT1262073B (it) * 1993-02-16 1996-06-19 Danieli Off Mecc Lingottiera per colata continua di bramme sottili
IT1267244B1 (it) * 1994-05-30 1997-01-28 Danieli Off Mecc Procedimento di colata continua per acciai ad alto contenuto di carbonio
EP0780176A3 (fr) * 1995-12-13 1999-05-06 Hitachi, Ltd. Dispositif et procédé pour la coulée continue
DE19728957A1 (de) * 1997-06-30 1999-01-07 Mannesmann Ag Verfahren und Vorrichtung zum Erzeugen von Dünnbrammen
IT1295512B1 (it) * 1997-10-14 1999-05-12 Danieli Off Mecc Cristallizzatore per colata continua di bramme sottili
DE19801822C1 (de) * 1998-01-15 1999-03-18 Mannesmann Ag Verfahren und Vorrichtung zum Stranggießen von Metallen
DE10057160A1 (de) * 2000-11-16 2002-05-29 Sms Demag Ag Verfahren und Vorrichtung zum Herstellen von Dünnbrammen
DE10226214A1 (de) * 2002-06-13 2003-12-24 Sms Demag Ag Stranggießkokille für flüssige Metalle, insbesondere für flüssigen Stahl
KR101620700B1 (ko) * 2014-07-24 2016-05-13 주식회사 포스코 쌍롤식 박판 주조 방법

Also Published As

Publication number Publication date
CN110198795B (zh) 2021-06-01
IT201600116859A1 (it) 2018-05-18
CN110198795A (zh) 2019-09-03
EP3541548B1 (fr) 2020-09-09
WO2018092090A1 (fr) 2018-05-24

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